CN105449000A - Double-active layer Cu2O/SnOp channel thin film transistor and preparation method thereof - Google Patents

Double-active layer Cu2O/SnOp channel thin film transistor and preparation method thereof Download PDF

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Publication number
CN105449000A
CN105449000A CN201510974464.7A CN201510974464A CN105449000A CN 105449000 A CN105449000 A CN 105449000A CN 201510974464 A CN201510974464 A CN 201510974464A CN 105449000 A CN105449000 A CN 105449000A
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active layer
semiconductor active
film
snop
film transistor
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赵高位
刘玉荣
廖荣
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South China University of Technology SCUT
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South China University of Technology SCUT
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78681Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising AIIIBV or AIIBVI or AIVBVI semiconductor materials, or Se or Te
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)

Abstract

The invention belongs to the technical field of semiconductors, and discloses a double-active layer Cu2O/SnOp channel thin film transistor and a preparation method thereof. The thin film transistor comprises a substrate, a grid electrode, a grid insulating medium layer, a first semiconductor active layer, a second semiconductor active layer, a source electrode and a drain electrode from bottom to top, wherein the first semiconductor active layer is a p-type SnO semiconductor active layer and the second semiconductor active layer is a Cu2O semiconductor active layer. According to the p-type SnO semiconductor active layer, oxygen vacancy is imported to properly optimize the valence band structure, so that the hole migration rate is improved; and through depositing a layer of Cu2O membrane on the SnO active layer, the surface leakage current is decreased, the switch current ratio is improved, the influences on the SnO layer from the external oxygen and water are decreased and the device stability is improved.

Description

A kind of two active layer Cu 2o/SnO p channel thin-film transistor and preparation method thereof
Technical field
The present invention relates to technical field of semiconductors, particularly a kind of two active layer structure Cu 2o/SnOp channel thin-film transistor and preparation method thereof.
Background technology
In recent years, the flat panel display being representative with active matrix liquid crystal display (AM-LCD) and active matrix organic light emitting diode display (AMOLED) obtains development at a high speed.The Primary Component that thin-film transistor (TFT) drives as active flat panel display, plays an important role to the display effect of flat-panel monitor.Thin-film transistor mainly comprises silica-based TFT, organic tft and oxide TFT, wherein amorphous silicon film transistor (a-SiTFT) and polycrystalline SiTFT (p-SiTFT) are because of technique relative maturity, good stability, be widely used in flat-panel monitor, remain the TFT technology of main flow at present.
In recent years, based on the TFT of metal-oxide semiconductor (MOS) because having the advantages such as relatively high carrier mobility, high light transmission, low temperature process, be expected to become follow-on main flow TFT technology.Along with improving constantly of oxide TFT electrical property, its range of application is not only at the active matrix driving of flat-panel monitor, be expected to the peripheral driving circuit that alternative si-substrate integrated circuit serves as display, realize fully integratedization flat panel display, and be applied to the fields such as Intelligent Sensorsystem, Intelligent Recognition card, wearable electronic system.Realize these application demands, adopt a kind of complementary type integrated device simultaneously comprising n and p channel TFT device to be optimal selection.But the oxide semiconductor material be applied at present in TFT is mostly N-shaped conduction type, as ZnO, In 2o 3, SnO 2and doping oxide, but due to the compensating action of its intrinsic defect, these oxides are difficult to form p-type electric-conducting type, are thus difficult to realize p channel TFT device.Therefore, the research and development based on p channel metal-oxide TFT device are most important.Research finds, Cu 2the metal-oxide film materials such as O, CuO, SnO have p-type semiconductor characteristic, and utilize these materials to serve as semiconductor active layer successfully to prepare p channel TFT device.At present, based on Cu 2the problems such as the research of the p ditch TFT device of the metal oxides such as O, SnO has obtained certain progress, but this kind of device ubiquity hole mobility is low, and tracking current is large, and off-state current is large, and hole concentration is high.
Summary of the invention
In order to overcome the above-mentioned shortcoming of prior art with not enough, the object of the present invention is to provide a kind of two active layer structure Cu 2o/SnOp channel thin-film transistor, can improve hole mobility effectively, reduces tracking current, thus reduces off-state current, improves switch current ratio, reduces the impact of water and oxygen in environment, improves the stability of device.
Another object of the present invention is to provide above-mentioned Cu 2the preparation method of the two active layer structure p channel thin-film transistor of O/SnO.
Object of the present invention is achieved through the following technical solutions:
The Cu of a kind of pair of active layer structure 2o/SnOp channel thin-film transistor, comprises substrate, grid, gate insulation dielectric layer, the first semiconductor active layer, the second semiconductor active layer, source electrode and drain electrode from the bottom to top successively.
Described first semiconductor active layer is p-type SnO semiconductor active layer, and its thickness is 10 ~ 30nm; Described second semiconductor active layer is Cu 2o semiconductor active layer, its thickness is 20 ~ 30nm.
Described grid part covers substrate, and described gate insulation dielectric layer segments cover gate, the complete covering gate insulating medium layer of described first semiconductor active layer, described second semiconductor active layer covers the first semiconductor active layer completely.
Described source electrode and drain electrode are oppositely arranged.
Described gate insulation dielectric layer is HfO 2/ Al 2o 3bilayer film or AlN film, its thickness is 50 ~ 300nm.
Described source electrode, drain electrode are Pt/Ni double-layer metal film or Au/Ni double-layer metal film, when described source electrode, drain electrode are for Pt/Ni double-layer metal film, and the thickness of Ni: 30 ~ 50nm, the thickness of Pt: 50 ~ 150nm.The thickness of described source electrode, drain electrode is 80 ~ 200nm.Described Ni layer is near the second semiconductor active layer.
Described grid material is the one in Pt, Au, Mo, ITO conductive film, and the thickness of grid is 100 ~ 200nm.
Described substrate is plastics or glass.
The Cu of described pair of active layer structure 2the preparation method of O/SnOp channel thin-film transistor, comprising:
(1) growing metal conductive film in substrate, is then etched into grid;
(2) on grid, deposit insulation film, form gate insulation dielectric layer; Described insulation film is HfO 2/ Al 2o 3bilayer film or AlN film;
(3) on gate insulation dielectric layer, deposited semiconductor film forms the first semiconductor active layer; Described first semiconductor active layer is p-type SnO semiconductor active layer;
(4) on the first semiconductor active layer, deposited semiconductor film forms the second semiconductor active layer, and the second semiconductor active layer is Cu 2o semiconductor active layer;
(5) depositing electrically conductive film on the second semiconductor active layer, photoetching forms source electrode and drain electrode; Described conductive film is Pt/Ni bilayer film or Au/Ni bilayer film;
(6) in atmosphere in 150 DEG C ~ 200 DEG C annealing in process.
The invention has the beneficial effects as follows:
(1) the p-type SnO semiconductor active layer prepared, introducing Lacking oxygen defect suitably can optimize valence band structure, thus improves the mobility in hole;
(2) by depositing one deck Cu on SnO active layer 2o film, reduces tracking current, improves switch current ratio, decreases external oxygen and water to the impact of SnO layer, improves the stability of device;
(3) preparation temperature is lower, easily realizes the flexibility of display device; Preparation technology and n tunnel oxide TFT compatibility, easily realize the cmos device based on sull, thus be conducive to expanding its range of application.
Accompanying drawing explanation
Fig. 1 (a) and Fig. 1 (b) is respectively a kind of two active layer Cu of the present invention 2the profile of the device architecture of one example of O/SnOp channel thin-film transistor and vertical view;
Fig. 2 (a) ~ (e) sequentially show the main technological steps of a manufacture method of thin-film transistor of the present invention, wherein:
Fig. 2 (a) illustrates the processing step that grid is formed;
Fig. 2 (b) illustrates the processing step of gate insulation dielectric layer growth;
Fig. 2 (c) illustrates the processing step of ground floor tin oxide semiconductor active layer growth;
Fig. 2 (d) illustrates the processing step of second layer cuprous oxide semiconductor active layer growth;
Fig. 2 (e) illustrates source, drain regions deposit and patterned processing step.
Embodiment
Below in conjunction with specific embodiments and the drawings, the present invention is described in further detail, but the substrate of embodiments of the present invention and adaptation is not limited thereto.
Embodiment
The Cu of two active layer structure of the present embodiment 2o/SnOp channel thin-film transistor comprises substrate (1), grid (2), gate insulation dielectric layer (3), p-type SnO semiconductor active layer (4), Cu from the bottom to top successively 2o semiconductor active layer (5), source electrode and drain electrode (6); Its structural representation as shown in Figure 1.
Described grid part covers substrate, described gate insulation dielectric layer segments cover gate, the complete covering gate insulating medium layer of described p-type SnO semiconductor active layer, described Cu 2the complete blanket p-type SnO semiconductor active layer of O semiconductor active layer.
Described source electrode and the opposing parallel setting of drain electrode.
The embodiment of the present invention also proposed above-mentioned Cu 2the preparation method of O/SnOp channel thin-film transistor, comprising:
1, substrate is made: the substrate of the present embodiment is plastics (as PET) substrate or glass substrate;
2, grid is prepared on the substrate: adopt magnetically controlled sputter method to prepare 100 ~ 200nmITO film, form grid by photoetching, as shown in Fig. 2 (a);
3, on grid, HfO is prepared 2/ Al 2o 3or AlN gate insulation dielectric layer:
Magnetron sputtering method is adopted to prepare HfO 2/ Al 2o 3or AlN gate insulation dielectric layer, for HfO 2/ Al 2o 3gate insulation dielectric layer, successively with Al 2o 3and HfO 2for target, pass into a certain amount of argon gas and oxygen in sputter procedure, form two insulating medium layer, the thickness of every one deck is regulated and controled by sputtering power and sputtering time; For AlN gate insulation dielectric layer, employing Al is target, passes into a certain amount of argon gas and nitrogen in sputter procedure, and its thickness is regulated and controled by sputtering power and sputtering time; In the present embodiment, described gate insulation thickness of dielectric layers is 50 ~ 200nm; As shown in Fig. 2 (b);
4, at described HfO 2/ Al 2o 3or AlN gate insulation dielectric layer prepares p-type SnO semiconductor active layer:
Adopt magnetron sputtering method at described HfO 2/ Al 2o 3the p-type SnO semiconductor active layer that one deck 10 ~ 20nm is thick prepared by the gate insulation dielectric layer of bilayer film or AlN film, as shown in Fig. 2 (c); Employing Sn is target, by regulating suitable argon gas and oxygen flow ratio, makes to there is appropriate Sn interstitial atom and O room in the SnO active layer film of deposition;
5, on described p-type SnO semiconductor active layer, one deck Cu is prepared 2o semiconductor active layer:
In the present embodiment, magnetron sputtering method is adopted, with Cu 2o is target, by regulating suitable argon flow amount, and the Cu that sputtering sedimentation one deck 20 ~ 30nm is thick on described p-type SnO semiconductor active layer 2o semiconductor active layer, as shown in Fig. 2 (d);
6, source electrode and drain electrode is prepared:
In the present embodiment, at described Cu 2o semiconductor active layer adopts magnetron sputtering method prepare the Pt/Ni metallic film of 100 ~ 200nm, wherein Ni thickness is 30 ~ 50nm, Pt thickness is that 50 ~ 150nm, Ni layer is near Cu 2o layer, and form source, drain electrode, as shown in Fig. 2 (e) by photoetching;
7, anneal:
In the present embodiment, by described Cu 2o/SnOp channel thin-film transistor is put in atmosphere, 150 DEG C ~ 200 DEG C annealing 30min.
The Cu proposed in embodiments of the present invention 2o/SnOp channel thin-film transistor and preparation method thereof has the following advantages: the SnO semiconductor active layer containing O room prepared by (1), and the defect of formation changes valence band structure, thus effectively improves the mobility in hole; (2) on SnO semiconductor active layer, one deck Cu is deposited 2o film, reduces tracking current, improves switch current ratio, decreases external oxygen and water to the impact of SnO layer, improves device stability; (3) preparation temperature is low, easily realizes the flexibility of active display; Preparation technology and n tunnel oxide TFT compatibility, easily realize the cmos device based on sull, thus be conducive to expanding its range of application.。
Above-mentioned concrete execution mode is detailed description made for the present invention, is the present invention's preferably execution mode, but does not assert that specific embodiment of the invention is only limited to this explanation.To the technical field of the invention, without departing from the inventive concept of the premise, the change done, replaces, and combination etc. are the substitute mode of equivalence, are included within protection scope of the present invention.

Claims (8)

1. the Cu of a two active layer structure 2o/SnOp channel thin-film transistor, is characterized in that: comprise substrate, grid, gate insulation dielectric layer, the first semiconductor active layer, the second semiconductor active layer, source electrode and drain electrode from the bottom to top successively; Described first semiconductor active layer is p-type SnO semiconductor active layer; Described second semiconductor active layer is Cu 2o semiconductor active layer.
2. the Cu of two active layer structure according to claim 1 2o/SnOp channel thin-film transistor, is characterized in that: the thickness of described first semiconductor active layer is 10 ~ 30nm; The thickness of described second semiconductor active layer is 20 ~ 30nm.
3. the Cu of two active layer structure according to claim 1 2o/SnOp channel thin-film transistor, is characterized in that: described gate insulation dielectric layer is HfO 2/ Al 2o 3bilayer film or AlN film, the thickness of described gate insulation dielectric layer is 50 ~ 300nm.
4. the Cu of two active layer structure according to claim 1 2o/SnOp channel thin-film transistor, is characterized in that: described source electrode, drain electrode are Pt/Ni double-layer metal film or Au/Ni double-layer metal film; The thickness of described source electrode, drain electrode is 80 ~ 200nm.
5. the Cu of two active layer structure according to claim 4 2o/SnOp channel thin-film transistor, is characterized in that: when described source electrode, drain electrode are for Pt/Ni double-layer metal film, the thickness of Ni film: 30 ~ 50nm, the thickness of Pt film: 50 ~ 150nm.
6. the Cu of two active layer structure according to claim 1 2o/SnOp channel thin-film transistor, it is characterized in that: described grid part covers substrate, described gate insulation dielectric layer segments cover gate, the complete covering gate insulating medium layer of described first semiconductor active layer, described second semiconductor active layer covers the first semiconductor active layer completely.
7. the Cu of two active layer structure according to claim 1 2o/SnOp channel thin-film transistor, is characterized in that: described grid material is the one in Pt, Au, Mo, ITO conductive film, and the thickness of described grid is 100 ~ 200nm;
Described substrate is plastics or glass.
8. the Cu of two active layer structure according to any one of claim 1 ~ 7 2the preparation method of O/SnOp channel thin-film transistor, is characterized in that comprising the steps:
(1) growing metal conductive film in substrate, is then etched into grid;
(2) on grid, deposit insulation film, form gate insulation dielectric layer; Described insulation film is HfO 2/ Al 2o 3bilayer film or AlN film;
(3) on gate insulation dielectric layer, deposited semiconductor film forms the first semiconductor active layer; Described first semiconductor active layer is p-type SnO semiconductor active layer;
(4) on the first semiconductor active layer, deposited semiconductor film forms the second semiconductor active layer, and the second semiconductor active layer is Cu 2o semiconductor active layer;
(5) depositing electrically conductive film on the second semiconductor active layer, photoetching forms source electrode and drain electrode; Described conductive film is Pt/Ni bilayer film or Au/Ni bilayer film;
(6) in atmosphere in 150 DEG C ~ 200 DEG C annealing in process.
CN201510974464.7A 2015-12-21 2015-12-21 Double-active layer Cu2O/SnOp channel thin film transistor and preparation method thereof Pending CN105449000A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107204284A (en) * 2017-05-09 2017-09-26 西北大学 The method that cuprous oxide semiconductor conductivity types are controlled based on deposition potential
CN108011042A (en) * 2017-06-17 2018-05-08 电子科技大学 Double-deck active layer thin film transistor (TFT) and preparation method
CN110739221A (en) * 2019-10-23 2020-01-31 昆明物理研究所 Preparation method of tin oxide film with adjustable band gap

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102254950A (en) * 2011-07-12 2011-11-23 北京大学深圳研究生院 Cuprous oxide thin film transistor and preparing method thereof
CN102263134A (en) * 2011-07-22 2011-11-30 北京大学深圳研究生院 Bipolar thin film transistor and preparation method thereof
CN205335261U (en) * 2015-12-21 2016-06-22 华南理工大学 Two active layer cu2OSnO p channel thin film transistor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102254950A (en) * 2011-07-12 2011-11-23 北京大学深圳研究生院 Cuprous oxide thin film transistor and preparing method thereof
CN102263134A (en) * 2011-07-22 2011-11-30 北京大学深圳研究生院 Bipolar thin film transistor and preparation method thereof
CN205335261U (en) * 2015-12-21 2016-06-22 华南理工大学 Two active layer cu2OSnO p channel thin film transistor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
H.A.AI-JAWHARI ETC: "Tunable Performance of P-Type Cu2O/SnO Bilayer Thin Film Transistors", 《ADVANCES IN SCIENCE AND TECHNOLOGY》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107204284A (en) * 2017-05-09 2017-09-26 西北大学 The method that cuprous oxide semiconductor conductivity types are controlled based on deposition potential
CN108011042A (en) * 2017-06-17 2018-05-08 电子科技大学 Double-deck active layer thin film transistor (TFT) and preparation method
CN110739221A (en) * 2019-10-23 2020-01-31 昆明物理研究所 Preparation method of tin oxide film with adjustable band gap

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Application publication date: 20160330