CN105418834B - 一种纸塑水性胶及其制备方法 - Google Patents
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Abstract
本发明提供了一种纸塑水性胶及其制备方法,本发明的纸塑水性胶是由单体料、水底料以及促进剂组成。本发明的纸塑水性胶所用原材料价格低廉,制备工艺简单,能够有效的提高工作效率。本发明的纸塑水性胶采用滴加法,中途加促进剂的方法制备而成,避免了常规乳化法的繁琐操作过程,缩短反应时间,为产品的大规模生产及应用奠定了有力的基础。本发明的纸塑水性胶所采用的原料都是环保型材料,有效的减少制作过程和使用过程中胶黏剂对工人造成的健康伤害。
Description
技术领域
本发明涉及材料领域,具体涉及一种纸塑水性胶及其制备方法。
背景技术
随着人们环保意识的逐步提高,印刷包装行业复膜工艺的环保性越来越被人们所重。现如今,水性复膜胶被大范围使用,逐步代替油性复膜胶,但是传统的水性复膜胶的制作方法都是采取的乳化法,其操作工艺繁琐,工作效率低。
比如,申请号为201010258149.1的专利“自交联水性复膜胶及其制备方法”中介绍了一种自交联水性复膜胶及其制备方法,但是其采用传统的乳化方法制作水性复膜胶,操作工艺繁琐,无法提高生产效率。
申请号为200510026475.9的专利“水性复膜胶及其制备方法”也公开了一种水性复膜胶及其制备方法,其采用传统的乳化方法和滴加法制作,操作工艺繁琐,滴加反应时间久,无法提高生产效率。
发明内容
为了解决传统复膜胶生产工艺复杂繁琐,工作效率低的问题,本发明希望提供一种纸塑水性胶及其制备方法。
具体而言,本发明提供一种纸塑水性胶,其特征在于,本发明的一种纸塑水性胶是由单体料和水底料、促进剂组成。
在一种优选实现方式中,所述单体料包括丙烯酸乙酯、丙烯酸丁酯、丙烯酸羟乙酯、甲基丙烯酸甲酯和丙烯酸;所述水底料包括去离子水、丙烯酸、氢氧化钠、过硫酸铵、乳化剂OP-10、邻苯二甲酸二丁酯和Ms-1;所述促进剂包括过硫酸铵和离子水。
在另一种优选实现方式中,所述单体料由丙烯酸乙酯20~24份、丙烯酸丁酯5~7份、丙烯酸羟乙酯3~6份、甲基丙烯酸甲酯10~12份以及丙烯酸0.5~2份组成。
在另一种优选实现方式中,所述水底料由离子水40~60份、丙烯酸0.5~2份、氢氧化钠0.05~0.1份、过硫酸铵0.05~0.1份、乳化剂OP-10为0.2~0.5份、邻苯二甲酸二丁酯2~5份以及Ms-10.1~0.5份组成。
在另一种优选实现方式中,所述促进剂由过硫酸铵0.2~0.5份以及离子水4~7份组成。
另一方面,本发明提供一种纸塑水性胶的制作方法,其特征在于,所述方法包括下述步骤:
(1)按重量百分比取单体料丙烯酸乙酯20~24份、丙烯酸丁酯5~7份、丙烯酸羟乙酯3~6份、甲基丙烯酸甲酯10~12份、丙烯酸0.5~2份混合均匀,获得混合单体;
(2)在反应釜中加入水底料离子水40~60份、丙烯酸0.5~2份、氢氧化钠0.05~0.1份、过硫酸铵0.05~0.1份、乳化剂OP-100.2~0.5份、邻苯二甲酸二丁酯2~5份以及Ms-10.1~0.5份,搅拌升温到78℃左右,开始滴加混合单体;
(3)维持反应体系在84~87℃之间,混合单体大约40分钟滴完,期间将促进剂分3次加入到反应釜中;
(4)滴加完毕后,保温反应20分钟,降温到45℃以下,用氨水调PH到6.5-7.0,出料,测试。
本发明的纸塑水性胶采用滴加法,中途加促进剂的制作工艺,工艺简单方便,缩短反应时间,大大提高生产工作效率。本发明的一种纸塑水性胶通过原材料的科学配比使得胶黏剂的剥离强度好,粘结强度高。
本发明在水底料中加入了邻苯二甲酸二丁酯,提高了剥离强度。
现有的制备方法所制备出的纸塑水性胶180℃的剥离强度通常在2-3N/cm之间;相比之下采用本发明的制备方法所制备出的纸塑水性胶180℃的剥离强度能够达到4.2N/cm。
具体实施方式
下面具体描述本发明的若干实施例,需要说明的是下述实施例仅作为示例而非对本发明的限制。
实施例1:
在本实施例中,制备所采用的原料(按重量计)如下:
(1)单体料:
(2)水底料:
(3)促进剂:
硫酸铵 0.3份
离子水 5份
上述纸塑水性胶的制备方法包括如下步骤:
(1)按重量百分比取单体料丙烯酸乙酯22份、丙烯酸丁酯6份、丙烯酸羟乙酯5份、甲基丙烯酸甲酯12份、丙烯酸1份混合均匀;
(2)在反应釜中加入水底料离子水50份、丙烯酸0.6份、氢氧化钠0.07份、过硫酸铵0.1份、乳化剂OP-10为0.5份、邻苯二甲酸二丁酯3份、Ms-1为0.2份,搅拌升温到78℃左右,开始滴加混合单体;
(3)维持反应体系在84~87℃之间,混合单体大约40分钟滴完,期间将促进剂分3次加入到反应釜中;
(4)滴加完毕后,保温反应20分钟,降温到45℃以下,用氨水调PH到6.5-7.0,出料,测试。
采用上面方式制备出的纸塑水性胶固含量:45%,粘度70mpa.s,PH值为7.0。本发明的申请人对所制成的水性胶进行了剥离强度测试,180℃剥离强度可达4.2N/cm。
实施例2:
在本实施例中,制备所采用的原料(按重量计)如下:
单体料:
水底料:
促进剂:
硫酸铵 0.4份
离子水 6份
上述纸塑水性胶的制备方法包括如下步骤:
(1)按重量百分比取单体料丙烯酸乙酯23份、丙烯酸丁酯5份、丙烯酸羟乙酯5份、甲基丙烯酸甲酯11份、丙烯酸0.8份混合均匀;
(2)在反应釜中加入水底料离子水55份、丙烯酸0.7份、氢氧化钠0.08份、过硫酸铵0.08份、反应型乳化剂0.4份、乳化剂OP-10为0.4份、邻苯二甲酸二丁酯4份以及Ms-10.3份,搅拌升温到78℃左右,开始滴加混合单体;
(3)维持反应体系在84~87℃之间,混合单体大约40分钟滴完,期间将促进剂分3次加入到反应釜中;
(4)滴加完毕后,保温反应20分钟,降温到45℃以下,用氨水调PH到6.5-7.0,出料,测试
采用上面方式制备出的纸塑水性胶固含量:42%,粘度60mpa.s,PH值为7.2。180℃剥离强度可达到4.1N/cm。
上述两个实施例的水性胶虽然剥离强度更高,但是在温度的稳定性方面和耐沉淀方面与普通的水性胶差别不大,因此发明人进一步实验得到了另一种优选实现方式,下面对其进行详细介绍。
实施例3:
在本实施例中,制备所采用的原料(按重量计)如下:
(1)单体料:
(2)水底料:
(3)促进剂:
硫酸铵 0.3份
离子水 5份
上述纸塑水性胶的制备方法包括如下步骤:
(1)按重量百分比取单体料丙烯酸乙酯22份、丙烯酸丁酯6份、丙烯酸羟乙酯5份、甲基丙烯酸甲酯12份、丙烯酸1份、乙烯乙酯0.15份,混合均匀,获得混合单体;
(2)在反应釜中加入水底料离子水50份、丙烯酸0.6份、氢氧化钠0.07份、过硫酸铵0.1份、乳化剂OP-10为0.5份、邻苯二甲酸二丁酯3份、Ms-1为0.2份、乙烯乙酯0.13份、丙三醇0.1份、乙二醇0.15份,搅拌升温到78℃左右,直到乙二醇大部分都挥发,开始滴加混合单体;
(3)维持反应体系在84~87℃之间,混合单体大约40分钟滴完,期间将促进剂分3次加入到反应釜中,最后再滴入;
(4)滴加完毕后,保温反应20分钟,降温到45℃以下,用氨水调PH到6.5-7.0,出料,测试。
采用上面方式制备出的纸塑水性胶固含量:45%,粘度70mpa.s,PH值为7.0。剥离强度可以维持上述两个实施例的水平。
并且,采用本实施例的制备方法,在高温和低温情况下均极其稳定,可以在-25摄氏度的情况下使用。申请人发现,虽然乙二醇在制备过程中挥发了大部分,但是加入其能促使水性胶中的各成分更好地彼此融合,改善水性胶的温度稳定性。此外本实施例中的丙三醇也发挥了作用,使得所制备出的水性胶的耐沉淀性能更佳,本申请的发明人对上面所制备出的三种水性胶分别进行了静置观察,结果在透明容器中静置半年之后,第三实施例中的水性胶均匀性最好,适量取出后,不需要经过摇晃即可正常使用。
虽然上面结合本发明的优选实施例对本发明的原理进行了详细的描述,本领域技术人员应该理解,上述实施例仅仅是对本发明的示意性实现方式的解释,并非对本发明包含范围的限定。实施例中的细节并不构成对本发明范围的限制,在不背离本发明的精神和范围的情况下,任何基于本发明技术方案的等效变换、简单替换等显而易见的改变,均落在本发明保护范围之内。
Claims (1)
1.一种纸塑水性胶的制作方法,其特征在于,所述方法包括下述步骤:
(1)按重量百分比取单体料丙烯酸乙酯22份、丙烯酸丁酯6份、丙烯酸羟乙酯5份、甲基丙烯酸甲酯12份、丙烯酸1份混合均匀;
(2)在反应釜中加入水底料离子水50份、丙烯酸0.6份、氢氧化钠0.07份、过硫酸铵0.1份、乳化剂OP-10为0.5份、邻苯二甲酸二丁酯3份、Ms-1为0.2份,搅拌升温到78℃左右,开始滴加混合单体;
(3)维持反应体系在84~87℃之间,混合单体大约40分钟滴完,期间将促进剂分3次加入到反应釜中;
(4)滴加完毕后,保温反应20分钟,降温到45℃以下,用氨水调PH到6.5-7.0,出料,测试。
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CN107840920A (zh) * | 2017-11-21 | 2018-03-27 | 江门新时代包装材料有限公司 | 一种水性丙烯酸压敏胶乳液及其制备方法 |
CN107815265A (zh) * | 2017-11-21 | 2018-03-20 | 江门新时代包装材料有限公司 | 一种超透明压敏胶粘带的制备方法及配方 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1135512A (zh) * | 1995-05-12 | 1996-11-13 | 四川联合大学 | 水乳液纸塑复合胶粘剂 |
CN1285382A (zh) * | 1999-08-23 | 2001-02-28 | 杭州富阳华源电热有限公司 | 复合交联型水性复膜胶粘剂的组成及制备方法 |
CN1554829A (zh) * | 2003-12-26 | 2004-12-15 | 李泽潜 | 干法无尘纸专用胶乳及其制备方法 |
CN101928534A (zh) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | 纸塑复合用单组份低温自交联乳液胶黏剂及其制备方法 |
-
2015
- 2015-12-29 CN CN201511004436.9A patent/CN105418834B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1135512A (zh) * | 1995-05-12 | 1996-11-13 | 四川联合大学 | 水乳液纸塑复合胶粘剂 |
CN1285382A (zh) * | 1999-08-23 | 2001-02-28 | 杭州富阳华源电热有限公司 | 复合交联型水性复膜胶粘剂的组成及制备方法 |
CN1554829A (zh) * | 2003-12-26 | 2004-12-15 | 李泽潜 | 干法无尘纸专用胶乳及其制备方法 |
CN101928534A (zh) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | 纸塑复合用单组份低温自交联乳液胶黏剂及其制备方法 |
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