CN105475332A - Insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor - Google Patents
Insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor Download PDFInfo
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- CN105475332A CN105475332A CN201510942092.XA CN201510942092A CN105475332A CN 105475332 A CN105475332 A CN 105475332A CN 201510942092 A CN201510942092 A CN 201510942092A CN 105475332 A CN105475332 A CN 105475332A
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- Prior art keywords
- fluorine pyridine
- worm amine
- pyridine worm
- pesticidal combination
- amine nitrile
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor. The insecticidal combination is characterized in that active components of the insecticidal combination are o-phenylendiamine insecticide A and sulfoxaflor, and the remaining are auxiliary components for preparing pesticide formulations. The weight part ratio of the active component o-phenylendiamine insecticide A to sulfoxaflor is (1-30):(30-1). The pesticide formulations capable of being prepared from the insecticidal combination comprise wettable powder, suspending agent, soluble liquid, emulsion in water and water dispersible granules. The total weight parts of the active components o-phenylendiamine insecticide A and sulfoxaflor in the pesticide formulations account for 5-40% the total weight parts of the formulations. The two effective active components o-phenylendiamine insecticide A and sulfoxaflor in the combination have an obvious synergistic effect, the insecticidal spectrum is expanded, the pesticide amount is reduced, the control effect is improved, residue is less, the duration is long, and the insecticidal combination is favorable for delaying pesticide resistance of pests and environmental protection.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile.
Background technology
The chemical structural formula of o-phenylenediamine insecticides A is as follows:
，
This insecticide is the new type disinsection immunomodulator compounds that Syngenta Co., Ltd announces, and disclosing its mechanism of action is at present ryanodine receptor agent, without more Experimental report or open, does not also have the site test in composite field open.
Fluorine pyridine worm amine nitrile (Sulfoxaflor), its chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide; Molecular formula: C
10h
10f
3n
3oS, structural formula is:
Fluorine pyridine worm amine nitrile is sulfimide insecticide, acts on binding site unique in choline receptor and plays insecticidal function.Can through leaf, stem, root absorption and entering in plant corpus.Fluorine pyridine worm amine nitrile is applicable to control cotton fleahopper, aphid, aleyrodid, plant hopper and coccid etc.; Efficiently, fast and the longevity of residure long, can effectively prevent and treat nicotinoids, chrysanthemum ester class, the suction juice class pest of organophosphate and carbamate pesticide generation resistance.There is the advantages such as rapid-action, strong drug action, consumption are low, in cotton and paddy rice market, there is extensive prospect.Although fluorine pyridine worm amine eyeball mechanism of action and anabasine insecticide similar, all act on the anabasine acceptor in insect bodies, Sulfoxaflor is the new class insecticide different with anabasine, has larger potential market.
The insecticide that Long-Time Service is single, insect is easy to develop immunity to drugs, and pesticide dosage is increased, and cause the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor, and effect field is more single.And research and develop the agricultural chemical compound that seems, then the R&D cycle is long, and screening compounds arrangement works is very numerous and diverse, and non-general research and development institution can bear.But the different mechanism of action and without the insecticide rational mixture by a certain percentage of cross resistance, crop disease prevention effect can be improved, reduce dosage, residual few, reduce environmental pollution, effectively reducing the pesticide resistance of crop, is the study hotspot of current medium and small research and development institution.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile; said composition contains o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile two kinds of effective active components, and can be prepared into the preparation being suitable for agricultural application, and this Pesticidal combination has notable synergistic effect; expand insecticidal spectrum; decrease pesticide volume, improve preventive effect, residual few; lasting period is long, and the pesticide resistance being conducive to delaying insect produces and environmental protection.
The application is a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile, its feature is that in this Pesticidal combination, active component is o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile, all the other are the auxiliary element of the preparation formulations of pesticide, and o-phenylenediamine insecticides A structural formula is as follows:
, wherein the ratio of weight and number of active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile is 1 ~ 30: 30 ~ 1.
In above-described Pesticidal combination, the ratio of weight and number of active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile is 5 ~ 20: 5 ~ 25.
The formulations of pesticide that above-described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
In the above formulations of pesticide, active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile total weight parts account for 5% ~ 40% of formulation total weight parts.
In the above formulations of pesticide, active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile total weight parts account for 8% ~ 27% of formulation total weight parts.
The application's Pesticidal combination may be used for preventing and treating paddy rice, cotton, wheat, fruit tree, insect on vegetables, may be used for preventing and treating Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gracilariidae, aphid section, Aleyrodidae, Cicadellidae, Delphacidae, Culculionidae, Chrysomelidae, Agromyzidae, Bemisia tabaci insect and nematode, acarid.Can effectively prevent and treat nicotinoids, chrysanthemum ester class, organophosphate and carbamate pesticide produces the suction juice class pest of resistance.
When the application's Pesticidal combination is prepared as wetting powder, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Fluorine pyridine worm amine nitrile 1 ~ 30 part
Dispersant 5 ~ 15 parts
Wetting agent 3 ~ 10 parts
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When the application's Pesticidal combination is prepared as suspending agent, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Fluorine pyridine worm amine nitrile 1 ~ 30 part
Dispersant 5 ~ 10 parts
Antifreezing agent 2 ~ 4 parts
Thickener 0.1 ~ 4 part
Defoamer 0.1 ~ 1 part
Water surplus.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination described in the application.
When the application's Pesticidal combination is prepared as aqueous emulsion, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Fluorine pyridine worm amine nitrile 1 ~ 30 part
Emulsifier 5 ~ 10 parts
Solvent 5 ~ 15 parts
Stabilizing agent 2 ~ 7 parts
Antifreezing agent 2 ~ 4 parts
Defoamer 0.1 ~ 8 part
Thickener 0.2 ~ 2 part
Water surplus.
The concrete production stage of this aqueous emulsion is: first former medicine o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.
When the application's Pesticidal combination is prepared as water dispersible granules, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Fluorine pyridine worm amine nitrile 1 ~ 30 part
Dispersant 4 ~ 12 parts
Wetting agent 3 ~ 8 parts
Disintegrant 2 ~ 8 parts
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: o-phenylenediamine insecticides, fluorine pyridine worm amine nitrile and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination.
Described emulsifier is selected from the mixture that calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether form.
Described solvent is methyl alcohol.
Described dispersant is selected from lignosulfonates.
Described wetting agent is selected from the one in lauryl sodium sulfate, spaonin powder.
Described disintegrant is selected from the one in bentonite, aluminium chloride.
Described thickener is selected from the one in xanthans, CMC, hydroxyethylcellulose, methylcellulose.
Described stabilizing agent is selected from the one in sodium citrate, resorcinol.
Described antifreezing agent is selected from the one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one in aliphatic alcohols compound.
Described filler is selected from the one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
In addition, the Pesticidal combination of the application compares similar medicament also has other obvious advantages a lot, the first, compares single dose sphere of action wider, can expand insecticidal spectrum; The second, greatly delay the generation of pest resistance to insecticide, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this Pesticidal combination is lower, more friendly to environment, is significant to the increasing both production and income of agricultural region.
Embodiment:
Clearly understand to make object of the present invention, technical scheme and advantage; the following specific embodiment of the present invention is described; following examples are the preferred embodiment of the application, do not represent only test example, and the application's protection domain is as the criterion with claims.
Indoor biometrics screening and field experiment:
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Determination of activity example:
(1) reagent agent
The former medicine of o-phenylenediamine insecticides A, Syngenta Co., Ltd, the former medicine of 98% fluorine pyridine worm amine nitrile.
(2) for examination worm source
Indoor diamondback moth larvae of for many generations raising, indoor conditions: temperature (26 ± 2)
oc, relative moisture 68% ± 5%, periodicity of illumination 16/8h (L/D).
(3) single dose assay method
Adopt dip method respectively two groups of former medicines all to be used a small amount of acetone solution, then be diluted to into the dense solution of 5 of equal difference with the Tween solution of 0.1%, be diluted in for subsequent use in beaker, and with clear water in contrast.
Diamondback moth larvae of the same size is flooded 5S in the liquid of leaching worm cage, and being placed on diameter after sucking unnecessary liquid is in the culture dish of 9cm, is placed with fresh vegetable leaf and adds a cover in ware.Every concentration process 10, repeats 4 times, if blank.Check lethality keep 24h in (27 ± 1) DEG C illumination box after, it is dead for touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to log concentration---lethality probit value analyzes (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
(4) the joint toxicity measuring method of different ratio
According to the toxicity test result of single dose, by active ingredient ratio of weight and number o-phenylenediamine insecticides A: fluorine pyridine worm amine nitrile is respectively 13:7,11:9,9:11,7:13,5:15.
Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press abundant method calculating co-toxicity coefficient (CTC) of Sun Yun.
(5) toxicity test result and analysis
Table 1 o-phenylenediamine insecticides A, fluorine pyridine worm amine nitrile are to the indoor measurement result of diamond-back moth
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein o-phenylenediamine insecticides A: synergistic effect when fluorine pyridine worm amine nitrile is 7: 13 is the most obvious, and co-toxicity coefficient is 173.25.Result of the test shows, fluorine pyridine worm amine nitrile, o-phenylenediamine insecticides A two kinds of medicaments all have higher activity to diamond-back moth in room conditions, the result of the test of different proportion proportioning shows, by active ingredient o-phenylenediamine insecticides A: when fluorine pyridine worm amine nitrile is 13:7,11:9,9:11,7:13,5:15, all show stronger synergistic effect, wherein with o-phenylenediamine insecticides A: when fluorine pyridine worm amine nitrile is 7: 13, synergistic effect is best.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 7:13 scope, to evaluate its field practical application effect.
Field experiment example: field experiment control beet armyworm test
(1) test method
Test and carry out in wild cabbage plantation, carry out routine to water spray by each process design concentration.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.During dispenser, field beet armyworm is 1 ~ 2 instar larvae peak period, every 667m
2be 70kg to the water yield.
Duration of test weather is good, and daily mean temperature is 18.5 ~ 27.9 DEG C.Dispenser fine day on the same day.
(2) investigation method
Diagonal 15 sampling is pressed, often some wild cabbage 2 ~ 3 strain (depending on insect density) choosing Beet Armyworm Eggs and larva in dispenser Qian Mei community.Beet exigua larvae head number in probability demarcation strain, in this, as insect population radix before dispenser.After dispenser the 3rd, 7,10d investigates the beet exigua larvae number determining residual survival in strain, respectively to correct Revision insect recluced rate as control efficiency.
(3) drug effect computational methods.
Revision insect recluced rate (%)=
× 100
Rectifying efficacies (%)=
× 100;
(4) poisoning investigation method
Duration of test observes each process community wild cabbage well-grown, all finds no poisoning phenomenon and occurs.
(5) field control effectiveness test result of the test
Table 2 treatment agent control Laphygma exigua Hubner field control effectiveness test result
As can be seen from Table 2, the successful of the mixture combination control Laphygma exigua Hubner of 7% o-phenylenediamine insecticides A+13% fluorine pyridine worm amine nitrile is better than 20% fluorine pyridine worm amine nitrile SC and contrasts single dose, 7% o-phenylenediamine insecticides A+13% fluorine pyridine worm amine nitrile insecticidal effect of 10 days after medicine is respectively 92.65%, 92.42% and 94.67%, insecticidal effect increases progressively along with the increase of consumption, estimate according to field, substantially disease is not had with 7% o-phenylenediamine insecticides A+13% fluorine pyridine worm amine nitrile wild cabbage, and growth fraction is more vigorous, and occur that disease is more with the wild cabbage of 20% fluorine pyridine worm amine nitrile SC single dose, the disease plant much about about 7% of ratio complex preparation.In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in each treatment agent, illustrates that it is safe to wild cabbage.
Claims (7)
1. one kind contains the Pesticidal combination of o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile, it is characterized in that: in this Pesticidal combination, active component is o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile, all the other are the auxiliary element of the preparation formulations of pesticide, and o-phenylenediamine insecticides A structural formula is as follows:
, wherein the ratio of weight and number of active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile is 1 ~ 30: 30 ~ 1.
2. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 1, is characterized in that: in described Pesticidal combination, the ratio of weight and number of active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile is 5 ~ 20: 5 ~ 25.
3. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 1 and 2, is characterized in that: the formulations of pesticide that described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
4. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 3, is characterized in that: in the formulations of pesticide, active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile total weight parts account for 5% ~ 40% of formulation total weight parts.
5. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 1 or 2 or 4, is characterized in that: in the formulations of pesticide, active component o-phenylenediamine insecticides A and fluorine pyridine worm amine nitrile total weight parts account for 8% ~ 27% of formulation total weight parts.
6. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 1 or 2 or 4, is characterized in that: this Pesticidal combination may be used for preventing and treating the insect on paddy rice, cotton, wheat, fruit tree, vegetables.
7. a kind of Pesticidal combination containing o-phenylenediamine insecticides and fluorine pyridine worm amine nitrile according to claim 6, is characterized in that: this Pesticidal combination may be used for preventing and treating Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gracilariidae, aphid section, Aleyrodidae, Cicadellidae, Delphacidae, Culculionidae, Chrysomelidae, Agromyzidae, Bemisia tabaci insect and nematode, acarid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510942092.XA CN105475332A (en) | 2015-12-16 | 2015-12-16 | Insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510942092.XA CN105475332A (en) | 2015-12-16 | 2015-12-16 | Insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor |
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| Publication Number | Publication Date |
|---|---|
| CN105475332A true CN105475332A (en) | 2016-04-13 |
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| CN201510942092.XA Withdrawn CN105475332A (en) | 2015-12-16 | 2015-12-16 | Insecticidal combination containing o-phenylendiamine insecticide and sulfoxaflor |
Country Status (1)
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006024523A1 (en) * | 2004-09-01 | 2006-03-09 | Syngenta Participation Ag | Phthalamide derivatives for use as insecticides |
| CN102458104A (en) * | 2009-04-28 | 2012-05-16 | 巴斯夫公司 | Pesticide compositions and applicators |
| CN104521995A (en) * | 2014-12-02 | 2015-04-22 | 广西安泰化工有限责任公司 | Tetra-flubendiamide-contained pesticidal composition and application thereof |
-
2015
- 2015-12-16 CN CN201510942092.XA patent/CN105475332A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006024523A1 (en) * | 2004-09-01 | 2006-03-09 | Syngenta Participation Ag | Phthalamide derivatives for use as insecticides |
| CN102458104A (en) * | 2009-04-28 | 2012-05-16 | 巴斯夫公司 | Pesticide compositions and applicators |
| CN104521995A (en) * | 2014-12-02 | 2015-04-22 | 广西安泰化工有限责任公司 | Tetra-flubendiamide-contained pesticidal composition and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 柴宝山等: "新型邻苯二甲酰胺类杀虫剂的研究进展", 《精细化工中间体》 * |
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Application publication date: 20160413 |