CN105350306A - Method for preparing ultrahigh molecular weight polyethylene precursor fiber - Google Patents

Method for preparing ultrahigh molecular weight polyethylene precursor fiber Download PDF

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Publication number
CN105350306A
CN105350306A CN201510938459.0A CN201510938459A CN105350306A CN 105350306 A CN105350306 A CN 105350306A CN 201510938459 A CN201510938459 A CN 201510938459A CN 105350306 A CN105350306 A CN 105350306A
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Prior art keywords
parts
mass
molecular weight
stir
weight polyethylene
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CN201510938459.0A
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Chinese (zh)
Inventor
李振国
蔡建南
刘兆峰
丁洪昌
陆红星
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Changshu Super Fibers Co Ltd
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Changshu Super Fibers Co Ltd
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Priority to CN201510938459.0A priority Critical patent/CN105350306A/en
Publication of CN105350306A publication Critical patent/CN105350306A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Abstract

The invention discloses a method for preparing an ultrahigh molecular weight polyethylene precursor fiber. The method comprises a fiber finishing step, wherein the fiber finishing step comprises the following sub-steps: (1) feeding the following raw materials in parts by mass: 1-2 parts of cetylpyridinium chloride, 3.3 parts of a siberian elm bark ethanol extract, 2.6 parts of n-butyllithium and 1.3 parts of nanoscale aluminum hydroxide to 39 parts by mass of deionized water, and mixing and stirring the raw materials evenly; (2) simultaneously adding the following raw materials in parts by mass: 3.4 parts of sodium n-butyl naphthalene sulfonate, 2.9 parts of calcium dodecyl benzene sulfonate, 1.6 parts of bifenthrin and 3.6 parts of sodium hexametaphosphate slowly, and further stirring the raw materials until the raw materials are fully mixed evenly, so as to prepare a finishing liquid; and (3) carrying out padding treatment on a hydroxyethyl cellulose fiber in the finishing liquid, and taking out and drying the hydroxyethyl cellulose fiber at a constant temperature. The method for preparing the ultrahigh molecular weight polyethylene precursor fiber comprises the fiber finishing step; and the finished hydroxyethyl cellulose fiber has excellent antibacterial property, flame retardant property and antistatic property.

Description

For the preparation of the method for ultra-high molecular weight polyethylene precursor fiber
Technical field
The present invention relates to the method for the preparation of ultra-high molecular weight polyethylene precursor fiber.
Background technology
Antibacterial, fire-retardant, the antistatic property of existing hydroxyethyl cellulose all have much room for improvement.
Summary of the invention
The object of the present invention is to provide a kind of method for the preparation of ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, the hydroxyethyl cellulose after arrangement has excellent antibacterial, fire-retardant, antistatic property.
For achieving the above object, technical scheme of the present invention is a kind of method for the preparation of ultra-high molecular weight polyethylene precursor fiber of design, and comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 ~ 2 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
Preferably, for the preparation of the method for ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
Preferably, for the preparation of the method for ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 2 parts by mass Cetylpyridinium Chlorides, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
Advantage of the present invention and beneficial effect are: provide a kind of method for the preparation of ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, and the hydroxyethyl cellulose after arrangement has excellent antibacterial, fire-retardant, antistatic property.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
The technical scheme that the present invention specifically implements is:
Embodiment 1
For the preparation of a method for ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 ~ 2 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
Embodiment 2
For the preparation of the method for ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
Embodiment 3
For the preparation of the method for ultra-high molecular weight polyethylene precursor fiber, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 2 parts by mass Cetylpyridinium Chlorides, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (3)

1. for the preparation of the method for ultra-high molecular weight polyethylene precursor fiber, it is characterized in that, comprise fibre finish step, described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 ~ 2 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
2. the method for the preparation of ultra-high molecular weight polyethylene precursor fiber according to claim 1, is characterized in that, comprises fibre finish step, and described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 1 parts by mass Cetylpyridinium Chloride, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
3. the method for the preparation of ultra-high molecular weight polyethylene precursor fiber according to claim 1, is characterized in that, comprises fibre finish step, and described fibre finish comprises the steps:
1) in 39 parts by mass deionized waters, drop into 2 parts by mass Cetylpyridinium Chlorides, 3.3 parts by mass Siberian elm brak ethanol extracts, 2.6 parts by mass n-BuLis, 1.3 parts by mass nanoscale aluminium hydroxide mixing, stir;
2) slowly add 3.4 parts by mass normal-butyl sodium naphthalene sulfonates, 2.9 parts by mass calcium dodecyl benzene sulfonates, 1.6 parts by mass Biphenthrins, 3.6 parts by mass calgons more simultaneously, continue to stir, to fully mixing, obtained dressing liquid;
3) hydroxyethyl cellulose is padded process in dressing liquid, constant temperature drying after taking out.
CN201510938459.0A 2015-12-16 2015-12-16 Method for preparing ultrahigh molecular weight polyethylene precursor fiber Pending CN105350306A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792972A (en) * 2010-03-22 2010-08-04 南通纺织职业技术学院 Flame-retardant antibacterial finishing method for cellulose carpets
CN103590249A (en) * 2013-11-20 2014-02-19 上海天伟纺织质量技术服务有限公司 Preparation method of water-repellent and oil-repellent antistatic finishing agent
CN104404789A (en) * 2014-12-15 2015-03-11 常熟市启弘纺织实业有限公司 Uniform printing and dyeing method for fabric
CN104611920A (en) * 2015-01-26 2015-05-13 江苏文凤化纤集团有限公司 Composite finishing agent for spinning

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792972A (en) * 2010-03-22 2010-08-04 南通纺织职业技术学院 Flame-retardant antibacterial finishing method for cellulose carpets
CN103590249A (en) * 2013-11-20 2014-02-19 上海天伟纺织质量技术服务有限公司 Preparation method of water-repellent and oil-repellent antistatic finishing agent
CN104404789A (en) * 2014-12-15 2015-03-11 常熟市启弘纺织实业有限公司 Uniform printing and dyeing method for fabric
CN104611920A (en) * 2015-01-26 2015-05-13 江苏文凤化纤集团有限公司 Composite finishing agent for spinning

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Application publication date: 20160224