CN105401234B - A kind of screw extruding method of composite fibre - Google Patents
A kind of screw extruding method of composite fibre Download PDFInfo
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- CN105401234B CN105401234B CN201511016336.8A CN201511016336A CN105401234B CN 105401234 B CN105401234 B CN 105401234B CN 201511016336 A CN201511016336 A CN 201511016336A CN 105401234 B CN105401234 B CN 105401234B
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- polyamide
- composite fibre
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/082—Melt spinning methods of mixed yarn
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/04—Melting filament-forming substances
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
Abstract
The present invention discloses a kind of screw extruding method of composite fibre, the composite fibre is composed of the following components: polyamide 66 spinning chips, low temperature terylene spinning slice and polytetrafluoroethylene (PTFE), twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six;Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six;It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.Polyamide 66 and the progress of low temperature terylene is compound, there is not the advantages of sufficient chemical reaction, each fiber still keeps respective physicochemical property, makes two kinds of fibers to concentrate on one between component, respective disadvantage is mutually made up, and performance is largely increased.
Description
Technical field
The invention belongs to production of chemical fibre fields, are related to the melt and dissolved method of chemical fibre, and in particular to composite fibre
Screw extruding method.
Background technique
It is raw material that chemical fibre, which is with natural polymer or artificial synthesized high-molecular compound, is spun by preparation
The processes such as silk stock solution, the spinning and post-processing fiber obtained with textile performance.Chemical fibre is divided into staple fibre and conjunction again
At fiber two major classes: 1. staple fibre is chemical fibre made of raw material with natural polymer (such as cellulose), such as viscous
Glue fiber, acetate fiber.2. synthetic fibers, such as poly- using artificial synthesized high-molecular compound as chemical fibre made of raw material
Ester fiber, poly- phthalein amine fiber, poly internal olefins nitrile fiber.Chemical fibre have intensity is high, wear-resisting, density is small, elasticity is good, it is not mouldy,
It is not afraid of the advantages that damaging by worms, is quick-drying washable, but the disadvantage is that dyeability is poor, electrostatic is big, fast light and weatherability is poor, water imbibition is poor.
Staple fibre mainly has viscose rayon, nitric acid ester fiber, acetate fiber, cuprammonium rayon and Azlon etc.,
Its towel viscose rayon point common viscose fiber and has New Viscose Fibre (such as high-wet-modulus fibres, superpower viscous of outstanding properties again
Glue fiber and permanent curl viscose rayon etc.).
Synthetic fibers mainly have daiamid-6 fiber, and poly internal olefins nitrile fiber gathers and matches fiber, poly internal olefins fiber, polyvinyl alcohol contracting
Formaldehyde fibers and special fibre.The 1950s carries out the study on the modification of synthetic fibers, mainly with physically or chemically side
Method improves the properties such as moisture absorption, dyeing, antistatic, fire-resistant, anti-pollution, the anti pilling of synthetic fibers, while also adding chemical fibre
Kind.
Usually first spinning melt is made in natural or synthesis polymer substance or inorganic matter by the preparation of chemical fibre
Or solution, liquid thread is then extruded as by spinning head (plate) by filtering, metering, then solidification forms fiber.At this time
Fiber is known as as-spun fibre, its mechanical property is very poor, it is necessary to by a series of post-processing procedures could accord with textile process and
Requirement.Post-processing carries out stretching and heat setting mainly for fiber, to improve the mechanical property and dimensional stability of fiber:
Stretching is to be orientated macromolecular or structural unit in as-spun fibre along fiber axis, and heat setting mainly makes internal stress pine in fiber
It relaxes.When spinning filament yarn, cylinder can be wound into through above-mentioned operation;The processes such as curling, cutting and packing must also be increased when staple fiber processed.
Polyamide fibre, that is, Fypro, wearability is better than cotton fiber, there is 4-6g/D under strength dry state, and strong has 7-
9.5g/D, sunlight resistance can protrude, and fiber is made at 255-260 DEG C or so, with melt spinning in fusing point.Terylene is a kind of common fibre
Dimension, wrinkle resistance is good, but terylene regain is low, there was only 0.4% when under standard state, when use phenomenon easy to produce static electricity.Hair
Bright people has found in the implementation of the present invention, and polyamide fibre and terylene are combined with each other and can make full use of respective advantage, and
Respective disadvantage is made up.But because of the difference of recipe ingredient and dosage, in the technical process of extrusion forming, different is squeezed
It presses temperature to influence the quality of composite fibre very big, in the case where no experiment condition or knowhow, has much not
Predictable factor.
Summary of the invention
In consideration of it, it is an object of that present invention to provide a kind of screw extrudings that can be improved polyamide fibre and terylene composite fibre quality
Method.
In order to solve the above technical problems, technical solution provided by the invention is to provide a kind of screw extruding of composite fibre
Method, the composite fibre are grouped as by following weight percentage group:
Polyamide 66 spinning chips: 50%-60%,
Low temperature terylene spinning slice: 35%-50%,
Polytetrafluoroethylene (PTFE): 3%-7%;
Twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six, and temperature is
One 260~262 DEG C of area, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, six
265~268 DEG C of area;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, and temperature is an area 258
~260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the composite fibre is by following
Weight percentage group is grouped as:
Polyamide 66 spinning chips: 50%,
Low temperature terylene spinning slice: 43%,
Polytetrafluoroethylene (PTFE): 7%.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the composite fibre is by following
Weight percentage group is grouped as:
Polyamide 66 spinning chips: 60%,
Low temperature terylene spinning slice: 35%,
Polytetrafluoroethylene (PTFE): 5%.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the composite fibre is by following
Weight percentage group is grouped as:
Polyamide 66 spinning chips: 57%,
Low temperature terylene spinning slice: 50%,
Polytetrafluoroethylene (PTFE): 3%.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the composite fibre is by following
Weight percentage group is grouped as:
Polyamide 66 spinning chips: 55%,
Low temperature terylene spinning slice: 42%,
Polytetrafluoroethylene (PTFE): 3%.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the composite fibre is by following
Weight percentage group is grouped as:
Polyamide 66 spinning chips: 50%,
Low temperature terylene spinning slice: 50%.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the concentric type spinning head packet
It includes a central circular spinning head and an annular spinning head being arranged concentrically is constituted.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, the concentric type spinning head packet
It includes a central circular spinning head and a fan annular spinning head being arranged concentrically is constituted.
A specific embodiment of the screw extruding method of composite fibre according to the present invention, polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head is fanned.
Compared with prior art, a technical solution in above-mentioned technical proposal has the advantages that
Polyamide 66 and the progress of low temperature terylene is compound, there is not sufficient chemical reaction between component, each fiber is still protected
The advantages of holding respective physicochemical property, making two kinds of fibers concentrates on one, and respective disadvantage is mutually made up, and performance obtains substantially
It improves.
Specific embodiment
It is illustrated combined with specific embodiments below.
Embodiment 1
The composite fibre is grouped as by following weight percentage group:
Polyamide 66 spinning chips: 50%,
Low temperature terylene spinning slice: 43%,
Polytetrafluoroethylene (PTFE): 7%.
Twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six, and temperature is
One 260~262 DEG C of area, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, six
265~268 DEG C of area;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, and temperature is an area 258
~260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.This is same
Cardioid spinning head includes that a central circular spinning head and an annular spinning head being arranged concentrically are constituted.Polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head.
Melting carries out subsequent processing after spinning head ejection, using existing method, to complete spinning work.
Embodiment 2
Composite fibre is grouped as by following weight percentage group:
Polyamide 66 spinning chips: 60%,
Low temperature terylene spinning slice: 35%,
Polytetrafluoroethylene (PTFE): 5%.
Twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six, and temperature is
One 260~262 DEG C of area, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, six
265~268 DEG C of area;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, and temperature is an area 258
~260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.This is same
Cardioid spinning head includes that a central circular spinning head and an annular spinning head being arranged concentrically are constituted.Polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head.
Melting carries out subsequent processing after spinning head ejection, using existing method, to complete spinning work.
Embodiment 4
Composite fibre is grouped as by following weight percentage group:
Polyamide 66 spinning chips: 57%,
Low temperature terylene spinning slice: 50%,
Polytetrafluoroethylene (PTFE): 3%.
Twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six, and temperature is
One 260~262 DEG C of area, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, six
265~268 DEG C of area;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, and temperature is an area 258
~260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.This is same
Cardioid spinning head includes that a central circular spinning head and an annular spinning head being arranged concentrically are constituted.Polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head.
Melting carries out subsequent processing after spinning head ejection, using existing method, to complete spinning work.
Embodiment 5
Composite fibre is grouped as by following weight percentage group:
Polyamide 66 spinning chips: 55%,
Low temperature terylene spinning slice: 42%,
Polytetrafluoroethylene (PTFE): 3%.
Embodiment 6
Composite fibre is grouped as by following weight percentage group:
Polyamide 66 spinning chips: 50%,
Low temperature terylene spinning slice: 50%.
Twin (double) screw extruder is added in polyamide 66 spinning chips, heating zone is six, and temperature is an area 260~262
DEG C, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, six areas 265~268
℃;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, and temperature is an area 258
~260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
It regard polyamide 66 melting and the melting of low temperature terylene as spinning material, spinning is sprayed by concentric type spinning head.This is same
Cardioid spinning head includes that a central circular spinning head and an annular spinning head being arranged concentrically are constituted.Polyamide 66 melting from
Central circular spinning head sprays spinning, and the melting of low temperature terylene sprays spinning from annular spinning head.
Melting carries out subsequent processing after spinning head ejection, using existing method, to complete spinning work.
In above-described embodiment, annular spinning head can be by fanning annular spinning head replacement.
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change
It also should be regarded as protection scope of the present invention into retouching.
Claims (6)
1. a kind of screw extruding method of composite fibre, which is characterized in that the composite fibre is by following weight percentage component
Composition: polyamide 66 spinning chips: 50%-60%, low temperature terylene spinning slice: 35%-50%, polytetrafluoroethylene (PTFE): 3%-
7%;
Twin (double) screw extruder is added in polyamide 66 spinning chips and polytetrafluoroethylene (PTFE), heating zone is six, and temperature is an area
260~262 DEG C, 265~268 DEG C of 2nd area, 265~268 DEG C of 3rd area, 265~268 DEG C of 4th area, 265~268 DEG C of 5th area, 6th area
265~268 DEG C;
Low temperature terylene spinning is sliced, another twin (double) screw extruder is added, heating zone is six, temperature be an area 258~
260 DEG C, 263~265 DEG C of 2nd area, 263~265 DEG C of 3rd area, 263~265 DEG C of 4th area, 263~265 DEG C of 5th area, six areas 263~
265℃;
Using melting extrusion after polyamide 66 and polytetrafluoroethylene (PTFE) mixing addition twin (double) screw extruder as spinning material, meanwhile, it will
Another twin (double) screw extruder melting extrusion is added as spinning material in low temperature terylene, sprays spinning by concentric type spinning head.
2. a kind of screw extruding method of composite fibre according to claim 1, which is characterized in that the composite fibre by
Following weight percentage group is grouped as: polyamide 66 spinning chips: 50%, low temperature terylene spinning slice: and 43%, polytetrafluoroethyl-ne
Alkene: 7%.
3. a kind of screw extruding method of composite fibre according to claim 1, which is characterized in that the composite fibre by
Following weight percentage group is grouped as: polyamide 66 spinning chips: 60%, low temperature terylene spinning slice: and 35%, polytetrafluoroethyl-ne
Alkene: 5%.
4. a kind of screw extruding method of composite fibre according to claim 1, which is characterized in that the composite fibre by
Following weight percentage group is grouped as: polyamide 66 spinning chips: 57%, low temperature terylene spinning slice: and 50%, polytetrafluoroethyl-ne
Alkene: 3%.
5. a kind of screw extruding method of composite fibre according to claim 1, which is characterized in that the composite fibre by
Following weight percentage group is grouped as: polyamide 66 spinning chips: 55%, low temperature terylene spinning slice: and 42%, polytetrafluoroethyl-ne
Alkene: 3%.
6. a kind of screw extruding method of composite fibre according to claim 1, which is characterized in that the concentric type spinneret
Head includes that a central circular spinning head and an annular spinning head being arranged concentrically are constituted.
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CN105386140B (en) * | 2015-12-29 | 2018-04-27 | 重庆市大通茂纺织科技有限公司 | A kind of chemical fibre ring blows cooling means |
CN106283230A (en) * | 2016-10-14 | 2017-01-04 | 海安县中山合成纤维有限公司 | A kind of production method of brocade/wash high-strength compound monofilament |
US20190345644A1 (en) * | 2016-12-27 | 2019-11-14 | Sabic Global Technologies B.V. | Fibers comprising fibrillated reinforcement material |
CN113430657B (en) * | 2021-06-25 | 2022-05-24 | 江苏恒力化纤股份有限公司 | Method for reducing spinning temperature of polyester industrial yarn |
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