CN105409968A - Water-soluble trichloroisocyanuric acid smoking disinfectant - Google Patents
Water-soluble trichloroisocyanuric acid smoking disinfectant Download PDFInfo
- Publication number
- CN105409968A CN105409968A CN201510975399.XA CN201510975399A CN105409968A CN 105409968 A CN105409968 A CN 105409968A CN 201510975399 A CN201510975399 A CN 201510975399A CN 105409968 A CN105409968 A CN 105409968A
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- China
- Prior art keywords
- disinfectant
- water
- closene
- sym
- soluble
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
Abstract
The invention relates to a formula and a preparation method for a water-soluble trichloroisocyanuric acid smoking disinfectant. The disinfectant comprises the following components by weight: 30 to 80 parts of trichloroisocyanuric acid, 20 to 40 parts of glucose, 5 to 15 parts of ammonium chloride and 5 to 30 parts of anhydrous sodium sulfate. The preparation method comprises the following steps: subjecting glucose and anhydrous sodium sulfate to mixing and crushing, and carrying out screening with a 200-mesh spin-vibrating sieve for subsequent usage; and mixing trichloroisocyanuric acid and ammonium chloride, carrying out screening with a 80-mesh spin-vibrating sieve, pouring obtained mixed powder into a stirring mixer and then carrying out uniform mixing, carrying out subpackaging with polyethylene plastic bags, and carrying out sealing so as to obtain the disinfectant. The disinfectant can be dissolved by adding water for sprinkling, spraying and drinking water disinfection, also can be ignited to form smoke for fumigation disinfection, and has the characteristics of safety, convenience, high efficiency, etc.
Description
Technical field
The invention belongs to disinfectant to manufacture and application, relate to a kind of formula and preparation method of chlorine-containing disinfectant, especially relate to a kind of fumigation, the formula of water-soluble dual-purpose type trichloro-isocyanuric acid disinfectant and preparation method.
Background technology
Sym-closene belongs to halogen disinfectant, has killing action to bacterium, fungi, gemma, virus etc., has the features such as efficient, wide spectrum, low toxicity.With conventional halogen class disinfectant as compared with bleaching powder, toluene-sodium-sulfonchloramide, sym-closene has that available chlorine content is high, stable in properties, Disinfection Effect are good, is thus widely used in the sterilizations such as environment, drinking-water, poultry house, fish pond.When carrying out poultry house sterilization, also develop the formulation that Smudging sterilizing uses in recent years.This formulation is mixed with combustion adjuvant, fuel, fire retardant etc. by sym-closene, and the heat energy that when lighting, fuel and combustion adjuvant produce passes to sym-closene, makes it evaporation gasification rapidly and form aerosol.The smoke particles energy long period is suspended in air, is full of each corner, hole, gap, is evenly attached on object and plays Disinfection Effect.Thus, this formulation is specially adapted to larger space (as feeding chicken in largely scale booth) needs to kill efficiently, fast the place of cause of disease, and medication economy, and power consumption is few, and labour intensity is low, thus be a kind of economical, to sterilize means efficiently.
At present, be that the Hypatmism type disinfectant of active ingredient remains in some problems in factory formula and technique with sym-closene.1. owing to needing to add carbon dust, wood dust, grass meal, starch etc. as incendiary agent in formula, so the formulation that this kind of formula is produced can not be used for environment and the disinfection of drinking water of molten water.Although 2. add fire retardant, still more than 300 DEG C are reached as fuel temperature when burning using carbon dust etc., at this temperature, part sym-closene (fusing point 225-230 DEG C) can decompose pernicious gases such as producing agene, and the detonation of local easily occurs.3. in order to make the product of preparation easily be lighted, often need in formula to add the combustion adjuvants such as potassium chlorate, potassium nitrate, ammonium nitrate to reduce its burning-point.But it is like this then increase the risk of product spontaneous combustion in storage and transport process.
Summary of the invention:
In view of the deficiencies in the prior art, a kind of fumigation of safety and stability molten water dual-purpose type trichloro-isocyanuric acid disinfectant is the object of the present invention is to provide to fill a prescription and preparation method thereof.
For solving the problem existing for background technology, present invention employs following technical scheme:
Stable fumigation molten water dual-purpose type trichloro-isocyanuric acid disinfectant and a preparing process thereof, is characterized in that, comprises following component by weight proportion: sym-closene 30-80 part, glucose 20-40 part, ammonium chloride 5-15 part, anhydrous sodium sulfate 5-30 part.
Preferably, a kind of stable fumigation molten water dual-purpose type trichloro-isocyanuric acid disinfectant and preparing process thereof, is characterized in that, comprise following component by weight proportion: sym-closene 40-70 part, glucose 30-40 part, ammonium chloride 5-10 part, anhydrous sodium sulfate 10-20 part.
The step of above-mentioned formula trichloro-isocyanuric acid disinfectant preparation method is as follows: 1. by glucose and anhydrous sodium sulfate co-grinding, crosses 200 order spin vibration sieves, for subsequent use.2. sym-closene mixes with ammonium chloride, crosses 80 order spin vibration sieves, for subsequent use.3. by the mixed powder that 2. 1. step obtain with step, jointly put into mixer, be uniformly mixed, be sub-packed in polyethylene plastic bag, seal and get final product.
Compared with prior art, advantage of the present invention and beneficial effect are, 1. the equal water soluble of used supplementary material, both can directly light plastic packaging bag and use as fumigation during use, also can carry out environment disinfected after thin up.2. using glucose as filler, utilizing glucose to be oxidized by oxygen produced carbonic acid gas and steam makes sym-closene form aerosol, and add ammonium chloride as smoke agent and cooling agent, anhydrous sodium sulfate is as fire retardant, make on the one hand to be fuming rapider, on the other hand local temperature is reduced, avoid the decomposition of active ingredient.3. for the ease of lighting, be less than 200 orders by pulverizing, technology controlling and process of sieving glucose granularity, greatly increase the surface area of dextran particles, make it easily under sym-closene oxidizing catalytic, free reaction with oxygen, just can continue to be fuming once ignite, until be gasified totally.In a word, instant invention overcomes the deficiencies in the prior art, simple and easy to do, be applicable to suitability for industrialized production, the product produced by the method, observe through stability test, indices all meets the requirement of Chinese veterinary pharmacopoeia statutory standards.
Embodiment
Be below specific embodiments of the invention, technical scheme of the present invention is described further, but protection scope of the present invention is not limited to these embodiments.Every do not deviate from the present invention's design change or equivalent substituting include within protection scope of the present invention.
Embodiment 1
Supplementary material composition and ratio:
60 parts, sym-closene powder, glucose 25 parts, ammonium chloride 5 parts, anhydrous sodium sulfate 10 parts.Technology point: glucose and anhydrous sodium sulfate co-grinding, crosses 200 order spin vibration sieves, and it is for subsequent use that the fine powder obtained drops into blender; Sym-closene powder mixes with ammonium chloride, and cross 80 order spin vibration sieves, the fine powder obtained drops into aforementioned blender, always mixes, and after sampling Detection (by " Chinese veterinary pharmacopoeia " prescriptive procedure) is qualified, is sub-packed in 100g polyethylene plastic bag, obtains final product.
Embodiment 2
Supplementary material composition and ratio:
40 parts, sym-closene powder, glucose 35 parts, ammonium chloride 15 parts, anhydrous sodium sulfate 20 parts.Technology point: glucose and anhydrous sodium sulfate co-grinding, crosses 200 order spin vibration sieves, and it is for subsequent use that the fine powder obtained drops into blender; Sym-closene powder mixes with ammonium chloride, and cross 80 order spin vibration sieves, the fine powder obtained drops into aforementioned blender, always mixes, and after sampling Detection (by " Chinese veterinary pharmacopoeia " prescriptive procedure) is qualified, is sub-packed in 200g polyethylene plastic bag, obtains final product.
Embodiment 3
In order to investigate the performance of prepared sym-closene powder disinfectant, have detected its burning-point and be fuming, solubility property.
Materials and methods
Trichloro-isocyanuric acid disinfectant, as the preparation of embodiment 1 method.
Whether dissolubility is tested: take 1g sample, put 250ml triangular flask, add 100ml purified water, jolting, observe and dissolve completely.
Burning point test: the disinfectant sample getting preparation is appropriate, and divide in plane ware, thickness is about 1cm, and places high temperature thermometer to measure real time temperature.In fume hood, plane ware good for device is placed in oil bath and improves temperature gradually, observe the temperature that sample starts to smolder and burn.
Smoke test: in the relatively airtight vacant room of volume about 50 cubic metres, the disinfectant sample of 100g preparation is placed on ground, cuts off one jiao, polyethylene packaging bag, lights with match.Observe from be fuming to being fuming the end time, and whether be full of smog from observing each corner outside window.
Result of the test and conclusion
Dissolubility test result: after the sample of preparation adds purified water, jolting gently, namely disperses, dissolves; Further thin up, solution keeps clear state, shows, this sample can meet molten water sterilization and use.
Burning point test result: after temperature rises to 75 DEG C, starts a small amount of spray of overflowing; 80 DEG C of effusion volume spray; When 120 DEG C, spontaneous combustion of being fuming rapidly.Result of the test shows, the smoking disinfectant burning-point prepared by the present invention is higher than the common kind in market (temperature of being fuming is generally lower than 45 DEG C).According to the requirement of " Chinese veterinary pharmacopoeia " relevant criterion, halogen disinfectant General Requirements is preserved in the cool (generally not higher than 20 DEG C), and therefore this preparation is safe in storage link.
Smoke test result: when lighting polyethylene plastic bag, originally visible naked light slightly, and cause rapidly disinfectant to be fuming; Disinfectant once being fuming, and is accelerated rapidly, and puts out packaging bag naked light.This may be relevant with the carbonic acid gas produced when being fuming.100g disinfectant from be fuming to end, be generally no more than 75 seconds.From observing outside window, in 120 seconds, smog can fill the air whole room.During strong illumination, can be observed obvious light path (Tyndall phenomenon), illustrate and define more homogeneous aerosol.
Claims (5)
1. a water-soluble sym-closene smoking disinfectant, is characterized in that, this disinfectant is prepared from by following component by weight proportion: sym-closene 30-80 part, glucose 20-40 part, ammonium chloride 5-15 part, anhydrous sodium sulfate 5-30 part.
2. the water-soluble sym-closene smoking disinfectant of one according to claim 1, it is characterized in that, this disinfectant is prepared from by following component by weight proportion: sym-closene 40-70 part, glucose 30-40 part, ammonium chloride 5-10 part, anhydrous sodium sulfate 10-20 part.
3. the water-soluble sym-closene smoking disinfectant of the one according to any one of claim 1-2, it is characterized in that: by pulverizing and sieving technique, control sym-closene, ammonium chloride fineness respectively below 80 orders, glucose, anhydrous sodium sulfate fineness are below 200 orders.
4. the water-soluble sym-closene smoking disinfectant of the one according to any one of claim 1-2, is characterized in that: described supplementary material, through pulverizing and sieving, is sub-packed in polyethylene plastic bag after mixing and makes pulvis.
5. the water-soluble sym-closene smoking disinfectant of the one according to any one of claim 1-2, it is characterized in that: this disinfectant both water-solublely can be made into suitable concn and pass through dilution, sprinkling, spraying etc. for drinking-water, utensil and environment disinfected, also can carry out fumigation by lighting the mode of being fuming to booth space.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510975399.XA CN105409968A (en) | 2015-12-23 | 2015-12-23 | Water-soluble trichloroisocyanuric acid smoking disinfectant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510975399.XA CN105409968A (en) | 2015-12-23 | 2015-12-23 | Water-soluble trichloroisocyanuric acid smoking disinfectant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105409968A true CN105409968A (en) | 2016-03-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510975399.XA Pending CN105409968A (en) | 2015-12-23 | 2015-12-23 | Water-soluble trichloroisocyanuric acid smoking disinfectant |
Country Status (1)
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| CN (1) | CN105409968A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821402A (en) * | 2017-10-19 | 2018-03-23 | 鄄城康泰化工有限公司 | A kind of sym-closene aerosol disinfectant |
| CN112931514A (en) * | 2021-02-05 | 2021-06-11 | 广州迈高化学有限公司 | Organic chlorine compound disinfectant and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125042A (en) * | 1995-08-23 | 1996-06-26 | 山东鲁南化学工业集团公司滕州消毒剂厂 | Dual-purpose disinfectant of water and smoke |
| CN1260117A (en) * | 1999-09-15 | 2000-07-19 | 山东农业大学动物保健品厂 | Smoke and water dual-purpose disinfectant |
| CN101647445A (en) * | 2009-09-03 | 2010-02-17 | 胡少平 | Compound disinfectant containing chlorine |
| CN102835425A (en) * | 2011-06-21 | 2012-12-26 | 唐山宏基伟业生物工程有限公司 | Preparation method of fumigating agent |
| CN103875677A (en) * | 2014-04-14 | 2014-06-25 | 宋巍 | Water-soluble and smoking dual-use disinfectant |
| CN104970041A (en) * | 2015-07-20 | 2015-10-14 | 柳州蓓蒂芬科技有限公司 | Disinfector |
-
2015
- 2015-12-23 CN CN201510975399.XA patent/CN105409968A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125042A (en) * | 1995-08-23 | 1996-06-26 | 山东鲁南化学工业集团公司滕州消毒剂厂 | Dual-purpose disinfectant of water and smoke |
| CN1260117A (en) * | 1999-09-15 | 2000-07-19 | 山东农业大学动物保健品厂 | Smoke and water dual-purpose disinfectant |
| CN101647445A (en) * | 2009-09-03 | 2010-02-17 | 胡少平 | Compound disinfectant containing chlorine |
| CN102835425A (en) * | 2011-06-21 | 2012-12-26 | 唐山宏基伟业生物工程有限公司 | Preparation method of fumigating agent |
| CN103875677A (en) * | 2014-04-14 | 2014-06-25 | 宋巍 | Water-soluble and smoking dual-use disinfectant |
| CN104970041A (en) * | 2015-07-20 | 2015-10-14 | 柳州蓓蒂芬科技有限公司 | Disinfector |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821402A (en) * | 2017-10-19 | 2018-03-23 | 鄄城康泰化工有限公司 | A kind of sym-closene aerosol disinfectant |
| CN112931514A (en) * | 2021-02-05 | 2021-06-11 | 广州迈高化学有限公司 | Organic chlorine compound disinfectant and preparation method and application thereof |
| CN112931514B (en) * | 2021-02-05 | 2022-02-15 | 广州迈高化学有限公司 | Organic chlorine compound disinfectant and preparation method and application thereof |
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Application publication date: 20160323 |