CN105419593A - 一种抗刮擦的水性汽车纳米涂料 - Google Patents
一种抗刮擦的水性汽车纳米涂料 Download PDFInfo
- Publication number
- CN105419593A CN105419593A CN201510987722.5A CN201510987722A CN105419593A CN 105419593 A CN105419593 A CN 105419593A CN 201510987722 A CN201510987722 A CN 201510987722A CN 105419593 A CN105419593 A CN 105419593A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- scratch
- coating
- automobile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002103 nanocoating Substances 0.000 title abstract 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 29
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910001369 Brass Inorganic materials 0.000 claims abstract description 16
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010951 brass Substances 0.000 claims abstract description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001661 Chitosan Polymers 0.000 claims abstract description 10
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 10
- 229920005646 polycarboxylate Polymers 0.000 claims abstract description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000010469 Glycine max Nutrition 0.000 claims abstract description 7
- 244000068988 Glycine max Species 0.000 claims abstract description 7
- 239000005642 Oleic acid Substances 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 7
- 239000003973 paint Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 claims description 18
- 239000002135 nanosheet Substances 0.000 claims description 15
- 229920003656 Daiamid® Polymers 0.000 claims description 9
- 241000555268 Dendroides Species 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 229920000180 alkyd Polymers 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000011247 coating layer Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 4
- 239000003082 abrasive agent Substances 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009279 wet oxidation reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种抗刮擦的水性汽车纳米涂料，属于汽车涂层的技术领域。本发明包括以下重量份的原料：醇酸树脂30-50、轻质碳酸钙20-30、乙二醇胺10-20、司盘-80？10-20、壳聚糖0.5-3、纳米氧化锌5-10、纳米二氧化锆5-10、纳米片状黄铜粉0.1-1、树枝状聚酰胺胺1-10、聚羧酸盐0.5-2、消泡剂0.1-1、水20-40，醇酸树脂是由大豆油酸和甘油聚合而成的。本发明为水性纳米涂料，兼具了水性涂料和纳米涂料的双重优点；性能环保、制备简单、涂装方便、涂层厚度小，节约原料，漆膜无异味，耐冲洗性能强，具有很好的韧性，附着力达到0级，厚度达到4H，涂层丰满度高，广泛应用于汽车的涂装。
Description
技术领域
本发明属于汽车涂层的技术领域，特别是指一种抗刮擦的水性汽车纳米涂料。
背景技术
汽车涂料就是指涂装在轿车等各类车辆车身及零部件上的涂料，一般指新车的涂料及辅助材料和车辆修补用涂料。随着我国汽车工业的发展，汽车保有量的增长，为我国汽车涂料产业提供了巨大的市场发展空间。
现有的汽车涂料容易出现漆面龟裂、脱落的现象；同时，由于车辆越来越多，汽车之间的刮擦也是避免不了的；现有的汽车漆的抗刮性能差，不能满足人们对汽车涂料的需求。
发明内容
本发明提供一种抗刮擦的水性汽车纳米涂料，解决了现有技术中汽车涂料附着力和耐刮擦性能差而影响其使用效果的问题。
本发明的一种抗刮擦的水性汽车纳米涂料，其主要是通过以下技术方案加以实现的：包括以下重量份的原料：醇酸树脂30-50份、轻质碳酸钙20-30份、乙二醇胺10-20份、司盘-8010-20份、壳聚糖0.5-3份、纳米氧化锌5-10份、纳米二氧化锆5-10份、纳米片状黄铜粉0.1-1份、树枝状聚酰胺胺1-10份、聚羧酸盐0.5-2份、消泡剂0.1-1份、水20-40份，所述醇酸树脂是由大豆油酸和甘油聚合而成的。
作为一种优选的实施方案，包括以下重量份的原料：醇酸树脂40份、轻质碳酸钙25份、乙二醇胺15份、司盘-8015份、壳聚糖1份、纳米氧化锌6份、纳米二氧化锆7份、纳米片状黄铜粉0.6份、树枝状聚酰胺胺6份、聚羧酸盐1份、消泡剂0.5份、水30份。
作为一种优选的实施方案，所述轻质碳酸钙的目数为1000-1200目，所述纳米氧化锌的粒径为20-30nm，所述纳米二氧化锆的粒径为30-40nm，所述纳米片状黄铜粉的粒径为10-20nm。
本发明的有益效果：本发明为一种水性汽车纳米涂料，兼具了水性涂料和纳米涂料的双重优点；本发明的抗刮擦的水性汽车纳米涂料，其原料VOC含量低，符合汽车涂料的环保要求，没有刺鼻的异味；制备简单、涂装方便、涂层厚度小，节约原料；烘干后的汽车面漆基本无异味，漆膜丰满、平整光亮，耐冲洗性能强，具有很好的韧性，附着力达到0级，漆膜厚度达到4H，保光率好，可广泛应用于汽车的涂装。
具体实施方式
下面将结合本发明的具体实施例对本发明的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明的一种抗刮擦的水性汽车纳米涂料，包括以下重量份的原料：醇酸树脂30-50份、轻质碳酸钙20-30份、乙二醇胺10-20份、司盘-8010-20份、壳聚糖0.5-3份、纳米氧化锌5-10份、纳米二氧化锆5-10份、纳米片状黄铜粉0.1-1份、树枝状聚酰胺胺1-10份、聚羧酸盐0.5-2份、消泡剂0.1-1份、水20-40份，所述醇酸树脂是由大豆油酸和甘油聚合而成的。
具体地，包括以下重量份的原料：醇酸树脂40份、轻质碳酸钙25份、乙二醇胺15份、司盘-8015份、壳聚糖1份、纳米氧化锌6份、纳米二氧化锆7份、纳米片状黄铜粉0.6份、树枝状聚酰胺胺6份、聚羧酸盐1份、消泡剂0.5份、水30份。
优选地，所述轻质碳酸钙的目数为1000-1200目，所述纳米氧化锌的粒径为20-30nm，所述纳米二氧化锆的粒径为30-40nm，所述纳米片状黄铜粉的粒径为10-20nm。
实施例一
本发明的一种抗刮擦的水性汽车纳米涂料，包括以下重量份的原料：醇酸树脂30份、轻质碳酸钙20份、乙二醇胺10份、司盘-8010份、壳聚糖0.5份、纳米氧化锌5份、纳米二氧化锆5份、纳米片状黄铜粉0.1份、树枝状聚酰胺胺1份、聚羧酸盐0.5份、消泡剂0.1份、水20份，这里醇酸树脂是由大豆油酸和甘油聚合而成的。
其中，轻质碳酸钙的目数为1000-1200目，纳米氧化锌的粒径为20-30nm，纳米二氧化锆的粒径为30-40nm，纳米片状黄铜粉的粒径为10-20nm。
实施例二
本发明的一种抗刮擦的水性汽车纳米涂料，包括以下重量份的原料：醇酸树脂40份、轻质碳酸钙25份、乙二醇胺15份、司盘-8015份、壳聚糖1份、纳米氧化锌6份、纳米二氧化锆7份、纳米片状黄铜粉0.6份、树枝状聚酰胺胺6份、聚羧酸盐1份、消泡剂0.5份、水30份，这里醇酸树脂是由大豆油酸和甘油聚合而成的。
其中，轻质碳酸钙的目数为1000-1200目，纳米氧化锌的粒径为20-30nm，纳米二氧化锆的粒径为30-40nm，纳米片状黄铜粉的粒径为10-20nm。
实施例三
本发明的一种抗刮擦的水性汽车纳米涂料，包括以下重量份的原料：醇酸树脂50份、轻质碳酸钙30份、乙二醇胺20份、司盘-8020份、壳聚糖3份、纳米氧化锌10份、纳米二氧化锆10份、纳米片状黄铜粉1份、树枝状聚酰胺胺10份、聚羧酸盐2份、消泡剂1份、水40份，这里醇酸树脂是由大豆油酸和甘油聚合而成的。
其中，轻质碳酸钙的目数为1000-1200目，纳米氧化锌的粒径为20-30nm，纳米二氧化锆的粒径为30-40nm，纳米片状黄铜粉的粒径为10-20nm。
将实施例一至实施例三的三种抗刮擦的水性汽车纳米涂料和市售的某水性汽车纳米涂料，分别均匀喷涂于马口铁上，涂膜厚度为25±5μm，在60℃的条件下烘烤30min，得到涂料板试样，并将所得涂料板试样进行性能测试实验。
1、采用三菱铅笔（负荷500g）测定漆膜硬度，按照划圈法（间隔1mm）╳6次（3M600#）测定漆膜的附着力。
2、干抗刮伤性，在试样板的透明涂层上涂以BonAmi磨料薄层，随后套上绝色毛毡指套，抵住接触试样板，进行往返10次的擦拭，以试验其刮伤情况。抗刮伤性是通过测定涂层板的刮伤区域相对未刮伤区域的20度视角的光泽度的相对比率，即光泽保持百分率来表示。
3、湿抗刮伤性，采用上述相似的程序，只是用湿氧化铝淤浆替代BonAmi磨料，该氧化铝淤浆是由294份的去离子水、21份的ASE-60增稠剂、25份氨基甲基丙醇的AMP95%水溶液以及7份氧化铝（120#棱角砂）组成。
所得实验结果如表1所示。
表1漆膜性能测试结果
由表1可以看出，本发明实施例一至实施例三所得的三种抗刮擦的水性汽车纳米涂料，其漆膜硬度级别更高，达到4H级别；其附着力均为0级，具有更好的附着性能；同时，其不论是在干抗刮伤性还是在湿抗刮伤性方面均有显著提高，其光泽保持率均得到了明显的提升，具有很好的耐刮伤性能；这较市售的水性汽车纳米涂料（表1中的对照样）具有明显的优势。
本发明的有益效果：本发明为一种水性汽车纳米涂料，兼具了水性涂料和纳米涂料的双重优点；本发明的抗刮擦的水性汽车纳米涂料，其原料VOC含量低，符合汽车涂料的环保要求，没有刺鼻的异味；制备简单、涂装方便、涂层厚度小，节约原料；烘干后的汽车面漆基本无异味，漆膜丰满、平整光亮，耐冲洗性能强，具有很好的韧性，附着力达到0级，漆膜厚度达到4H，保光率好，可广泛应用于汽车的涂装。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (3)
1.一种抗刮擦的水性汽车纳米涂料，其特征在于，包括以下重量份的原料：
醇酸树脂30-50份、轻质碳酸钙20-30份、乙二醇胺10-20份、司盘-8010-20份、壳聚糖0.5-3份、纳米氧化锌5-10份、纳米二氧化锆5-10份、纳米片状黄铜粉0.1-1份、树枝状聚酰胺胺1-10份、聚羧酸盐0.5-2份、消泡剂0.1-1份、水20-40份，所述醇酸树脂是由大豆油酸和甘油聚合而成的。
2.根据权利要求1所述的抗刮擦的水性汽车纳米涂料，其特征在于，包括以下重量份的原料：
醇酸树脂40份、轻质碳酸钙25份、乙二醇胺15份、司盘-8015份、壳聚糖1份、纳米氧化锌6份、纳米二氧化锆7份、纳米片状黄铜粉0.6份、树枝状聚酰胺胺6份、聚羧酸盐1份、消泡剂0.5份、水30份。
3.根据权利要求1或2所述的抗刮擦的水性汽车纳米涂料，其特征在于：
所述轻质碳酸钙的目数为1000-1200目，所述纳米氧化锌的粒径为20-30nm，所述纳米二氧化锆的粒径为30-40nm，所述纳米片状黄铜粉的粒径为10-20nm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510987722.5A CN105419593B (zh) | 2015-12-25 | 2015-12-25 | 一种抗刮擦的水性汽车纳米涂料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510987722.5A CN105419593B (zh) | 2015-12-25 | 2015-12-25 | 一种抗刮擦的水性汽车纳米涂料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105419593A true CN105419593A (zh) | 2016-03-23 |
| CN105419593B CN105419593B (zh) | 2018-04-10 |
Family
ID=55498148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510987722.5A Active CN105419593B (zh) | 2015-12-25 | 2015-12-25 | 一种抗刮擦的水性汽车纳米涂料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105419593B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752846A (zh) * | 2016-12-24 | 2017-05-31 | 严志海 | 一种耐磨抗刮的水性汽车涂料 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1456618A (zh) * | 2003-05-29 | 2003-11-19 | 四川大学 | 聚合物/无机复合纳米粉体的汽车面漆及其制备方法 |
| CN101085883A (zh) * | 2007-05-25 | 2007-12-12 | 阮付林 | 一种水性上光涂料及其制备方法 |
| CN101701127A (zh) * | 2009-07-03 | 2010-05-05 | 长春华日涂料有限公司 | 一种单组份自干水性工业漆 |
| CN104592843A (zh) * | 2014-12-26 | 2015-05-06 | 上海乘鹰新材料有限公司 | 一种高平整度的水转印膜涂料及其制备方法 |
-
2015
- 2015-12-25 CN CN201510987722.5A patent/CN105419593B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1456618A (zh) * | 2003-05-29 | 2003-11-19 | 四川大学 | 聚合物/无机复合纳米粉体的汽车面漆及其制备方法 |
| CN101085883A (zh) * | 2007-05-25 | 2007-12-12 | 阮付林 | 一种水性上光涂料及其制备方法 |
| CN101701127A (zh) * | 2009-07-03 | 2010-05-05 | 长春华日涂料有限公司 | 一种单组份自干水性工业漆 |
| CN104592843A (zh) * | 2014-12-26 | 2015-05-06 | 上海乘鹰新材料有限公司 | 一种高平整度的水转印膜涂料及其制备方法 |
Non-Patent Citations (3)
| Title |
|---|
| 代少俊等: "《涂料和黏合剂》", 31 August 2014 * |
| 宋启煌等: "《精细化工工艺学（第三版）》", 31 August 2013 * |
| 彭俊等: "《汽车涂装技术》", 30 September 2011 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752846A (zh) * | 2016-12-24 | 2017-05-31 | 严志海 | 一种耐磨抗刮的水性汽车涂料 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105419593B (zh) | 2018-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103289551A (zh) | 一种木纹转印水性漆和铝合金木纹转印型材及其制造方法 | |
| CN104497787A (zh) | 水性涂料应用于铁路支座产品上的涂装 | |
| CN109504244B (zh) | 一种水性卷钢涂料及其制备方法 | |
| CN104845499A (zh) | 水性环氧厚浆漆的制备方法 | |
| CN104962189A (zh) | 一种铝粉塑胶水漆及其制备方法 | |
| CN104449336A (zh) | 自修复水性木器面漆 | |
| CN110669413A (zh) | 一种厚浆型低表面处理潮湿固化底漆、其制备方法与使用方法 | |
| CN103396714B (zh) | 真空电镀专用清漆 | |
| CN111019490A (zh) | 一种聚酯型高光水性卷铝涂料及其制备方法 | |
| CN109181461B (zh) | 一种环保水性汽车金属闪光漆及其制备方法 | |
| CN105419593A (zh) | 一种抗刮擦的水性汽车纳米涂料 | |
| CN111040541A (zh) | 一种水性丙烯酸氨基烤漆及制备方法 | |
| CN104031501A (zh) | 水性金属涂料 | |
| CN108948906A (zh) | 一种水性金属卷材专用烤漆及其使用方法 | |
| CN111876060A (zh) | 一种高耐磨抗刮伤的水性聚氨酯漆及其制备方法 | |
| CN105400398A (zh) | 一种防沾污汽车纳米涂料 | |
| CN104341902A (zh) | 一种环保铝粉塑胶漆 | |
| CN105419594A (zh) | 一种防腐汽车纳米涂料 | |
| CN110804372A (zh) | 一种适用于水性面漆的uv真空喷涂透明底漆 | |
| CN113308196A (zh) | 一种快干型水性涂料 | |
| CN106833316A (zh) | 一种玻璃油漆 | |
| CN107141953A (zh) | 一种氨基烤漆及其制备方法 | |
| CN105368280A (zh) | 一种防沾污水性汽车纳米涂料 | |
| CN112552790A (zh) | 一种尾气速冷器外壳专用石墨烯防腐涂料及其制备方法 | |
| CN111961393A (zh) | 一种abs塑料材质用水性金粉涂料及其制备方法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Shanjiang Inventor after: Hu Zhongyuan Inventor after: Qin Shaojie Inventor after: Cheng Lu Inventor after: Wang Jie Inventor before: Zhang Ming |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180313 Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1 Applicant after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: Donghai West Road 266000 Shandong city of Qingdao province No. 37 Building 2 10 storey office building room 3 No. 02 Applicant before: Qingdao Bozhong Chemical Technology Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20180410 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20180410 |