CN105417535B - 一种通过拉伸制备石墨烯材料的方法 - Google Patents
一种通过拉伸制备石墨烯材料的方法 Download PDFInfo
- Publication number
- CN105417535B CN105417535B CN201511004655.7A CN201511004655A CN105417535B CN 105417535 B CN105417535 B CN 105417535B CN 201511004655 A CN201511004655 A CN 201511004655A CN 105417535 B CN105417535 B CN 105417535B
- Authority
- CN
- China
- Prior art keywords
- stretching
- graphite powder
- graphene
- prepared
- graphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 64
- 239000000463 material Substances 0.000 title claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 124
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 47
- 238000010008 shearing Methods 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 239000007767 bonding agent Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 47
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
- 239000012188 paraffin wax Substances 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 20
- 239000004831 Hot glue Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 150000001299 aldehydes Chemical class 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920003986 novolac Polymers 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 abstract description 45
- 239000010439 graphite Substances 0.000 abstract description 45
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 231100000719 pollutant Toxicity 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 description 12
- 239000010410 layer Substances 0.000 description 9
- 238000007711 solidification Methods 0.000 description 7
- 230000008023 solidification Effects 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000002096 quantum dot Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000005489 elastic deformation Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 230000005492 condensed matter physics Effects 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/32—Size or surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Landscapes
- Carbon And Carbon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511004655.7A CN105417535B (zh) | 2015-12-29 | 2015-12-29 | 一种通过拉伸制备石墨烯材料的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511004655.7A CN105417535B (zh) | 2015-12-29 | 2015-12-29 | 一种通过拉伸制备石墨烯材料的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105417535A CN105417535A (zh) | 2016-03-23 |
CN105417535B true CN105417535B (zh) | 2017-05-31 |
Family
ID=55496157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201511004655.7A Expired - Fee Related CN105417535B (zh) | 2015-12-29 | 2015-12-29 | 一种通过拉伸制备石墨烯材料的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105417535B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106365156B (zh) * | 2016-08-28 | 2018-07-06 | 桂林新艺制冷设备有限责任公司 | 一种制备石墨烯的方法 |
CN106947436B (zh) | 2017-05-10 | 2022-10-14 | 中国科学院宁波材料技术与工程研究所 | 一种热界面材料及其制备和应用 |
CN109273134B (zh) * | 2017-07-18 | 2021-08-13 | 新南创新私人有限公司 | 用石墨制备石墨烯和石墨烯复合导体 |
CN107858019A (zh) * | 2017-10-12 | 2018-03-30 | 桂林浩新科技服务有限公司 | 一种制备单片滑石粉的方法 |
CN108793149B (zh) * | 2018-07-26 | 2020-05-12 | 杭州高烯科技有限公司 | 一种增强氧化石墨烯膜的方法及一种高强石墨烯膜的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675806A (zh) * | 2012-06-11 | 2012-09-19 | 合肥博发新材料科技有限公司 | 一种pp/膨胀石墨导热复合材料及其制备方法 |
CN103180244A (zh) * | 2010-10-28 | 2013-06-26 | 英派尔科技开发有限公司 | 石墨烯通过多层共挤出的剥离 |
CN104884243A (zh) * | 2012-10-19 | 2015-09-02 | 新泽西鲁特格斯州立大学 | 制备石墨烯补强的聚合物基质复合材料的原位剥离法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1396193B1 (it) * | 2009-10-07 | 2012-11-16 | Polimeri Europa Spa | Composizioni polimeriche nanocomposite termoplastiche espansibili con migliorata capacita' di isolamento termico. |
-
2015
- 2015-12-29 CN CN201511004655.7A patent/CN105417535B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103180244A (zh) * | 2010-10-28 | 2013-06-26 | 英派尔科技开发有限公司 | 石墨烯通过多层共挤出的剥离 |
CN102675806A (zh) * | 2012-06-11 | 2012-09-19 | 合肥博发新材料科技有限公司 | 一种pp/膨胀石墨导热复合材料及其制备方法 |
CN104884243A (zh) * | 2012-10-19 | 2015-09-02 | 新泽西鲁特格斯州立大学 | 制备石墨烯补强的聚合物基质复合材料的原位剥离法 |
Also Published As
Publication number | Publication date |
---|---|
CN105417535A (zh) | 2016-03-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105417535B (zh) | 一种通过拉伸制备石墨烯材料的方法 | |
CN103282306B (zh) | 转移石墨烯膜的方法和制造透明导电膜的方法 | |
CN103253659B (zh) | 一种超声波剥离石墨制备石墨烯的方法 | |
CN106189088B (zh) | 一种碳纳米管-氧化石墨烯混杂增强复合材料的制备方法 | |
CN102993756B (zh) | 一种低密度聚合物改性沥青防水卷材 | |
CN102732037B (zh) | 石墨烯泡沫∕聚合物高导电复合材料及其制备方法和应用 | |
Sumdani et al. | Recent advances of the graphite exfoliation processes and structural modification of graphene: a review | |
CN102530933B (zh) | 以乳化沥青作粘结剂的人造石墨制品及其制备方法 | |
CN102753476A (zh) | 碳纳米管片材及其制造方法 | |
Xu et al. | Flexible supercapacitor electrode based on lignosulfonate-derived graphene quantum dots/graphene hydrogel | |
CN101121791A (zh) | 碳纳米管/聚合物复合材料的制备方法 | |
FR2893947A1 (fr) | Composition pulverulente de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres. | |
CN106744900A (zh) | 一种高分散性石墨烯的制备方法 | |
JP2010189597A5 (zh) | ||
CN106744870A (zh) | 一种用于浆体研磨剥离石墨烯的研磨介质 | |
CN103951916A (zh) | 一种rgo/氧化铁填充的聚偏氟乙烯复合吸波材料及其制备方法 | |
CN108529679A (zh) | 一种通过多元醇剥离制备二硫化钼纳米片的方法 | |
He et al. | Electrochemically modified graphite for fast preparation of large-sized graphene oxide | |
CN104291330A (zh) | 一种改性功能化石墨烯纳米材料的制备方法 | |
CN111170864A (zh) | 石墨烯分散剂及其制备方法、石墨烯的制备方法 | |
CN111003702B (zh) | 一种由石墨烯纳米片组成的二维层流矩阵碳材料及其制备方法 | |
CN104231295A (zh) | 一种石墨烯预浸料的制备方法 | |
CN105502357B (zh) | 一种机械剥离制备石墨烯专用剥离剂及制备方法 | |
CN106365156B (zh) | 一种制备石墨烯的方法 | |
CN108587664A (zh) | 一种细镶嵌结构中间相沥青及其制备方法和其在高强高密石墨材料中的应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Wei Ying Inventor before: Chen Qing Inventor before: Zeng Juntang Inventor before: Ye Renhai Inventor before: Chen Bing |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180111 Address after: No. 28, building No. 28, No. 1, Xinhua Street, Xincheng, Hohhot City, the Inner Mongolia Autonomous Region, No. 14 Patentee after: Wei Ying Address before: Qingyang District of Chengdu City, Sichuan province 610091 Dragon Industrial Port East Road 4 Patentee before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170531 Termination date: 20201229 |