CN105399929A - 包含给受体型噻吩吡啶共聚物的光伏材料的制备方法 - Google Patents

包含给受体型噻吩吡啶共聚物的光伏材料的制备方法 Download PDF

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CN105399929A
CN105399929A CN201510909320.3A CN201510909320A CN105399929A CN 105399929 A CN105399929 A CN 105399929A CN 201510909320 A CN201510909320 A CN 201510909320A CN 105399929 A CN105399929 A CN 105399929A
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pyridine copolymer
photovoltaic material
receptor type
thiophene
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康达莲
赵杰
邓会超
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Suzhou Guohuan Environment Detection Co Ltd
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Suzhou Guohuan Environment Detection Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3229—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing nitrogen and sulfur as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/91—Photovoltaic applications

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Photovoltaic Devices (AREA)

Abstract

本发明属于光伏材料领域，具体涉及一种包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，包括如下步骤：将给受体型噻吩吡啶共聚物50%～60%；SnO21%～10%；硅烷偶联剂1%～2%、硫化亚铜5%～10%、二氯甲烷20%-40%混合后加热到400-500摄氏度并在400-500摄氏度保持1-2h；所述百分比为质量百分含量。本发明既含金属又含共聚物、光能转化率较高。

Description

包含给受体型噻吩吡啶共聚物的光伏材料的制备方法
技术领域
本发明属于光伏材料领域，具体涉及一种包含给受体型噻吩吡啶共聚物的光伏材料的制备方法。
背景技术
现有的光伏材料一般采用共聚物形式或者金属配合物形式，但没有既含金属又含共聚物的材料。
发明内容
本发明的目的在于克服上述问题，提供一种既含金属又含共聚物、光能转化率较高的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法。
为实现上述目的，本发明所采用的技术方案为：包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，包括如下步骤：将给受体型噻吩吡啶共聚物50%～60%；SnO21%～10%；硅烷偶联剂1%～2%、硫化亚铜5%～10%、二氯甲烷20%-40%混合后加热到400-500摄氏度并在400-500摄氏度保持1-2h；所述百分比为质量百分含量。
前述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，所述的给受体型噻吩吡啶共聚物为3-己基噻吩-co-吡啶共聚物，制备过程如下：以2,5-二溴-3-己基噻吩和2,5-二溴吡啶为原料，以1,3-双（二苯基膦）丙烷二氯化镍为催化剂，采用格氏试剂法合成3-己基噻吩-co-吡啶共聚物。
前述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，将给受体型噻吩吡啶共聚物50%～60%；SnO21%～10%；硅烷偶联剂1%～2%、硫化亚铜5%～10%、二氯甲烷20%-40%混合后在30min内加热到400-500摄氏度并在400-500摄氏度保持1-2h。
前述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，还包括如下步骤：在400-500摄氏度保持1-2h后涂布到光伏材料载体表面。
前述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，还包括如下步骤：涂布到光伏材料载体表面后，用冷风对载体表面进行冷却。
前述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，将给受体型噻吩吡啶共聚物60%；SnO25%；硅烷偶联剂2%、硫化亚铜8%、二氯甲烷25%混合后在30min内加热到450摄氏度并在450摄氏度保持1h。
本发明既含金属又含共聚物、光能转化率较高。
具体实施方式
下面结合具体实施例，对本发明技术方案作进一步详细说明。
包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，将给受体型噻吩吡啶共聚物60%；SnO25%；硅烷偶联剂2%、硫化亚铜8%、二氯甲烷25%混合后在30min内加热到450摄氏度并在450摄氏度保持1h。百分比为质量百分含量。所述的给受体型噻吩吡啶共聚物为3-己基噻吩-co-吡啶共聚物，制备过程如下：以2,5-二溴-3-己基噻吩和2,5-二溴吡啶为原料，以1,3-双（二苯基膦）丙烷二氯化镍为催化剂，采用格氏试剂法合成3-己基噻吩-co-吡啶共聚物。在400-500摄氏度保持1-2h后涂布到光伏材料载体表面。涂布到光伏材料载体表面后，用冷风对载体表面进行冷却。
上述实施例得到的光伏材料，计算其光能转换效率，计算在单位面积的光伏材料上的光照总能量以及单位面积的光伏材料储存的电能，单位面积的光伏材料储存的电能除以上述的光照总能量得到光电转换效率为30%。
上述实施例不以任何形式限制本发明，凡采用等同替换或等效变换的方式所获得的技术方案，均落在本发明的保护范围内。

Claims (6)

1.包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，包括如下步骤：
将给受体型噻吩吡啶共聚物50%～60%；SnO21%～10%；硅烷偶联剂1%～2%、硫化亚铜5%～10%、二氯甲烷20%-40%混合后加热到400-500摄氏度并在400-500摄氏度保持1-2h；所述百分比为质量百分含量。
2.根据权利要求1所述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，所述的给受体型噻吩吡啶共聚物为3-己基噻吩-co-吡啶共聚物，制备过程如下：以2,5-二溴-3-己基噻吩和2,5-二溴吡啶为原料，以1,3-双（二苯基膦）丙烷二氯化镍为催化剂，采用格氏试剂法合成3-己基噻吩-co-吡啶共聚物。
3.根据权利要求1所述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，将给受体型噻吩吡啶共聚物50%～60%；SnO21%～10%；硅烷偶联剂1%～2%、硫化亚铜5%～10%、二氯甲烷20%-40%混合后在30min内加热到400-500摄氏度并在400-500摄氏度保持1-2h。
4.根据权利要求1所述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，还包括如下步骤：在400-500摄氏度保持1-2h后涂布到光伏材料载体表面。
5.根据权利要求4所述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，还包括如下步骤：涂布到光伏材料载体表面后，用冷风对载体表面进行冷却。
6.根据权利要求1所述的包含给受体型噻吩吡啶共聚物的光伏材料的制备方法，其特征在于，将给受体型噻吩吡啶共聚物60%；SnO25%；硅烷偶联剂2%、硫化亚铜8%、二氯甲烷25%混合后在30min内加热到450摄氏度并在450摄氏度保持1h。
CN201510909320.3A 2015-12-10 2015-12-10 包含给受体型噻吩吡啶共聚物的光伏材料的制备方法 Pending CN105399929A (zh)

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CN112542554A (zh) * 2019-09-20 2021-03-23 Tcl集团股份有限公司 复合材料及其制备方法和量子点发光二极管

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CN112542554A (zh) * 2019-09-20 2021-03-23 Tcl集团股份有限公司 复合材料及其制备方法和量子点发光二极管
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Application publication date: 20160316