CN105421075A - Deodorizing care agent used for fabrics and preparation method thereof - Google Patents

Deodorizing care agent used for fabrics and preparation method thereof Download PDF

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Publication number
CN105421075A
CN105421075A CN201510991376.8A CN201510991376A CN105421075A CN 105421075 A CN105421075 A CN 105421075A CN 201510991376 A CN201510991376 A CN 201510991376A CN 105421075 A CN105421075 A CN 105421075A
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China
Prior art keywords
care agent
peculiar smell
spends
parts
solution
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Pending
Application number
CN201510991376.8A
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Chinese (zh)
Inventor
葛乃君
陈红霞
陆鹏
丁可敬
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Jiangsu Goldsun Textile Science and Technology Co Ltd
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Jiangsu Goldsun Textile Science and Technology Co Ltd
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Priority to CN201510991376.8A priority Critical patent/CN105421075A/en
Publication of CN105421075A publication Critical patent/CN105421075A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a deodorizing care agent used for fabrics and a preparation method thereof. The deodorizing care agent includes: nonylphenol polyoxyethylene ether, undecylenic acid glyceride, distearate, a softener and water. The preparation method comprises the following steps: adding the undecylenic acid glyceride to the nonylphenol polyoxyethylene ether with stirring, adding 1/2 parts by weight of the deionized water with stirring, adding the softener, regulating the pH value of the solution to 7.0-7.5; adding the distearate to the other 1/2 parts by weight of the deionized water, and mixing the two solutions with stirring, and defoaming the solution. The deodorizing cares the fabrics to enable the fabric to be soft and smooth and also can effectively eliminate and inhibit odors after fabric care is finished.

Description

A kind of fabric spends peculiar smell care agent and preparation method thereof
Technical field
The invention belongs to household chemicals technical field, be specifically related to a kind of fabric and spend peculiar smell care agent and preparation method thereof.
Background technology
Environmental odors is one of problem of puzzlement people always, especially foreign flavor indoors.The indoor main place as mankind's activity, keeps with fresh air, particularly important.Generally, the speed of growing of normal person bacterium is comparatively slow, can not produce obvious peculiar smell.But research shows with age, the especially male sex, according to individual physique difference, all can produce and certain add age smelly (main component is unsaturated aldehyde).Among body odor, as mainly the stink recognized by the elderly, namely so-called " adding age smelly " is profoundly relevant to the unsaturated aldehyde of octenal, nonenyl aldehyde etc.The palmitoleic acid (palmitoleic acid) increased in the sebum of person in middle and old age's layer in age is by the oxidation Decomposition of being undertaken by lipid peroxide or reside bacterium by skin and decompose, and can produce the nonenyl aldehyde as odorant, uncomfortable sensation is made us in generation.In addition for the crowd that physique is poor, in its metabolic thing or secretion, contain a large amount of pathogens, can severe contamination air.At present for bed body smell solution, general is all adopt the methods such as fragrance is covered, antibiotic and sterilizing to process the textiles more with human contact, clothing etc., on the one hand, disinfectant, antiseptic are large to textiles damage, increase and decreased effectiveness with washing times; On the other hand, fragrance is covered and is not suitable for all environment and crowd, and is not suitable for Long-Time Service.So for the weaving face fabric high with mankind's activity participation, be badly in need of a kind of environmental protection, easy to use and effective peculiar smell minimizing technology.
Summary of the invention
The object of the invention is overcome the deficiencies in the prior art and provide a kind of fabric to spend peculiar smell care agent and preparation method thereof, this care agent effectively can not only be eliminated bed body smell and suppress the generation of bed body smell, also clothing is had to the effect of soft nursing simultaneously.
A kind of fabric spends peculiar smell care agent, comprises: polyoxyethylene nonylphenol ether 1 ~ 5 part, endecatylene acid glyceride 2 ~ 10 parts, distearate 0.5 ~ 3 part, softener 0.5 ~ 3 part, 20 ~ 50 parts, water with weight parts.
Further, described care agent also comprises 0.1 ~ 0.3 part of essence with parts by weight.
Further, described softener is anionic softener or nonionic silicone oil softener.
Further, described care agent also comprises 0.2 ~ 1 part of sodium chloride with parts by weight.
Described fabric spends the preparation method of peculiar smell care agent, comprises the following steps:
Step 1, is added in polyoxyethylene nonylphenol ether by endecatylene acid glyceride, stirs, adds 1/2 parts by weight of deionized water, stirs, obtains solution A;
Step 2, softener adds in step 1 gained solution A, and adjust ph, to 7.0-7.5, obtains solution B;
Step 3, adds to distearate in residuals weight part deionized water, obtains solution C;
Step 4, mixes solution B with solution C, stirs, after froth breaking and get final product.
Further, the concrete steps of step 3 be in deionized water distearate being added to 40-60 DEG C insulated and stirred to dissolving, then cooling naturally under stirring.
Further, also sodium chloride can be added in step 2.
Effect of going peculiar smell care agent to have submissive nursing fabric of the present invention, and effectively can eliminate peculiar smell and suppress the generation of peculiar smell after completing fabric nursing.
Detailed description of the invention
Below by detailed description of the invention, the present invention is described in further detail.But it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting scope of the present invention.Unreceipted concrete technology or condition person in embodiment, according to the technology described by the document in this area or condition (" dyeing and finishing technology and principle " that such as reference Zhao Tao writes, China Textiles Press, 2009; " fabric construction and the design " of Shen Lanping work, China Textiles Press, 2005) or carry out according to product description.Agents useful for same or the unreceipted production firm person of instrument, being can by the conventional products of commercial acquisition.
Fabric of the present invention spends peculiar smell care agent and comprises polyoxyethylene nonylphenol ether, endecatylene acid glyceride, distearate, softener.
Endecatylene acid glyceride derives from pure plant, can be antimycotic, is a kind of grease with antiseptic property, and can effectively eliminates peculiar smell in environment, such as ammonia, acids, aldehydes smell.Polyoxyethylene nonylphenol ether has excellent emulsifying capacity, plays W/O effect in body series.Distearate has thickening, emulsification, controls viscosity, and thickening effect is good, makes care agent have good finishing effect.Softener can make face liber submissive, possesses nursing efficacy, can also reduce fibre damage in arrangement process simultaneously, protection fiber strength.Sodium chloride can thickening, thus improves the ability of aggregation of ionic surface active agent.
Endecatylene acid glyceride is water-fast ester type compound, and emulsifying agent must be used first to carry out emulsification, endecatylene acid glyceride is connected with surfactant lipophilic group, is then dispersed in aqueous phase; If do not carry out emulsification to be directly dispersed in aqueous phase, it can be caused to lose efficacy because of oxidation, its function cannot be played, produce floating oil or rotten.Nonylphenol polyoxyethylene ether emulsifier is w/o type nonionic emulsifier, its chemical stability counter-anions type or cationic surface active agent good, acid and alkali-resistance is stablized, hydrophobic end is allowed to be connected with surfactant, when nursing fabric, make water-wet side and fabric fibre adhesion stronger, after fabric dries, can better play peculiar smell effectiveness; Deionized water is adopted to make mixture be aqueous phase state by oil phase state transfer, guarantee stable system system.
Embodiment 1
Fabric spends peculiar smell care agent, comprises with weight parts:
Above-mentioned fabrics spends the preparation method of odor function care agent, takes following steps:
Step 1, is added in polyoxyethylene nonylphenol ether by endecatylene acid glyceride, stirs, under stirring, slowly adds 1/2 parts by weight of deionized water, continues to stir, obtains stable homogeneous solution A after mixing;
Step 2, adds to softener in step 1 gained solution A, by acetic acid adjust ph to 7.0-7.5, obtains solution B;
Step 3, slowly adds to distearate in the surplus deionized water of 40-50 DEG C, at the uniform velocity insulated and stirred, until dissolve, stops heating up, then under stirring, naturally cools to obtain solution C;
Step 4, mixes solution B with solution C, and after fully stirring, standing, vacuum decompression froth breaking, obtains and remove odor function care agent.
Embodiment 2
Fabric spends peculiar smell care agent, comprises with weight parts:
Above-mentioned fabrics spends the preparation method of odor function care agent, takes following steps:
Step 1, is added in polyoxyethylene nonylphenol ether by endecatylene acid glyceride, stirs, under stirring, slowly adds 1/2 parts by weight of deionized water, continues to stir, obtains stable homogeneous solution A after mixing;
Step 2, adds in step 1 gained solution A by sodium chloride, softener, by acetic acid adjust ph to 7.0-7.5, obtains solution B;
Step 3, slowly adds to distearate in the surplus deionized water of 40-50 DEG C, at the uniform velocity insulated and stirred, until dissolve, stops heating up, then under stirring, naturally cools to obtain solution C;
Step 4, mixes solution B with solution C, and after fully stirring, standing, vacuum decompression froth breaking, obtains and remove odor function care agent.
Embodiment 3
Fabric spends peculiar smell care agent, comprises with weight parts:
Above-mentioned fabrics spends the preparation method of odor function care agent, takes following steps:
Step 1, is added in polyoxyethylene nonylphenol ether by endecatylene acid glyceride, stirs, under stirring, slowly adds 1/2 parts by weight of deionized water, continues to stir, obtains stable homogeneous solution A after mixing;
Step 2, adds to softener in step 1 gained solution A, by acetic acid adjust ph to 7.0-7.5, obtains solution B;
Step 3, slowly adds to distearate in the surplus deionized water of 40-50 DEG C, at the uniform velocity insulated and stirred, until dissolve, stops heating up, then under stirring, naturally cools to obtain solution C;
Step 4, mixes solution B with solution C, and after fully stirring, standing, vacuum decompression froth breaking, obtains and remove odor function care agent.
Get the room temperature clear water of certain volume, odor function care agent will be gone to join in clear water, and addition is 5g/L, after mixing, is soaked wherein common fabric, soak time 3-5min, wrings out or airing after dewatering.
Detection method: smelly eliminating (acetic acid, ammonia)-detect tube method.
Sample size: 100 square centimeters
Initial concentration: acetic acid (15,30ppm), ammonia (50,100ppm)
Gas is filled: 3L carrier gas: nitrogen
Place at 20 DEG C after 2 hours, measure residual concentration with detector tube
Slip (%)={ 1-(the residual odor concentration of sample)/(the residual odor concentration of empty test) } x100
Qualified benchmark: ammonia more than 70%, acetic acid more than 70%.
Result is as follows:

Claims (7)

1. fabric spends a peculiar smell care agent, it is characterized in that: comprise with parts by weight: polyoxyethylene nonylphenol ether 1 ~ 5 part, endecatylene acid glyceride 2 ~ 10 parts, distearate 0.5 ~ 3 part, softener 0.5 ~ 3 part, 20 ~ 50 parts, water.
2. fabric according to claim 1 spends peculiar smell care agent, it is characterized in that: described care agent also comprises 0.1 ~ 0.3 part of essence with parts by weight.
3. fabric according to claim 1 spends peculiar smell care agent, it is characterized in that: described softener is anionic softener or nonionic silicone oil softener.
4. fabric according to claim 1 spends peculiar smell care agent, it is characterized in that: described care agent also comprises 0.2 ~ 1 part of sodium chloride with parts by weight.
5. fabric according to claim 1 spends the preparation method of peculiar smell care agent, it is characterized in that: comprise the following steps:
Step 1, is added in polyoxyethylene nonylphenol ether by endecatylene acid glyceride, stirs, adds 1/2 parts by weight of deionized water, stirs, obtains solution A;
Step 2, softener adds in step 1 gained solution A, and adjust ph, to 7.0-7.5, obtains solution B;
Step 3, adds to distearate in residuals weight part deionized water, obtains solution C;
Step 4, mixes solution B with solution C, stirs, after froth breaking and get final product.
6. fabric according to claim 5 spends the preparation method of peculiar smell care agent, it is characterized in that: the concrete steps of step 3 be in deionized water distearate being added to 40-60 DEG C insulated and stirred to dissolving, then cooling naturally under stirring.
7. fabric according to claim 5 spends the preparation method of peculiar smell care agent, it is characterized in that: also can add sodium chloride in step 2.
CN201510991376.8A 2015-12-25 2015-12-25 Deodorizing care agent used for fabrics and preparation method thereof Pending CN105421075A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN105421075A true CN105421075A (en) 2016-03-23

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101210386A (en) * 2006-12-29 2008-07-02 上海和黄白猫有限公司 Peculiar smell removing softening agent
CN102330348A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Finishing agent for deodorizing sweat-proof and anti-mosquito textile
CN103061061A (en) * 2012-09-14 2013-04-24 方孝贤 Method for manufacturing fabric with peculiar-smell dispelling and antimicrobic functions
CN103351963A (en) * 2013-07-01 2013-10-16 安徽华强羽绒有限公司 Odor-eliminating eider down caring agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101210386A (en) * 2006-12-29 2008-07-02 上海和黄白猫有限公司 Peculiar smell removing softening agent
CN102330348A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Finishing agent for deodorizing sweat-proof and anti-mosquito textile
CN103061061A (en) * 2012-09-14 2013-04-24 方孝贤 Method for manufacturing fabric with peculiar-smell dispelling and antimicrobic functions
CN103351963A (en) * 2013-07-01 2013-10-16 安徽华强羽绒有限公司 Odor-eliminating eider down caring agent and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
朱洪法 等: "《无机化工产品手册》", 31 December 2008 *
李俊 等: ""纺织品的护肤整理加工及其应用"", 《染整技术》 *

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Application publication date: 20160323