CN105419710B - Water-resistant type cloud stone glue and its preparation and application - Google Patents
Water-resistant type cloud stone glue and its preparation and application Download PDFInfo
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- CN105419710B CN105419710B CN201510934550.5A CN201510934550A CN105419710B CN 105419710 B CN105419710 B CN 105419710B CN 201510934550 A CN201510934550 A CN 201510934550A CN 105419710 B CN105419710 B CN 105419710B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
A kind of water-resistant type cloud stone glue and its preparation and application, belong to adhesive for building technical field.Including component A and component B, component A is made up of following raw material：20 60 parts of 50 80 parts of water-resistant type resin, 5 20 parts of diluent, 0.05 0.4 parts of polymerization inhibitor, 0.03 0.3 parts of accelerator, 13 parts of thixotropic agent and reinforcer；Component B is made up of following raw material：13 parts of 40 60 parts of curing agent, 30 50 parts of plasticizer, 0.5 1.5 parts of emulsifying agent and thixotropic agent.Application method：Used after component A is well mixed with component B in mass ratio 100: 13.Significantly improve water resistance；Embody ultimate attainment chemical resistance；Curing rate is fast, adhesive strength is high, pliability and elasticity is good, color inhibition and wet-hot aging performance are excellent.Embody convenience when using.
Description
Technical field
The invention belongs to adhesive for building technical field, and in particular to a kind of water-resistant type cloud stone glue, and further relate to it
Preparation and application.
Background technology
Cloud stone glue is widely used in bonding between all kinds of stone materials or for such as crack of stone surface, hole, sand holes
Etc flaw fill up and the repairing to stone material mark of break.
Cloud stone glue has point of one pack system and bi-component, cloud stone glue such as CN102146571B (cloud stone glue and its system of one pack system
Standby technique) and CN103571422B (a kind of cloud stone glue)；The typical document of the cloud stone glue of bi-component disclose as
CN101735760A (a kind of cloud stone glue and preparation method thereof).Coagulated because bi-component cloud stone glue has relative to one pack system cloud stone glue
The strong point such as glue speed is fast, hardening time is short and adhesive strength is high, thus bi-component cloud stone glue is generally used at present.
The component A of bi-component cloud stone glue in prior art raw material is mostly：Unsaturated polyester resin, polymerization inhibitor, rush
Enter agent, filler and thickener；Component B raw material is mostly curing agent, plasticizer, filler and thickener, this can be seen in foregoing
CN101735760A.In use, component A is well mixed by a certain percentage with component B.
Pass through the reading to being not limited to patent document exemplified above：Why hot in cloud stone glue raw material people are
Inner feelings in using unsaturated polyester resin, be because unsaturated polyester resin main chain on have substantial amounts of ester bond and double bond, with compared with
High reactivity.But the weakness of unsaturated polyester resin is not often people's enough attention, so-called weakness is as shunk
Rate is big, wet-heat resisting and resistance to acids and bases are poor, the ester bond easy fracture particularly under long-term hygrothermal environment, exactly in view of this factor, contains
The cloud stone glue for having unsaturated polyester resin is usually not used for the structural bonding of construction material, such as because losing toughness and elasticity
And dry-hang stone is cannot be used for, so as to have impact on the expansion of its purposes to a certain extent.
The content of the invention
The task of the present invention is that providing one kind helps to improve water resistance, is conducive to enhancing chemical resistance, beneficial
It is easy to embody good toughness and elastic water-resistant type cloud stone glue in promoting adhesive strength and having.
The present invention another task be to provide a kind of preparation method of water-resistant type cloud stone glue, by this method prepare it is water-fast
Type cloud stone glue can ensure that its described technique effect is able to embody comprehensively.
The present invention another task be to provide a kind of application method of water-resistant type cloud stone glue, this method has instant
Allocate and allocate quick and convenient strong point.
What the task of the present invention was performed by, a kind of water-resistant type cloud stone glue, including component A and component B, described group
A is divided to be made up of the following raw material matched by weight：50-80 parts of water-resistant type resin, 5-20 parts of diluent, polymerization inhibitor 0.05-
20-60 parts of 0.4 part, 0.03-0.3 parts of accelerator, 1-3 parts of thixotropic agent and reinforcer；Described component B by it is following by weight
The raw material of number proportioning is constituted：1-3 parts of 40-60 parts of curing agent, 30-50 parts of plasticizer, 0.5-1.5 parts of emulsifying agent and thixotropic agent.
In the specific embodiment of the present invention, described water-resistant type resin is the polyester that organosilicon modifier is modified
Resin and vinyl modified epoxy resin are by any weight than the mixture that mixes；Described organosilicon modifier is methyl three
Butanone oximino silane, MTMS, methyl triacetyl silane, r- aminopropyl triethoxysilanes, r- (2,3- rings
The oxygen of oxygen third) more than one or both of propyl trimethoxy silicane mixture.
In another specific embodiment of the present invention, described vinyl modified epoxy resin changes for methacrylic acid
The mixture of one or both of property bisphenol A type epoxy resin, acrylic modified phenolic resin.
In another specific embodiment of the present invention, described diluent is styrene；Described polymerization inhibitor is benzene
Mixing more than one or both of quinone, quinhydrones, methylnaphthohydroquinone, t-butyl catechol, tert-butylhydroquinone, naphthoquinones
Thing.
In another specific embodiment of the present invention, described accelerator is DMA, N, N- diethyls
Mixture more than one or both of base aniline, N, N- dimethyl-p-toluidines；The thixotropic agent is rilanit special, gas
Mixing more than one or both of aerosil, low molecular polyamides wax, low molecular weight polyethylene, organobentonite
Thing.
In the also specific embodiment of the present invention, reinforcer is silicon powder, silica flour, talcum powder, heavy
Mixture more than one or both of calcium carbonate, calcite in powder, enhancing chopped fiber；Described curing agent is benzoyl peroxide first
Acyl.
In a still more specific embodiment of the invention, the plasticizer is propylene glycol dibenzoate, poly- second two
Alcohol phthalic acid ester, diphenyl phosphate isodecyl ester, repefral, dibutyl phthalate, phthalic acid
Mixture more than one or both of dioctyl ester；Described emulsifying agent be sorbester p17, polysorbate60, OP-10 in one kind or
Two or more mixtures.
What another task of the present invention was performed by, a kind of preparation method of water-resistant type cloud stone glue, including following step
Suddenly：
A component A) is prepared：By 5-20 parts of 50-80 parts of water-resistant type resin, the diluent, the polymerization inhibitor that weigh by weight
0.05-0.4 parts and 0.03-0.3 part of accelerator put intos in the reaction vessel for carrying agitator and stirred successively, then will be by weighing
In 1-3 parts of input reaction vessels of thixotropic agent for weighing of amount number, high-speed stirred, then put into and claim by weight into reaction vessel
20-60 parts of the reinforcer taken, then stirs, vacuumizes, and blowing obtains component A；
B component B) is prepared：30-50 parts of 40-60 parts of curing agent and plasticizer weighing by weight are sequentially added into band
Stirred evenly in the reaction vessel for having agitator, then added into reaction vessel 05-1.5 parts of the emulsifying agent that weighs by weight after
It is continuous to stir, 1-3 parts of the thixotropic agent weighed by weight is added in most backward reaction vessel, at a high speed scattered stirring, discharging,
Obtain component B.
The present invention so that in a specific embodiment, step A) described in the mixing time stirred be
10-20min, the time of the high-speed stirred is 10-15min, and the time then stirred is 15-30min；Step B) in institute
The time stirred evenly stated is 10-15min, and the described time for continuing to stir is 5-10min, the scattered stirring of described high speed
Time be 10-15min.
What the another task of the present invention was performed by, a kind of application method of water-resistant type cloud stone glue, it is by component A
Used after being well mixed with component B in mass ratio 100: 1-3.
Technical scheme that the present invention is provided has technical effect that；Due to having abandoned the unsaturated polyester (UP) tree in prior art
Fat and water-resistant type resin is employed, and because water-resistant type resin has excellent crosslink density and can be formed with three-dimensional network
Structure, thus will not be hydrolyzed and be significantly improved water resistance；Due to emerging from pole with excellent acid-proof alkaline
The chemical resistance of cause；Curing rate is fast, adhesive strength is high, pliability and elasticity is good, color inhibition and wet-hot aging performance are excellent.
The preparation method of offer can comprehensively ensure the aforementioned techniques effect of water-resistant type cloud stone glue.The application method of offer only need to be by component
A and component B is mixed, and has the convenience for being easy to embody when using.
Embodiment
Embodiment 1：
The preparation method for the water-resistant type cloud stone glue that the present invention is provided comprises the following steps：
A component A) is prepared：By 0.05 part of 15 parts of 50 parts of water-resistant type resin, styrene, quinhydrones weighing by weight, spy
0.05 part of butylhydroquinone and N, 0.08 part of accelerine put into the reaction vessel such as reactor with agitator successively
In stir, time of stirring is 20min, then by the 1 part of input reaction vessel of rilanit special weighed by weight
In, high-speed stirred 15min, then 40 parts of the silicon powder weighed by weight and enhancing chopped fiber 10 are put into reaction vessel
Part, 30min is then stirred, is vacuumized, blowing is simultaneously filling, obtains component A, the water-resistant type resin described in this step is by organosilicon
The mixture that 10 parts of 40 parts of the polyester resin of modifier modification and vinyl modified epoxy resin is mixed, described organosilicon changes
Property agent be MTMS, and described vinyl modified epoxy resin is acrylic modified bisphenol type epoxy
Resin；
B component B) is prepared：By 30 parts of 60 parts of benzoyl peroxide and diphenyl phosphate isodecyl ester weighing by weight
Sequentially add and stirred evenly in the reaction vessel with agitator, the time stirred evenly is 15min, is then added into reaction vessel by weight
0.5 part of 0.5 part of the polysorbate60 (Tween-60) that weighs of amount number and OP-10 continue to stir, and the time for continuing to stir is
3 parts of the aerosil weighed by weight is added in 10min, most backward reaction vessel, at a high speed scattered stirring 15min,
Discharge and filling, obtain component B.
Embodiment 2：
The preparation method for the water-resistant type cloud stone glue that the present invention is provided comprises the following steps：
A component A) is prepared：By 20 parts of 80 parts of water-resistant type resin, the styrene, the methylnaphthohydroquinone 0.1 that weigh by weight
Part, 0.2 part of naphthoquinones, 0.1 part of t-butyl catechol and 0.2 part of N, N- diethylaniline and N, N- dimethyl-p-toluidine 0.1
Part puts into reaction vessel such as reactor with agitator and stirred successively, and the time of stirring is 15min, then will be by weight
It is high in 1 part of 1 part of low molecular weight polyethylene, low molecular polyamides wax and 1 part of input reaction vessel of bentonite that amount number is weighed
Speed stirring 10min, then 60 parts of the silicon powder weighed by weight is put into reaction vessel, 15min is then stirred, takes out true
Sky, blowing is simultaneously filling, obtains component A, the polyester resin that the water-resistant type resin described in this step is modified by organosilicon modifier
40 parts of mixtures for being mixed with 40 parts of vinyl modified epoxy resin, described organosilicon modifier is methyl trimethoxy epoxide silicon
The mixture of alkane, methyl tributanoximo silane and methyl triacetyl silane, and described vinyl modified epoxy resin is
The mixture of acrylic modified bisphenol A type epoxy resin and acrylic modified phenolic resin；
B component B) is prepared：By 15 parts of 40 parts of benzoyl peroxide, repefral weighing by weight,
20 parts of 15 parts of dibutyl phthalate and dioctyl phthalate, which are sequentially added in the reaction vessel with agitator, to be stirred evenly,
The time stirred evenly is 10min, then added into reaction vessel 1.5 parts of the sorbester p17 (Span-80) that weighs by weight after
It is continuous to stir, continue the time of stirring for 10min, the hydrogenation weighed by weight is sequentially added in most backward reaction vessel
0.5 part of 1 part of castor oil, 0.5 part of aerosil and low molecular weight polyethylene, scattered stirring 10min, discharges and fills at a high speed
Dress, obtains component B.
Embodiment 3：
The preparation method for the water-resistant type cloud stone glue that the present invention is provided comprises the following steps：
A component A) is prepared：By 0.05 part of 5 parts of 65 parts of water-resistant type resin, styrene, the benzoquinones, the N that weigh by weight,
0.03 part of N- diethylanilines put into reaction vessel such as reactor with agitator and stirred successively, and the time of stirring is
10min, then holds the 1 part of input reaction of 1 part of the low molecular weight polyethylene weighed by weight and low molecular polyamides wax
In device, high-speed stirred 12min, then put into reaction vessel 8 parts of 10 parts of the talcum powder that weighs by weight and silica flour with
And 2 parts of rilanit special, 20min is then stirred, is vacuumized, blowing is simultaneously filling, obtains component A, water-fast described in this step
The mixture that 30 parts of 35 parts of the polyester resin that is modified by organosilicon modifier of type resin and vinyl modified epoxy resin is mixed,
Described organosilicon modifier is the mixed of r- aminopropyl triethoxysilanes and r- (2,3- the third oxygen of epoxy) oxypropyl trimethyl silane
Compound, and described vinyl modified epoxy resin is acrylic modified phenolic resin；
B component B) is prepared：By 50 parts of the benzoyl peroxide and polyethylene glycol phthalic acid ester that weigh by weight
50 parts sequentially add in the reaction vessel with agitator and stir evenly, and the time stirred evenly is 12min, is then added into reaction vessel
1.5 parts of the special nonionic surfactants of Tao Shi (Tergitol-XD) weighed by weight continue to stir, and continue to stir
The time mixed is 8min, adds 0.5 part of the aerosil and low molecule weighed by weight in most backward reaction vessel
0.5 part of weight northylen, scattered stirring 12min, discharges and filling, obtains component B at a high speed.
Embodiment 4：
The preparation method for the water-resistant type cloud stone glue that the present invention is provided comprises the following steps：
A component A) is prepared：By 10 parts of 70 parts of water-resistant type resin, styrene weighing by weight, tertiary butyl to benzene two
0.25 part of phenol, N, 0.04 part of accelerine, N, 0.04 part of N- diethylanilines and 0.04 part of N, N- dimethyl-p-toluidine
Stirred successively in reaction vessel such as reactor of the input with agitator, the time of stirring is 18min, then will by weight
In 2.5 parts of input reaction vessels of rilanit special that number is weighed, high-speed stirred 14min, then input presses weight into reaction vessel
20 parts of 20 parts of powdered whiting and silica flour that amount number is weighed, then stir 25min, vacuumize, blowing is simultaneously filling, obtains group
Divide A, 50 parts of polyester resin and vinyl modified epoxy that the water-resistant type resin described in this step is modified by organosilicon modifier
The mixture that 20 parts of resin is mixed, described organosilicon modifier is methyl triacetyl silane, and described vinyl changes
Property epoxy resin be acrylic modified bisphenol A type epoxy resin；
B component B) is prepared：By 55 parts of the benzoyl peroxide, the polyethylene glycol phthalic acid ester 20 that weigh by weight
20 parts of part and propylene glycol dibenzoate, which are sequentially added in the reaction vessel with agitator, to be stirred evenly, and the time stirred evenly is 14min,
Then 0.3 part of the polysorbate60 (Tween-60) weighed by weight, sorbester p17 (Span-80) 0.4 are added into reaction vessel
Part continues to stir with OP-100.3 parts, continues the time of stirring for 6min, is sequentially added in most backward reaction vessel by heavy
0.5 part of 0.5 part of aerosil, low molecular polyamides wax and 0.5 part of low molecular weight polyethylene that amount number is weighed, at a high speed
Scattered stirring 14min, discharges and filling, obtains component B.
Use example 1：
Used after the component A obtained by embodiment 1 is well mixed with component B in mass ratio 100: 1.5.
Used after the component A obtained by embodiment 2 is well mixed with component B in mass ratio 100: 2.
Used after the component A obtained by embodiment 3 is well mixed with component B in mass ratio 100: 3.
Used after the component A obtained by embodiment 4 is well mixed with component B in mass ratio 100: 1.
The water-resistant type cloud stone glue obtained as above-described embodiment 1 to 4 has the technique effect shown in following table after tested.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Presetting period (25 DEG C) | 3′12″ | 2′50″ | 2′25″ | 3′35″ |
| Hardening time (25 DEG C) | 6′15″ | 5′53″ | 5′16″ | 6′45″ |
| Modulus of elasticity in static bending ＞ 5000MPa | 5800MPa | 5500MPa | 5200MPa | 5300MPa |
| Compression shear strength (stone material-stone material) ＞ 14MPa | 15.5MPa | 15.8MPa | 15.9MPa | 14.8MPa |
| 55 degree of hot-water soaks, 7 days intensity ＞ 12MPa | 12.8MPa | 12.5MPa | 12.1MPa | 13.2MPa |
Claims (9)
1. a kind of water-resistant type cloud stone glue, including component A and component B, it is characterised in that described component A by it is following by weight
The raw material of proportioning is constituted：50-80 parts of water-resistant type resin, 5-20 parts of diluent, 0.05-0.4 parts of polymerization inhibitor, accelerator 0.03-0.3
20-60 parts of part, 1-3 parts of thixotropic agent and reinforcer；Described component B is made up of the following raw material matched by weight：Gu
1-3 parts of 40-60 parts of agent, 30-50 parts of plasticizer, 0.5-1.5 parts of emulsifying agent and thixotropic agent, described water-resistant type resin are organic
Polyester resin and the vinyl modified epoxy resin that silica modifier is modified are by any weight than the mixture that mixes；Described has
Machine silica modifier is methyl tributanoximo silane, MTMS, methyl triacetyl silane, the second of r- aminopropyls three
Mixture more than one or both of TMOS, r- (oxygen of 2,3- epoxies third) propyl trimethoxy silicane.
2. water-resistant type cloud stone glue according to claim 1, it is characterised in that described vinyl modified epoxy resin is first
The mixture of one or both of base Acryrylic acid modified bisphenol A epoxy resin, acrylic modified phenolic resin.
3. water-resistant type cloud stone glue according to claim 1, it is characterised in that described diluent is styrene；Described resistance
Poly- agent is more than one or both of benzoquinones, quinhydrones, methylnaphthohydroquinone, t-butyl catechol, tert-butylhydroquinone, naphthoquinones
Mixture.
4. water-resistant type cloud stone glue according to claim 1, it is characterised in that described accelerator be DMA,
Mixture more than one or both of N, N- diethylaniline, N, N- dimethyl-p-toluidines；The thixotropic agent is hydrogenation
One or both of castor oil, aerosil, low molecular polyamides wax, low molecular weight polyethylene, organobentonite
Mixture above.
5. water-resistant type cloud stone glue according to claim 1, it is characterised in that reinforcer is silicon powder, silica flour, talcum
Mixture more than one or both of powder, powdered whiting, calcite in powder, enhancing chopped fiber；Described curing agent was
BP.
6. water-resistant type cloud stone glue according to claim 1, it is characterised in that the plasticizer be propylene glycol dibenzoate,
Polyethylene glycol phthalic acid ester, diphenyl phosphate isodecyl ester, repefral, dibutyl phthalate, adjacent benzene
Mixture more than one or both of diformazan dioctyl phthalate；Described emulsifying agent is in sorbester p17, polysorbate60, OP-10
One or more kinds of mixtures.
7. a kind of preparation method of water-resistant type cloud stone glue as claimed in claim 1, it is characterised in that comprise the following steps：
A component A) is prepared：By 5-20 parts of 50-80 parts of water-resistant type resin, the diluent, the polymerization inhibitor 0.05- that weigh by weight
0.4 part and 0.03-0.3 part of accelerator put into the reaction vessel for carrying agitator and stirred successively, then will by weight
In 1-3 parts of input reaction vessels of thixotropic agent that number is weighed, high-speed stirred, then put into what is weighed by weight into reaction vessel
20-60 parts of reinforcer, then stirs, vacuumizes, and blowing obtains component A；
B component B) is prepared：30-50 parts of 40-60 parts of curing agent and plasticizer weighing by weight are sequentially added to carry and stirred
Stirred evenly in the reaction vessel for mixing device, 05-1.5 parts of the emulsifying agent weighed by weight is then added into reaction vessel and continues to stir
Mix uniform, 1-3 parts of the thixotropic agent weighed by weight is added in most backward reaction vessel, scattered stirring, discharging, are obtained at a high speed
Component B.
8. the preparation method of water-resistant type cloud stone glue according to claim 7, it is characterised in that step A）Described in stirring
Uniform mixing time is 10-20min, and the time of the high-speed stirred is 10-15min, and the time then stirred is 15-
30min；Step B）Described in the time stirred evenly be 10-15min, the described time for continuing to stir is 5-10min, institute
The time for the scattered stirring of high speed stated is 10-15min.
9. a kind of application method of water-resistant type cloud stone glue as claimed in claim 1, it is characterised in that it is by component A and component
Used after B in mass ratio 100: 1-3 is well mixed.
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| CN201510934550.5A CN105419710B (en) | 2015-12-15 | 2015-12-15 | Water-resistant type cloud stone glue and its preparation and application |
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|---|---|---|---|
| CN201510934550.5A CN105419710B (en) | 2015-12-15 | 2015-12-15 | Water-resistant type cloud stone glue and its preparation and application |
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| CN105419710B true CN105419710B (en) | 2017-10-17 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266104A (en) * | 2017-05-18 | 2017-10-20 | 刘冠辰 | A kind of gold copy trailing its repair handicraft repair member |
| CN107964383A (en) * | 2017-11-30 | 2018-04-27 | 安徽坤大化学锚固有限公司 | A kind of cold resisting type cloud stone glue for building and its processing technology |
| CN108841347A (en) * | 2018-07-03 | 2018-11-20 | 杨辉 | A kind of high temperature not increasing any stabilizer not sagging cloud stone glue |
| CN109852316B (en) * | 2018-12-28 | 2021-10-29 | 蚌埠赛尔时代工贸有限公司 | High-strength water-resistant marble adhesive |
| CN110003835B (en) * | 2019-04-22 | 2021-06-08 | 湖北坤能科技有限公司 | Anchoring agent for railway maintenance and preparation and application methods thereof |
| CN113059701A (en) * | 2021-03-11 | 2021-07-02 | 吾尚良品环境服务(上海)有限公司 | Environment-friendly stone surface maintenance method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN101974304A (en) * | 2010-11-08 | 2011-02-16 | 武汉理工大学 | Vinylester resin stone adhesive and preparation method thereof |
-
2015
- 2015-12-15 CN CN201510934550.5A patent/CN105419710B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN101974304A (en) * | 2010-11-08 | 2011-02-16 | 武汉理工大学 | Vinylester resin stone adhesive and preparation method thereof |
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