CN105384412A - Eco-friendly waterproof paint - Google Patents
Eco-friendly waterproof paint Download PDFInfo
- Publication number
- CN105384412A CN105384412A CN201510934795.8A CN201510934795A CN105384412A CN 105384412 A CN105384412 A CN 105384412A CN 201510934795 A CN201510934795 A CN 201510934795A CN 105384412 A CN105384412 A CN 105384412A
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- CN
- China
- Prior art keywords
- parts
- waterproof paint
- environmental
- ether
- water reducer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00508—Cement paints
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses eco-friendly waterproof paint and belongs to the technical field of paint. The eco-friendly waterproof paint comprises, by weight, 70-96 parts of low-heat portland cement, 0-10 parts of fly ash, 0-10 parts of limestone powder, 4-15 parts of dispersible latex powder, 0.3-0.5 parts of cellulose ether and 0.5-0.8 parts of a water reducer. The eco-friendly waterproof paint has the advantages of environmental friendliness, good water resistance, high later strength, good use performance and low cost.
Description
Technical field
The present invention relates to a kind of waterproof paint, particularly relate to a kind of Environmental-protecwaterproof waterproof paint.
Background technology
Water-proof material on market is several, and one is polyurethanes waterproof paint, and this kind of material is generally be made up as starting material of Polyurethane and coal tar.The tar gas toxicity that it volatilizees is large, and is not easy to remove, and is therefore prohibited from using in 2000 in China.The polyurethane waterproofing coating still sold replaces coal tar as raw material with pitch.But when using this coating, general employing is diluted containing the organic solvent such as toluene, dimethylbenzene, thus also containing toxic; Waterproof paint conventional is in the market two-component type waterproof paint, one of its composition is latax, in order to improve the film forming properties of coating, usually in latax, add organic solvent, thus make the content of volatile organic solvent and free formaldehyde higher, can irritating smell be produced in construction process, stimulate skin and the respiratory system of people, harm people healthy, the anti-ultraviolet property of two-component type waterproof paint is poor, and produce, transport comparatively bother; Another kind of is polymer cement-base waterproof coating, the emulsion that it is synthesized by multiple waterborne polymeric forms with the high grade cement being mixed with various additive, the flexibility of polymkeric substance (resin) and the rigidity of cement became one, and make it in impermeability with stability, show excellence.Its advantage is that easy construction, comprehensive cost are low, and the duration is short, and asepsis environment-protecting.Therefore, polyalcohol cement basis has become the leading role in waterproof paint market.
If publication number is CN103275584A, name is called the patent of invention of " a kind of polymer cement waterproof paint ", and the coating of this patent is made up of polyacrylic ester 100 ~ 120 parts, 70 ~ 88 parts, styrene-butadiene rubber(SBR), 2 ~ 9 parts, calcium carbonate, lignocellulose 3 ~ 10 parts, silica powder 0.2 ~ 2 part, cement 60 ~ 75 parts, dispersion agent 12 ~ 15 parts, defoamer 1 ~ 5 part, 10 ~ 20 parts, calcium carbonate, membrane-forming agent 1 ~ 4 part.Employ polyacrylic ester and the styrene-butadiene rubber(SBR) of larger proportion in this patent, the two can discharge toxic substance when temperature is higher, and stimulate human body skin and mucous membrane, Long Term Contact is easily carcinogenic, the health of harmful to human.
Summary of the invention
It is bad that the present invention is intended to solve the feature of environmental protection that in prior art, polyurethanes waterproof paint, polymer cement-base waterproof coating all exist, and the problem be detrimental to health, proposes a kind of new Environmental-protecwaterproof waterproof paint.
In order to realize foregoing invention object, technical scheme of the present invention is as follows:
A kind of Environmental-protecwaterproof waterproof paint, is characterized in that: comprise following raw material by weight: low-heat portland cement 70 ~ 96 parts, 0 ~ 10 part, flyash, limestone powder 0 ~ 10 part, redispersable latex powder 4 ~ 15 parts, ether of cellulose 0.3 ~ 0.5 part, water reducer 0.5 ~ 0.8 part.
The fineness of described limestone powder is 200 ~ 400 orders.
Described redispersable latex powder is the one in ethylene-vinyl acetate copolymer, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer.
Described ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 15000 ~ 50000mPas.
Described water reducer is powdery naphthalene water reducer, and water-reducing rate is 10 ~ 30%, to improve the workability of coating.
The present invention, relative to prior art, has following beneficial effect:
(1) waterproof paint of the present invention avoids adding of organic solvent, and the feature of environmental protection is better, and has good water proof anti-seepage and anti-ultraviolet performance; Compared with general polymer cement-base waterproof coating of the prior art, the cement that the present invention adopts is low-heat portland cement, its hydration process is slow, and hydration heat is low, reduce because the distortion of water consumption and temperature difference generation in cement hydration process, and the later strength of material and overall use properties can be improved; In addition, in the present invention, select redispersable latex powder, compared with the emulsion adopted in prior art, the content of volatile organic matter in waterproof paint can be reduced by high degree, and environment-protecting asepsis, extend the working life of waterproof paint simultaneously, reduce the cost of user; Flyash in the present invention has activity, reacts with hydrolysis product of cement, and is industrial residue, can turn waste into wealth, alleviate environmental stress, reduce costs; Limestone powder in the present invention plays the effect of filling, and the ether of cellulose in formula plays thickening, resists and hang from above and water conservation, prevents aquation incomplete, affects the effect of later strength, improve product use properties; To sum up, by coordinated effect and the specific proportion design of each raw material in formula, such that waterproof paint of the present invention has environmental protection, water resistance is good, later strength is high, use properties is good and the advantage that cost is low.
(2) fineness of the limestone powder in the present invention is 200 ~ 400 orders, and the limestone powder within the scope of this fineness effectively can reduce the Young's modulus of waterproof paint, avoids waterproof paint water requirement excessive, and the problem of drying shrinkage, cracking appears in the later stage of causing.
(3) redispersable latex powder of the present invention is the one in ethylene-vinyl acetate copolymer, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, these two kinds of raw materials are after being dissolved in water, two-step film forming process can not discharge harmful material, and has good anti-ultraviolet property and higher thermotolerance and stability.
(4) ether of cellulose of the present invention is ethoxyl methyl cellulose ether, and viscosity is 15000 ~ 50000mPas, and this raw material is solubilized in cold weather conditions, and film forming properties is good, and still can keep good use properties at relatively high temperatures.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 70 parts, 0 part, flyash, limestone powder 0 part, redispersable latex powder 4 parts, ether of cellulose 0.3 part, water reducer 0.5 part.
Embodiment 2
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 96 parts, 0 part, flyash, limestone powder 0 part, redispersable latex powder 4 parts, ether of cellulose 0.3 part, water reducer 0.5 part.
In the present embodiment, the fineness of limestone powder is 200 orders; Redispersable latex powder is ethylene-vinyl acetate copolymer; Ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 50000mPas.
Embodiment 3
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 80 parts, 5 parts, flyash, limestone powder 5 parts, redispersable latex powder 10 parts, ether of cellulose 0.5 part, water reducer 0.8 part.
In the present embodiment, the fineness of limestone powder is 400 orders; Redispersable latex powder is vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer; Ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 15000mPas; Water reducer is powdery naphthalene water reducer.
Embodiment 4
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 80 parts, 10 parts, flyash, limestone powder 5 parts, redispersable latex powder 4 parts, ether of cellulose 0.4 part, water reducer 0.6 part.
In the present embodiment, the fineness of limestone powder is 300 orders; Redispersable latex powder is vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer; Ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 30000mPas; Water reducer is powdery naphthalene water reducer.
Embodiment 5
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 85 parts, 5 parts, flyash, limestone powder 10 parts, redispersable latex powder 10 parts, ether of cellulose 0.3 part, water reducer 0.7 part.
In the present embodiment, the fineness of limestone powder is 200 orders; Redispersable latex powder is the mixture of vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer and ethylene-vinyl acetate copolymer, and blending ratio is 1:3; Ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 20000mPas; Water reducer is powdery naphthalene water reducer.
Embodiment 6
A kind of Environmental-protecwaterproof waterproof paint, comprises following raw material by weight: low-heat portland cement 90 parts, 10 parts, flyash, limestone powder 10 parts, redispersable latex powder 15 parts, ether of cellulose 0.5 part, water reducer 0.8 part.
In the present embodiment, the fineness of Wingdale is 350 orders; Redispersable latex powder is the mixture of vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer and ethylene-vinyl acetate copolymer, and blending ratio is 1:1; Ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 40000mPas; Water reducer is powdery naphthalene water reducer.
The waterproof paint using method of the present embodiment is as follows: first with steel brush, basic unit is carried out surperficial bristle process, removing dirt, after then being taken by proportioning by each raw material of the present embodiment, adds 30 parts ~ 40 parts water and stirs into pasty state, then 3 ~ 5min is left standstill, brush with cylinder after stirring again, after brushing first pass, arrange cracking resistance grid cloth, after top layer is slightly dry, carry out second layer brushing, as the case may be, select brushing number of times.
The waterproof paint performance index of above-described embodiment 1 ~ embodiment 6 detect as following table 1:
Table 1:
As can be seen from upper table 1, the impermeability of coating of the present invention is good, and indices is all higher than standard gauge definite value; And the shrinking percentage of this coating is low, can reduce the performance failure that waterproof paint causes because of shrinkage cracking, workability is excellent, not containing organic solvent, belongs to environmentally friendly waterproof paint.
Claims (5)
1. an Environmental-protecwaterproof waterproof paint, is characterized in that: comprise following raw material by weight: low-heat portland cement 70 ~ 96 parts, 0 ~ 10 part, flyash, limestone powder 0 ~ 10 part, redispersable latex powder 4 ~ 15 parts, ether of cellulose 0.3 ~ 0.5 part, water reducer 0.5 ~ 0.8 part.
2. a kind of Environmental-protecwaterproof waterproof paint as claimed in claim 1, is characterized in that: the fineness of described limestone powder is 200 ~ 400 orders.
3. a kind of Environmental-protecwaterproof waterproof paint as claimed in claim 1, is characterized in that: described redispersable latex powder is the one in ethylene-vinyl acetate copolymer, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer.
4. a kind of Environmental-protecwaterproof waterproof paint as claimed in claim 1, is characterized in that: described ether of cellulose is ethoxyl methyl cellulose ether, and viscosity is 15000 ~ 50000mPas.
5. a kind of Environmental-protecwaterproof waterproof paint as described in any one of Claims 1 to 4, is characterized in that: described water reducer is powdery naphthalene water reducer, and water-reducing rate is 10 ~ 30%.
Priority Applications (1)
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CN201510934795.8A CN105384412A (en) | 2015-12-15 | 2015-12-15 | Eco-friendly waterproof paint |
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CN201510934795.8A CN105384412A (en) | 2015-12-15 | 2015-12-15 | Eco-friendly waterproof paint |
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CN105384412A true CN105384412A (en) | 2016-03-09 |
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CN201510934795.8A Pending CN105384412A (en) | 2015-12-15 | 2015-12-15 | Eco-friendly waterproof paint |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590092A (en) * | 2016-12-28 | 2017-04-26 | 嘉华特种水泥股份有限公司 | Indoor waterproof coating |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101723636A (en) * | 2009-12-19 | 2010-06-09 | 山西大学 | Coal mine underground coal bed waterproof paint |
CN101811851A (en) * | 2009-12-18 | 2010-08-25 | 河南省绿韵建材有限公司 | Polymer cement-base waterproof coating dry powder |
CN102219446A (en) * | 2011-03-28 | 2011-10-19 | 湖南盛林建材科技有限公司 | Modified emulsified bitumen cement waterproof coating and preparation method thereof |
-
2015
- 2015-12-15 CN CN201510934795.8A patent/CN105384412A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101811851A (en) * | 2009-12-18 | 2010-08-25 | 河南省绿韵建材有限公司 | Polymer cement-base waterproof coating dry powder |
CN101723636A (en) * | 2009-12-19 | 2010-06-09 | 山西大学 | Coal mine underground coal bed waterproof paint |
CN102219446A (en) * | 2011-03-28 | 2011-10-19 | 湖南盛林建材科技有限公司 | Modified emulsified bitumen cement waterproof coating and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
林宗寿主编: "《胶凝材料学》", 31 August 2014 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590092A (en) * | 2016-12-28 | 2017-04-26 | 嘉华特种水泥股份有限公司 | Indoor waterproof coating |
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Application publication date: 20160309 |
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