CN104278338A - Gel spinning method for manufacturing aramid fiber III - Google Patents
Gel spinning method for manufacturing aramid fiber III Download PDFInfo
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- CN104278338A CN104278338A CN201410621783.5A CN201410621783A CN104278338A CN 104278338 A CN104278338 A CN 104278338A CN 201410621783 A CN201410621783 A CN 201410621783A CN 104278338 A CN104278338 A CN 104278338A
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- aramid iiii
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/06—Washing or drying
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
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- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Artificial Filaments (AREA)
Abstract
The invention provides a gel spinning method for manufacturing aramid fiber III, belonging to the technical field of chemical synthesis fibers. The gel spinning method comprises the following technological steps: A. extruding a spinning stock solution through a metering pump and a spinneret to form fine flow entering an air layer; B. leading the extruded fine flow passing through the air layer to enter first-level freezing liquid to form gel fibers and treating by adopting negative stretching; C. leading the gel fibers to enter second-level freezing liquid, performing plasticized positive stretching and further freezing to form aramid fiber III with a collection state primary structure; D. washing, oiling and drying the secondarily frozen and formed aramid fiber III to obtain aramid fiber III protofilament; and E. performing heat setting to the aramid fiber III protofilament to obtain finished fibers. According to the gel spinning method, the performance of the aramid fiber III products can be further improved, the fiber production efficiency can be markedly increased, the fiber impregnation strength of the finished fiber is improved to 5.8GPa, and the spinning speed achieves 30-100m/min.
Description
Technical field
The present invention relates to a kind of spinning process of aramid IIII fiber, more particularly, the present invention relates to a kind of spinning technique adopting gel spinning to manufacture aramid IIII fiber, belong to chemical synthetic fiber technical field.
Background technology
Aramid fiber III polymer is by paraphthaloyl chloride, and p-phenylenediamine (PPD), the three kinds of monomer copolycondensations of 5 (6)-amido-2-(4-aminocarbonyl phenyl) benzimidazole form, and polymer is by manufacturing high performance aramid IIII fiber after spinning.Aramid IIII fiber has high strength, high-modulus, high temperature resistant, corrosion resistant excellent properties, is usually used in manufacturing fibre reinforced composites, is widely used in the Application Areas such as aircraft component, armoring shellproof, individual soldier protection, advance automotive.
Current disclosed aramid IIII fiber spining technology has wet spinning, dry spinning, dry-wet spinning method, and wherein real the domestic of industrialization only has wet spinning process at present.Chinese patent 201010108545.6 discloses a kind of high-performance heterocyclic aramid fiber and Synthesis and applications thereof, and adopt wet spinning process, its wet spinning step comprises: spray silk, and solidify, plasticization drawing, washing, oils, dry, heat treatment, the steps such as surface treatment.Although the aramid IIII fiber not only excellent performance adopting this technology to manufacture, and obtain market accreditation.But the wet-spinning techniques spinning speed of aramid fiber III is comparatively slow, and production efficiency is lower, causes procedure of fibre production cost very high, makes fiber be difficult to obtain large-scale application and promote.
Chinese patent 201010192686.0 discloses a kind of preparation method of aramid IIII fiber, comprise: (1) synthesis spinning solution: adopt p-phenylenediamine (PPD), paraphthaloyl chloride and 5 (6)-amido-2-(4-aminocarbonyl phenyl) benzimidazole, three kinds of monomers to be raw material, with dimethylacetylamide/lithium chloride for the copolymerization of solvent low temperature; (2) adopt dry-spinning process spinning, after spinning head, directly enter hot inert gas path by previous step gained spinning solution, utilize hot inert gas by the solvent evaporation removing in spinning solution, obtain the precursor solidified; (3) by precursor through washing and heat treatment after, through reel, obtain aramid IIII fiber.The method is dry spinning, and its spinning solution solid content is high, and spinning speed is fast, and spinning efficiency increases substantially, and fiber manufacturing cost obviously reduces, and obtained aramid IIII fiber mechanical property is improved, and has broad prospect of application.But owing to there is the associated real world problem such as technical maturity and through engineering approaches difficulty, this technology has no commercial application.
Chinese patent 201310494249.8 discloses a kind of dry spray-wet-spinning method manufacturing aramid IIII fiber that middle blue morning twilight chemical research designing institute develops in wet spinning technical foundation.Although this invention has increased substantially spinning speed and the production efficiency of aramid IIII fiber, effectively reduce procedure of fibre production cost, and the fiber manufactured also has premium properties and exterior quality, cost performance is high, but still need further to improve in fibre property.
Gel spinning, also known as gel spinning, belongs to solution-polymerized SBR category.During spinning, spinning solution there is no sovent diffusion in solidification forming process, only heat exchange occurs, and thus as-spun fibre contains a large amount of solvent, in gel state.So far, the technology of gel spinning has more and more leveled off to maturation, in the production of high-strength high-modulus fibre, have very important status.The PVA fiber of gel method production, PTFE fiber, UHMWPE fiber have been widely used in various field, and Patents document is as follows:
Chinese patent 200980146604.4 discloses a kind of gel spinning process preparing UHMWPE fiber, and described method comprises the following steps: a) slurry containing UHMWPE and spin solvent to be supplied to extruder; B) slurry is made to change the solution of UHMWPE in spin solvent in an extruder into; C) make step b) solution by comprising the spinnerets of multiple spinneret orifice thus being spun into fluid UHMWPE fiber; D) cool this fluid UHMWPE fiber thus form gel UHMWPE fiber; E) from gel UHMWPE fiber, spin solvent is removed at least partly; And f) before removing spin solvent, period or the UHMWPE fiber that stretches at least one stretching step afterwards, the every cm of described spinnerets
2there are 6 spinneret orifices at the most.
Chinese patent 201110223871.6 discloses a kind of method manufacturing superhigh molecular weight polyethylene fibers gel spinning, ultrahigh molecular weight polyethylene powder and solvent is carried out preliminary treatment through double screw extruder under certain condition, obtains extruding liquid; Above-mentioned liquid of extruding is processed again through single screw extrusion machine under certain condition, obtains extruded material; By above-mentioned extruded material under certain condition through techniques such as spray silk, static balance, extraction, preliminary elongational, ultra-drawings, obtain superhigh molecular weight polyethylene fibers gel spinning.The invention solves in existing superhigh molecular weight polyethylene fibers gel spinning technical process, the too high shearing force of high temperature was used for making strand superelevation orientation, thus cause the technical problem that strand severely degrade, screw efficiency are low, substantially increase the spinnability of fiber thread, improve its molecularly oriented, enhance its strength and toughness.
But, adopt gel method to produce aramid IIII fiber and but have no relevant report up to now.
Summary of the invention
The object of the present invention is to provide one with known polymer fluid for raw material, employing gel spinning technology continous-stable manufactures the method for aramid IIII fiber product.The method not only effectively can improve spinning speed, and further increases fibrous mechanical property, improves while achieving production efficiency and properties of product.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of manufacture aramid IIII fiber gel spinning process, is characterized in that processing step is as follows:
A, spinning solution are measured through measuring pump and are extruded formation thread by spinning head and enter one section of height 5 ~ 30mm air layer;
B, entered in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer, fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-40 ~-90%;
C, gelatinous fibre enter in the second level solidification liquid of higher concentration, and through plasticization drawing and simultaneously further solidification forming is the fiber with state of aggregation primary structure, and gelatinous fibre adopts to plastify and just stretches in the solidification liquid of the second level, and positive extensibility is 80 ~ 160%;
D, through the aramid IIII fiber with state of aggregation primary structure of secondary solidification forming by washing, oil, drying process obtains aramid IIII fiber precursor;
E, aramid IIII fiber precursor become finished fiber after HEAT SETTING process.
The intrinsic viscosity of the spinning solution polymer described in steps A is 5 ~ 9dL/g.Within the scope of this intrinsic viscosity, both can not be too large because of intrinsic viscosity, polymer dissolution performance declines, and causes production efficiency to reduce; Also can not be too little because of intrinsic viscosity, and fibre property is reduced.
Described in steps A, the air layer of height, both can avoid because air layer height is too high, and it is serious by air flow effect that thread extruded by spinning head, the problem of easy doubling; There will not be again because air layer is too low, be subject to solidification liquid influence of fluctuations, cause the situation of spinning instability.Wherein air layer height is preferably 10 ~ 20mm.
First order solidification liquid described in step B is the mixed liquor of organic solvent and water.Described organic solvent is any one in ethanol, DMA, DMF, 1-METHYLPYRROLIDONE.
The content of organic solvent described in first order solidification liquid is 1 ~ 20%wt.Organic solvent content is too high, causes spinning head to extrude thread coagulation result in solidification liquid and is deteriorated, thus be unfavorable for the enforcement of postorder stretch orientation technique.Wherein in first order solidification liquid, organic solvent content is preferably 5 ~ 15%wt.
Under the negative stretch ratio of in stepb-40 ~-90%, both can not be too large because of negative stretch ratio, cause and thread formation gel state generation deleterious effects is extruded to spinning head; Again can not be too little because of negative stretch ratio, cause fiber normally cannot draw spinning.
Second level solidification liquid described in step C adopts has the organic solvent of same composition and the mixed liquor of water with first order solidification liquid.Described organic solvent is any one in ethanol, DMA, DMF, 1-METHYLPYRROLIDONE.
The content of organic solvent described in the solidification liquid of the second level is 20 ~ 40%wt.As the organic solvent content in the solidification liquid of the second level is too low, then the tensility of gelatinous fibre can reduce, thus affects fibre property; And organic solvent content is too high, solidification liquid and gelatinous fibre internal solvent concentration difference can be caused again too large, and coagulation result is deteriorated, and the organic solvent of high-load also can increase postorder washing procedure load, is difficult to thus remove the impurity in primary filament completely.Wherein in the solidification liquid of the second level, organic solvent content is preferably 25 ~ 35%wt.
Under the positive extensibility of 80% ~ 160% described in step C, both can not be too low because of draw ratio, affect the structural behaviour of finished fiber; Again can not be too high because of draw ratio, and spinning process stability will be worsened, and then fiber quality is impacted.
The washings that washing procedure described in step D adopts are deionized water, and temperature is 80 ~ 95 DEG C.Temperature is too low, and clean result is not good.
The heat treatment method that HEAT SETTING process described in step e is namely conventional, or the method that heat treatment combines with hot-stretch.
Described heat treatment and hot-stretch device are conventional path equipment.Heat treatment temperature is 350 ~ 390 DEG C, and hot-stretch temperature is 390 ~ 430 DEG C.
The invention has the advantages that:
1, relative to conventional wet lay spining technology, the present invention can increase substantially Fiber spinning speeds, improves fibre production efficiency.Gel spinning speed of the present invention reaches 30m/min ~ 100m/min, while raising fibre production efficiency, effectively reduces fiber manufacturing cost.Through putting into practice further proof, adopt inventive gel spin processes to manufacture aramid IIII fiber, not only stable processing technique, and fibre property and exterior quality are held concurrently excellence.
2, gel spinning technology of the present invention further increases fibrous mechanical property.Compare with the fiber of wet spinning technology manufacture, the aramid IIII fiber mechanical property that gel spinning technology manufactures is more excellent, reaches 5.8GPa.In the present invention, spinning head is extruded thread and form gel fast in first order solidification liquid, then enter in the solidification liquid of the second level and fully stretch and solidification forming, be solidified into state of aggregation primary structure, stability and the fiber product quality of spinning technique effectively improve.
3, the apparent state of fiber of the inventive method manufacture is better.Wet spinning technology is owing to limiting by operational characteristic, and the fiber surface of production exists gully, and lousiness phenomenon is difficult to avoid completely.The aramid IIII fiber that gel spinning technology manufactures is without lousiness, and smooth surface, fiber softening, monofilament disperses, and the apparent state of fiber is more excellent.
Detailed description of the invention
Embodiment 1
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 6.5dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 15mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of ethanol and water, and wherein the content of ethanol is 15%wt; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-80%;
C, gelatinous fibre enter in the solidification liquid that the second level ethanol of higher concentration and water forms, and wherein ethanol content is 30%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 160%;
D, adopt the washing of 80 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after Overheating Treatment and hot-stretch; Described heat treatment temperature is 350 DEG C, and hot-stretch temperature is 390 DEG C.
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.6GPa.
Embodiment 2
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 7.2dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 20mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of DMA and water, and wherein the content of DMA is 6%wt; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-70%;
C, gelatinous fibre enter in the solidification liquid that the second level DMA of higher concentration and water forms, and wherein DMA content is 35%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 135%;
D, adopt the washing of 90 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after Overheating Treatment; Described heat treatment temperature is 380 DEG C.
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.5GPa.
Embodiment 3
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 8.1dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 10mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of DMF and water, and wherein the content of DMF is 10%; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-55%;
C, gelatinous fibre enter in the solidification liquid that the second level DMF of higher concentration and water forms, and wherein DMF content is 25%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 110%;
D, adopt the washing of 95 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after Overheating Treatment and hot-stretch; Described heat treatment temperature is 390 DEG C, and hot-stretch temperature is 400 DEG C.
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.8GPa.
Embodiment 4
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 5.0dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 5mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of DMF and water, and wherein the content of DMF is 20%wt; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-40%;
C, gelatinous fibre enter in the solidification liquid that the second level DMF of higher concentration and water forms, and wherein DMF content is 40%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 80%;
D, adopt the washing of 92 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after Overheating Treatment; Described heat treatment temperature is 360 DEG C,
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.3GPa.
Embodiment 5
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 6.9dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 30mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of DMA and water, and wherein the content of DMA is 1%wt; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-63%;
C, gelatinous fibre enter in the solidification liquid that the second level DMA of higher concentration and water forms, and wherein DMA content is 33%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 105%;
D, adopt the washing of 86 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after Overheating Treatment; Described heat treatment temperature is 370 DEG C.
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.7GPa.
Embodiment 6
A kind of manufacture aramid IIII fiber gel spinning process, processing step is as follows:
A, spinning solution polymer intrinsic viscosity are 9.0dL/g, and stoste is extruded through measuring pump accurate-metering and by spinning head and formed thread and enter one section of height 19mm air layer;
B, enter in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer; Described solidification liquid is the mixed liquid of 1-METHYLPYRROLIDONE and water, and wherein the content of 1-METHYLPYRROLIDONE is 13%wt; Fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-90%;
C, gelatinous fibre enter in the solidification liquid that the second level 1-METHYLPYRROLIDONE of higher concentration and water forms, and wherein 1-METHYLPYRROLIDONE content is 20%wt; Gelatinous fibre carries out plastifying the operation of positive stretch orientation in the solidification liquid of the second level, and extensibility is 136%;
D, adopt the washing of 90 DEG C of deionized waters through the aramid IIII fiber of secondary solidification forming, then oil, obtain aramid IIII fiber precursor after drying;
E, fiber precursor become finished fiber after hot-stretch; Described hot-stretch temperature is 430 DEG C.
The aramid fiber III finished fiber impregnation silk intensity of preparation is 5.8GPa.
Claims (10)
1. manufacture an aramid IIII fiber gel spinning process, it is characterized in that processing step is as follows:
A, spinning solution are measured through measuring pump and are extruded formation thread by spinning head and enter one section of height 5 ~ 30mm air layer;
B, entered in the first order solidification liquid of low concentration become gelatinous fibre by the thread of extruding of air layer, fiber adopts negative stretch in first order solidification liquid, and negative stretch ratio is-40 ~-90%;
C, gelatinous fibre enter in the second level solidification liquid of higher concentration, and through plasticization drawing and simultaneously further solidification forming is the fiber with state of aggregation primary structure, and gelatinous fibre adopts to plastify and just stretches in the solidification liquid of the second level, and positive extensibility is 80 ~ 160%;
D, through the aramid IIII fiber with state of aggregation primary structure of secondary solidification forming by washing, oil, drying process obtains aramid IIII fiber precursor;
E, aramid IIII fiber precursor become finished fiber after HEAT SETTING process.
2. manufacture aramid IIII fiber gel spinning process according to claim 1, is characterized in that: the intrinsic viscosity of the spinning solution polymer described in steps A is 5 ~ 9dL/g.
3. manufacture aramid IIII fiber gel spinning process according to claim 1, is characterized in that: the height of air layer described in steps A is 10 ~ 20mm.
4. manufacture aramid IIII fiber gel spinning process according to claim 1, it is characterized in that: the first order solidification liquid described in step B is the mixed liquor of organic solvent and water, described organic solvent is ethanol, N, any one in N-dimethylacetylamide, DMF, 1-METHYLPYRROLIDONE.
5. manufacture aramid IIII fiber gel spinning process according to claim 4, is characterized in that: the content of the organic solvent in described first order solidification liquid is 1 ~ 20%wt.
6. the manufacture aramid IIII fiber gel spinning process according to claim 4 or 5, is characterized in that: the organic solvent content in described first order solidification liquid is preferably 5 ~ 15%wt.
7. manufacture aramid IIII fiber gel spinning process according to claim 1, is characterized in that: the second level solidification liquid described in step C adopts has the organic solvent of same composition and the mixed liquor of water with first order solidification liquid; Described organic solvent is any one in ethanol, DMA, DMF, 1-METHYLPYRROLIDONE.
8. manufacture aramid IIII fiber gel spinning process according to claim 7, is characterized in that: the content of the organic solvent in the solidification liquid of the described second level is 20 ~ 40%wt.
9. the manufacture aramid IIII fiber gel spinning process according to claim 7 or 8, is characterized in that: the organic solvent content in the solidification liquid of the described second level is preferably 25 ~ 35%wt.
10. manufacture aramid IIII fiber gel spinning process according to claim 1, is characterized in that:
The washings that washing procedure described in step D adopts are deionized water, and temperature is 80 ~ 95 DEG C.
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Cited By (4)
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CN106757452A (en) * | 2016-12-26 | 2017-05-31 | 中蓝晨光化工研究设计院有限公司 | A kind of spinning process of aramid IIII fiber |
CN108330560A (en) * | 2018-01-30 | 2018-07-27 | 东莞市联洲知识产权运营管理有限公司 | A kind of preparation method of the ultra-high molecular weight polyethylene/aramid fiber composite nano fiber prepared based on gel electrospinning |
CN110468461A (en) * | 2018-05-10 | 2019-11-19 | 中国科学院苏州纳米技术与纳米仿生研究所 | Polyamide airsetting glue fiber, preparation method and application |
CN113564967A (en) * | 2021-07-09 | 2021-10-29 | 江苏瑞盛新材料科技有限公司 | PPTA gel particles, para-aramid paper and preparation method |
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CN103498204A (en) * | 2013-10-21 | 2014-01-08 | 中蓝晨光化工研究设计院有限公司 | Coagulation shaping method and device for manufacturing aramid III fibers through dry spray-wet spinning method |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106757452A (en) * | 2016-12-26 | 2017-05-31 | 中蓝晨光化工研究设计院有限公司 | A kind of spinning process of aramid IIII fiber |
CN106757452B (en) * | 2016-12-26 | 2019-07-12 | 中蓝晨光化工有限公司 | A kind of spinning process of aramid IIII fiber |
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CN110468461A (en) * | 2018-05-10 | 2019-11-19 | 中国科学院苏州纳米技术与纳米仿生研究所 | Polyamide airsetting glue fiber, preparation method and application |
CN113564967A (en) * | 2021-07-09 | 2021-10-29 | 江苏瑞盛新材料科技有限公司 | PPTA gel particles, para-aramid paper and preparation method |
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