CN105385852A - Treating method for extracting potassium through industrial residue straw ash - Google Patents
Treating method for extracting potassium through industrial residue straw ash Download PDFInfo
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- CN105385852A CN105385852A CN201510747833.9A CN201510747833A CN105385852A CN 105385852 A CN105385852 A CN 105385852A CN 201510747833 A CN201510747833 A CN 201510747833A CN 105385852 A CN105385852 A CN 105385852A
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- potassium
- straw ash
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- solution
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 239000011591 potassium Substances 0.000 title claims abstract description 74
- 229910052700 potassium Inorganic materials 0.000 title claims abstract description 74
- 239000010902 straw Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 63
- 239000004568 cement Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001914 filtration Methods 0.000 claims abstract description 19
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002956 ash Substances 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 17
- 239000001110 calcium chloride Substances 0.000 claims description 16
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 15
- 239000000428 dust Substances 0.000 claims description 13
- 239000000284 extract Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 229910052602 gypsum Inorganic materials 0.000 claims description 11
- 239000010440 gypsum Substances 0.000 claims description 11
- 239000004566 building material Substances 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000706 filtrate Substances 0.000 claims description 9
- 239000003546 flue gas Substances 0.000 claims description 9
- 239000002244 precipitate Substances 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 3
- 229910001414 potassium ion Inorganic materials 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000004567 concrete Substances 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000013049 sediment Substances 0.000 abstract 2
- 238000005265 energy consumption Methods 0.000 abstract 1
- 239000002440 industrial waste Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 6
- 238000013461 design Methods 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/28—Cements from oil shales, residues or waste other than slag from combustion residues, e.g. ashes or slags from waste incineration
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Ceramic Engineering (AREA)
- Combustion & Propulsion (AREA)
- Structural Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a treating method for extracting potassium through industrial residue straw ash. The treating method mainly includes the steps of material preparing, mixing, sediment filtering, certain thermotechnical technology water removing and the like; dry and wet straw ash can be used as the main raw material, and calcium chloride residues are used as the auxiliary material for extracting potassium materials; and residual sediment can be used for producing cement materials of building products. The treating method has the advantages that cement strength is high, concrete compatibility is good, the technology is advanced and reasonable, energy consumption is low, efficiency is high, investment is saved, cost is low, secondary pollution is avoided, and environmental protection is facilitated. According to an existing method for treating straw ash, the additional value is low, productivity is low, the dosage is small, and straw ash high in potassium content cannot be used for building products. The treating method for extracting potassium through industrial residue straw ash is a good method for thoroughly overcoming the technical defects of straw ash, eliminating a large amount of straw ash and a large number of other industrial waste residues, lowering environment pollution and facilitating environment protection.
Description
[technical field]
The present invention relates to industrial residue straw ash and extract potassium technical field, particularly relate to a kind for the treatment of process utilizing industrial residue straw ash to extract potassium.
[background technology]
From status both at home and abroad, just starting straw ash waste residue utilization in the country that the industry seventies is flourishing is the U.S., there is India subsequently, Thailand, New Zealand, Japan, the countries such as Australia have studied stalk on a small quantity for building material product, utilization ratio is about 30%, excellent straw ash entirely, a large amount of ropy ash is all stack and landfill, our country is less for the production of building material product to development research straw ash at present, only has about 3-5%, excellent thin ash entirely, other 90% ropy ashes are landfill entirely, seriously cause the secondary pollution to environment, because the maximum defect of straw ash is that water regain is large, potassium content is high at about 10-16%, add that straw ash itself is containing a large amount of amorphous Si o
2if straw ash calcining not exclusively, will change crystallization Sio into
2, he just have impact on the quality of straw ash for this reason, and in building material product, it can be the water yield increasing in building material product, potassium composition is higher, the product made can cause swelling fracture, for this reason, a large amount of use straw ash is difficult to accomplish, added value is low again, be difficult to the extensive one of the main reasons utilized, at present, stalk ash quantity is discharged every year at about 8,600 ten thousand tons by China, overall utilization is about 12%, a large amount of farmland can only be utilized to stack and landfill, meet the waste water after rainy day pouring, Liu Ru riverbed, Heisui River, severe contamination water resources, fine day is met wind one and is blown the pitch-black a slice of dust all over the sky, severe contamination atmospheric environment, so, this is that the world inscribes deeply.
Therefore, for overcoming the deficiency of above-mentioned technology and designing a kind of method that industrial residue straw ash and calcium chloride waste residue can be utilized to extract potassium product, particularly straw is utilized to generation current factory, straw, soybean stalk, cornstalk, rice straw, the waste residue of discharging after the combustion power generations such as rice husk, containing potassium composition at about 10-16%, adopt a kind of potassium product that advanced Technology is extracted, it is the method for a kind of minimizing and the harmless treatment carried out, there is a kind for the treatment of process utilizing industrial residue straw ash to extract potassium of environmental protection, contriver's problem to be solved just.
[summary of the invention]
For the deficiencies in the prior art; the object of this invention is to provide a kind for the treatment of process utilizing industrial residue straw ash to extract potassium; it is the problem that can cause severe contamination for straw ash to air and water source; potassium material is extracted with remaining waste residue straw ash all for building material product production cement for improving the high straw ash process advanced technologies of a kind of added value; solve straw ash water regain large simultaneously; the defect that potassium content is high; non-secondary pollution, the straw ash being conducive to protection of the environment extracts the method for potassium material.
For achieving the above object, the present invention can adopt following technical scheme: a kind for the treatment of process utilizing industrial residue straw ash to extract potassium, straw ash of the present invention extracts potassium material, take straw ash as main raw material(s), be aided with industrial residue calcium chloride, chemical gypsum extracts potassium material through technique and forms, its extracting method comprises the steps:
1. getting the raw materials ready: starting material are straw ash, is the waste residue that straw electric generation plant is discharged, and calcium chloride is the waste residue producing soda ash discharge, chemical gypsum, is the waste residue that chemical plant is discharged;
2. raw material ratio: according to raw material sources, chemical composition, the needs in the middle of reality, can in two kinds of situation, and design proportion scheme is specific as follows:
A kind of is as one of main component in batching with straw ash, and the potassium material proportion scheme extracted in straw ash, the feature of this material is can by the batching of suitable calcium chloride as auxiliary material, and percentage is straw ash 80-90%, calcium chloride 10-20%;
Another kind is containing chemical gypsum in batching, and its batching percentage is straw ash is 70-80%, and auxiliary material calcium chloride is 10-25%, and auxiliary material chemical gypsum is 5-10%.
Technological line is batching, mixing, add water, stir, enter slip No. 1 settling tank, after aquation precipitation, and extract solution out and enter No. 2 ponds and carry out filtering out solution, enter No. 3 solution pools extracting potassium in order to extracting potassium, filtrate is entered No. 4 ponds again, then injected clear water, filtrate in No. 4 ponds is mixed together to add water with the material recruiting No. 2 schemes and stirs, slip enters in No. 5 ponds again and precipitates, solution extraction after precipitation is entered No. 6 ponds filter, and solution will be filtered out send in No. 3 ponds and extract potassium, the filtering precipitate of last iterative cycles enters in No. 7 ponds, the material that building material product produces cement is used in order to processing, its technique is when waiting for that material is good shaping, shaped objects just required for system, when waiting for that material body possesses into kiln roasting condition again, just enter kiln roasting, and then, in order to reach the potassium composition extracted completely in straw ash, and in order to not allow dust etc. enter atmospheric layer in roasting process, just going out the unconcerned dust collection equipment of device water in flue gas, the vaporific current of production are made to become countercurrent direction with the flue gas of discharge, collect the dust in flue gas, meanwhile, also the potassium composition volatilized in roasting process is made to enter Shui Cao, in the solution of dust suction, and after entering and waiting for that in solution, potassium ion reaches finite concentration in No. 8 ponds, the filtrate of carrying out after filtration treatment enters in No. 3 ponds, in order to extracting potassium, Here it is potassium material of the present invention.
In filtration, in order to improve potassium solution filtration efficiency and can effectively remove drift and throw out, in the light of actual conditions to carry out technique gear before filtration and block and vibration treatment.
According to this technique, extraction potassium solution is directly sloughed moisture through more than 100 degree temperature, the product finally obtained is exactly potassium material and product of the present invention.
Compared with prior art, beneficial effect of the present invention is:
1, by the production technique of the extraction potassium material of the design, accomplishing that the industrial residue of different sources can fully utilize, the potassium material extracted, is the indispensable trace element of animals and plants and the mankind; Remaining material, for producing cement in building materials, not only remove and in cement, to have wished that content is more few even there is no best composition better, as compositions such as chlorine, potassium and sodium, but, in these compositions, during raw material straw ash particularly, containing abundant potassium in straw ash, potassium human body and agriculture in be rare useful materials, for this reason, in this extraction potassium technique, be provided with the composition extracting and reclaim potassium in straw ash specially, meanwhile, be provided with again in this explained hereafter various solid particle can be stoped to enter atmospheric layer method; By the production technique of the design, remaining material is made in manufacture of cement material, not only the cement of other mixing material grinding appropriate separately or can be added, and expect to mix or add again appropriate blended material pulverizing cement with portland cement heat, can accomplish to have complementary advantages, not only reduce the aquation intensity of water requirement and raising cement, and improve cement each side use properties, increase the concrete work-ing life of cement production systD thus.
[embodiment]
Below in conjunction with specific embodiment, set forth the present invention further, should be understood that these embodiments are only not used in for illustration of the present invention and limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values drop on application appended claims limited range equally.
A kind for the treatment of process utilizing industrial residue straw ash to extract potassium, straw ash of the present invention extracts potassium material, be be main raw material(s) with straw ash, be aided with the material through special technology such as industrial residue calcium chloride and extract potassium material and form, its extracting method comprises the steps:
Utilize straw ash to extract the treatment process of potassium material, it is characterized in that comprising the steps:
Getting the raw materials ready: starting material are straw ash, is the waste residue that straw electric generation plant is discharged, and calcium chloride is the waste residue producing soda ash discharge, chemical gypsum, is the waste residue that chemical plant is discharged;
Raw material ratio: according to raw material sources, chemical composition, the needs in the middle of reality, can in two kinds of situation, and design proportion scheme is specific as follows:
A kind of is with straw ash as one of main component in batching, and will extract the potassium material proportion scheme in straw ash.The feature of this material is can by the batching of suitable calcium chloride as auxiliary material, and percentage is straw ash 80-90%, calcium chloride 10-20%;
Another kind is containing chemical gypsum in batching, and its batching percentage is straw ash is 70-80%, and auxiliary material calcium chloride is 10-25%, and auxiliary material chemical gypsum is 5-10%.
Technological line is batching, mixing, add water, stir, enter slip No. 1 settling tank, after aquation precipitation, and extract solution out and enter No. 2 ponds and carry out filtering out solution, enter No. 3 solution pools extracting potassium in order to extracting potassium, filtrate is entered No. 4 ponds again, then injected clear water, filtrate in No. 4 ponds is mixed together to add water with the material recruiting No. 2 schemes and stirs, slip enters in No. 5 ponds again and precipitates, solution extraction after precipitation is entered No. 6 ponds filter, and solution will be filtered out send in No. 3 ponds and extract potassium, the filtering precipitate of last iterative cycles enters in No. 7 ponds, the material that building material product produces cement is used in order to processing, its technique is when waiting for that material is good shaping, shaped objects just required for system, when waiting for that material body possesses into kiln roasting condition again, just enter kiln roasting, and then, in order to reach the potassium composition extracted completely in straw ash, and in order to not allow dust etc. enter atmospheric layer in roasting process, just going out the unconcerned dust collection equipment of device water in flue gas, the vaporific current of production are made to become countercurrent direction with the flue gas of discharge, collect the dust in flue gas, meanwhile, also the potassium composition volatilized in roasting process is made to enter Shui Cao, in the solution of dust suction, and after entering and waiting for that in solution, potassium ion reaches finite concentration in No. 8 ponds, the filtrate of carrying out after filtration treatment enters in No. 3 ponds, in order to extracting potassium, Here it is potassium material of the present invention.
In filtration, in order to improve potassium solution filtration efficiency and can effectively remove drift and throw out, in the light of actual conditions to carry out technique gear before filtration and block and vibration treatment.
According to this technique, extraction potassium solution is directly sloughed moisture through more than 100 degree temperature, the product finally obtained is exactly potassium material and product of the present invention.
By the production technique of the extraction potassium material of the design, accomplishing that the industrial residue of different sources can fully utilize, the potassium material extracted, is the indispensable trace element of animals and plants and the mankind; Remaining material, for producing cement in building materials, not only remove and in cement, to have wished that content is more few even there is no best composition better, as compositions such as chlorine, potassium and sodium, but, in these compositions, during raw material straw ash particularly, containing abundant potassium in straw ash, potassium human body and agriculture in be rare useful materials, for this reason, in this extraction potassium technique, be provided with the composition extracting and reclaim potassium in straw ash specially, meanwhile, be provided with again in this explained hereafter various solid particle can be stoped to enter atmospheric layer method; By the production technique of the design, remaining material is made in manufacture of cement material, not only the cement of other mixing material grinding appropriate separately or can be added, and expect to mix or add again appropriate blended material pulverizing cement with portland cement heat, can accomplish to have complementary advantages, not only reduce the aquation intensity of water requirement and raising cement, and improve cement each side use properties, increase the concrete work-ing life of cement production systD thus.
Claims (2)
1. utilize industrial residue straw ash to extract a treatment process for potassium material, it is characterized in that comprising the steps:
1. get the raw materials ready: starting material are straw ash, calcium chloride, chemical gypsum;
2. prepare burden: straw ash, calcium chloride, chemical gypsum carry out raw material ratio;
3. technological line is batching, mixing, add water, stir, enter slip No. 1 settling tank, after aquation precipitation, and extract solution out and enter No. 2 ponds and carry out filtering out solution, enter No. 3 solution pools extracting potassium in order to extracting potassium, filtrate is entered No. 4 ponds again, then injected clear water, filtrate in No. 4 ponds is mixed together to add water with the material recruiting No. 2 schemes and stirs, slip enters in No. 5 ponds again and precipitates, solution extraction after precipitation is entered No. 6 ponds filter, and solution will be filtered out send in No. 3 ponds and extract potassium, the filtering precipitate of last iterative cycles enters in No. 7 ponds, the material that building material product produces cement is used in order to processing, its technique is when waiting for that material is good shaping, shaped objects just required for system, when waiting for that material body possesses into kiln roasting condition again, just enter klining, and then, in order to reach the potassium composition extracted completely in straw ash, and in order to not allow dust etc. enter atmospheric layer in roasting process, just going out the unconcerned dust collection equipment of device water in flue gas, the vaporific current of production are made to become countercurrent direction with the flue gas of discharge, collect the dust in flue gas, meanwhile, also the potassium composition volatilized in roasting process is made to enter pond, in the solution of dust suction, and after entering and waiting for that in solution, potassium ion reaches finite concentration in No. 8 ponds, the filtrate of carrying out after filtration treatment enters in No. 3 ponds, in order to extracting potassium, Here it is potassium material of the present invention,
4. in filtering, in order to improve potassium solution filtration efficiency and can effectively remove drift and throw out, in the light of actual conditions to carry out technique gear before filtration and block and vibration treatment;
5. according to this technique, extraction potassium solution is directly sloughed moisture through more than 100 degree temperature, the product finally obtained is exactly potassium material and product of the present invention.
2. a kind for the treatment of process utilizing industrial residue straw ash to extract potassium material according to claim 1, it is characterized in that, raw material ratio is specific as follows:
1. a kind of is as one of main component in batching with straw ash, and the potassium material proportion scheme extracted in straw ash, the feature of this material is can by the batching of suitable calcium chloride as auxiliary material, and percentage is straw ash 80-90%, calcium chloride 10-20%;
2. another kind is containing chemical gypsum in batching, and its batching percentage is straw ash is 70-80%, and auxiliary material calcium chloride is 10-25%, and auxiliary material chemical gypsum is 5-10%.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101037948A (en) * | 2006-03-16 | 2007-09-19 | 天津焰旺科技发展有限公司 | Method for biomass power generating and extracting K |
CN101062777A (en) * | 2006-04-28 | 2007-10-31 | 刘洪旺 | Technical method for extracting potassium chloride by comprehensive utilization of straw power generation ash slag and soda alkali waste slag |
WO2008000085A1 (en) * | 2006-06-30 | 2008-01-03 | The University Of Western Ontario | Process for producing a concrete additive from an agricultural residue |
CN101172889A (en) * | 2007-10-23 | 2008-05-07 | 徐秀山 | Process for the separation of tripotassium salt in stalk ash |
-
2015
- 2015-11-06 CN CN201510747833.9A patent/CN105385852B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101037948A (en) * | 2006-03-16 | 2007-09-19 | 天津焰旺科技发展有限公司 | Method for biomass power generating and extracting K |
CN101062777A (en) * | 2006-04-28 | 2007-10-31 | 刘洪旺 | Technical method for extracting potassium chloride by comprehensive utilization of straw power generation ash slag and soda alkali waste slag |
WO2008000085A1 (en) * | 2006-06-30 | 2008-01-03 | The University Of Western Ontario | Process for producing a concrete additive from an agricultural residue |
CN101172889A (en) * | 2007-10-23 | 2008-05-07 | 徐秀山 | Process for the separation of tripotassium salt in stalk ash |
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