CN105462389A - Preparation method of organic-inorganic composite waterproof agent for exterior-wall gypsum building materials - Google Patents
Preparation method of organic-inorganic composite waterproof agent for exterior-wall gypsum building materials Download PDFInfo
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- CN105462389A CN105462389A CN201510824302.5A CN201510824302A CN105462389A CN 105462389 A CN105462389 A CN 105462389A CN 201510824302 A CN201510824302 A CN 201510824302A CN 105462389 A CN105462389 A CN 105462389A
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- gypsum
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a preparation method of an organic-inorganic composite waterproof agent for exterior-wall gypsum building materials. Main raw materials of the organic-inorganic composite waterproof agent comprise methyl methacrylate, silica nanoparticles, polyvinyl alcohol, dibutyl phthalate, ammonium persulfate and an emulsifier. The organic material and inorganic polymer compounded waterproof emulsion obtained by the formula and the preparation method has integrated characteristics of organic materials' good caking property, strong corrosion resistance and compact and waterproof coating and inorganic materials' ageing resistance, pollution resistance, high hardness of coating and the like. The product is especially applied in preparing of exterior-wall gypsum, can remarkably enhance waterproofness of gypsum products and even more can show excellent physical and mechanical properties.
Description
Technical field
The present invention relates to building materials of gypsum technical field, especially a kind of preparation method of the Organic-inorganic composite water-resisting agent for exterior wall building materials of gypsum.
Background technology
Gypsum belongs to air-setting material, is applicable to doing materials for wall, have raw material sources extensively, material produce energy consumption is low, the advantages such as processing performance is good.But plastering water resistance is very low, cause its in wet condition intensity sharply decline and creep properties increase, be limited on exterior wall and apply.In light gypsum building materials, 90% is all abscess, because capillary effect causes foamed gypsum water-intake rate more than 120%, there is the situations such as flexural deformation after making moist in plastering moisture absorption, causes soft, rotten of construction wall, causes the very serious even recurring structure of strength degradation to cave in; And after abscess is filled by free-water, thermal conductivity sharply rises, it is made to lose heat-insulating property.So although building materials of gypsum has plurality of advantages, the poor problem of its water tolerance seriously constrains its development, and therefore the water resistance research of gypsum building material has become important research direction in the industry.
At present, WATER REPELLENT is carried out mainly through following three kinds of modes: one is at gypsum surface coating or brushing water-proof material; But the method is after defect appears in coated surface or local, exposed gypsum by water-soluble erosion, reduces water resistance when running into water.Be in gypsum, add ground slag or pozzolanic materials on the other hand, improve the melded system of building block; But pozzolanic materials causes the whiteness of plastering to reduce, affect that it is ornamental, and easily cause deuterogenesis to ftracture.The third aspect is admixture water-latex type water-resisting agent in gypsum mainly, improves the water resistance of gypsum; Although the method can keep the decorative effect of gypsum block, can reach again the object of waterproof, in prior paraffin emulsion, acrylic emulsion use procedure, addition content is large, can have a negative impact to the intensity of gypsum.Although the intensity effect of organosilicon waterproof agent for building to gypsum is little, but the Methyl-CpG binding proteins in silicon-type water-resisting agent is water-soluble in a large number, not strong with base material binding ability, very easily run off along with the large quantity of moisture in plastering production process, and then cause the decline of gypsum water resistance.
Summary of the invention
The present invention is to solve for the deficiencies in the prior art, provide a kind of preparation method of the Organic-inorganic composite water-resisting agent for exterior wall building materials of gypsum, its weight composition and preparation method as follows:
Described emulsifying agent is the one in tween-80, Arlacel-80 or OP-10 emulsifying agent.
Nano SiO 2 particle is immersed in methyl methacrylate monomer, silica dioxide granule is fully infiltrated, stand-by.To in the polyvinyl alcohol dissolved, add the silica dioxide granule and polymethylmethacrylate that fully infiltrate, add ammonium persulphate after stirring, tween-80, be warming up to 70 DEG C, continue to stir and the 2h that refluxes, add ammonium persulphate and be warming up to 85 DEG C, stopping heating after half an hour, in time cooling to 50 DEG C, add dibutyl phthalate to stir, cool.
This law is bright by organic materials and the composite water-proof emulsion prepared of inorganic polymer, combines that organic materials cohesiveness is good, erosion resistance is strong, the fine and close waterproof of film and inorganic materials is ageing-resistant, anti-pollution, hardness of film high.Significantly can not only strengthen the water resistance of plastering, more can demonstrate excellent physical and mechanical property.
Embodiment
Embodiment one:
50.4g nano SiO 2 particle is immersed in 61.4g methyl methacrylate monomer, silica dioxide granule is fully infiltrated, stand-by.To in the 100.8g polyvinyl alcohol dissolved, the silica dioxide granule fully infiltrated before adding and polymethylmethacrylate, ammonium persulphate 11.2g and 5.6g Arlacel-80 is added after stirring, be warming up to 70 DEG C, continue to stir and the 2h that refluxes, again add ammonium persulphate 11.2g and be warming up to 85 DEG C, after half an hour, stop heating, in time cooling to 50 DEG C, add dibutyl phthalate 39.2g and stir until cool.
Embodiment two:
51.2g nano SiO 2 particle is immersed in 64g methyl methacrylate monomer, silica dioxide granule is fully infiltrated, stand-by.To in the 40g polyvinyl alcohol dissolved, the silica dioxide granule fully infiltrated before adding and polymethylmethacrylate, ammonium persulphate 9.6g is added after stirring, 9.6g emulsifier op-10, is warming up to 70 DEG C, continues to stir and the 2h that refluxes, again add ammonium persulphate 9.6g and be warming up to 85 DEG C, stop heating after half an hour, in time cooling to 50 DEG C, add dibutyl phthalate 48g and stir until cool.
Embodiment three:
64.8g nano SiO 2 particle is immersed in 75.6g methyl methacrylate monomer, silica dioxide granule is fully infiltrated, stand-by.To in the 122.4g polyvinyl alcohol dissolved, the silica dioxide granule fully infiltrated before adding and polymethylmethacrylate, ammonium persulphate 14.4g and 10.8g tween-80 is added after stirring, be warming up to 70 DEG C, continue to stir and the 2h that refluxes, again add ammonium persulphate 14.4g and be warming up to 85 DEG C, after half an hour, stop heating, in time cooling to 50 DEG C, add dibutyl phthalate 57.6g and stir until cool.
Claims (5)
1. a preparation method for the Organic-inorganic composite water-resisting agent of exterior wall building materials of gypsum, is characterized in that: standby in order to below legal system: be immersed in by nano SiO 2 particle in methyl methacrylate monomer, silica dioxide granule is fully infiltrated, stand-by; To in the polyvinyl alcohol dissolved, add the silica dioxide granule and polymethylmethacrylate that fully infiltrate, add ammonium persulphate after stirring, tween-80, be warming up to 70 DEG C, continue to stir and the 2h that refluxes, add ammonium persulphate and be warming up to 85 DEG C, stopping heating after half an hour, in time cooling to 50 DEG C, add dibutyl phthalate to stir, cool.
2. preparation method's method of the Organic-inorganic composite water-resisting agent of exterior wall building materials of gypsum according to claim 1, it is characterized in that: methyl methacrylate 18-25%, nano SiO 2 particle 15-20%, polyvinyl alcohol 36-48%, dibutyl phthalate 12-16%, ammonium persulphate 2-7%, 2-5% tween-80.
3. preparation method's method of the Organic-inorganic composite water-resisting agent of the exterior wall building materials of gypsum according to claim 1 and 2, is characterized in that: the particle diameter of nano SiO 2 particle is between 60-80 nanometer.
4. preparation method's method of the Organic-inorganic composite water-resisting agent of the exterior wall building materials of gypsum according to claim 1 and 2, is characterized in that: described emulsifying agent is the one in tween-80, Arlacel-80 or OP-10 emulsifying agent.
5. preparation method's method of the Organic-inorganic composite water-resisting agent of the exterior wall building materials of gypsum according to claim 1 and 2, is characterized in that: the stirring velocity in described step is 2500r/min, and described heat-up rate is 10 DEG C/min.
Priority Applications (1)
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CN201510824302.5A CN105462389A (en) | 2015-11-24 | 2015-11-24 | Preparation method of organic-inorganic composite waterproof agent for exterior-wall gypsum building materials |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106186801A (en) * | 2016-07-19 | 2016-12-07 | 仇颖莹 | A kind of preparation method of composite modified waterproofing gypsum agent |
CN108424487A (en) * | 2018-02-27 | 2018-08-21 | 盐城普菲特新材料科技有限公司 | A kind of organic-silicon-modified emulsion water-proof agent of desulfurated plaster and preparation method thereof |
CN111535075A (en) * | 2020-05-18 | 2020-08-14 | 杭州西红柿环保科技有限公司 | Full-degradable fluoride-free paper pulp molding seedling cup and preparation method thereof |
CN112832524A (en) * | 2021-03-15 | 2021-05-25 | 福建筑兆建设有限公司 | Dry construction method for masonry |
CN114561135A (en) * | 2022-04-25 | 2022-05-31 | 北京悦筑新天节能科技有限公司 | Composite emulsion and preparation method and application thereof |
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CN1218081A (en) * | 1998-10-29 | 1999-06-02 | 化学工业部星火化工厂 | Organic silicone waterproofing agent and application thereof |
CN1534075A (en) * | 2003-03-31 | 2004-10-06 | 刘国斌 | Compositie water proofing agent used for building waterproof |
CN101050350A (en) * | 2007-04-20 | 2007-10-10 | 济南大学 | Composite waterproofing agent of gypsum |
CN101891411A (en) * | 2009-05-19 | 2010-11-24 | 北京建筑材料科学研究总院有限公司 | Waterproofing gypsum agent preparation method |
CN104829161A (en) * | 2015-04-02 | 2015-08-12 | 安徽建筑大学 | Novel waterproof agent for building gypsum, and preparation method thereof |
-
2015
- 2015-11-24 CN CN201510824302.5A patent/CN105462389A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1218081A (en) * | 1998-10-29 | 1999-06-02 | 化学工业部星火化工厂 | Organic silicone waterproofing agent and application thereof |
CN1534075A (en) * | 2003-03-31 | 2004-10-06 | 刘国斌 | Compositie water proofing agent used for building waterproof |
CN101050350A (en) * | 2007-04-20 | 2007-10-10 | 济南大学 | Composite waterproofing agent of gypsum |
CN101891411A (en) * | 2009-05-19 | 2010-11-24 | 北京建筑材料科学研究总院有限公司 | Waterproofing gypsum agent preparation method |
CN104829161A (en) * | 2015-04-02 | 2015-08-12 | 安徽建筑大学 | Novel waterproof agent for building gypsum, and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106186801A (en) * | 2016-07-19 | 2016-12-07 | 仇颖莹 | A kind of preparation method of composite modified waterproofing gypsum agent |
CN108424487A (en) * | 2018-02-27 | 2018-08-21 | 盐城普菲特新材料科技有限公司 | A kind of organic-silicon-modified emulsion water-proof agent of desulfurated plaster and preparation method thereof |
CN111535075A (en) * | 2020-05-18 | 2020-08-14 | 杭州西红柿环保科技有限公司 | Full-degradable fluoride-free paper pulp molding seedling cup and preparation method thereof |
CN112832524A (en) * | 2021-03-15 | 2021-05-25 | 福建筑兆建设有限公司 | Dry construction method for masonry |
CN114561135A (en) * | 2022-04-25 | 2022-05-31 | 北京悦筑新天节能科技有限公司 | Composite emulsion and preparation method and application thereof |
CN114561135B (en) * | 2022-04-25 | 2022-07-26 | 北京悦筑新天节能科技有限公司 | Composite emulsion and preparation method and application thereof |
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Application publication date: 20160406 |