CN105399390A - Method for preparing gypsum binder from titanium gypsum - Google Patents

Method for preparing gypsum binder from titanium gypsum Download PDF

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Publication number
CN105399390A
CN105399390A CN201510840600.3A CN201510840600A CN105399390A CN 105399390 A CN105399390 A CN 105399390A CN 201510840600 A CN201510840600 A CN 201510840600A CN 105399390 A CN105399390 A CN 105399390A
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CN
China
Prior art keywords
gypsum
titanium gypsum
titanium
method utilizing
major ingredient
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510840600.3A
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Chinese (zh)
Inventor
简理
欧阳兆辉
张恒明
周建锋
黄训华
余刚锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Qingjaing Chemical Huanggang Co Ltd
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Wuhan Qingjaing Chemical Huanggang Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Wuhan Qingjaing Chemical Huanggang Co Ltd filed Critical Wuhan Qingjaing Chemical Huanggang Co Ltd
Priority to CN201510840600.3A priority Critical patent/CN105399390A/en
Publication of CN105399390A publication Critical patent/CN105399390A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a method for preparing gypsum binder from titanium gypsum and solves the problems of land occupation, resource waste, environmental pollution and the like in the prior art. The method is characterized in that the titanium gypsum is stirred and mixed uniformly with other raw materials and auxiliary materials, and the general type (G) gypsum binder meeting requirements of the national standard JC/T 1025-2007 can be prepared. According to the method, the use way of the titanium gypsum can be broadened, and the gypsum binder prepared from the titanium gypsum can be used together with titanium gypsum blocks, so that better conditions can be provided for use of large amount of titanium gypsum.

Description

Titanium gypsum is utilized to produce the method for bonding gypsum
Technical field
The invention belongs to gypsum building material technical field, be specifically related to the method that one utilizes titanium gypsum production coventional type (G) bonding gypsum.
Background technology
Along with the production production capacity of China's titanium white powder enterprise constantly increases, the quantity discharged of titanium gypsum increases year by year.Current most domestic titanium white production enterprise is all direct stacking to titanium gypsum, and a large amount of stackings of titanium gypsum not only take a large amount of soil, contaminate environment, returns titanium white production enterprise and brings huge economical load.Titanium gypsum can be utilized effectively become titanium white production enterprise can the key point of sustainable and healthy development.Domestic had titanium white production enterprise to start to utilize titanium gypsum production gypsum block, thus titanium gypsum can be utilized in a large number, utilize titanium gypsum production bonding gypsum can increase the utilization ways of titanium gypsum, the bonding gypsum that titanium gypsum is produced can use together with titanium gypsum building block, thus provides better condition for a large amount of uses realizing titanium gypsum.
summary of the invention:
The object of the invention is to propose a kind of scientific formulation, simple to operate, turn waste into wealth, the method utilizing titanium gypsum production coventional type (G) bonding gypsum of energy-conserving and environment-protective.
Realizing technical solution of the present invention is: the bonding gypsum produced by stirring with the auxiliary material that titanium gypsum, desulfurated plaster and hydraulicity cement are suitable for major ingredient is equipped with, and each raw material obtains by following weight proportion:
Titanium gypsum: 35% ~ 60%
Desulfurated plaster: 30% ~ 60%
Hydraulicity cement: 0% ~ 20%;
The consumption of auxiliary material is to obtain by the part by weight accounting for major ingredient:
Retardant: 0.5 ‰ ~ 5 ‰
Thickening material: 0 ‰ ~ 4 ‰
Binding agent: 0 ‰ ~ 5 ‰
Composite high-early strength water reducer: 0 ‰ ~ 6 ‰.
Described titanium gypsum is the plaster of Paris of titanium gypsum through calcining of titanium white production enterprise by-product.
Described desulfurated plaster is the plaster of Paris of desulfurated plaster through calcining of enterprise's by-products such as coal-burning power plant.
Described hydraulicity cement is 42.5 silicate cements.
Described retardant is gypsum special retarder.
Described thickening material is thickening material Vltra tears general in prior art.
Described binding agent is water-holding agent polyvinyl alcohol 2488 general in prior art.
Described composite high-early strength water reducer is gypsum specific complex early strength water-reducing agent.
The present invention, by being uniformly mixed major ingredient (titanium gypsum, desulfurated plaster and hydraulicity cement) and auxiliary material (retardant, thickening material, binding agent and composite high-early strength water reducer), just can produce coventional type (G) bonding gypsum complied with the national standard requirements.
Beneficial effect of the present invention: utilize the titanium gypsum of titanium dioxide enterprise by-product to produce bonding gypsum, the utilization ways of titanium gypsum can not only be increased, can also use together with titanium gypsum building block, thus provide better condition for a large amount of uses realizing titanium gypsum.
Embodiment
With embodiment, bonding gypsum is produced to titanium gypsum of the present invention and do following explaining.
Embodiment one:
Major ingredient: titanium gypsum: 35kg, desulfurated plaster: 55kg, 42.5 ordinary Portland cements: 10kg;
Auxiliary material: retardant: 0.25kg, hydroxypropyl level methylcellulose gum: 0.2kg, polyvinyl alcohol: 0.25kg, composite high-early strength water reducer: 0.3kg.
Preparation method: above major ingredient and auxiliary material are uniformly mixed the coventional type bonding gypsum just can produced and comply with the national standard requirements.
Embodiment two:
Major ingredient: titanium gypsum: 40kg, desulfurated plaster: 48kg, 42.5 ordinary Portland cements: 12kg;
Auxiliary material: retardant: 0.28kg, hydroxypropyl level methylcellulose gum: 0.2kg, polyvinyl alcohol: 0.25kg, composite high-early strength water reducer: 0.32kg.
Preparation method: above major ingredient and auxiliary material are uniformly mixed the coventional type bonding gypsum just can produced and comply with the national standard requirements.
Embodiment three:
Major ingredient: titanium gypsum: 45kg, desulfurated plaster: 43kg, 42.5 ordinary Portland cements: 12kg;
Auxiliary material: retardant: 0.3kg, hydroxypropyl level methylcellulose gum: 0.25kg, polyvinyl alcohol: 0.3kg, composite high-early strength water reducer: 0.3kg.
Preparation method: above major ingredient and auxiliary material are uniformly mixed coventional type (G) bonding gypsum just can produced and comply with the national standard requirements.

Claims (8)

1. the method utilizing titanium gypsum to produce bonding gypsum, it is passed through fully to stir coventional type (G) bonding gypsum complied with the national standard requirements be made major ingredient and auxiliary material, it is characterized in that: major ingredient comprises titanium gypsum, desulfurated plaster and hydraulic cementing materials, auxiliary material comprises retardant, thickening material, binding agent and composite high-early strength water reducer, and it is as follows that ratio all calculated by weight by each raw material:
Titanium gypsum: 35% ~ 60%
Desulfurization stone: 30% ~ 60%
Hydraulic cementing materials: 0% ~ 20%
Retardant consumption is 0.5 ‰ ~ 5 ‰ of major ingredient
Thickening material consumption is 0 ‰ ~ 4 ‰ of major ingredient
Consumption of binder is 0 ‰ ~ 5 ‰ of major ingredient
Composite high-early strength water reducer consumption is 0 ‰ ~ 6 ‰ of major ingredient.
2. the method utilizing titanium gypsum to produce bonding gypsum according to claim 1, is characterized in that: titanium gypsum is through the plaster of Paris of calcining.
3. the method utilizing titanium gypsum to produce bonding gypsum according to claim 1 and 2, is characterized in that: desulfurated plaster is through the plaster of Paris of calcining.
4. the method utilizing titanium gypsum to produce bonding gypsum according to claim 3, is characterized in that: hydraulic cementing materials is 42.5 ordinary Portland cements.
5. the method utilizing titanium gypsum to produce bonding gypsum according to claim 4, is characterized in that: retardant is gypsum special retarder.
6. the method utilizing titanium gypsum to produce bonding gypsum according to claim 5, is characterized in that: thickening material is Vltra tears.
7. the method utilizing titanium gypsum to produce bonding gypsum according to claim 6, is characterized in that: binding agent is polyvinyl alcohol 2488.
8. the method utilizing titanium gypsum to produce bonding gypsum according to claim 7, is characterized in that: composite high-early strength water reducer is gypsum specific complex early strength water-reducing agent.
CN201510840600.3A 2015-11-27 2015-11-27 Method for preparing gypsum binder from titanium gypsum Pending CN105399390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510840600.3A CN105399390A (en) 2015-11-27 2015-11-27 Method for preparing gypsum binder from titanium gypsum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510840600.3A CN105399390A (en) 2015-11-27 2015-11-27 Method for preparing gypsum binder from titanium gypsum

Publications (1)

Publication Number Publication Date
CN105399390A true CN105399390A (en) 2016-03-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107434391A (en) * 2016-05-25 2017-12-05 北新集团建材股份有限公司 A kind of water-fast bonding gypsum powder and preparation method thereof
CN107805028A (en) * 2017-11-21 2018-03-16 常州可赛成功塑胶材料有限公司 A kind of preparation method of high-strength waterproof binder materials

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139198A (en) * 2007-08-15 2008-03-12 深圳清华大学研究院 Chemical industrial gypsum building materials and method for manufacturing same
CN101314530A (en) * 2008-07-07 2008-12-03 昆明理工大学 Method for producing building material with low-temperature ceramic modified industry by-product gypsum
CN101348340A (en) * 2008-09-12 2009-01-21 镇江沃地新材料投资有限公司 Gypsum based gel material prepared from undisturbed industry by-product gypsum and preparation thereof
KR20140115420A (en) * 2013-03-19 2014-10-01 영진글로벌(주) Cement and concrete composition
CN104211365A (en) * 2014-09-13 2014-12-17 长沙海弘建材有限公司 Gypsum-based plastering mortar and preparation method thereof
CN104355588A (en) * 2014-10-24 2015-02-18 河南兴安新型建筑材料有限公司 Special adhesive gypsum for autoclaved aerated concrete product
CN104944817A (en) * 2015-06-03 2015-09-30 攀枝花学院 Recycling method of sulfate process titanium dioxide by-product titanium gypsum

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139198A (en) * 2007-08-15 2008-03-12 深圳清华大学研究院 Chemical industrial gypsum building materials and method for manufacturing same
CN101314530A (en) * 2008-07-07 2008-12-03 昆明理工大学 Method for producing building material with low-temperature ceramic modified industry by-product gypsum
CN101348340A (en) * 2008-09-12 2009-01-21 镇江沃地新材料投资有限公司 Gypsum based gel material prepared from undisturbed industry by-product gypsum and preparation thereof
KR20140115420A (en) * 2013-03-19 2014-10-01 영진글로벌(주) Cement and concrete composition
CN104211365A (en) * 2014-09-13 2014-12-17 长沙海弘建材有限公司 Gypsum-based plastering mortar and preparation method thereof
CN104355588A (en) * 2014-10-24 2015-02-18 河南兴安新型建筑材料有限公司 Special adhesive gypsum for autoclaved aerated concrete product
CN104944817A (en) * 2015-06-03 2015-09-30 攀枝花学院 Recycling method of sulfate process titanium dioxide by-product titanium gypsum

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107434391A (en) * 2016-05-25 2017-12-05 北新集团建材股份有限公司 A kind of water-fast bonding gypsum powder and preparation method thereof
CN107805028A (en) * 2017-11-21 2018-03-16 常州可赛成功塑胶材料有限公司 A kind of preparation method of high-strength waterproof binder materials
CN107805028B (en) * 2017-11-21 2020-01-14 山东正大防水材料股份有限公司 Preparation method of high-strength waterproof cementing material

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