CN105401487A - Making method of moisture-resistant and antibiotic wallpaper - Google Patents
Making method of moisture-resistant and antibiotic wallpaper Download PDFInfo
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- CN105401487A CN105401487A CN201510695669.1A CN201510695669A CN105401487A CN 105401487 A CN105401487 A CN 105401487A CN 201510695669 A CN201510695669 A CN 201510695669A CN 105401487 A CN105401487 A CN 105401487A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/28—Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Abstract
The invention discloses a making method of moisture-resistant and antibiotic wallpaper. The method comprises the following steps: selecting a substrate layer, and carrying out a printing technology to form a printing layer having a pattern on the substrate layer to make semi-finished wallpaper; printing a god sand layer on the front surface of the semi-finished wallpaper through a cylinder registering technology; sequentially coating the back surface of the semi-finished wallpaper with an antibiotic layer, a moisture-resistant layer and a dry adhesive layer; and placing the above obtained wallpaper in an oven after printing, and drying. The antibiotic layer is attached to the inside of the wallpaper to realize a good antibiosis effect, and the formula of the moisture-resistant layer is optimized to realize good moisture resistance.
Description
Technical field
The present invention relates to adornment technical field, be specifically related to a kind of preparation method of moisture-proof, antibiotic wallpaper.
Background technology
Wallpaper, also referred to as wallpaper, wall paper, being a kind of indoor hardware fitting for papering metope, being widely used in the interior decoration etc. in house, office, hotel, hotel.Material is not limited to paper, also comprises other materials.
Because have the advantages that other house decorative materials multiple such as color is various, pattern enriches, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at the developed countries and regions such as American-European, Japanese.
Wallpaper is divided into a lot of class, as overlay film wallpaper, coating wallpaper, embossing wallpaper etc.Usually produce body paper with bleached wood pulp, then through the processing process of different operation, cover as coating, printing, embossing or surface and mould, dispatch from the factory after cutting, packing.There is certain intensity, toughness, appearance attractive in appearance and good water repelling property.
Wallpaper is the important component part of Modern Interior Decoration material, is one of indoor wall surface primary decoration finishing material, because wallpaper has good decorative effect, so obtain applying more and more widely.Along with improving constantly of socioeconomic development and people's level of production, hotel and house emerge in multitude, and people require more and more higher to the fitting-up of indoor, more focus on the decorative effect of surface of wall.At present, increasing people is devoted to the research of wallpaper, but research stays in the decorative effect aspect of wallpaper mostly, as changed the aspects such as pattern, more focuses on surface.And after wallpaper more applies and be Indoor environment finishing, occupy indoor very large area, if it can have some function, as antibacterial functions, then can play good effect.And the wallpaper of prior art does not all possess antibacterial functions.Prior art more focuses on the fancy design on surface, the collocation of color and the decorative effect of entirety, few to the functional emphasis of wallpaper, especially to the antibiotic property of wallpaper, the research of health application function is not enough, can not meet consumers in general to the requirement of wallpaper with antibacterial functions.In order to adapt to the needs of special space environment, the place that as crowded in hospital, school etc. and bacterium is easily propagated, the wallpaper as decorative material for internal wall should have antibacterial function.Therefore, people urgently wish that a kind of antibacterial wallpaper and preparation method thereof is come out.
The environment for use of wallpaper is often subject to the restriction of its performance, particularly in the place that ambient humidity is larger, also have larger requirement to the humidity resistance of wallpaper, otherwise greatly will reduce the service life of wallpaper.
Summary of the invention
The object of this invention is to provide a kind of wallpaper preparation method with good antibacterial protection against the tide.
For reaching above-mentioned purpose, providing a kind of preparation method of 1 one kinds of moisture-proof, antibiotic wallpapers in one embodiment of the present of invention, comprising the following steps:
1), choose substrate layer, and on substrate layer, form the figuratum printed layers of tool by typography, obtained wallpaper semi-finished product;
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process;
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; Be completed for printing and be placed on drying in oven;
Wherein the raw material components of antibiotic layer comprises: water lustering oil 50 parts ~ 100 parts, antiseptic 5 parts ~ 10 parts;
The raw material components of damp-proof layer comprises: EHMA 50 parts ~ 100 parts, bisphenol A type epoxy resin 20 parts ~ 50 parts, polyacrylic resin 10 parts ~ 30 parts, ethyl acetate 10 parts ~ 30 parts, antimonous oxide 0.1 part ~ 1 part, 0.1 part ~ 1 part, aluminium hydroxide, sodium carboxymethylcellulose 1 part ~ 5 parts, DBSA 1 part ~ 5 parts.
Preferably, substrate layer is the one in PVC coated paper, pure paper, non-woven paper, nonwoven fabric, gauze or gauze.
Preferably, the typography of substrate layer formation pattern comprises gravure, convex print, screen printing, ink-jet, printing, brushing, drawing or anglicanum.
Preferably, the raw material of Jinsha layer comprises
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
Preferably, the feedstock composition preparation method of Jinsha layer is: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion again, low whipping speed is under 500 ~ 2000r/min condition, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
Preferably, the method for preparing raw material of antibiotic layer is
Take component by weight, water lustering oil is placed in homogenizer, under the rotating speed of 500r/min ~ 2000r/min, add antiseptic stir 10min ~ 30min.
Preferably, the raw material amount of antibiotic layer is 15g/m
2~ 100g/m
2; The raw material amount of described damp-proof layer is 100g/m
2~ 300g/m
2; The coating thickness of described dryness glue-line is 2mm ~ 5mm.
Preferably, diaphragm is attached with outside Jinsha layer.
Preferably, antiseptic is Inorganic Ag System Antimicrobial Agents.
Preferably, water lustering oil is water-based matte gloss oil or transparent highlight water-based gloss oil.
In sum, the present invention has the following advantages:
The present invention, by adhering to antibiotic layer in wallpaper, can playing good antibacterial effect, simultaneously by being optimized the formula of damp-proof layer, reaching more excellent moisture effect.
Detailed description of the invention
The preparation of raw material
1, the preparation of antibiotic layer raw material:
Method one:
A, component: water-based matte gloss oil 60 parts, Inorganic Ag System Antimicrobial Agents 6 parts;
B, preparation method: take component by weight, water lustering oil is placed in homogenizer, add antiseptic and stir 15min under the rotating speed of 1000r/min; Obtain the antimicrobial mix for the formation of antibiotic layer.
Method two:
A, component: transparent highlight water-based gloss oil 80 parts, Inorganic Ag System Antimicrobial Agents 5 parts;
B, preparation method: take component by weight, water lustering oil is placed in homogenizer, add antiseptic and stir 20min under the rotating speed of 2000r/min; Obtain the antimicrobial mix for the formation of antibiotic layer.
2, the preparation of Jinsha layer raw material:
A, component:
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
B, preparation method: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion, low whipping speed is under 500 ~ 2000r/min condition again, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
Embodiment 1
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, sodium carboxymethylcellulose 2 parts, DBSA 1 part.
Embodiment 2
1), choose pure paper as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of screen printing, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50/min; Oven temperature is first with 150 DEG C of oven dry, then forms adhesion effect by 200 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 50g/m
2; The raw material amount of damp-proof layer is 200g/m
2; The coating thickness of dryness glue-line is 4mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, sodium carboxymethylcellulose 2 parts, DBSA 1 part.
Damp-proof layer raw material components is on the impact of moisture effect
Embodiment 3
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, sodium carboxymethylcellulose 2 parts, DBSA 1 part.
Embodiment 4
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, DBSA 1 part.
Embodiment 5
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, sodium carboxymethylcellulose 2 parts.
Embodiment 6
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part.
Moisture-resistant test
The wallpaper that the described method of embodiment 3 ~ 6 is produced is carried out water vapour transit dose mensuration.
Test standard: ASTMF372; 2
Testing equipment: automatic multiple-head moisture-inhibiting analyzer
Experimental enviroment: 37 DEG C, RH=100%
Result of the test is as table 1:
Table 1: the moisture-vapor transmission (24h) in embodiment 3 ~ 6
| Embodiment | Moisture-vapor transmission |
| Embodiment 3 | 0.12g/m 2 |
| Embodiment 4 | 0.18g/m 2 |
| Embodiment 5 | 0.25g/m 2 |
| Embodiment 6 | 0.32g/m 2 |
Can be learnt by the comparing result of table 1, antimonous oxide, aluminium hydroxide and sodium carboxymethylcellulose is not added in embodiment 6, its moisture-vapor transmission is higher than embodiment 3 ~ 5, illustrate and after adding DBSA, aluminium hydroxide and sodium carboxymethylcellulose, the humidity resistance of wallpaper to be had a certain upgrade, wherein comparatively remarkable to the lifting of humidity resistance to add in embodiment 3 after DBSA and sodium carboxymethylcellulose, the wallpaper humidity resistance prepared of the embodiment 4 adding aluminium hydroxide and DBSA also tool has a distinct increment.In sum, the present invention can promote the humidity resistance of damp-proof layer adding DBSA, aluminium hydroxide and sodium carboxymethylcellulose, and then improves moisture effect.
Claims (10)
1. a preparation method for moisture-proof, antibiotic wallpaper, comprises the following steps:
1), choose substrate layer, and on substrate layer, form the figuratum printed layers of tool by typography, obtained wallpaper semi-finished product;
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process;
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; Be completed for printing and be placed on drying in oven;
The raw material components of wherein said antibiotic layer comprises: water lustering oil 50 parts ~ 100 parts, antiseptic 5 parts ~ 10 parts; The raw material components of described damp-proof layer comprises: EHMA 50 parts ~ 100 parts, bisphenol A type epoxy resin 20 parts ~ 50 parts, polyacrylic resin 10 parts ~ 30 parts, ethyl acetate 10 parts ~ 30 parts, antimonous oxide 0.1 part ~ 1 part, 0.1 part ~ 1 part, aluminium hydroxide, sodium carboxymethylcellulose 1 part ~ 5 parts, DBSA 1 part ~ 5 parts.
2. preparation method as claimed in claim 1, is characterized in that: described substrate layer is the one in PVC coated paper, pure paper, non-woven paper, nonwoven fabric, gauze or gauze.
3. preparation method as claimed in claim 1, is characterized in that: the typography that described substrate layer forms pattern comprises gravure, convex print, screen printing, ink-jet, printing, brushing, drawing or anglicanum.
4. preparation method as claimed in claim 1, is characterized in that: the raw material of described Jinsha layer comprises
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
5. preparation method as claimed in claim 4, it is characterized in that: the feedstock composition preparation method of described Jinsha layer is: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion again, low whipping speed is under 500 ~ 2000r/min condition, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
6. preparation method as claimed in claim 1, is characterized in that: the preparation method of described antibiotic layer raw material is:
Take component by weight, water lustering oil is placed in homogenizer, under the rotating speed of 500r/min ~ 2000r/min, add antiseptic stir 10min ~ 30min.
7. preparation method as claimed in claim 1, is characterized in that: the raw material amount of described antibiotic layer is 15g/m
2~ 100g/m
2; The raw material amount of described damp-proof layer is 100g/m
2~ 300g/m
2; The coating thickness of described dryness glue-line is 2mm ~ 5mm.
8. preparation method as claimed in claim 1, is characterized in that: be attached with diaphragm outside described Jinsha layer.
9. preparation method as claimed in claim 1, is characterized in that: described antiseptic is Inorganic Ag System Antimicrobial Agents.
10. preparation method as claimed in claim 1, is characterized in that: described water lustering oil is water-based matte gloss oil or transparent highlight water-based gloss oil.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810082408.6A CN108360302B (en) | 2015-10-26 | 2015-10-26 | Wallpaper |
| CN201510695669.1A CN105401487B (en) | 2015-10-26 | 2015-10-26 | A kind of preparation method of moisture-proof, antibiotic wallpaper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510695669.1A CN105401487B (en) | 2015-10-26 | 2015-10-26 | A kind of preparation method of moisture-proof, antibiotic wallpaper |
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|---|---|---|---|
| CN201810082408.6A Division CN108360302B (en) | 2015-10-26 | 2015-10-26 | Wallpaper |
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| CN105401487A true CN105401487A (en) | 2016-03-16 |
| CN105401487B CN105401487B (en) | 2018-09-25 |
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| CN201810082408.6A Active CN108360302B (en) | 2015-10-26 | 2015-10-26 | Wallpaper |
| CN201510695669.1A Expired - Fee Related CN105401487B (en) | 2015-10-26 | 2015-10-26 | A kind of preparation method of moisture-proof, antibiotic wallpaper |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803857A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly wallpaper |
| CN105803851A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly inflaming retardant wallpaper |
| CN106117979A (en) * | 2016-07-28 | 2016-11-16 | 江苏昌悦重工科技有限公司 | A kind of moistureproof electric power box |
| CN106833312A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of Antimicrobial preservative wallpaper and preparation method thereof |
| CN106906699A (en) * | 2017-04-06 | 2017-06-30 | 合肥欧克斯新型建材有限公司 | A kind of moistureproof mosquito repellent wallpaper |
| CN108621620A (en) * | 2018-03-16 | 2018-10-09 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of bankbook printing technology |
| CN108656768A (en) * | 2018-03-16 | 2018-10-16 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of deposit receipt printing method |
| CN112323541A (en) * | 2020-08-20 | 2021-02-05 | 安徽紫荆花墙饰材料股份有限公司 | Production method of antibacterial and antibacterial wallpaper |
| CN113981745A (en) * | 2021-11-10 | 2022-01-28 | 江海职业技术学院 | Green's high wearability fireproof wallpaper |
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| CN104481106A (en) * | 2014-12-15 | 2015-04-01 | 广东玉兰装饰材料有限公司 | Wallpaper and preparation process of wallpaper |
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| CN101356314A (en) * | 2005-12-15 | 2009-01-28 | 陶氏环球技术公司 | Improved cellulose articles containing an additive composition |
| CN102660908A (en) * | 2012-05-14 | 2012-09-12 | 广东玉兰装饰材料有限公司 | Antibacterial wallpaper and preparation method thereof |
| CN102953514A (en) * | 2012-11-21 | 2013-03-06 | 吴江杰杰织造有限公司 | Novel wallpaper |
| CN104452476A (en) * | 2014-12-12 | 2015-03-25 | 广东玉兰装饰材料有限公司 | Sand wallpaper and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803857A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly wallpaper |
| CN105803851A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly inflaming retardant wallpaper |
| CN106117979A (en) * | 2016-07-28 | 2016-11-16 | 江苏昌悦重工科技有限公司 | A kind of moistureproof electric power box |
| CN106833312A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of Antimicrobial preservative wallpaper and preparation method thereof |
| CN106906699A (en) * | 2017-04-06 | 2017-06-30 | 合肥欧克斯新型建材有限公司 | A kind of moistureproof mosquito repellent wallpaper |
| CN108621620A (en) * | 2018-03-16 | 2018-10-09 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of bankbook printing technology |
| CN108656768A (en) * | 2018-03-16 | 2018-10-16 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of deposit receipt printing method |
| CN112323541A (en) * | 2020-08-20 | 2021-02-05 | 安徽紫荆花墙饰材料股份有限公司 | Production method of antibacterial and antibacterial wallpaper |
| CN113981745A (en) * | 2021-11-10 | 2022-01-28 | 江海职业技术学院 | Green's high wearability fireproof wallpaper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108360302A (en) | 2018-08-03 |
| CN105401487B (en) | 2018-09-25 |
| CN108360302B (en) | 2021-01-01 |
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