CN105331170A - Environment-friendly nano-fire-proofing coating and preparation method thereof - Google Patents
Environment-friendly nano-fire-proofing coating and preparation method thereof Download PDFInfo
- Publication number
- CN105331170A CN105331170A CN201510873412.0A CN201510873412A CN105331170A CN 105331170 A CN105331170 A CN 105331170A CN 201510873412 A CN201510873412 A CN 201510873412A CN 105331170 A CN105331170 A CN 105331170A
- Authority
- CN
- China
- Prior art keywords
- nano
- environment
- frie retardant
- adds
- retardant coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to the field of coatings, and particularly relates to an environment-friendly nano-fire-proofing coating and a preparation method thereof. The environment-friendly nano-fire-proofing coating is prepared from, by mass, 15%-25% of film forming matter, 5%-15% of nano pentaerythritol, 20%-30% of ammonium polyphosphate, 5%-15% of air sources, 5%-15% of titanium dioxide, 2%-20% of nanofiller, 5%-10% of reinforced fibers, 15%-30% of deionized water, 0.3%-0.5% of a wetting dispersant, 0.2%-0.5% of a defoaming agent, 0.2%-0.5% of a stabilizing agent, 0.1%-0.6% of a thickening agent and 0.3%-0.8% of a film forming auxiliary. The environment-friendly nano-fire-proofing coating is good in water resistance and ageing resistance, capable of being used outdoors for a long time, excellent in fire-proofing effect and good in physical and chemical property.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of environment-protection nano frie retardant coating and preparation method thereof.
Background technology
Frie retardant coating is a kind of functional coating, is widely used in the flameproof protection in many places such as steel construction, cable, top ceiling, wall, tunnel and aircraft.Traditional frie retardant coating adopts organic solvent as solvent mostly, endanger larger to environment and workmen, therefore the aqueous fire-proof coating of environmental protection becomes the needs of development, but restriction for various reasons, often there is water resistance difference in aqueous fire-proof coating, the defects such as shock-resistant, artificial ageing resistance and poor adhesive force, are applied to outdoor easily efflorescence simultaneously for a long time, lose fire line.
Summary of the invention
The present invention seeks to solve aqueous fire-proof coating poor water resistance, ageing resistance difference and the long-time problem for the easy efflorescence in outdoor;
The technical solution adopted in the present invention is: the two thin mechanism of the lotus leaf utilizing nano material to have, and by special producing technique and interpolation strongthener, solves the problem.
Environment-protection nano frie retardant coating, is made up of the raw material of following mass percent: film forming matter 15% ~ 25%, nanometer tetramethylolmethane 5% ~ 15%, ammonium polyphosphate 20% ~ 30%, source of the gas 5% ~ 15%, titanium dioxide 5% ~ 15%, Nano filling 2% ~ 20%, fortifying fibre 5% ~ 10%, deionized water 15% ~ 30%, wetting dispersing agent 0.3% ~ 0.5%, defoamer 0.2% ~ 0.5%, stablizer 0.2% ~ 0.5%, thickening material 0.1% ~ 0.6%, film coalescence aid 0.3% ~ 0.8%; Its preparation method is as follows: the first step, takes above-mentioned raw materials respectively according to the above ratio; Second step, adds dispersing apparatus by deionized water, wetting dispersing agent, defoamer and stablizer; 3rd step, add titanium dioxide, fortifying fibre, Nano filling, source of the gas and nanometer tetramethylolmethane successively, add half thickening material and make its viscosity at 6000 ~ 10000cp, continue to be dispersed to temperature and reach 50 DEG C ~ 55 DEG C, open cooling circulating water, cool the temperature to 25 DEG C ~ 30 DEG C; 4th step, adds ammonium polyphosphate, is uniformly dispersed; 5th step, adds emulsion and keeps temperature 25 DEG C ~ 30 DEG C, add remaining half thickening material and film coalescence aid after being uniformly dispersed; 6th step, crosses 80 eye mesh screen plastic barrels and packs after being uniformly dispersed.
Described film coalescence aid is formed by vinyl acetate, tertiary ethylene carbonate, acrylate, vinylchlorid, St or multi-component copolymer, and the 5th step adds.
The described main content of nanometer tetramethylolmethane is more than 98%, and the 3rd step adds.
The described ammonium polyphosphate polymerization degree is more than 1000, and small molecules content is within 0.5%, and the 4th step adds.
Described source of the gas is one or both mixtures in trimeric cyanamide, Dyhard RU 100, clorafin or three kinds of mixtures, and the 3rd step adds.
Described titanium dioxide is rutile-type or anatase thpe white powder, and the 3rd step adds.
Described Nano filling is one or more mixtures in nano-aluminum hydroxide, nano boric acid sodium, nano silicon micronization, nano silicon, nano kaoline, nanometer Zinic stearas, nano scandium oxide, nano yttrium oxide, nanmeter antimong trioxide, and the 3rd step adds.
Described fortifying fibre is one or more mixtures in glass fibre, mineral fibre, carbon fiber, and the 3rd step adds.
Described wetting dispersing agent is separate the one in the polymkeric substance of the low-molecular(weight)polymer of flocculation-type, the high molecular polymer separating flocculation-type, control flocculation-type, and second step adds.
Described defoamer is one or more mixtures in polydimethylsiloxane, organic modified polyorganosiloxane, organosilicon, and second step adds.
Described stablizer is the one in isothiazolinone, BIT, and second step adds.
Described thickening material is one or more mixtures in xanthan gum, hydroxylated cellulose, alkali swollen thickener, and the 3rd step and the 5th step add.
Described film coalescence aid is the one in propandiol butyl ether, 1-Methoxy-2-propyl acetate, and the 5th step adds.
The invention has the beneficial effects as follows: environment-protection nano frie retardant coating water-tolerant provided by the invention, ageing resistance is good, can for a long time in outdoor application, and flameproof effect is excellent simultaneously, good physical and chemical properties.
Embodiment
Below in conjunction with embodiments of the invention, carry out clear and detailed description to the technical scheme in the embodiment of the present invention, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1:
Environment-protection nano frie retardant coating and preparation method thereof, its composition of raw materials table 1 composed as follows:
| Starting material | Consumption (mass percent) |
| R661 emulsion | 20 |
| Preniphor TM EPFR-APP222H | 25 |
| Nanometer tetramethylolmethane | 9 |
| Trimeric cyanamide | 8 |
| Titanium dioxide | 8 |
| Nano-aluminum hydroxide | 1.5 |
| Nano silicon | 1 |
| Nano yttrium oxide | 0.5 |
| Fortifying fibre LCF101 | 5 |
| BYK-021 | 0.2 |
| BYK-182 | 0.3 |
| Propandiol butyl ether | 0.6 |
| Xanthan gum | 0.2 |
| Isothiazolinone | 0.2 |
| Deionized water | 20.5 |
Embodiment 2:
Environment-protection nano frie retardant coating and preparation method thereof, its composition of raw materials table 2 composed as follows:
| Starting material | Consumption (mass percent) |
| PE3909 emulsion | 18 |
| Preniphor TM EPFR-APP224 | 26 |
| Nanometer tetramethylolmethane | 9 |
| Dyhard RU 100 | 2 |
| Trimeric cyanamide | 8 |
| Titanium dioxide | 8 |
| Nano boric acid sodium | 1.5 |
| Nano silicon micronization | 1 |
| Nano scandium oxide | 0.5 |
| Carbon fiber | 3 |
| BYK-021 | 0.2 |
| BYK-182 | 0.3 |
| Propandiol butyl ether | 0.6 |
| Xanthan gum | 0.2 |
| Isothiazolinone | 0.2 |
| Deionized water | 21.5 |
Embodiment 3:
Environment-protection nano frie retardant coating and preparation method thereof, its composition of raw materials table 3 composed as follows:
| Starting material | Consumption (mass percent) |
| Dm230 emulsion | 18 |
| Preniphor TM EPFR-APP262 | 28 |
| Nanometer tetramethylolmethane | 8 |
| Dyhard RU 100 | 1 |
| Trimeric cyanamide | 8 |
| Titanium dioxide | 8.5 |
| Nano kaoline | 2 |
| Nanometer Zinic stearas | 1 |
| Nanmeter antimong trioxide | 1 |
| Glass fibre | 4 |
| BYK-021 | 0.2 |
| BYK-182 | 0.3 |
| Propandiol butyl ether | 0.6 |
| Xanthan gum | 0.2 |
| Isothiazolinone | 0.2 |
| Deionized water | 19 |
Table 4: the performance of environment-protection nano frie retardant coating of the present invention
Most preferred embodiment of the present invention is illustrated, and the various change made by those of ordinary skill in the art or remodeling all can not depart from the scope of the present invention.
Claims (13)
1. environment-protection nano frie retardant coating, it is characterized in that: be made up of the raw material of following mass percent: film forming matter 15% ~ 25%, nanometer tetramethylolmethane 5% ~ 15%, ammonium polyphosphate 20% ~ 30%, source of the gas 5% ~ 15%, titanium dioxide 5% ~ 15%, Nano filling 2% ~ 20%, fortifying fibre 5% ~ 10%, deionized water 15% ~ 30%, wetting dispersing agent 0.3% ~ 0.5%, defoamer 0.2% ~ 0.5%, stablizer 0.2% ~ 0.5%, thickening material 0.1% ~ 0.6%, film coalescence aid 0.3% ~ 0.8%;
Its preparation method is as follows: the first step, takes above-mentioned raw materials respectively according to the above ratio; Second step, adds dispersing apparatus by deionized water, wetting dispersing agent, defoamer and stablizer; 3rd step, add titanium dioxide, fortifying fibre, Nano filling, source of the gas and nanometer tetramethylolmethane successively, add half thickening material and make its viscosity at 6000 ~ 10000cp, continue to be dispersed to temperature and reach 50 DEG C ~ 55 DEG C, open cooling circulating water, cool the temperature to 25 DEG C ~ 30 DEG C; 4th step, adds ammonium polyphosphate, is uniformly dispersed; 5th step, adds emulsion and keeps temperature 25 DEG C ~ 30 DEG C, add remaining half thickening material and film coalescence aid after being uniformly dispersed; 6th step, crosses 80 eye mesh screen plastic barrels and packs after being uniformly dispersed.
2. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described film coalescence aid is formed by vinyl acetate, tertiary ethylene carbonate, acrylate, vinylchlorid, St or multi-component copolymer, the 5th step adds.
3. environment-protection nano frie retardant coating according to claim 1, is characterized in that: the described main content of nanometer tetramethylolmethane is more than 98%, and the 3rd step adds.
4. environment-protection nano frie retardant coating according to claim 1, is characterized in that: the described ammonium polyphosphate polymerization degree is more than 1000, and small molecules content is within 0.5%, and the 4th step adds.
5. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described source of the gas is one or both mixtures in trimeric cyanamide, Dyhard RU 100, clorafin or three kinds of mixtures, and the 3rd step adds.
6. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described titanium dioxide is rutile-type or anatase thpe white powder, and the 3rd step adds.
7. environment-protection nano frie retardant coating according to claim 1, it is characterized in that: described Nano filling is one or more mixtures in nano-aluminum hydroxide, nano boric acid sodium, nano silicon micronization, nano silicon, nano kaoline, nanometer Zinic stearas, nano scandium oxide, nano yttrium oxide, nanmeter antimong trioxide, and the 3rd step adds.
8. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described fortifying fibre is one or more mixtures in glass fibre, mineral fibre, carbon fiber, and the 3rd step adds.
9. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described wetting dispersing agent is separate the one in the polymkeric substance of the low-molecular(weight)polymer of flocculation-type, the high molecular polymer separating flocculation-type, control flocculation-type, and second step adds.
10. environment-protection nano frie retardant coating according to claim 1, is characterized in that: described defoamer is one or more mixtures in polydimethylsiloxane, organic modified polyorganosiloxane, organosilicon, and second step adds.
11. environment-protection nano frie retardant coatings according to claim 1, is characterized in that: described stablizer is the one in isothiazolinone, BIT, and second step adds.
12. environment-protection nano frie retardant coatings according to claim 1, is characterized in that: described thickening material is one or more mixtures in xanthan gum, hydroxylated cellulose, alkali swollen thickener, and the 3rd step and the 5th step add.
13. environment-protection nano frie retardant coatings according to claim 1, is characterized in that: described film coalescence aid is the one in propandiol butyl ether, 1-Methoxy-2-propyl acetate, and the 5th step adds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510873412.0A CN105331170A (en) | 2015-12-02 | 2015-12-02 | Environment-friendly nano-fire-proofing coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510873412.0A CN105331170A (en) | 2015-12-02 | 2015-12-02 | Environment-friendly nano-fire-proofing coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105331170A true CN105331170A (en) | 2016-02-17 |
Family
ID=55281947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510873412.0A Pending CN105331170A (en) | 2015-12-02 | 2015-12-02 | Environment-friendly nano-fire-proofing coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105331170A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163732A (en) * | 2017-06-29 | 2017-09-15 | 苏州吉云新材料技术有限公司 | A kind of high-wearing feature fireproof coating |
| CN107619634A (en) * | 2017-09-30 | 2018-01-23 | 镇江泽枫霖建筑材料有限公司 | A kind of energy-saving study on formula of fireproof paint |
| CN107629527A (en) * | 2017-09-30 | 2018-01-26 | 镇江泽枫霖建筑材料有限公司 | A kind of environmental type study on formula of fireproof paint |
| CN107629588A (en) * | 2017-10-30 | 2018-01-26 | 阜南县民安人防工程设备有限公司 | A kind of thermal insulation wall surface fireproof coating |
| CN108504257A (en) * | 2018-03-01 | 2018-09-07 | 广东至诚化学工业有限公司 | A kind of fire resistant coating and preparation method thereof |
| CN110684408A (en) * | 2019-09-29 | 2020-01-14 | 靖江市海鸿塑胶科技有限公司 | Nano efficient flame-retardant coating for water supply pipeline and production process thereof |
| CN111363427A (en) * | 2018-12-26 | 2020-07-03 | 四川天府防火材料有限公司 | Environment-friendly halogen-free water-based cable fireproof coating and preparation method thereof |
| CN112961528A (en) * | 2021-02-08 | 2021-06-15 | 大厂金隅涂料有限责任公司 | Environment-friendly fireproof coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1824716A (en) * | 2005-12-22 | 2006-08-30 | 北京首创纳米科技有限公司 | Aqueous environmental protection ultration expansion type steel structure fireproof paint and its preparation method |
| CN101955710A (en) * | 2010-05-14 | 2011-01-26 | 袁雪祥 | Water-borne nano ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN102827519A (en) * | 2012-09-12 | 2012-12-19 | 山东长星集团有限公司 | Fireproof paint |
| CN102838907A (en) * | 2012-08-24 | 2012-12-26 | 华南理工大学 | Waterborne ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN103131283A (en) * | 2013-03-19 | 2013-06-05 | 哈尔滨博元生物科技有限公司 | Water-based indoor facing smokeless fire-retardant paint |
-
2015
- 2015-12-02 CN CN201510873412.0A patent/CN105331170A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1824716A (en) * | 2005-12-22 | 2006-08-30 | 北京首创纳米科技有限公司 | Aqueous environmental protection ultration expansion type steel structure fireproof paint and its preparation method |
| CN101955710A (en) * | 2010-05-14 | 2011-01-26 | 袁雪祥 | Water-borne nano ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN102838907A (en) * | 2012-08-24 | 2012-12-26 | 华南理工大学 | Waterborne ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN102827519A (en) * | 2012-09-12 | 2012-12-19 | 山东长星集团有限公司 | Fireproof paint |
| CN103131283A (en) * | 2013-03-19 | 2013-06-05 | 哈尔滨博元生物科技有限公司 | Water-based indoor facing smokeless fire-retardant paint |
Non-Patent Citations (4)
| Title |
|---|
| 刘益军: "《聚氨酯原料及助剂手册》", 31 January 2013 * |
| 周春隆等: "《有机颜料化学及工艺学》", 30 June 2014 * |
| 徐峰等: "《功能性建筑涂料》", 31 May 2005 * |
| 曾贵玉等: "《微纳米含能材料》", 31 May 2015 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163732A (en) * | 2017-06-29 | 2017-09-15 | 苏州吉云新材料技术有限公司 | A kind of high-wearing feature fireproof coating |
| CN107619634A (en) * | 2017-09-30 | 2018-01-23 | 镇江泽枫霖建筑材料有限公司 | A kind of energy-saving study on formula of fireproof paint |
| CN107629527A (en) * | 2017-09-30 | 2018-01-26 | 镇江泽枫霖建筑材料有限公司 | A kind of environmental type study on formula of fireproof paint |
| CN107629588A (en) * | 2017-10-30 | 2018-01-26 | 阜南县民安人防工程设备有限公司 | A kind of thermal insulation wall surface fireproof coating |
| CN108504257A (en) * | 2018-03-01 | 2018-09-07 | 广东至诚化学工业有限公司 | A kind of fire resistant coating and preparation method thereof |
| CN111363427A (en) * | 2018-12-26 | 2020-07-03 | 四川天府防火材料有限公司 | Environment-friendly halogen-free water-based cable fireproof coating and preparation method thereof |
| CN110684408A (en) * | 2019-09-29 | 2020-01-14 | 靖江市海鸿塑胶科技有限公司 | Nano efficient flame-retardant coating for water supply pipeline and production process thereof |
| CN112961528A (en) * | 2021-02-08 | 2021-06-15 | 大厂金隅涂料有限责任公司 | Environment-friendly fireproof coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105331170A (en) | Environment-friendly nano-fire-proofing coating and preparation method thereof | |
| WO2011090292A2 (en) | Water-resistant and anti-corrosion ceramic coating material using nanoscale flakes | |
| CN111439985B (en) | Inorganic interior wall coating and preparation method thereof | |
| CN102533028A (en) | Water-based, primer-free and high-performance exterior water coating | |
| CN103319971A (en) | Metalized aqueous fluorocarbon coating for exterior wall and preparation method thereof | |
| CN105130369A (en) | Aqueous internal wall inorganic coating and preparation method thereof | |
| CN109694630A (en) | Aqueous, environmental protective heat-insulating flame-retardant coating and preparation method thereof | |
| CN110885630A (en) | Organic silicon water-based high-temperature-resistant special coating and preparation method thereof | |
| CN105400330A (en) | High-performance exterior-wall elastic paint and preparation method thereof | |
| CN113136143A (en) | Matte interior wall latex paint and preparation method thereof | |
| CN106700814A (en) | Water-based high-adhesion diving joint priming paint as well as preparation method and application thereof | |
| CN114273188B (en) | Fluorine-carbon aluminum veneer and preparation method thereof | |
| CN104725969A (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| CN108441070A (en) | A kind of heat-resistant fireproof coating and preparation method thereof | |
| CN107043565A (en) | A kind of inorganic powder inner wall putty of antistatic and its application | |
| CN113402908A (en) | Inorganic interior wall fireproof coating and preparation method thereof | |
| CN110724414A (en) | Stain-resistant high-temperature-resistant water-based paint and preparation method thereof | |
| CN112029408A (en) | Environment-friendly waterproof coating and preparation method thereof | |
| CN111218136A (en) | Organic-inorganic hybrid fireproof coating and preparation method thereof | |
| CN203305606U (en) | Heat-resistant BOPET (biaxially-oriented polyethylene terephthalate) protective film for fireproof plate | |
| CN104497760A (en) | Extra-weather-resistant fireproof coating | |
| CN103589306A (en) | High-permeability UV (ultraviolet) primer | |
| CN105623404A (en) | Preparation method for imidized SMA-modified cationic styrene acrylic sealing primer | |
| CN104559592A (en) | Fluorocarbon elastic paint and preparation method thereof | |
| CN110981282A (en) | Anticorrosive antibacterial stone-like paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Yan Inventor after: Peng Hongjun Inventor after: Yu Chengyang Inventor after: Zheng Hongxia Inventor after: Li Renwang Inventor after: Jiang Ao Inventor before: Peng Hongjun Inventor before: Li Yan Inventor before: Yu Chengyang Inventor before: Zheng Hongxia |
|
| COR | Change of bibliographic data | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160217 |
|
| RJ01 | Rejection of invention patent application after publication |