CN105452210B - 制备丙烯醛的方法 - Google Patents

制备丙烯醛的方法 Download PDF

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Publication number
CN105452210B
CN105452210B CN201480031746.7A CN201480031746A CN105452210B CN 105452210 B CN105452210 B CN 105452210B CN 201480031746 A CN201480031746 A CN 201480031746A CN 105452210 B CN105452210 B CN 105452210B
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CN
China
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weight ppm
reaction gas
sulphur
reaction
reaction tube
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Expired - Fee Related
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CN201480031746.7A
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English (en)
Chinese (zh)
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CN105452210A (zh
Inventor
M·斯特凡
H·米勒
P·罗特
C·韦克贝克
H·雅各布
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Evonik Operations GmbH
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Evonik Degussa GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480031746.7A 2013-06-03 2014-05-23 制备丙烯醛的方法 Expired - Fee Related CN105452210B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361830459P 2013-06-03 2013-06-03
US61/830,459 2013-06-03
EP13170210 2013-06-03
EP13170210.2 2013-06-03
PCT/EP2014/060717 WO2014195157A1 (de) 2013-06-03 2014-05-23 Verfahren zur herstellung von acrolein

Publications (2)

Publication Number Publication Date
CN105452210A CN105452210A (zh) 2016-03-30
CN105452210B true CN105452210B (zh) 2018-11-20

Family

ID=48536735

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480031746.7A Expired - Fee Related CN105452210B (zh) 2013-06-03 2014-05-23 制备丙烯醛的方法

Country Status (6)

Country Link
US (1) US9822051B2 (enExample)
EP (1) EP3004041B1 (enExample)
JP (1) JP2016520630A (enExample)
CN (1) CN105452210B (enExample)
SG (1) SG11201509776VA (enExample)
WO (1) WO2014195157A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3120926A1 (de) * 2015-07-20 2017-01-25 Evonik Degussa GmbH Verfahren zur herstellung von mischoxidkatalysatoren
US11078147B2 (en) 2018-03-21 2021-08-03 Rohm And Haas Company Method for preparing acrolein
BR112020016752A2 (pt) 2018-03-21 2020-12-15 Rohm And Haas Company Processo para preparar ácido acrílico.
CN113926467B (zh) * 2020-06-29 2024-05-28 中国石油化工股份有限公司 一种不饱和醛催化剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3009960A (en) * 1958-10-03 1961-11-21 Cities Service Res & Dev Co Oxidation of olefins to unsaturated aldehydes
CN1235953A (zh) * 1998-05-18 1999-11-24 株式会社日本触媒 制备丙烯醛和丙烯酸的方法
CN1438986A (zh) * 2000-06-28 2003-08-27 巴斯福股份公司 丙烯的加氢甲酰基化产物的制备以及丙烯酸和/或丙烯醛的制备
CN101400639A (zh) * 2006-02-07 2009-04-01 阿肯马法国公司 丙烯酸的制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19627850A1 (de) * 1996-07-10 1998-01-15 Basf Ag Verfahren zur Herstellung von Acrylsäure und Methacrylsäure
JP3959202B2 (ja) * 1998-05-18 2007-08-15 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
DE10028582A1 (de) * 2000-06-14 2001-12-20 Basf Ag Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan
JP2002322116A (ja) * 2001-04-25 2002-11-08 Nippon Shokubai Co Ltd （メタ）アクリル酸の製造方法
DE102004038053A1 (de) 2004-08-05 2006-04-27 Degussa Ag Verfahren zur Herstellung von 3-(Methylthio)propanal
DE102005003990A1 (de) 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
DE102006015710A1 (de) 2005-10-14 2007-04-26 Degussa Gmbh Mischoxidationskatalysatoren für die katalytische Gasphasenoxidation von Olefinen und Verfahren zu ihrer Herstellung
CN101164694A (zh) 2006-10-20 2008-04-23 德古萨股份公司 用于催化气相氧化的混合氧化物催化剂
DE102006054519A1 (de) 2006-11-20 2008-05-21 Evonik Degussa Gmbh Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden
DE102007004350A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
DE102007004351A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
EP2641898A1 (de) 2012-03-20 2013-09-25 Evonik Industries AG Verfahren zur Herstellung von Methionin

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3009960A (en) * 1958-10-03 1961-11-21 Cities Service Res & Dev Co Oxidation of olefins to unsaturated aldehydes
CN1235953A (zh) * 1998-05-18 1999-11-24 株式会社日本触媒 制备丙烯醛和丙烯酸的方法
CN1438986A (zh) * 2000-06-28 2003-08-27 巴斯福股份公司 丙烯的加氢甲酰基化产物的制备以及丙烯酸和/或丙烯醛的制备
CN101400639A (zh) * 2006-02-07 2009-04-01 阿肯马法国公司 丙烯酸的制备方法

Also Published As

Publication number Publication date
CN105452210A (zh) 2016-03-30
WO2014195157A1 (de) 2014-12-11
US9822051B2 (en) 2017-11-21
EP3004041A1 (de) 2016-04-13
JP2016520630A (ja) 2016-07-14
SG11201509776VA (en) 2015-12-30
US20160107968A1 (en) 2016-04-21
EP3004041B1 (de) 2020-05-06

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Address after: Essen, Germany

Patentee after: Evonik Operations Ltd.

Address before: Essen, Germany

Patentee before: EVONIK DEGUSSA GmbH

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20181120