CN105415790A - 快速反应粘强力交叉膜自粘防水卷材及其制备工艺 - Google Patents

快速反应粘强力交叉膜自粘防水卷材及其制备工艺 Download PDF

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CN105415790A
CN105415790A CN201510877900.9A CN201510877900A CN105415790A CN 105415790 A CN105415790 A CN 105415790A CN 201510877900 A CN201510877900 A CN 201510877900A CN 105415790 A CN105415790 A CN 105415790A
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邓海军
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Deng Haijun
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Tianjin Zhonghai Huana Science And Technology Development Co Ltd
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Abstract

本发明公开了快速反应粘强力交叉膜自粘防水卷材，自上而下依次包括上覆面层、反应型湿铺自粘胶质层和下覆面层，所述上覆面层的周围边缘设有搭接边即边膜；所述上覆面层为强力交叉叠压聚乙烯膜，所述强力交叉叠压聚乙烯膜是由两层高密度聚乙烯膜45°交叉复合热压形成；所述搭接边为涂硅隔离膜，所述下覆面层也采用涂硅隔离膜，所述涂硅隔离膜为聚对苯二甲酸乙二醇酯涂硅隔离膜；本发明的优点在于：提高了防水卷材的寿命且施工更加方便，具有优异的尺寸稳定性，耐候性，抗紫外线性能和双向耐撕裂性能，粘接牢固，不串水；有良好的“自愈能力”，可使局部受穿刺点自行愈合。

Description

快速反应粘强力交叉膜自粘防水卷材及其制备工艺
技术领域
本发明涉及一种自粘防水卷材，具体地说是一种CMS快速反应粘强力交叉膜自粘防水卷材及其制备工艺，属于自粘防水卷材领域。
背景技术
目前我国建筑工程及各类基础设施建设工程中常见的防水材料主要有涂料类和卷材类。防水涂料存在施工厚度不易控制;与基面牢固结合，易受基面裂缝影响产生伸缩开裂;大部分涂料不易在长期受水浸的环境中使用，也不易在阳光暴露的地方使用;施工时要多次涂刷，施工周期长，在施工过程中易产生溶剂，污染环境。而卷材类的防水材料使用过程中最大的障碍是与基面的粘结问题，现在市场上的自粘防水卷材价格昂贵，性能较好的高分子防水卷材是通过涂胶与基面粘结，胶黏剂的使用寿命较短，造成卷材与基面粘结失效产生串水、漏水等现象。并且，在普通的防水工程中，一般采用薄型(0.14mm厚)的高密度聚乙烯(HDPE)膜作为上覆面材料，该类HDPE膜延伸性能优异（≥450%），但其抗拉强度较小（只有130N/5cm左右），而且横纵向拉力不均匀，若在高速铁路、地铁、洞体隧道等要求高的防水防渗工程当中，HDPE膜就不能满足其要求。而若使用高分子片材作为防水层，其施工方式是在干燥基面上用热空气焊接方法，防水材料和基面是点粘，如果出现防水层破损，就会出现整个防水层窜水，容易出现安全事故和质量事故。因此，需对现有自粘卷材的覆面材料进行改进以满足市场的需求。
发明内容
为了解决上述问题，本发明设计了一种快速反应粘强力交叉膜自粘防水卷材及其制备工艺，改善了防水施工时卷材本身搭接边无强度或加设增强层延伸率小导致的渗漏问题，提高了防水卷材的寿命且施工更加方便，解决了普通覆面材料纵横向拉力不均匀的问题，具有优异的尺寸稳定性，耐候性，抗紫外线性能和双向耐撕裂性能，解决了卷材与基面的粘结问题并且粘接牢固，不串水；层有良好的“自愈能力”，可使局部受穿刺点自行愈合。
本发明的技术方案为：
快速反应粘强力交叉膜自粘防水卷材，所述防水卷材自上而下依次包括上覆面层、反应型湿铺自粘胶质层和下覆面层，所述上覆面层的周围边缘设有搭接边即边膜；所述上覆面层为强力交叉叠压聚乙烯膜，所述强力交叉叠压聚乙烯膜是由两层高密度聚乙烯膜45°交叉复合热压形成；所述搭接边为涂硅隔离膜，所述下覆面层也采用涂硅隔离膜，所述涂硅隔离膜为聚对苯二甲酸乙二醇酯（PET）涂硅隔离膜。
所述反应型湿铺自粘胶质层由以下重量份的原料制成：
100号沥青42-52份、粉末丁苯橡胶（SBR）9-14份、碳9树脂8-10份、软化剂基础油12-14份、滑石粉10-20份、添加剂丁基橡胶10-28份。
所述反应型湿铺自粘胶质层的制备方法，包括以下步骤：
（1）向搅拌罐中加入100#沥青，升温至160±5℃，加入软化剂基础油；
（2）待温度升至180±5℃时加入SBR胶，搅拌1.5～2小时，温度控制在185～200℃，待溶化后，边搅拌边用胶体磨研磨1.5小时，至充分混匀时加入碳9树脂，继续搅拌0.5小时；
（3）当配料罐降温至155～160℃时，将碳9树脂打入配料罐;
（4）用导热油加热使温度升到175～180℃时，兑入滑石粉和添加剂丁基橡胶，搅拌25～35分钟，搅拌充分后进行降温，在温度降至150±5℃时，即制得自粘胶质层。
上述快速反应粘强力交叉膜自粘防水卷材的制备工艺，包括以下步骤：
1.制备反应型湿铺自粘胶质层
2.上覆面层即强力交叉膜、边膜、下覆面层即隔离膜装入放卷架上，展开膜；
3.将步骤1制备的150±5℃的反应型湿铺自粘胶质层防水材料均匀的涂布于上、下覆面层之间，调整夹辊间的距离为1.2-2.0mm，并冷却至温度为105-115℃，即得到本发明防水卷材；
4.经干燥、卷曲、包装，入库。
本发明的优点在于：与现有技术相比，不仅具有传统高分子自粘卷材所具有的优异性能，还具有以下优点:
（1）该发明在卷材的强力交叉膜面层设置了搭接边改性沥青粘接层，改善了防水施工时卷材本身搭接边无强度或加设增强层延伸率小导致的渗漏问题，提高了防水卷材的寿命且施工更加方便；
（2）其上覆面层采用强力交叉叠压聚乙烯膜，解决了普通覆面材料纵横向拉力不均匀的问题，具有优异的尺寸稳定性，耐候性，抗紫外线性能和双向耐撕裂性能；
（3）反应型湿铺自粘胶质层能与混凝土基层快速结合有优异的自愈性能和局部自锁水性能，该胶料中的高分子聚合物与水泥水化物形成互穿网络结构，解决了卷材与基面的粘结问题并且粘接牢固，不串水；
（4）自粘层有良好的“自愈能力”，可使局部受穿刺点自行愈合；
（5）该发明对施工环境有良好的适应性，潮湿基层可施工，无需底涂、溶剂、燃料，一定程度上避免了环境污染；便于检修，即使出现个别渗漏，也不会出现串流现象，渗漏点与破坏点一致；能适应大幅气候变化，在异形部位也能形成良好的黏贴，不会出现空鼓现象。
下面结合附图和实施例对本发明作进一步说明。
附图说明
图1为本发明实施例的结构示意图；
图2为本发明实施例自粘胶质层的制备工艺流程图；
图3为本发明实施例自粘防水卷材的制备工艺流程图。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
除非另有说明，本发明中所采用的百分数均为重量百分数。
实施例1
如图1所示，一种快速反应粘强力交叉膜自粘防水卷材，所述防水卷材自上而下依次包括上覆面层1、反应型湿铺自粘胶质层3和下覆面层4，所述上覆面层的周围边缘设有搭接边即边膜2；所述上覆面层为强力交叉叠压聚乙烯膜，所述强力交叉叠压聚乙烯膜是由两层高密度聚乙烯膜45°交叉复合热压形成；所述搭接边为涂硅隔离膜，所述下覆面层也采用涂硅隔离膜，所述涂硅隔离膜为聚对苯二甲酸乙二醇酯（PET）涂硅隔离膜。
所述反应型湿铺自粘胶质层由以下重量份的原料制成：
100号沥青42-52份、粉末丁苯橡胶（SBR）9-14份、碳9树脂8-10份、软化剂基础油12-14份、滑石粉10-20份、添加剂丁基橡胶10-28份。
如图2所示，所述反应型湿铺自粘胶质层的制备方法，包括以下步骤：
（1）向搅拌罐中加入100#沥青，升温至160±5℃，加入软化剂基础油；
（2）待温度升至180±5℃时加入SBR胶，搅拌1.5～2小时，温度控制在185～200℃，待溶化后，边搅拌边用胶体磨研磨1.5小时，至充分混匀时加入碳9树脂，继续搅拌0.5小时；
（3）当配料罐降温至155～160℃时，将碳9树脂打入配料罐;
（4）用导热油加热使温度升到175～180℃时，兑入滑石粉和添加剂丁基橡胶，搅拌25～35分钟，搅拌充分后进行降温，在温度降至150±5℃时，即制得自粘胶质层。
如图3所示，上述快速反应粘强力交叉膜自粘防水卷材的制备工艺，包括开膜、涂油、冷却、覆膜、卷曲和包装、入库，具体包括以下步骤：
1.制备反应型湿铺自粘胶质层
2.上覆面层即强力交叉膜、边膜、下覆面层即隔离膜装入放卷架上，展开膜；
3.将步骤1制备的150±5℃的反应型湿铺自粘胶质层防水材料均匀的涂布于上、下覆面层之间，调整夹辊间的距离为1.2-2.0mm，并冷却至温度为105-115℃，即得到本发明防水卷材；
4.经干燥、卷曲、包装，入库。
本发明中所用原料均为本领域生产中常用原料，均可从市场中得到，且对于生产结果不会产生影响；本发明中所采用的各种设备，均为本领域生产工艺中使用的常规设备，且各设备的操作、参数等均按照常规操作进行，并无特别之处。

Claims (6)

1.快速反应粘强力交叉膜自粘防水卷材，其特征在于：所述防水卷材自上而下依次包括上覆面层、反应型湿铺自粘胶质层和下覆面层，所述上覆面层的周围边缘设有搭接边即边膜；所述上覆面层为强力交叉叠压聚乙烯膜，所述强力交叉叠压聚乙烯膜是由两层高密度聚乙烯膜45°交叉复合热压形成；所述搭接边为涂硅隔离膜，所述下覆面层也采用涂硅隔离膜，所述涂硅隔离膜为聚对苯二甲酸乙二醇酯涂硅隔离膜。
2.根据权利要求1所述的快速反应粘强力交叉膜自粘防水卷材，其特征在于：所述反应型湿铺自粘胶质层由以下重量份的原料制成：
100号沥青42-52份、粉末丁苯橡胶9-14份、碳9树脂8-10份、软化剂基础油12-14份、滑石粉10-20份、添加剂丁基橡胶10-28份。
3.根据权利要求1或2所述的快速反应粘强力交叉膜自粘防水卷材，其特征在于，所述反应型湿铺自粘胶质层的制备方法，包括以下步骤：
（1）向搅拌罐中加入100#沥青，升温至160±5℃，加入软化剂基础油；
（2）待温度升至180±5℃时加入SBR胶，搅拌1.5～2小时，温度控制在185～200℃，待溶化后，边搅拌边用胶体磨研磨1.5小时，至充分混匀时加入碳9树脂，继续搅拌0.5小时；
（3）当配料罐降温至155～160℃时，将碳9树脂打入配料罐;
（4）用导热油加热使温度升到175～180℃时，兑入滑石粉和添加剂丁基橡胶，搅拌25～35分钟，搅拌充分后进行降温，在温度降至150±5℃时，即制得自粘胶质层。
4.一种如权利要求1-3任意一项所述快速反应粘强力交叉膜自粘防水卷材的制备工艺，其特征在于，包括以下步骤：
（1）制备反应型湿铺自粘胶质层；
（2）上覆面层即强力交叉膜、边膜、下覆面层即隔离膜装入放卷架上，展开膜；
（3）将步骤1制备的150±5℃的反应型湿铺自粘胶质层防水材料均匀的涂布于上、下覆面层之间，调整夹辊间的距离为1.2-2.0mm，并冷却至温度为105-115℃，即得到本发明防水卷材；
（4）经干燥、卷曲、包装，入库。
5.根据权利要求1所述的制备工艺，其特征在于：所述反应型湿铺自粘胶质层由以下重量份的原料制成：
100号沥青42-52份、粉末丁苯橡胶9-14份、碳9树脂8-10份、软化剂基础油12-14份、滑石粉10-20份、添加剂丁基橡胶10-28份。
6.根据权利要求4或5所述的制备工艺，其特征在于：所述反应型湿铺自粘胶质层的制备方法，包括以下步骤：
（1）向搅拌罐中加入100#沥青，升温至160±5℃，加入软化剂基础油；
（2）待温度升至180±5℃时加入SBR胶，搅拌1.5～2小时，温度控制在185～200℃，待溶化后，边搅拌边用胶体磨研磨1.5小时，至充分混匀时加入碳9树脂，继续搅拌0.5小时；
（3）当配料罐降温至155～160℃时，将碳9树脂打入配料罐;
（4）用导热油加热使温度升到175～180℃时，兑入滑石粉和添加剂丁基橡胶，搅拌25～35分钟，搅拌充分后进行降温，在温度降至150±5℃时，即制得自粘胶质层。
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CN117445509A (zh) * 2023-05-24 2024-01-26 沧州兆阳纸塑包装有限公司 多层多角度强力交叉膜
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CN106273884A (zh) * 2016-08-08 2017-01-04 吉林市欧创实业有限公司 一种基因融合反应粘结型湿铺防水卷材及其施工方法
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