CN105405945A - Composite substrate and method of manufacturing GaN-based LED by using substrate - Google Patents

Composite substrate and method of manufacturing GaN-based LED by using substrate Download PDF

Info

Publication number
CN105405945A
CN105405945A CN201510712388.2A CN201510712388A CN105405945A CN 105405945 A CN105405945 A CN 105405945A CN 201510712388 A CN201510712388 A CN 201510712388A CN 105405945 A CN105405945 A CN 105405945A
Authority
CN
China
Prior art keywords
substrate
compound
gan
layer
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510712388.2A
Other languages
Chinese (zh)
Inventor
冯猛
陈立人
刘恒山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOCUS LIGHTINGS TECHNOLOGY Co Ltd
Original Assignee
FOCUS LIGHTINGS TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FOCUS LIGHTINGS TECHNOLOGY Co Ltd filed Critical FOCUS LIGHTINGS TECHNOLOGY Co Ltd
Priority to CN201510712388.2A priority Critical patent/CN105405945A/en
Publication of CN105405945A publication Critical patent/CN105405945A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0066Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0075Processes for devices with an active region comprising only III-V compounds comprising nitride compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/26Materials of the light emitting region
    • H01L33/30Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table
    • H01L33/32Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table containing nitrogen

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

The invention discloses a composite substrate, which comprises a first substrate and a second substrate. The first substrate and the second substrate are mutually composite; the first substrate comprises an upper surface and a lower surface opposite to the upper surface; the upper surface of the first substrate is used for growing a GaN epitaxial layer; the lower surface of the first substrate is used for being composite with the second substrate; and the second substrate has a thermal expansion coefficient smaller than 3*10<-6>/K. In comparison with the prior art, the composite substrate of the invention comprises the first substrate and the second substrate which are mutually composite, the second substrate has a low thermal expansion coefficient, the thermal expansion coefficient can relieve the deformation quantity of the substrate material in the case of high and low temperature conversion, warping of the GaN-based LED epitaxial wafer can be reduced, the inner stress is reduced, and thus, the composite substrate can reduce influences caused by thermal mismatch between the GaN and the substrate.

Description

A kind of compound substrate and utilize it to prepare the method for GaN base LED
Technical field
The present invention relates to technical field of semiconductor luminescence, particularly relate to a kind of compound substrate and utilize it to prepare the method for GaN base LED.
Background technology
Light-emitting diode (Light-EmittingDiode, LED) is a kind of semiconductor electronic component that can be luminous.This electronic component occurred as far back as 1962, and can only send the ruddiness of low luminosity in early days, develop other monochromatic versions afterwards, the light that can send even to this day is throughout visible ray, infrared ray and ultraviolet, and luminosity also brings up to suitable luminosity.And purposes is also by the beginning as indicator light, display panel etc.; Along with the continuous progress of technology, light-emitting diode has been widely used in display, television set daylighting decoration and illumination.
At present, the commercialization extensive LED preparation MOCVD mode that adopts is made more.Utilize mocvd method epitaxial growth GaN backing material used to select substrate should select commaterial, its lattice mismatch is little, thermal coefficient of expansion is low as far as possible.But because GaN base material has high fusing point and very large nitrogen saturated vapor pressure, be difficult to the GaN substrate obtaining large-area high-quality.Owing to lacking the substrate with GaN Lattice Matching, at present on GaN base LED, the general foreign substrate that there is lattice mismatch and coefficient of thermal expansion mismatch that adopts carries out epitaxial growth, and the most frequently used foreign substrate has sapphire and silicon substrate.But, this bi-material all has larger lattice mismatch and coefficient of thermal expansion mismatch with GaN epitaxial layer, cannot the high-quality GaN epitaxial structure of direct growth, the thermal coefficient of expansion difference 35% of Sapphire Substrate and GaN, the thermal coefficient of expansion difference 54% of silicon substrate and GaN.So large thermal mismatching can introduce more defect and larger stress, causes the warpage of LED to become large, and affects the luminous efficiency of LED.
Therefore, for above-mentioned technical problem, be necessary a kind of compound substrate to be provided and to utilize it to prepare the method for GaN base LED.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of compound substrate and utilize it to prepare the method for GaN base LED.
To achieve these goals, the technical scheme that provides of the embodiment of the present invention is as follows:
A kind of compound substrate, for growing GaN epitaxial loayer, it is characterized in that, described compound substrate comprises the first substrate and second substrate of compound each other, wherein, described first substrate comprises upper surface and the lower surface opposing with upper surface, and the upper surface of described first substrate is used for growing GaN epitaxial loayer, the lower surface of described first substrate is used for and described second substrate compound, and the thermal coefficient of expansion of described second substrate is less than 3 × 10 -6/ K.
As a further improvement on the present invention, the thickness of described second substrate is 0.5 ~ 10 μm.
As a further improvement on the present invention, can not there is thermal decomposition in described second substrate at 1100 DEG C, and to NH 3keep inertia.
As a further improvement on the present invention, described first substrate is sapphire or silicon substrate or carborundum or zinc oxide, and described second substrate is silicon dioxide or silicon nitride.
As a further improvement on the present invention, described GaN epitaxial layer comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
Correspondingly, a kind of method utilizing above-mentioned compound substrate to prepare GaN base LED, described preparation method comprises:
S1, provide one first substrate, it comprises upper surface and the lower surface opposing with upper surface;
S2, the lower surface of described first substrate cover second substrate formed compound substrate;
S3, described compound substrate is carried out pickling, and dry;
S4, grow some GaN epitaxial layer at the upper surface of described first substrate, form GaN base LED.
As a further improvement on the present invention, described first substrate is sapphire or silicon substrate or carborundum or zinc oxide.
As a further improvement on the present invention, the thermal coefficient of expansion of described second substrate is less than 3 × 10 -6/ K, described second substrate is silicon dioxide or silicon nitride.
As a further improvement on the present invention, described " described compound substrate is carried out pickling, and dries " step is specially:
Compound substrate is first used NH 4the mixed solution cleaning of F and HF, then use H 2sO 4and H 2o 2mixed solution cleaning, finally utilize washed with de-ionized water, dry in hot nitrogen.
As a further improvement on the present invention, the thickness of described second substrate is 0.5 ~ 10 μm.
The present invention has following beneficial effect:
Compound substrate in the present invention comprises the first substrate and second substrate of compound each other, and wherein, the second substrate is low coefficient of thermal expansion materials.The material of low thermal coefficient of expansion can alleviate the deformation quantity that backing material occurs when high and low temperature shift, thus reduces the warpage of GaN base LED, and reduces its internal stress.Therefore, compound substrate can reduce between GaN and substrate due to impact that thermal mismatching causes.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, the accompanying drawing that the following describes is only some embodiments recorded in the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the structural representation of compound substrate in the embodiment of the invention;
Fig. 2 is the method step flow chart utilizing compound substrate to prepare GaN base LED in the embodiment of the invention.
Embodiment
Technical scheme in the present invention is understood better in order to make those skilled in the art person, below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, should belong to the scope of protection of the invention.
Ginseng Fig. 1 introduces an execution mode of compound substrate 100 structure for the preparation of GaN base LED of the present invention.This structure comprises: the first substrate 10 and the second substrate 20 of compound each other, wherein, first substrate 10 comprises upper surface 11 and the lower surface 12 opposing with upper surface 11, and its upper surface 11 is for growing GaN epitaxial loayer, and the second substrate 20 covers on the lower surface 12 of the first substrate 10.Preferably, the second substrate 20 is low coefficient of thermal expansion materials, and the deformation occurred when being heated is little, and particularly, thermal coefficient of expansion is less than 3 × 10 -6/ K.Because GaN epitaxial layer prepares in MOCVD reaction chamber in NH3 atmosphere, temperature usually 700 ~ 1100 DEG C of changes, therefore, require that the material of the second substrate 20 thermal decomposition can not occur at 1100 DEG C, and to NH3 keep inertia.
Further, the first substrate 10 can be sapphire, silicon substrate, carborundum, zinc oxide etc., and the second substrate 20 can be silicon dioxide, silicon nitride etc., and the thermal coefficient of expansion of silicon dioxide is 0.5 × 10 -6/ K, the thermal coefficient of expansion of silicon nitride is 2.7 × 10 -6/ K, and the stability of the two is all fine.Further, the thickness of the second substrate 20 is 0.5 ~ 10 μm.GaN epitaxial layer comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
Coordinate with reference to Fig. 2, introduce the present invention and utilize compound substrate to prepare an embodiment of GaN base LED method, the method specifically comprises the following steps:
S1, provide one first substrate 10, it comprises upper surface 11 and the lower surface 12 opposing with upper surface 11.
S2, cover the second substrate 20 at the lower surface 11 of described first substrate 10 and form compound substrate.Adopt the method for PECVD that the lower surface 11 of the first substrate 10 is covered the second substrate 20, by the lower surface of the first substrate 10 upward, be placed in the load plate of PECVD device, the temperature of PECVD cavity is risen to 250 DEG C ~ 350 DEG C, Pressure Drop is to about 50Torr, utilize gaseous source, plasma auxiliary under be second substrate 20 of 0.5 ~ 10 μm at lower surface 11 deposit thickness of the first substrate 10.Treat that PECVD cavity is down to room temperature and gets back to normal pressure, take out compound substrate.
S3, described compound substrate is carried out pickling, and dry.Compound substrate is first used NH 4the mixed solution cleaning of F and HF, then use H 2sO 4and H 2o 2mixed solution cleaning, finally utilize washed with de-ionized water, dry in hot nitrogen.
S4, upper surface growing GaN epitaxial loayer at described first substrate.By facing up of the upper surface 11 of the first substrate 10 in compound substrate 100, be placed on the load plate of MOCVD, adopt conventional GaN base LED technique growing GaN epitaxial loayer.GaN epitaxial layer comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
In order to better set forth the present invention, some are below provided to utilize compound substrate to prepare the specific embodiment of GaN base LED method.
Embodiment 1
The compound substrate of sapphire and silicon nitride
By the Sapphire Substrate back side upwards, be placed in the load plate of PECVD, the temperature of PECVD cavity is risen to 350 DEG C, Pressure Drop, to about 50Torr, utilizes N 2o, NH 3and SiH 4for gaseous source, plasma auxiliary under be the silicon nitride material of 2um at the backside deposition thickness of Sapphire Substrate.Treat that PECVD cavity is down to room temperature and gets back to normal pressure, take out compound substrate.
Compound substrate is first used NH 4mixed solution (the NH of F and HF 4the mol ratio of F and HF is at 1:2) middle cleaning 10min, then use H 2sO 4and H 2o 2mixed solution (volume ratio is 3:1) clean 15min, after finally utilizing washed with de-ionized water 3 times, dry in hot nitrogen.
C. by the sapphire of compound substrate towards upper, be placed on the load plate of MOCVD, adopt conventional GaN base LED technique growth LED epitaxial structure.Epitaxial layer structure comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
Embodiment 2
The compound substrate of sapphire and silicon dioxide
By the Sapphire Substrate back side upwards, be placed in the load plate of PECVD, the temperature of PECVD cavity is risen to 250 DEG C, Pressure Drop, to about 50Torr, utilizes N 2o and SiH 4for gaseous source, plasma auxiliary under be the SiO of 2um at the backside deposition thickness of Sapphire Substrate 2material.Treat that PECVD cavity is down to room temperature and gets back to normal pressure, take out compound substrate.
Compound substrate is first used NH 4cleaning 10min in the mixed solution (mol ratio of NH4F and HF is at 2:1) of F and HF, then use H 2sO 4and H 2o 2mixed solution (volume ratio is 3:1) clean 15min, after finally utilizing washed with de-ionized water 3 times, dry in hot nitrogen.
By the sapphire of compound substrate towards upper, be placed on the load plate of MOCVD, adopt conventional GaN base LED technique growth LED epitaxial structure.Epitaxial layer structure comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
Embodiment 3
The compound substrate of silicon and silicon nitride
By the silicon substrate back side upwards, be placed in the load plate of PECVD, the temperature of PECVD cavity is risen to 350 DEG C, Pressure Drop, to about 50Torr, utilizes N2O, NH3 and SiH 4for gaseous source, plasma auxiliary under be the SiN material of 2um at the backside deposition thickness of silicon substrate.Treat that PECVD cavity is down to room temperature and gets back to normal pressure, take out compound substrate.
Compound substrate is first used NH 4mixed solution (the NH of F and HF 4the mol ratio of F and HF is at 1:2) middle cleaning 10min, then use H 2sO 4and H 2o 2mixed solution (volume ratio is 3:1) clean 15min, after finally utilizing washed with de-ionized water 3 times, dry in hot nitrogen.
By the silicon face of compound substrate upwards, be placed on the load plate of MOCVD, adopt conventional GaN base LED technique growth LED epitaxial structure.Epitaxial layer structure comprises AlN resilient coating, AlGaN stress-buffer layer, involuntary GaN layer of mixing, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
Embodiment 4
The compound substrate of silicon and silicon dioxide
By the silicon substrate back side upwards, be placed in the load plate of PECVD, the temperature of PECVD cavity is risen to 250 DEG C, Pressure Drop, to about 50Torr, utilizes N 2o and SiH 4for gaseous source, plasma auxiliary under be the SiO of 2um at the backside deposition thickness of silicon substrate 2material.Treat that PECVD cavity is down to room temperature and gets back to normal pressure, take out compound substrate.
Compound substrate is first used NH 4cleaning 10min in the mixed solution (mol ratio of NH4F and HF is at 1:2) of F and HF, then use H 2sO 4and H 2o 2mixed solution (volume ratio is 3:1) clean 15min, after finally utilizing washed with de-ionized water 3 times, dry in hot nitrogen.
By the silicon face of compound substrate upwards, be placed on the load plate of MOCVD, adopt conventional GaN base LED technique growth LED epitaxial structure.Epitaxial layer structure comprises AlN resilient coating, AlGaN stress-buffer layer, involuntary GaN layer of mixing, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.Any Reference numeral in claim should be considered as the claim involved by limiting.
In addition, be to be understood that, although this specification is described according to execution mode, but not each execution mode only comprises an independently technical scheme, this narrating mode of specification is only for clarity sake, those skilled in the art should by specification integrally, and the technical scheme in each embodiment also through appropriately combined, can form other execution modes that it will be appreciated by those skilled in the art that.

Claims (10)

1. a compound substrate, it is characterized in that, described compound substrate comprises the first substrate and second substrate of compound each other, wherein, described first substrate comprises upper surface and the lower surface opposing with upper surface, the upper surface of described first substrate is used for growing GaN epitaxial loayer, and the lower surface of described first substrate is used for and described second substrate compound, and the thermal coefficient of expansion of described second substrate is less than 3 × 10 -6/ K.
2. compound substrate according to claim 1, is characterized in that, the thickness of described second substrate is 0.5 ~ 10 μm.
3. compound substrate according to claim 1, is characterized in that, described second substrate thermal decomposition can not occur at 1100 DEG C, and to NH 3keep inertia.
4. compound substrate according to claim 1, is characterized in that, described first substrate is sapphire or silicon substrate or carborundum or zinc oxide, and described second substrate is silicon dioxide or silicon nitride.
5. compound substrate according to claim 1, is characterized in that, described GaN epitaxial layer comprises low temperature buffer layer, involuntaryly mixes GaN layer, n-type GaN layer, InGaN/GaN quantum well layer, p-type GaN layer.
6. utilize the compound substrate described in claim 1 to prepare a method of GaN base LED, it is characterized in that, described preparation method comprises:
S1, provide one first substrate, it comprises upper surface and the lower surface opposing with upper surface;
S2, the lower surface of described first substrate cover second substrate formed compound substrate;
S3, described compound substrate is carried out pickling, and dry;
S4, grow some GaN epitaxial layer at the upper surface of described first substrate, form GaN base LED.
7. preparation method according to claim 6, is characterized in that, described first substrate is sapphire or silicon substrate or carborundum or zinc oxide.
8. preparation method according to claim 6, is characterized in that, the thermal coefficient of expansion of described second substrate is less than 3 × 10 -6/ K, described second substrate is silicon dioxide or silicon nitride.
9. preparation method according to claim 6, is characterized in that, described " described compound substrate is carried out pickling, and dries " step is specially:
Compound substrate is first used NH 4the mixed solution cleaning of F and HF, then use H 2sO 4and H 2o 2mixed solution cleaning, finally utilize washed with de-ionized water, dry in hot nitrogen.
10. preparation method according to claim 6, is characterized in that, the thickness of described second substrate is 0.5 ~ 10 μm.
CN201510712388.2A 2015-10-28 2015-10-28 Composite substrate and method of manufacturing GaN-based LED by using substrate Pending CN105405945A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510712388.2A CN105405945A (en) 2015-10-28 2015-10-28 Composite substrate and method of manufacturing GaN-based LED by using substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510712388.2A CN105405945A (en) 2015-10-28 2015-10-28 Composite substrate and method of manufacturing GaN-based LED by using substrate

Publications (1)

Publication Number Publication Date
CN105405945A true CN105405945A (en) 2016-03-16

Family

ID=55471320

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510712388.2A Pending CN105405945A (en) 2015-10-28 2015-10-28 Composite substrate and method of manufacturing GaN-based LED by using substrate

Country Status (1)

Country Link
CN (1) CN105405945A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019128524A1 (en) * 2017-12-29 2019-07-04 重庆伟特森电子科技有限公司 Method for eliminating wafer warpage and composite substrate
CN113948390A (en) * 2021-08-30 2022-01-18 西安电子科技大学 Silicon-based AlGaN/GaN HEMT based on substrate back epitaxial layer and preparation method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04322476A (en) * 1991-04-22 1992-11-12 Kyocera Corp Manufacture of semiconductor light-emitting device
JPH0661527A (en) * 1992-08-07 1994-03-04 Nippon Telegr & Teleph Corp <Ntt> Semiconductor light-emitting element and its manufacture
US7198671B2 (en) * 2001-07-11 2007-04-03 Matsushita Electric Industrial Co., Ltd. Layered substrates for epitaxial processing, and device
CN104979440A (en) * 2014-04-10 2015-10-14 传感器电子技术股份有限公司 Structured substrate
CN205092261U (en) * 2015-10-28 2016-03-16 聚灿光电科技股份有限公司 Composite substrate has its gaN base LED chip

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04322476A (en) * 1991-04-22 1992-11-12 Kyocera Corp Manufacture of semiconductor light-emitting device
JPH0661527A (en) * 1992-08-07 1994-03-04 Nippon Telegr & Teleph Corp <Ntt> Semiconductor light-emitting element and its manufacture
US7198671B2 (en) * 2001-07-11 2007-04-03 Matsushita Electric Industrial Co., Ltd. Layered substrates for epitaxial processing, and device
CN104979440A (en) * 2014-04-10 2015-10-14 传感器电子技术股份有限公司 Structured substrate
CN205092261U (en) * 2015-10-28 2016-03-16 聚灿光电科技股份有限公司 Composite substrate has its gaN base LED chip

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019128524A1 (en) * 2017-12-29 2019-07-04 重庆伟特森电子科技有限公司 Method for eliminating wafer warpage and composite substrate
CN113948390A (en) * 2021-08-30 2022-01-18 西安电子科技大学 Silicon-based AlGaN/GaN HEMT based on substrate back epitaxial layer and preparation method
CN113948390B (en) * 2021-08-30 2024-03-19 西安电子科技大学 Silicon-based AlGaN/GaN HEMT based on substrate back epitaxial layer and preparation method

Similar Documents

Publication Publication Date Title
CN104037287B (en) LED epitaxial wafer grown on Si substrate and preparation method thereof
US10014436B2 (en) Method for manufacturing a light emitting element
CN102185052B (en) Manufacturing method of modulation-doped gallium nitride series light-emitting diode
CN103035794B (en) A kind of growth LED on a si substrate and preparation method thereof
CN104037293B (en) Light-emitting diode (LED) epitaxial wafer growing on Si patterned substrate and preparation process of LED epitaxial wafer
CN101728472A (en) Multilayer LED chip structure and preparation method thereof
CN105914270B (en) The manufacturing method of silicon based gallium nitride LED epitaxial structure
CN105006503A (en) LED epitaxial structure and preparation method therefor
CN203910840U (en) LED epitaxial wafer grown on Si patterned substrate
CN104037291B (en) A kind of semi-polarity GaN film being grown on patterned silicon substrate and preparation method thereof
CN104952986A (en) Production method of GaN-based white LED epitaxial structure
CN104505443A (en) GaN-based LED epitaxial structure and production method thereof
CN105405945A (en) Composite substrate and method of manufacturing GaN-based LED by using substrate
CN205092261U (en) Composite substrate has its gaN base LED chip
CN204289495U (en) A kind of GaN base LED epitaxial structure
CN103872192A (en) Manufacturing method for LED (Light Emitting Diode) chip
CN204464312U (en) A kind of large scale GaN base LED epitaxial structure
CN102709414B (en) Epitaxial growth method of novel GaN (gallium nitride)-based LED (light emitting diode) quantum well active region
CN103681986B (en) A kind of gallium nitride based LED epitaxial slice and preparation method thereof
US20090050929A1 (en) Semiconductor substrate with nitride-based buffer layer for epitaxy of semiconductor opto-electronic device and fabrication thereof
WO2017028555A1 (en) Gan base material based on si substrate and preparation method therefor
CN217522030U (en) High-luminous-efficiency LED epitaxial wafer and LED chip
CN106653959B (en) A kind of preparation method of LED epitaxial wafer
CN104752568A (en) GaN-based LED epitaxial structure preparation method for improving the crystal quality
KR100722818B1 (en) Method of manufacturing light emitting diode

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160316