KR20150093311A - Fumigation Smoking Composition For Controlling Disease And Method For Controlling Disease Using The Composition - Google Patents

Fumigation Smoking Composition For Controlling Disease And Method For Controlling Disease Using The Composition Download PDF

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KR20150093311A
KR20150093311A KR1020140013914A KR20140013914A KR20150093311A KR 20150093311 A KR20150093311 A KR 20150093311A KR 1020140013914 A KR1020140013914 A KR 1020140013914A KR 20140013914 A KR20140013914 A KR 20140013914A KR 20150093311 A KR20150093311 A KR 20150093311A
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South Korea
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chlorine dioxide
water
agent
smoke
oxidizing agent
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KR1020140013914A
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Korean (ko)
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한병건
이경우
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한병건
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Priority to KR1020140013914A priority Critical patent/KR20150093311A/en
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Priority to KR1020210053849A priority patent/KR20210071880A/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

Abstract

The present invention relates to a composition for a fumigation and smoking control agent and a control method using the composition. The method can safely use chlorine dioxide for controlling a house agricultural product, wherein the chlorine dioxide prevents plant damage caused when spraying existing chlorine dioxide, does not remain in an agricultural product, has low manufacturing costs, and is not harmful to a human body. The present invention fumigates a greenhouse space as the chlorine dioxide, evaporated by slowly heating the fumigation and smoking control agent, is spread in the greenhouse space. In addition, the large amount of smoke, absorbed with an adhesive and penetrating ingredient, and a chlorine dioxide ingredient are combined, and a smoking particle is produced, thereby exhibiting a strong control effect against a disease of the house agricultural product.

Description

훈증훈연 방제제 조성물 및 그 조성물을 이용한 방제방법{Fumigation Smoking Composition For Controlling Disease And Method For Controlling Disease Using The Composition}FIELD OF THE INVENTION [0001] The present invention relates to a fumigation inhibitor composition and a control method using the same,

본 발명은 훈증훈연 방제제 조성물 및 그 조성물을 이용한 방제방법에 관한 것으로, 더욱 상세하게는 이산화염소를 유효성분으로 포함하여 제조된 훈증훈연제 조성물을 이용하여 밀폐 가능한 장소로서 하우스 농작물의 병해 방제와 건물 소독용으로 사용할 수 있는 훈증훈연 방제제 조성물 및 그 조성물을 이용한 방제방법에 관한 것이다.
The present invention relates to a composition for fumigant smoke suppressant and a method for controlling the same using the composition, and more particularly, to a method for controlling harmfulness of a house crop and a building using a fumigant smoke composition prepared by containing chlorine dioxide as an active ingredient, The present invention relates to a fumigation inhibitor composition for fumigation which can be used for disinfection and a method of controlling the composition.

일반적으로 온실에서 주로 사용하는 분무식 살포방법은 농약에 다량의 물을 섞어 희석하고 분무입자를 크게(300㎛) 하여 병해충에 직접 살포하는 방식이다. 이러한 분무식 농약 살포 방법은 주로 노지(논, 밭, 과수원 등)에서 사용해 오던 살포방법이다. Generally, spray spraying method which is mainly used in a greenhouse is a method in which a large amount of water is mixed with pesticides to dilute the sprayed particles, and the spray particles are largely sprayed (300 μm) onto pests. This spraying method of spraying pesticides is a spraying method that has been mainly used in a field (rice field, field, orchard, etc.).

노지에서의 농약 살포는 분무입자를 크게 하여 살포할 수 밖에 없는데, 이는 분무입자가 작으면 공중으로 쉽게 퍼져나가 방제 대상지역이 아닌 장소로 이동하여 피해를 줄 수 있기 때문이다. 온실은 노지와는 달리 밀폐 가능한 공간으로서 분무식 살포방법은 적합하지 못하다.Spraying of pesticides in the paddy field can only be carried out by spraying particles with a large size, because if the spray particles are small, they can easily spread to the air and move to a place other than the area to be controlled. Unlike the greenhouse, the greenhouse is a sealable space and spraying method is not suitable.

또한 분무식 농약 살포방법은 자동방제가 어려워 작업자가 농약을 직접 작물에 살포해야 하므로 살포시 독성 성분의 농약에 작업자가 그대로 노출되어 농약 중독의 위험성이 크고 작업 시간도 많이 소요될 뿐만 아니라 농작물에 균일하게 살포되지 못하는 문제점도 있다.In addition, since spraying method of spraying pesticide is difficult to automatic control, workers need to spray pesticide directly on the crops. Therefore, the risk of poisoning of the pesticide is high and the worker is exposed to the poisonous pesticide, There is also a problem that can not be.

인력 의존형 그리고 농약 살포자의 농약중독 위험성에 따른 문제를 해결하기 위하여 온실에 일정 간격으로 수십 내지 수백 개의 노즐을 설치하고 고압펌프를 이용하여 다량의 물에 희석된 농약을 높은 압력으로 가압한 후 연결 파이프를 통하여 노즐로 공급하여 분무하는 연무식 농약 살포방법이 개발되어 사용되고 있다. In order to solve the problem caused by the pesticide poisoning risk of the pesticide sprayer, it is necessary to install several tens to several hundred nozzles at regular intervals in the greenhouse, press the pesticide diluted in a large amount of water with high pressure by using the high pressure pump, The spraying method of spraying the pesticide with the spraying agent is developed and used.

이러한 살포 방식은 자동살포가 가능하여 노동력을 줄이고 농약 중독의 위험성을 줄일 수 있으나 설치 비용이 많이 들고 다량으로 사용되는 물의 특성 즉 높은 휘발성과 낮은 침투성으로 인해 방제효과가 매우 낮기 때문에 보편적으로 사용되지 않고 있다.Such a spraying method can reduce the labor force and reduce the risk of poisoning of pesticides by enabling automatic spraying, but it is not universally used because it has a very low control effect due to high installation cost and high water volatility and low permeability have.

이산화염소는 휘발성이 강하며 열과 자외선에 의해 쉽게 분해하며 강력한 산화와 표백 작용을 가지고 있는데, 이러한 특성을 고려하여 종래에는 이산화염소가 유독성 무기물 제거, 중금속 제거, 살균 및 소독, 의류표백, 악취제거 등 다양한 용도로 사용되고 있다. 그러나, 이산화염소가 강력한 살균, 살박테리아, 살바이러스 등 각종 병해에 방제효과가 뛰어나고 인체에 해롭지 않은 물질임에도 이산화염소를 살포하면 활성도가 매우 높고 쉽게 분해하는 제약요건으로 인하여 식물에 쉽게 약해를 발생시켜 농작물의 방제용으로는 사용되지 못함에 따라 농업 분야에서는 토양 소독, 용기 소독, 관주용 물의 소독과 같이 이산화염소가 제한적으로만 사용되었다.
Considering these characteristics, chlorine dioxide has been widely used for removing toxic minerals, removing heavy metals, disinfection and disinfection, bleaching clothes, deodorizing, etc. In the past, chlorine dioxide has a high volatility and is easily decomposed by heat and ultraviolet rays. It is used for various purposes. However, since chlorine dioxide is highly effective in controlling various diseases such as sterilization, live bacteria, deadly virus and the like, it is not harmful to human body. However, when chlorine dioxide is sprayed, its activity is very high. As it is not used for controlling crops, chlorine dioxide was only used in the agricultural sector, such as disinfection of soil, disinfection of containers, and disinfection of water for communal use.

한국공개특허 제10-2002-0055488호(2002.07.09. 공개)Korean Patent Laid-Open No. 10-2002-0055488 (published on July 9, 2002)

없음none

본 발명의 일 측면은 종래의 이산화염소를 분무식으로 살포시 발생하는 식물 약해를 방지하고, 농작물에 잔류하지 않으며 제조 비용이 낮고 인체에 유해하지 않은 이산화염소를 하우스 농작물의 방제용 또는 건물 소독용으로 안전하게 사용하는 것이다.One aspect of the present invention is to provide a method of preventing plant phytotoxicity that occurs when conventional chlorine dioxide is sprayed by spraying and to remove chlorine dioxide which is not left on crops and has low manufacturing cost and is not harmful to the human body, It is safe to use.

본 발명의 다른 측면은 훈증훈연 방제제를 서서히 가열하여 증발되는 이산화염소가 온실 공간에 확산되어 훈증 처리하고, 부착성 및 침투성 성분을 흡수한 다량의 연기와 이산화염소 성분이 결합하여 훈연 입자를 발생시킴으로써 하우스 농작물의 병해에 강력한 방제효과를 발휘하는 것이다.
Another aspect of the present invention is that the fuming agent is gradually heated to evaporate chlorine dioxide diffused in the greenhouse space to fumigate, and a large amount of smoke and chlorine dioxide components absorbing the adhesive and permeable components are combined to generate fumed particles It is a powerful control effect against the disease of house crops.

이와 같은 본 발명의 실시예에 따른 훈증훈연 방제제 조성물은, 산화제와 발연제와 연소속도 조절제를 증류수로 용해시킨 다음 이산화염소를 혼합하여 제조한다.The fumigant anti-fogging agent composition according to an embodiment of the present invention is prepared by dissolving an oxidizing agent, a fumigant, and a combustion rate regulator with distilled water, followed by mixing chlorine dioxide.

상기 이산화염소는 일정한 농도의 액상 또는 수용성이며 분말 상태로 사용한다.The chlorine dioxide is used at a constant concentration in a liquid state or in a water-soluble, powdery state.

상기 산화제가 물에 용해도가 높고 상기 이산화염소와 반응하지 않으며 저온에서 분해되어 산소를 발생함으로써 상기 발연제의 연소를 촉진시킬 수 있는 유기화합물 또는 무기화합물이다.The oxidizing agent is an organic compound or an inorganic compound which has high solubility in water and does not react with the chlorine dioxide and decomposes at a low temperature to generate oxygen to promote combustion of the fuming agent.

상기 산화제가 물에 용해도가 높은 염소산나트륨, 아염소산나트륨, 과염소산 나트륨, 질산나트륨, 및 아질산나트륨으로 이루어진 군에서 선택된다.The oxidizing agent is selected from the group consisting of sodium chlorate, sodium chlorite, sodium perchlorate, sodium nitrate, and sodium nitrite, which are highly soluble in water.

상기 산화제가 물에 용해도가 높은 염소산염, 아염소산염, 및 과염소산염으로 이루어진 군에서 선택된다.The oxidizing agent is selected from the group consisting of chlorate, chlorite, and perchlorate having high solubility in water.

상기 발연제가 상기 이산화염소를 안정화시키고 물에 용해도가 높은 단당류, 이당류, 및 다당류로 이루어진 군으로부터 선택된다.Wherein the fogging agent is selected from the group consisting of monosaccharides, disaccharides, and polysaccharides which stabilize the chlorine dioxide and are highly soluble in water.

상기 발연제가 상기 이산화염소를 안정화시키고 물에 용해도가 높은 솔비톨이다.The fogging agent is a sorbitol which stabilizes the chlorine dioxide and has high solubility in water.

상기 이산화염소와 상기 산화제의 비율이 중량비 1 : 30~300 이고, 상기 산화제와 연소속도조절제와 발연제 및 증류수의 비율이 중량비 1 : 0.4~0.9 : 0.4~0.8 : 2~6 이다.Wherein the ratio of the chlorine dioxide to the oxidizing agent is in the range of 1: 0.4 to 0.9: 0.4 to 0.8: 2 to 6, and the ratio of the oxidizing agent, the combustion rate regulating agent,

상기 연속속도조절제가 물에 용해도가 높고 물과 열에 안정한 염화암모늄, 요소, 술팜산 구아니딘으로 이루어진 군에서 선택된다.The continuous rate controlling agent is selected from the group consisting of ammonium chloride, urea, and guanidine sulfamate, which are high in water solubility and stable to water and heat.

상기 연소속도조절제가 물에 용해도가 높고 열에 안정한 염화암모늄과 요소의 혼합물이다.The burn rate modifier is a mixture of ammonium chloride and urea, which is highly soluble in water and stable to heat.

이와 같은 본 발명의 실시예에 따른 훈증훈연 방제제 조성물을 이용한 방제방법은, 혼합용기에 증류수와 산화제와 연소속도조절제와 발연제 및 이산화염소를 넣고 교반하여 액상의 훈증훈연 방제제를 제조하는 단계; 상기 액상 용액으로 제조한 훈증훈연 방제제를 가열용기에 넣고, 열원을 이용하여 가열용기를 서서히 가열하여 비점이 낮은 이산화염소가 서서히 증발하여 농작물에 대하여 훈증 처리하는 단계; 상기 가열용기의 액상 용액을 일정 시간 가열하여 물이 완전히 증발하면 액상 용액이 점도가 높고 열전도율이 낮은 점액질로 변화하는 단계; 상기 액상 용액의 온도가 산화제의 분해 온도에 도달하면 연소속도조절제에 의하여 연소 속도를 지연시켜 점액질로부터 부착성 및 침투성 성분을 흡수한 다량의 연기를 온실 공간에 확산하는 단계; 상기 온실 공간에 확산된 연기와 이산화염소 성분이 결합하여 부착성 및 침투성을 가진 훈연 입자를 생성시킴으로써 농작물에 대한 훈연 효과를 발휘하는 단계를 포함하는 것을 특징으로 한다.
The method for controlling the fumigant anti-fog formulation according to an embodiment of the present invention comprises the steps of adding distilled water, an oxidant, a combustion rate regulator, a fumigant, and chlorine dioxide to a mixing vessel and stirring the mixture to prepare a liquid fumigant fumigant; The fumigant fume control agent prepared in the liquid solution is placed in a heating vessel and the heating vessel is gradually heated by using a heat source to gradually evaporate chlorine dioxide having low boiling point to fumigate the crops; Heating the liquid solution of the heating vessel for a predetermined time to completely evaporate the water; and changing the liquid solution to a mucilage having a high viscosity and a low thermal conductivity; Dissolving a large amount of smoke in the greenhouse space, which absorbs adherence and permeability components from the mucus by retarding the burning rate by the burning rate regulator when the temperature of the liquid solution reaches the decomposition temperature of the oxidizing agent; The method of the present invention is characterized in that the smoke diffused in the greenhouse space is combined with the chlorine dioxide component to generate fume particles having adherence and permeability, thereby exhibiting a fume effect on the crops.

본 발명은 이산화염소를 포함하는 훈증훈연 방제제를 액상 제조하여 사용하므로 취급상 안전하며 각종 농작물의 방제용으로 폭 넓게 사용할 수 있다.The present invention uses a fumed fume control agent containing chlorine dioxide in a liquid phase and is safe for handling and can be widely used for controlling various crops.

또한 본 발명은 일반적인 훈연제와 다르게 액상 제조된 방제제의 산화제가 액체 상태에서 분해하므로 발화되지 않으며 고열에 이산화염소가 분해되지 않아 병해 방제효과를 극대화할 수 있다.
In addition, the present invention differs from conventional fumigants in that the oxidizer of the liquid agent prepared in the liquid phase is decomposed in the liquid state, so that it does not ignite and the chlorine dioxide is not decomposed into the high temperature, thereby maximizing the effect of controlling the disease.

도 1은 본 발명에 따른 훈증훈연 방제제를 이용하여 훈증 및 훈연 처리하는 일련의 과정을 도식적으로 나타낸 도면이다.
도 2는 본 발명에 따른 액상 제조된 훈증훈연 방제제를 가열용기에 넣고 가열하는 과정에서 상태 변화를 설명하기 위한 도면이다.
도 3은 본 발명에 따른 훈증훈연 방제제의 제조 과정과 방제 방법을 설명하기 위한 흐름도이다.
도 4는 본 발명에 따른 훈증훈연 방제제를 가열하는 과정에서 변화하는 이산화염소의 잔류량을 나타낸 그래프이다. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing a series of processes of fumigation and smoke treatment using a fumigant anti-fogging agent according to the present invention. FIG.
FIG. 2 is a view for explaining a state change in a process of putting a liquid fumed fume inhibitor according to the present invention into a heating container and heating it.
FIG. 3 is a flow chart for explaining the manufacturing process and the controlling method of the fuming anti-fogging agent according to the present invention.
FIG. 4 is a graph showing the residual amount of chlorine dioxide changing in the process of heating the fuming anti-fogging agent according to the present invention.

이하 본 발명의 실시예를 첨부도면에 따라 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

일반적으로 연기(훈연 입자)는 가연물이 고열에 노출되어 발생하는데 발생 즉시 고열의 연기 입자는 주위의 공기 중의 수분과 결합 응축되면서 입자 크기가 커지게 된다. 고체나 분말 형태의 훈연제 역시 연기 입자가 공기 중의 수분과 결합하므로 부착력과 점착력이 결여된 입자가 형성될 뿐 아니라 공기 중에서 곧바로 건조되어 방제 효과가 낮아지는 단점이 있다.Generally, fumes (smoke particles) are generated by exposure to a high temperature of a combustible material. As soon as the smoke particles of high temperature coalesce with the moisture in the surrounding air, the particle size becomes large. The smoke or smoke powder in the form of a solid or a powder has a disadvantage in that smoke particles are combined with moisture in the air to form particles lacking the adhesion and adhesion,

본 발명은 이산화염소를 포함한 훈증훈연 방제제를 액상 용액으로 제조하여 가열과정에서 급격한 온도 상승을 억제하여 이산화염소가 분해되지 않고 서서히 증발되어 훈증 처리하고, 일정시간 경과 후 부착성 및 침투성을 갖는 훈연 입자를 발생시킴으로써 방제 대상물에 대한 방제효과를 극대화할 수 있도록 하는 것이다.
The present invention relates to a process for producing a fumed fume inhibitor containing chlorine dioxide, which comprises preparing a liquid fuming agent as a liquid solution, fuming the chlorine dioxide by slowly evaporating the chlorine dioxide by suppressing the rapid temperature rise during the heating process, The particles are generated so as to maximize the control effect on the object to be controlled.

1. 하우스 농작물의 훈증훈연 방제제 조성물 1. House fumigation smoke Antiseptic composition

본 발명의 훈증훈연 방제제는 이산화염소에 산화제, 발연제, 그리고 연소속도조절제를 혼합하고 증류수로 희석하여 액상 용액으로 제조할 수 있다. 여기서 이산화염소는 일정한 농도를 갖는 액상 또는 수용성이며 분말 상태로 사용할 수 있다.The fuming anti-fogging agent of the present invention can be prepared as a liquid solution by mixing an oxidizing agent, a fuming agent, and a combustion rate controlling agent into chlorine dioxide and diluting with distilled water. Here, chlorine dioxide can be used in a liquid state having a constant concentration or in a water-soluble and powdery state.

본 발명에 있어 산화제로는 물에 용해도가 높고, 이산화염소와 반응하지 않으며 저온에서 분해되어 산소를 발생함으로써 발연제의 연소를 촉진시킬 수 있는 유기화합물 또는 무기산화물을 사용할 수 있다. 산화제가 물에 용해도가 높은 염소산나트륨, 아염소산나트륨, 과염소산 나트륨, 질산나트륨, 및 아질산나트륨으로 이루어진 군에서 선택될 수 있다. 또한 산화제가 물에 용해도가 높은 염소산염, 아염소산염, 및 과염소산염으로 이루어진 군에서 선택될 수 있다. 이 중 물에 대한 용해도가 높고 안정된 염소산염(NaClO3)이 바람직하다. 이들 산화제로는 단독 또는 2종 이상 혼합하여 사용할 수 있다.As the oxidizing agent in the present invention, an organic compound or an inorganic oxide which has high solubility in water, does not react with chlorine dioxide, decomposes at low temperature to generate oxygen to promote combustion of the fuming agent can be used. The oxidizing agent may be selected from the group consisting of sodium chlorate, sodium chlorite, sodium perchlorate, sodium nitrate, and sodium nitrite, which are highly soluble in water. Also, the oxidizing agent may be selected from the group consisting of chlorates, chlorites, and perchlorates having high solubility in water. Among them, chlorate (NaClO 3 ) which is highly soluble in water and stable is preferable. These oxidizing agents may be used alone or in combination of two or more.

본 발명에 있어 발연제가 이산화염소를 안정화시키고 물에 용해도가 높은 단당류, 이당류, 및 다당류로 이루어진 군으로부터 선택될 수 있다. 발연제로서 솔비톨(sorbitol)을 사용할 수 있다. 이러한 발연제 사용시 산화제와 격렬한 반응이 일어날 수 있으므로 연소속도조절제를 부가하여 사용할 필요가 있다. In the present invention, the fogging agent may be selected from the group consisting of monosaccharides, disaccharides, and polysaccharides which stabilize chlorine dioxide and have high solubility in water. Sorbitol can be used as a fogging agent. When such a fumigant is used, a vigorous reaction with the oxidant may occur. Therefore, it is necessary to add a combustion rate regulator.

본 발명에 있어 연속속도조절제가 물에 용해도가 높고 물과 열에 안정한 염화암모늄(ammonium chloride), 요소, 술팜산 구아니딘(sulfamic acid guanidine)으로 이루어진 군에서 선택될 수 있다. 또한 연소속도조절제가 물에 용해도가 높고 열에 안정한 염화암모늄과 요소의 혼합물을 사용할 수 있다. In the present invention, the continuous rate controlling agent may be selected from the group consisting of ammonium chloride, urea, and sulfamic acid guanidine, which are high in water solubility and stable to water and heat. It is also possible to use a mixture of ammonium chloride and urea, which has a high solubility in water and is thermally stable, in the combustion rate modifier.

이산화염소, 산화제, 발연제, 연소속도조절제, 증류수의 혼합비율은 다음과 같다. 이산화염소 성분과 산화제의 비율은 중량비 1 : 30~300 이며, 바람직하게는 1 : 100 이다. 산화제와 연소속도조절제와 발연제 및 증류수의 비율은 중량비 1 : 0.4~0.9 : 0.4~0.8 : 2~6 이며, 바람직하게는 중량비 1 : 0.8 : 0.6 : 6 이다.
The mixing ratios of chlorine dioxide, oxidizing agent, fogging agent, combustion rate regulator and distilled water are as follows. The weight ratio of the chlorine dioxide component to the oxidizing agent is 1: 30 to 300, preferably 1: 100. The ratio of the oxidizing agent, the combustion rate regulator, the fumigant and the distilled water is 1: 0.4-0.9: 0.4-0.8: 2 -6, preferably 1: 0.8: 0.6: 6 by weight.

2. 훈증훈연 방제제의 훈증 및 훈연 과정 2. Fumigation and fumigation process of fumigant fumigant

도 1은 본 발명에 따른 하우스 농작물의 훈증훈연 방제제를 이용하여 훈증 및 훈연 처리하는 일련의 과정을 도식적으로 나타낸 도면이고, 도 2는 본 발명에 따른 액상 제조된 하우스 농작물의 훈증훈연 방제제를 가열용기에 넣고 가열하는 과정에서 상태 변화를 설명하기 위한 도면이다. FIG. 1 is a schematic view showing a series of processes of fumigation and smoke treatment using a fumigant fuming agent for house crops according to the present invention. FIG. 2 is a graph showing the fumigation and smoke treatment of house crops according to the present invention. And is a diagram for explaining a state change in the process of heating in a heating container.

본 발명은 이산화염소를 포함하는 훈증훈연 방제제를 액상 제조하고, 가열용기에 액상의 훈증훈연 방제제를 넣고 전기히터 또는 훈증훈연기를 이용하여 가열용기를 서서히 가열한다. 초기 가열시 50 ℃ 저온에서 대부분의 이산화염소가 증발한다. 이때 증발하는 이산화염소 성분(W1)이 온실 공간에 확산함에 따라 훈증 처리가 이루어진다. In the present invention, a fumigant anti-fogging agent containing chlorine dioxide is prepared in the form of a liquid, a liquid fumigant anti-fogging agent is placed in a heating vessel, and the heating vessel is gradually heated using an electric heater or fumigated smoke. Most of the chlorine dioxide evaporates at a low temperature of 50 ° C during the initial heating. At this time, the fumigant is treated as the evaporating chlorine dioxide component (W1) diffuses into the greenhouse space.

가열 시간이 증가함에 따라 가열용기의 액상 용액은 점도가 높고 열전도율이 낮은 점액질(R)로 변화한다. 이때 점액질 상태로 변화하는 액상 용액에서는 유체 이동이 제한됨에 따라 가열용기의 하부 온도가 상부 온도보다 높아지게 된다. 이후 가열용기의 바닥온도가 130℃ 정도로 높아져 산화제의 분해온도에 도달하면 산화제가 분해를 시작하여 연기(W2)를 발생시킨다. As the heating time increases, the liquid solution in the heating vessel changes to a mucilage (R) having a high viscosity and a low thermal conductivity. At this time, in the liquid solution changing into the mucus state, the fluid movement is restricted, so that the lower temperature of the heating container becomes higher than the upper temperature. Then, when the bottom temperature of the heating vessel becomes as high as about 130 ° C and reaches the decomposition temperature of the oxidizing agent, the oxidizing agent starts to decompose to generate smoke (W2).

연기(W2)는 가열용기 하부에서 상부로 상승하면서 점액질로부터 부착성 및 침투성 성분을 흡수하여 온실 공간에 확산하고, 남아있는 이산화염소도 증발하게 된다. The smoke (W2) rises upward from the bottom of the heating vessel, absorbing the adhesive and permeable components from the mucus, diffuses into the greenhouse space, and the remaining chlorine dioxide evaporates.

이전에 증발되어 온실 공간에 확산된 이산화염소와 연기와 함께 증발되는 이산화염소는 다량의 연기에 휩싸여 부착성 및 침투성을 가진 훈연 입자(W3)를 생성하고, 생성된 훈연 입자(W3)는 농작물에 쉽게 부착 및 침투할 수 있어 농작물에 대한 방제효과를 발휘하게 된다.
Chlorine dioxide diffused in the greenhouse space previously evaporated and chlorine dioxide evaporated together with the smoke produced fume particles (W3) having adherence and permeability by being surrounded by a large amount of smoke, and the generated fume particles (W3) It can be easily adhered and infiltrated, so that the effect of controlling the crops is exhibited.

이상 설명한 본 발명의 훈증훈연 방제제의 제조 과정 및 방제방법을 상세히 설명한다.The manufacturing process and the controlling method of the fuming smoke prevention agent of the present invention described above will be described in detail.

도 3에 도시한 바와 같이, 훈증훈연 방제제의 제조 과정(S100)과 훈증 및 훈연 처리를 이용한 방제 과정(S200)으로 구분한다.As shown in FIG. 3, the manufacturing process (S100) of a fumigant fume inhibitor and the control process (S200) using fumigation and smoke treatment are distinguished.

먼저, 혼합용기(스테인리스 용기 또는 플라스틱 용기)에 일정량의 물을 채우고 정해진 비율에 따라 산화제와 연소속도조절제를 넣고 섞어서 1차 교반한다(S101). 물의 혼합량은 방제제의 제조용량에 따라 정하며, 1차 교반으로 산화제와 연소속도조절제가 용해된다.First, a predetermined amount of water is filled in a mixing vessel (stainless container or plastic vessel), and an oxidizing agent and a combustion rate adjusting agent are added according to a predetermined ratio, and the mixture is stirred for the first time (S101). The amount of water to be mixed is determined according to the production capacity of the controlling agent, and the oxidizing agent and the combustion rate controlling agent are dissolved by the primary stirring.

1차 교반 과정에서는 흡열 반응으로 반응 온도가 낮아져 제조시간이 증가할 수 있지만, 가열수단을 이용하여 반응 온도를 높이면 제조시간을 단축할 수 있다. 산화제와 연소속도조절제가 물에 완전 용해된 다음 정해진 비율에 따라 발연제를 넣고 섞어서 2차 교반한다(S102). 2차 교반으로 발연제가 완전 용해되면 정해진 비율에 따라 이산화염소를 넣고 3차 교반하여 액상의 훈증훈연 방제제를 제조한다(S103).In the primary stirring process, the reaction temperature may be lowered due to the endothermic reaction to increase the production time. However, if the reaction temperature is increased by the heating means, the production time can be shortened. After the oxidizing agent and the combustion rate regulator are completely dissolved in water, the fuming agent is added according to a predetermined ratio, and the mixture is stirred for a second time (S102). When the fuming agent is completely dissolved by the secondary agitation, chlorine dioxide is added in accordance with a predetermined ratio, and the resulting mixture is stirred with a third stirring to prepare a liquid fuming agent (S103).

상부가 개방된 가열용기에 액상 용액으로 제조한 훈증훈연 방제제를 넣고, 전기히터 등과 같은 열원을 이용하여 가열용기를 서서히 가열하면 물이 증발하게 된다(S201). 초기 가열시 물의 증발과 함께 비점이 낮은 이산화염소가 서서히 증발하여 온실 공간에 확산된다. 온실 공간에 확산된 이산화염소 성분(W1)으로 하우스 농작물에 대한 훈증 처리가 시작된다(S202). When the heating vessel is gradually heated by using a heat source such as an electric heater, water is evaporated (S201). During the initial heating, chlorine dioxide with a low boiling point evaporates slowly and evaporates into the greenhouse space. The fumigation process for the house crop is started with the chlorine dioxide component (W1) diffused in the greenhouse space (S202).

물의 증발 잠열로 인하여 가열용기에 수용된 액상 용액의 온도는 물의 증발 온도 이상으로 상승하지 않으나 물이 완전히 증발하게 되면 액상 용액의 온도는 다시 상승하여 액상 용액의 증발온도까지 높아진다. 이때 액상 용액은 점도가 높고 열전도율이 낮은 점액질(R)로 변화하고, 가열용기 하부 온도가 상부 온도보다 높아지게 된다(S203).Due to the latent heat of evaporation of water, the temperature of the liquid solution contained in the heating vessel does not rise above the evaporation temperature of water, but when the water completely evaporates, the temperature of the liquid solution rises again to the evaporation temperature of the liquid solution. At this time, the liquid solution changes to the mucoside (R) having a high viscosity and a low thermal conductivity, and the temperature of the bottom of the heating container becomes higher than the upper temperature (S203).

발연제는 증발이 잘되지 않으므로 액상 용액의 온도가 더욱 상승하고 산화제의 분해 온도에 도달하면 산화제가 분해를 시작함에 따라 연기(W2)를 발생한다(S204). 이때 산화제가 분해되면서 발연제와 강하게 반응하여 급격한 연소가 시작될 수 있는데, 이러한 급격한 연소가 연기 발생을 저해시키게 된다. 따라서 급격한 연소를 방해하려면 연소 속도를 지연하기 위한 연소속도조절제가 필요하다. 연소속도조절제에 의하여 연소 속도를 지연시킴에 따라 다량의 연기가 발생하게 된다. 연기는 점액질로부터 부착성 및 침투성 성분을 흡수하여 온실 공간에 확산된다. 온실 공간에서 연기와 이산화염소 성분이 결합하여 부착성 및 침투성을 가진 훈연 입자(W3)를 생성한다. 훈연 입자(W3)는 점액질로부터 부착성과 침투성 성분을 흡수함에 따라 농작물에 부착 및 침투가 용이하다.
When the temperature of the liquid solution further increases and the oxidizing agent reaches the decomposition temperature, smoke (W2) is generated as the oxidizing agent starts to decompose (S204). At this time, the oxidizing agent decomposes and reacts strongly with the fuming agent to start the rapid combustion. Such rapid combustion hinders the generation of smoke. Therefore, in order to prevent rapid combustion, a combustion rate regulator is required to retard the combustion rate. A large amount of smoke is generated as the burning rate is delayed by the combustion rate regulator. The smoke absorbs the adhesive and permeable components from the mucus and diffuses into the greenhouse space. Smoke and chlorine dioxide components combine in the greenhouse space to produce fume particles (W3) with adherence and permeability. Smoke particles (W3) are easy to adhere to and penetrate into crops as they absorb adhesive and permeable components from the mucus.

3. 훈증 및 훈연 처리과정에서 이산화염소 측정시험 3. Chlorine dioxide measurement test during fumigation and smoke treatment

가열용기 안에 염소산나트륨 10g, 염화암모늄 8g, 솔비톨 6g을 넣고 증류수 50g을 부가한 다음 액상의 이산화염소(농도 2000ppm) 250g를 넣고 혼합한다. 가열용기는 직경 220mm, 깊이 30mm를 가지고 알루미늄 합금재질로 제작한다.Add 10 g of sodium chlorate, 8 g of ammonium chloride and 6 g of sorbitol in a heating vessel, add 50 g of distilled water, add 250 g of liquid chlorine dioxide (concentration 2000 ppm) and mix. The heating vessel is made of aluminum alloy material with a diameter of 220 mm and a depth of 30 mm.

전기히터(전력용량 300W)의 열판 위에 가열용기를 올려놓고 가열한다. 도 4에 도시한 바와 같이, 가열용기에 수용된 액상 용액의 온도는 상승함에 따라 이산화염소가 증발하여 이산화염소 잔류량이 감소하는 것을 실험으로 확인하였다.
Place the heating vessel on a hot plate of an electric heater (electric power capacity 300W) and heat it. As shown in FIG. 4, it was experimentally confirmed that the chlorine dioxide evaporated as the temperature of the liquid solution contained in the heating vessel rises and the chlorine dioxide residual amount decreases.

[실시예 1][Example 1]

염소산나트륨 10g, 염화암모늄 8g, 솔비톨 6g을 넣고 증류수 50g을 부가한 다음 액상의 이산화염소(농도 2000ppm) 250g을 혼합한 후 2개 훈증훈연기에 나누어 비닐하우스로 축조한 온실(면적 660m2)에서 일몰 후 토마토의 잎곰팡이병 방제를 실시하였다.10 g of sodium chlorate, 8 g of ammonium chloride and 6 g of sorbitol were added, and 50 g of distilled water was added. Then, 250 g of liquid chlorine dioxide (concentration of 2000 ppm) was mixed and then divided into two fumigated fumes and a green house (area 660 m 2 ) After sunset, tomato foliar disease control was performed.

참고예 1-1 : 스미렉스 수화제(유효성분 프로시미돈 50%) 55g을 물 100ℓ에 섞어 [실시예 1]과 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.Reference Example 1-1: 55 g of Sumirex water-soluble agent (50% of active component Proximidone) was added to 100 liters of water and sprayed to the same greenhouse as the [Example 1] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

참고예 1-2 : 이산화염소(농도 1000ppm) 2g을 물 10ℓ에 섞어 [실시예 1]과 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.
Reference Example 1-2: 2 g of chlorine dioxide (concentration of 1000 ppm) was added to 10 liters of water and sprayed to the same greenhouse as the [Example 1] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

[실시예 2][Example 2]

염소산나트륨 10g, 염화암모늄 8g, 솔비톨 6g을 넣고 증류수 50g을 부가한 다음 액상의 이산화염소(농도 2000ppm) 250g을 혼합한 후 2개 훈증훈연기에 나누어 비닐하우스로 축조한 온실(면적 600m2)에서 일몰 후 호박의 흰가루병 방제를 실시하였다.10 g of sodium chlorate, 8 g of ammonium chloride and 6 g of sorbitol were added and 50 g of distilled water was added. Then 250 g of liquid chlorine dioxide (concentration of 2000 ppm) was mixed and then divided into two fumigated smoke and the greenhouses (area 600 m 2 ) After the sunset, the powdery mildew of pumpkin was controlled.

참고예 2-1 : 트리후민 수화제(유효성분 트리후미졸 30%) 25g을 물 100ℓ에 섞어 [실시예 2]와 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.Reference Example 2-1: 25 g of a trihydrate wetting agent (30% of active ingredient trifumizole) was added to 100 liters of water and sprayed to the same greenhouse as the [Example 2] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

참고예 2-2 : 이산화염소(농도 1000ppm) 2g을 물 10ℓ에 섞어 [실시예 2]와 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.
Reference Example 2-2: 2 g of chlorine dioxide (concentration of 1000 ppm) was added to 10 liters of water and sprayed to the same greenhouse as the [Example 2] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

[실시예 3][Example 3]

염소산나트륨 10g, 염화암모늄 8g, 솔비톨 6g을 넣고 증류수 50g을 부가한 다음 액상의 이산화염소(농도 2000ppm) 250g을 혼합한 후 2개 훈증훈연기에 나누어 비닐하우스로 축조한 온실(면적 660m2)에서 일몰 후 오이의 노균병 방제를 실시하였다.10 g of sodium chlorate, 8 g of ammonium chloride and 6 g of sorbitol were added, and 50 g of distilled water was added. Then, 250 g of liquid chlorine dioxide (concentration of 2000 ppm) was mixed and then divided into two fumigated fumes and a green house (area 660 m 2 ) After the sunset, the control of cucumber mildew was carried out.

참고예 3-1 : 해비치 입상수화제(유효성분 47%) 33.5g을 물 100ℓ에 섞어 [실시예 3]과 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.Reference Example 3-1: 33.5 g of a honeycomb granulated wastewater (active ingredient 47%) was mixed with 100 L of water and sprayed to the same greenhouse as the [Example 3] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

참고예 3-2 : 이산화염소(농도 1000ppm) 2g을 물 10ℓ에 섞어 [실시예 3]과 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.
Reference Example 3-2: 2 g of chlorine dioxide (concentration of 1000 ppm) was added to 10 liters of water and sprayed to the same greenhouse as the [Example 3] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

[실시예 4][Example 4]

염소산나트륨 10g, 염화암모늄 8g, 솔비톨 6g을 넣고 증류수 50g을 부가한 다음 액상의 이산화염소(농도 2000ppm) 250g을 혼합한 후 2개 훈증훈연기에 나누어 비닐하우스로 축조한 온실(면적 690m2)에서 일몰 후 고추의 바이러스 방제를 실시하였다.10 g of sodium chlorate, 8 g of ammonium chloride and 6 g of sorbitol were added, and 50 g of distilled water was added. Then 250 g of liquid chlorine dioxide (concentration of 2000 ppm) was mixed and then divided into two fumigated fumes and a green house (area of 690 m 2 ) After the sunset, virus control of pepper was performed.

참고예 4-1 : 골든벨 입상수화제(유효성분 49.35%) 100g을 물 100ℓ에 섞어 [실시예 4]와 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.Reference Example 4-1: 100 g of Golden Bell granulated wadding agent (active ingredient 49.35%) was added to 100 liters of water and sprayed to the same greenhouse as the [Example 4] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

참고예 4-2 : 이산화염소(농도 1000ppm) 2g을 물 10ℓ에 섞어 [실시예 4]와 동일 온실의 작물에 분무 방법으로 살포하였다. 여기서 살포입자의 평균 입자크기는 200㎛ 이다.Reference Example 4-2: 2 g of chlorine dioxide (concentration of 1000 ppm) was added to 10 liters of water and sprayed to the same greenhouse as the [Example 4] by spraying method. Here, the average particle size of the sprayed particles is 200 mu m.

시험방법Test Methods 유효성분Active ingredient 방제방법How to control 방제효과Control effect 약해Weak 실시예 1Example 1 이산화염소Chlorine dioxide 훈증훈연Fumigation smoke ++++++++ 없음none 참고예 1-1Reference Example 1-1 스미렉스Sumirex 분무Spray ++++ 없음none 참고예 1-2Reference Example 1-2 이산화염소Chlorine dioxide 분무Spray ++ 있음has exist 실시예 2Example 2 이산화염소Chlorine dioxide 훈증훈연Fumigation smoke ++++++++ 없음none 참고예 2-1Reference Example 2-1 트리후민Trimmin 분무Spray ++ 없음none 참고예 2-2Reference Example 2-2 이산화염소Chlorine dioxide 분무Spray ++ 있음has exist 실시예 3Example 3 이산화염소Chlorine dioxide 훈증훈연Fumigation smoke ++++++++ 없음none 참고예 3-1Reference Example 3-1 해비치Haevichi 분무Spray ++ 없음none 참고예 3-2Reference Example 3-2 이산화염소Chlorine dioxide 분무Spray ++ 있음has exist 실시예 4Example 4 이산화염소Chlorine dioxide 훈증훈연Fumigation smoke ++++++++ 없음none 참고예 4-1Reference Example 4-1 골든벨Golden Bell 분무Spray ++ 없음none 참고예 4-2Reference Example 4-2 이산화염소Chlorine dioxide 분무Spray ++ 있음has exist

++++ : 95% 이상, +++ : 71~94%, ++ : 51~70%, + : 50% 이하 ++++: not less than 95%, +++: 71 to 94%, ++: 51 to 70%, +: not more than 50%

상기 실시예에서와 같이 훈증훈연 방제제가 일반 농약에 비하여 방제 효과가 높게 나타났다. 또한 이산화염소를 직접 살포하는 경우 식물 약해가 발생하지만, 본 발명의 훈증훈연 방제제를 이용하는 경우 약해가 발생되지 않았다. As in the above examples, the effect of controlling fuming smoke was higher than that of general pesticides. In addition, when the chlorine dioxide is directly sprayed, plant phytotoxicity occurs, but when the fumigant fungicide of the present invention is used, the phytotoxicity is not generated.

이상과 같이 본 발명은 액상으로 훈증훈연 방제제를 액상 제조하여 사용하므로 기존의 훈연제보다 취급이 안전하며 농작물의 방제용으로 폭넓게 사용할 수 있다. 본 발명의 훈증훈연 방제제는 일반 훈연제와 다르게 물을 포함한 액체 상태로 되어 있어 산화제가 액상에서 분해하므로 발화로 인한 안전사고를 방지하고 고온 가열시 이산화염소가 분해되지 않아 방제효과를 더욱 높일 수 있다.
As described above, the present invention can be widely used for the control of crops because it is safer to handle than conventional fumigants because it uses a liquid phase to produce a liquid fumigation agent for fuming smoke. The fumigant anti-fogging agent of the present invention is in a liquid state including water, unlike a normal fumigant, so that the oxidizer is decomposed in the liquid phase, thereby preventing safety accidents caused by ignition, and chlorine dioxide is not decomposed during heating at high temperature, .

W1 : 온실공간에 확산된 이산화염소 성분
W2 : 온실공간에 확산된 연기
W3 : 온실공간에 확산된 이산화염소 성분이 연기에 휩싸여 생성된 훈연 입자W1: chlorine dioxide component diffused into the greenhouse space
W2: Smoke spreading in greenhouse space
W3: Chlorine dioxide component diffused in the greenhouse space is formed by fumed particles

Claims (12)

산화제와 발연제와 연소속도 조절제를 증류수로 용해시킨 다음 이산화염소를 혼합하여 제조하는 훈증훈연 방제제 조성물. A composition for fuming smoke control agent prepared by dissolving an oxidizing agent, a fuming agent and a combustion rate regulator with distilled water, and then mixing the chlorine dioxide. 제1항에 있어서,
상기 이산화염소는 일정한 농도의 액상인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the chlorine dioxide is a liquid at a constant concentration. 제1항에 있어서,
상기 이산화염소는 수용성이며 분말 상태인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the chlorine dioxide is water-soluble and powdery. 제1항에 있어서,
상기 산화제가 물에 용해도가 높고 상기 이산화염소와 반응하지 않으며 저온에서 분해되어 산소를 발생함으로써 상기 발연제의 연소를 촉진시킬 수 있는 유기화합물 또는 무기화합물인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the oxidizing agent is an organic compound or an inorganic compound which has a high solubility in water and does not react with the chlorine dioxide and decomposes at a low temperature to generate oxygen to promote combustion of the fuming agent. 제1항에 있어서,
상기 산화제가 물에 용해도가 높은 염소산나트륨, 아염소산나트륨, 과염소산 나트륨, 질산나트륨, 및 아질산나트륨으로 이루어진 군에서 선택되는 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the oxidant is selected from the group consisting of sodium chlorate, sodium chlorite, sodium perchlorate, sodium nitrate, and sodium nitrite, which are highly soluble in water. 제1항에 있어서,
상기 산화제가 물에 용해도가 높은 염소산염, 아염소산염, 및 과염소산염으로 이루어진 군에서 선택되는 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the oxidizing agent is selected from the group consisting of chlorates, chlorites, and perchlorates having high solubility in water. 제1항에 있어서,
상기 발연제가 상기 이산화염소를 안정화시키고 물에 용해도가 높은 단당류, 이당류, 및 다당류로 이루어진 군으로부터 선택되는 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the fogging agent is selected from the group consisting of monosaccharides, disaccharides, and polysaccharides that stabilize the chlorine dioxide and are highly soluble in water. 제1항에 있어서,
상기 발연제가 상기 이산화염소를 안정화시키고 물에 용해도가 높은 솔비톨인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the fogging agent stabilizes the chlorine dioxide and has high solubility in water. 제1항에 있어서,
상기 이산화염소와 상기 산화제의 비율이 중량비 1 : 30~300 이고, 상기 산화제와 연소속도조절제와 발연제 및 증류수의 비율이 중량비 1 : 0.4~0.9 : 0.4~0.8 : 2~6 인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the ratio of the chlorine dioxide to the oxidizing agent is in the range of 1:30 to 300 and the ratio of the oxidizing agent, the combustion rate regulator, the fogging agent and the distilled water is 1: 0.4 to 0.9: 0.4 to 0.8: 2 to 6, . 제1항에 있어서,
상기 연속속도조절제가 물에 용해도가 높고 물과 열에 안정한 염화암모늄, 요소, 술팜산 구아니딘으로 이루어진 군에서 선택되는 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the continuous rate controlling agent is selected from the group consisting of ammonium chloride, urea, and guanidine sulfamate which are highly soluble in water and stable to water and heat. 제1항에 있어서,
상기 연소속도조절제가 물에 용해도가 높고 열에 안정한 염화암모늄과 요소의 혼합물인 훈증훈연 방제제 조성물.The method according to claim 1,
Wherein the combustion rate modifier is a mixture of ammonium chloride and urea which is high in solubility in water and stable to heat. 혼합용기에 증류수와 산화제와 연소속도조절제와 발연제 및 이산화염소를 넣고 교반하여 액상의 훈증훈연 방제제를 제조하는 단계;
상기 액상 용액으로 제조한 훈증훈연 방제제를 가열용기에 넣고, 열원을 이용하여 가열용기를 서서히 가열하여 비점이 낮은 이산화염소가 서서히 증발하여 농작물에 대하여 훈증 처리하는 단계;
상기 가열용기의 액상 용액을 일정 시간 가열하여 물이 완전히 증발하면 액상 용액이 점도가 높고 열전도율이 낮은 점액질로 변화하는 단계;
상기 액상 용액의 온도가 산화제의 분해 온도에 도달하면 연소속도조절제에 의하여 연소 속도를 지연시켜 점액질로부터 부착성 및 침투성 성분을 흡수한 다량의 연기를 온실 공간에 확산하는 단계;
상기 온실 공간에 확산된 연기와 이산화염소 성분이 결합하여 부착성 및 침투성을 가진 훈연 입자를 생성시킴으로써 농작물에 대한 훈연 효과를 발휘하는 단계를 포함하는 것을 특징으로 하는 훈증훈연 방제제 조성물을 이용한 방제방법.Mixing a distilled water, an oxidizing agent, a combustion rate regulator, a fuming agent, and chlorine dioxide into a mixing vessel and stirring to prepare a liquid fumigation agent;
The fumigant fume control agent prepared in the liquid solution is placed in a heating vessel and the heating vessel is gradually heated by using a heat source to gradually evaporate chlorine dioxide having low boiling point to fumigate the crops;
Heating the liquid solution of the heating vessel for a predetermined time to completely evaporate the water; and changing the liquid solution to a mucilage having a high viscosity and a low thermal conductivity;
Dissolving a large amount of smoke in the greenhouse space, which absorbs adherence and permeability components from the mucus by retarding the burning rate by the burning rate regulator when the temperature of the liquid solution reaches the decomposition temperature of the oxidizing agent;
And a step of producing fume particles having adhesion and permeability by combining the smoke diffused in the greenhouse space and the chlorine dioxide component to exert a fuming effect on the crops. .
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