CN105420764A - Plating solution brightener material composition and preparation method of plating solution brightener - Google Patents
Plating solution brightener material composition and preparation method of plating solution brightener Download PDFInfo
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- CN105420764A CN105420764A CN201510829463.3A CN201510829463A CN105420764A CN 105420764 A CN105420764 A CN 105420764A CN 201510829463 A CN201510829463 A CN 201510829463A CN 105420764 A CN105420764 A CN 105420764A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
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Abstract
The invention discloses a plating solution brightener material composition and a preparation method of the plating solution brightener. The composition is prepared from water, sodium benzoate, nonylphenol polyoxyethylene ether, acetic acid, DL-methionine, ethane and iso-butane. Relative to 100 parts by weight of water, the composition is composed of10-30 parts of sodium benzoate, 10-30 parts of nonylphenol polyoxyethylene ether, 1-5 parts of acetic acid, 1-3 parts of DL-methionine, 1-5 part of ethane and 1-5 parts of iso-butane. According to the design, the lustre of the product appearance is greatly improved, and the probability of lower lustre of plated coatings prepared by simply using general plating solutions is greatly lowered, so that the production quality is improved and the waste product number is reduced.
Description
Technical field
The present invention relates to electroplate liquid additive Material Field, particularly, relate to the preparation method of a kind of electroplate liquid brightening agent material compositions and electroplate liquid brightening agent.
Background technology
Plating is as a kind of conventional material surface treatment method, use in actual production and life is very extensive, but in the use procedure of electroplate liquid, often its coating surface formed is comparatively dim, be not easy the metalluster occurring comparatively light, thus make the metal appearance being coated with above-mentioned coating glossy not, when a lot of to have when requirement outward appearance product then may be caused to occur defective phenomenon, and then substantially increase the production cost of product.
Therefore, provide a kind of glossiness that effectively can improve product surface coating, the preparation method of the electroplate liquid brightening agent material compositions and electroplate liquid brightening agent that greatly reduce the disqualification rate of product is the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, often surface is comparatively dim to the object of the invention is to overcome in prior art the coating electroplating formation, be not easy the metalluster occurring comparatively light, thus make the metal appearance being coated with above-mentioned coating glossy not, when a lot of to have when requirement outward appearance product then may be caused to occur defective phenomenon, and then substantially increase the problem of production cost of product, thus a kind of glossiness that effectively can improve product surface coating is provided, greatly reduce the electroplate liquid brightening agent material compositions of the disqualification rate of product and the preparation method of electroplate liquid brightening agent.
To achieve these goals, the invention provides a kind of electroplate liquid brightening agent material compositions, wherein, described composition comprises water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane; Wherein,
Relative to the described water of 100 weight parts, the content of described Sodium Benzoate is 10-30 weight part, the content of described polyoxyethylene nonylphenol ether is 10-30 weight part, the content of described acetic acid is 1-5 weight part, the content of described DL-methionine is 1-3 weight part, the content of described ethane is 1-5 weight part, and the content of described Trimethylmethane is 1-5 weight part.
Present invention also offers a kind of preparation method of electroplate liquid brightening agent, wherein, described preparation method comprises: water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane are mixed, obtained electroplate liquid brightening agent; Wherein,
Relative to the described water of 100 weight parts, the consumption of described Sodium Benzoate is 10-30 weight part, the consumption of described polyoxyethylene nonylphenol ether is 10-30 weight part, the consumption of described acetic acid is 1-5 weight part, the consumption of described DL-methionine is 1-3 weight part, the consumption of described ethane is 1-5 weight part, and the consumption of described Trimethylmethane is 1-5 weight part.
Pass through technique scheme, water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane are mixed obtained electroplate liquid brightening agent by the present invention according to a certain percentage, and then make by the material of aforementioned proportion obtain electroplate liquid brightening agent in for electroplate liquid time effectively can improve the plating of this electroplate liquid after the luminance brightness of coating surface that formed, and then greatly improve the gloss of product appearance, thus reduction uses the probability that the glossiness of the coating obtained by general electroplate liquid is lower merely greatly, and then the raising quality of production, quantity of reducing the number of rejects and seconds.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of electroplate liquid brightening agent material compositions, wherein, described composition comprises water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane; Wherein,
Relative to the described water of 100 weight parts, the content of described Sodium Benzoate is 10-30 weight part, the content of described polyoxyethylene nonylphenol ether is 10-30 weight part, the content of described acetic acid is 1-5 weight part, the content of described DL-methionine is 1-3 weight part, the content of described ethane is 1-5 weight part, and the content of described Trimethylmethane is 1-5 weight part.
Above-mentioned design is by mixing obtained electroplate liquid brightening agent according to a certain percentage by water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane, and then make by the material of aforementioned proportion obtain electroplate liquid brightening agent in for electroplate liquid time effectively can improve the plating of this electroplate liquid after the luminance brightness of coating surface that formed, and then greatly improve the gloss of product appearance, thus reduction uses the probability that the glossiness of the coating obtained by general electroplate liquid is lower merely greatly, and then the raising quality of production, quantity of reducing the number of rejects and seconds.
Certainly, in order to the luminance brightness making the electroplate liquid brightening agent obtained can improve obtained coating surface further when being actually used in electroplate liquid, one of the present invention preferred embodiment in, relative to the described water of 100 weight parts, the content of described Sodium Benzoate is 15-25 weight part, the content of described polyoxyethylene nonylphenol ether is 15-25 weight part, the content of described acetic acid is 2-4 weight part, the content of described DL-methionine is 1-2 weight part, the content of described ethane is 2-4 weight part, and the content of described Trimethylmethane is 2-4 weight part.
Certainly, in order to make the electroplate liquid brightening agent obtained can improve glossiness better when reality uses, one of the present invention more preferred embodiment in, described composition can also comprise magnesium nitrate and SODIUMNITRATE.
Certainly, here the amount that magnesium nitrate and the content of SODIUMNITRATE can use according to this area routine regulates, such as, one of the present invention preferred embodiment in, relative to the described water of 100 weight parts, the content of described magnesium nitrate is 1-3 weight part, and the content of described SODIUMNITRATE is 1-3 weight part.
Present invention also offers a kind of preparation method of electroplate liquid brightening agent, wherein, described preparation method comprises: water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane are mixed, obtained electroplate liquid brightening agent; Wherein,
Relative to the described water of 100 weight parts, the consumption of described Sodium Benzoate is 10-30 weight part, the consumption of described polyoxyethylene nonylphenol ether is 10-30 weight part, the consumption of described acetic acid is 1-5 weight part, the consumption of described DL-methionine is 1-3 weight part, the consumption of described ethane is 1-5 weight part, and the consumption of described Trimethylmethane is 1-5 weight part.
Similarly, in order to the luminance brightness making the electroplate liquid brightening agent obtained more effectively can improve the coating that electroplate liquid is formed when reality uses, one of the present invention preferred embodiment in, relative to the described water of 100 weight parts, the consumption of described Sodium Benzoate is 15-25 weight part, the consumption of described polyoxyethylene nonylphenol ether is 15-25 weight part, the consumption of described acetic acid is 2-4 weight part, the consumption of described DL-methionine is 1-2 weight part, the consumption of described ethane is 2-4 weight part, and the consumption of described Trimethylmethane is 2-4 weight part.
Certainly, one of the present invention more preferred embodiment in, described preparation method can also comprise add magnesium nitrate and SODIUMNITRATE mixing.
Here magnesium nitrate and the consumption of SODIUMNITRATE can regulate according to actual needs, such as, one of the present invention more preferred embodiment in, relative to the described water of 100 weight parts, the consumption of described magnesium nitrate is 1-3 weight part, and the consumption of described SODIUMNITRATE is 1-3 weight part.
The hybrid mode that described mixing process can adopt this area routine to adopt operates, such as, one of the present invention preferred embodiment in, described mixing process can for being uniformly mixed, and certainly, the condition of stirring can be not construed as limiting, such as, one of the present invention preferred embodiment in, in order to make mixing effect better and save production cost as far as possible, stir speed (S.S.) can be adjusted to 50-200r/min.
Below will be described the present invention by embodiment.In following examples, described Sodium Benzoate, described polyoxyethylene nonylphenol ether, described acetic acid, described DL-methionine, described ethane, described Trimethylmethane, described magnesium nitrate and described SODIUMNITRATE are conventional commercial product.Described electroplate liquid is the commercially available Zinc-nickel alloy electroplating liquid of the limpid Environmental Protection Technology Co., Ltd in Suzhou supply.
Embodiment 1
It is that 50r/min stirs that the mixing of 100g water, 15g Sodium Benzoate, 15g polyoxyethylene nonylphenol ether, 2g acetic acid, 1gDL-methionine(Met), 2g ethane, 2g Trimethylmethane, 1g magnesium nitrate and 1g SODIUMNITRATE is placed on stir speed (S.S.), obtained electroplate liquid brightening agent A1.
Embodiment 2
It is that 200r/min stirs that the mixing of 100g water, 25g Sodium Benzoate, 25g polyoxyethylene nonylphenol ether, 4g acetic acid, 2gDL-methionine(Met), 4g ethane, 4g Trimethylmethane, 3g magnesium nitrate and 3g SODIUMNITRATE is placed on stir speed (S.S.), obtained electroplate liquid brightening agent A2.
Embodiment 3
It is that 100r/min stirs that the mixing of 100g water, 20g Sodium Benzoate, 20g polyoxyethylene nonylphenol ether, 3g acetic acid, 1gDL-methionine(Met), 3g ethane, 3g Trimethylmethane, 2g magnesium nitrate and 2g SODIUMNITRATE is placed on stir speed (S.S.), obtained electroplate liquid brightening agent A3.
Embodiment 4
Be prepared according to the preparation method of embodiment 1, unlike, the consumption of described Sodium Benzoate is 10g, the consumption of described polyoxyethylene nonylphenol ether is 10g, and the consumption of described acetic acid is 1g, and the consumption of described DL-methionine is 1g, the consumption of described ethane is 1g, the consumption of described Trimethylmethane is 1g, does not add magnesium nitrate and SODIUMNITRATE, obtained electroplate liquid brightening agent A4.
Embodiment 5
Be prepared according to the preparation method of embodiment 2, unlike, the consumption of described Sodium Benzoate is 30g, the consumption of described polyoxyethylene nonylphenol ether is 30g, and the consumption of described acetic acid is 5g, and the consumption of described DL-methionine is 3g, the consumption of described ethane is 5g, the consumption of described Trimethylmethane is 5g, does not add magnesium nitrate and SODIUMNITRATE, obtained electroplate liquid brightening agent A5.
Comparative example 1
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described Sodium Benzoate is 5g, the consumption of described polyoxyethylene nonylphenol ether is 5g, the consumption of described acetic acid is 0.5g, and the consumption of described DL-methionine is 0.5g, and the consumption of described ethane is 0.5g, the consumption of described Trimethylmethane is 0.5g, obtained electroplate liquid brightening agent D1.
Comparative example 2
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described Sodium Benzoate is 50g, the consumption of described polyoxyethylene nonylphenol ether is 50g, the consumption of described acetic acid is 10g, and the consumption of described DL-methionine is 5g, and the consumption of described ethane is 10g, the consumption of described Trimethylmethane is 10g, obtained electroplate liquid brightening agent D2.
Test case
Above-mentioned obtained A1-A5, D1 and D2 are added in electroplate liquid respectively, and by the above-mentioned electroplate liquid plating iron plate surface being added with electroplate liquid brightening agent, simultaneously, the electroplate liquid plating iron plate surface of electroplate liquid brightening agent will be added with, form comparative example D3, detect above-mentioned iron plate surface gloss, the result obtained is as shown in table 1.
Table 1
| Numbering | Surface gloss |
| A1 | Glossiness is high |
| A2 | Glossiness is high |
| A3 | Glossiness is high |
| A4 | Glossiness is good |
| A5 | Glossiness is good |
| D1 | Glossiness is dimer |
| D2 | Glossiness is dimer |
| D3 | Comparatively gloss |
Can be found out by table 1, the glossiness of the coating that electroplate liquid is formed after plating effectively can be improved when electroplate liquid brightening agent obtained is within the scope of the present invention in for electroplate liquid, but then do not possess the effect of this good raising coating glossiness outward when reality uses at the electroplate liquid brightening agent that the scope of the invention obtains, therefore, the electroplate liquid brightening agent obtained by the present invention effectively improves the glossiness of coating, substantially increases the qualification rate of product.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1. an electroplate liquid brightening agent material compositions, is characterized in that, described composition comprises water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane; Wherein,
Relative to the described water of 100 weight parts, the content of described Sodium Benzoate is 10-30 weight part, the content of described polyoxyethylene nonylphenol ether is 10-30 weight part, the content of described acetic acid is 1-5 weight part, the content of described DL-methionine is 1-3 weight part, the content of described ethane is 1-5 weight part, and the content of described Trimethylmethane is 1-5 weight part.
2. composition according to claim 1, wherein, relative to the described water of 100 weight parts, the content of described Sodium Benzoate is 15-25 weight part, the content of described polyoxyethylene nonylphenol ether is 15-25 weight part, and the content of described acetic acid is 2-4 weight part, and the content of described DL-methionine is 1-2 weight part, the content of described ethane is 2-4 weight part, and the content of described Trimethylmethane is 2-4 weight part.
3. composition according to claim 1 and 2, wherein, described composition also comprises magnesium nitrate and SODIUMNITRATE.
4. composition according to claim 3, wherein, relative to the described water of 100 weight parts, the content of described magnesium nitrate is 1-3 weight part, and the content of described SODIUMNITRATE is 1-3 weight part.
5. a preparation method for electroplate liquid brightening agent, is characterized in that, described preparation method comprises: water, Sodium Benzoate, polyoxyethylene nonylphenol ether, acetic acid, DL-methionine, ethane and Trimethylmethane are mixed, obtained electroplate liquid brightening agent; Wherein,
Relative to the described water of 100 weight parts, the consumption of described Sodium Benzoate is 10-30 weight part, the consumption of described polyoxyethylene nonylphenol ether is 10-30 weight part, the consumption of described acetic acid is 1-5 weight part, the consumption of described DL-methionine is 1-3 weight part, the consumption of described ethane is 1-5 weight part, and the consumption of described Trimethylmethane is 1-5 weight part.
6. preparation method according to claim 5, wherein, relative to the described water of 100 weight parts, the consumption of described Sodium Benzoate is 15-25 weight part, the consumption of described polyoxyethylene nonylphenol ether is 15-25 weight part, and the consumption of described acetic acid is 2-4 weight part, and the consumption of described DL-methionine is 1-2 weight part, the consumption of described ethane is 2-4 weight part, and the consumption of described Trimethylmethane is 2-4 weight part.
7. the preparation method according to claim 5 or 6, wherein, described preparation method also comprises and adds magnesium nitrate and SODIUMNITRATE mixing.
8. preparation method according to claim 7, wherein, relative to the described water of 100 weight parts, the consumption of described magnesium nitrate is 1-3 weight part, and the consumption of described SODIUMNITRATE is 1-3 weight part.
9. the preparation method according to claim 5 or 6, wherein, described mixing process is for being uniformly mixed, and stir speed (S.S.) is 50-200r/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107904631A (en) * | 2017-11-28 | 2018-04-13 | 江苏澳光电子有限公司 | A kind of plating solution and its application for stainless steel surface palladium plating |
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| CN101063220A (en) * | 2007-05-22 | 2007-10-31 | 昆明理工大学 | Zinc and Zn-Fe alloy electroplating brightener |
| CN101922028A (en) * | 2009-06-16 | 2010-12-22 | 武汉奥化表面工程有限公司 | Galvanized iron (vanadium) alloy process of acid system |
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| CN107904631A (en) * | 2017-11-28 | 2018-04-13 | 江苏澳光电子有限公司 | A kind of plating solution and its application for stainless steel surface palladium plating |
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Application publication date: 20160323 |