CN105325407A - Surfactant containing humic acid - Google Patents

Surfactant containing humic acid Download PDF

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Publication number
CN105325407A
CN105325407A CN201410391477.7A CN201410391477A CN105325407A CN 105325407 A CN105325407 A CN 105325407A CN 201410391477 A CN201410391477 A CN 201410391477A CN 105325407 A CN105325407 A CN 105325407A
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CN
China
Prior art keywords
humic acid
containing humic
fulvic acid
acid
fulvic
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Pending
Application number
CN201410391477.7A
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Chinese (zh)
Inventor
宋淑芹
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Individual
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Individual
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Publication date
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Priority to CN201410391477.7A priority Critical patent/CN105325407A/en
Publication of CN105325407A publication Critical patent/CN105325407A/en
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Abstract

The invention relates to a surfactant containing humic acid. The surfactant containing humic acid comprises the following components by weight: 20 to 50% of polyethylether modified trisiloxane and 50 to 70% of a compound containing humic acid. A preparation method for the surfactant containing humic acid comprises a step of uniformly mixing 20 to 50 wt% of polyethylether modified trisiloxane with 50 to 70 wt% of the compound containing humic acid. The surfactant containing humic acid can compensate for the defect of low surface activity of fulvic acid and improves the effective utilization rate and efficacy of fulvic acid; meanwhile, According to the invention, the surfactant containing humic acid is compounded with pesticide, fertilizer or the like and can reduce the application amount of pesticide, fertilizer or the like and substantially improve the appilication effect of pesticide, fertilizer or the like.

Description

A kind of containing humic acid surfactant
Technical field
The present invention relates to a kind of containing humic acid surfactant, particularly relate to a kind of fulvic acid surfactant.
Background technology
Humic acid is extensively present in natural world, is a kind of abundant natural resources, in soil, lake, river and marine environment, all has distribution, and the resource of humic acid being mainly distributed in China in soil, peat, coal, weathered coal is particularly abundant.Humic acid has acidity, hydrophily, interfacial activity, cation exchange capacity (CEC), complexing power, absorption dispersibility etc.; humic acid is the closest with the relation of agricultural; be widely used in the fields such as soil, fertilizer, plant physiology and nutrition, plant protection, the ecological agriculture, there is fertilizer synergistic, improve soil, stimulate plant growth, improve the functions such as agricultural product quality.
Fulvic acid is a kind of short carbon chain molecular structure material extracted from natural humic acid, it is a water-soluble good part in humic acid, also be the major part that humic acid plays function, there is controlling plant diseases, excite plant microbiological active, improve chemical fertilizer and agricultural chemicals utilization, Promoting plant growth, improve the functions such as soil structure, often be added into fertilizer, agricultural chemicals (weed killer herbicide, insecticide, bactericide) etc. in product, but the surface-active of fulvic acid itself is not high, make the effective rate of utilization of fulvic acid not high, also cause fertilizer simultaneously, agricultural chemicals etc. run off in a large number, effect is not obvious.
Summary of the invention
The object of this invention is to provide a kind of containing humic acid surfactant, effectively overcome that prior art fulvic acid surface-active is not high, effective rate of utilization is not high, make the technological deficiencies such as fertilizer, agricultural chemicals etc. run off in a large number, effect is not obvious.
For achieving the above object, the invention provides a kind of containing humic acid surfactant, comprise the constituent of following percentage by weight: polytrimethylene ether changes trisiloxanes 20%-50%, containing humic acid compound 50%-70%.
On the basis of technique scheme, the purity that described polytrimethylene ether changes trisiloxanes is more than 50%, and described is powder containing humic acid compound, and fineness is more than 75 orders.
Further, described is any one or any combination of fulvic acid or fulvic acid salt containing humic acid compound.
Preferably, described is fulvic acid containing humic acid compound, and the purity of described fulvic acid is more than 60%.Described is fulvic acid salt containing humic acid compound, and in described fulvic acid salt, the percentage by weight of fulvic acid is more than 60%, and described fulvic acid salt is any one or any combination of sodium fulvic acid, fulvic acid potassium or fulvic acid ammonium.
Present invention also offers a kind of preparation method containing humic acid surfactant, comprising:
By percentage by weight be 20%-50% that polytrimethylene ether changes trisiloxanes, percentage by weight is 50%-70% is even containing humic acid compound.
On the basis of technique scheme, the purity that described polytrimethylene ether changes trisiloxanes is more than 50%, and described is powder containing humic acid compound, and fineness is more than 75 orders.
Further, described is any one or any combination of fulvic acid or fulvic acid salt containing humic acid compound.
Preferably, described is fulvic acid containing humic acid compound, and the purity of described fulvic acid is more than 60%.Described is fulvic acid salt containing humic acid compound, and in described fulvic acid salt, the percentage by weight of fulvic acid is more than 60%, and described fulvic acid salt is any one or any combination of sodium fulvic acid, fulvic acid potassium or fulvic acid ammonium.
The invention provides a kind of containing humic acid surfactant and preparation method thereof, have the following advantages:
1, surface-active is high, effective rate of utilization is high.The present invention changes trisiloxanes containing polytrimethylene ether in humic acid surfactant and has characteristics such as reducing surface tension, high expansion and high permeability, polytrimethylene ether is changed trisiloxanes and fulvic acid organically combines, the defect that fulvic acid surface-active is low can be made up, and improve the effective rate of utilization of fulvic acid; Simultaneously by the present invention containing humic acid surfactant and agricultural chemicals, fertilizer etc. composite, liquid can be made to sprawl rapidly on blade face, and penetrate wax coat, through target, significantly improve the effective rate of utilization such as agricultural chemicals, fertilizer, reduce the injected volume such as agricultural chemicals, fertilizer, make fertilizer synergistic and reduce Pesticide use amount, improve the safety using agricultural chemicals, playing effects such as reducing environmental pollution, improve the ecological environment.
2, effect is remarkable.The present invention changes the combination of trisiloxanes and fulvic acid containing humic acid surfactant by polytrimethylene ether, the effective rate of utilization of fulvic acid and effect are significantly improved, and fulvic acid has control plant pest, excites plant microbiological activity, improves soil structure, improves chemical fertilizer and agricultural chemicals utilization, Promoting plant growth, raising crop yield, improves the effects such as agricultural product quality; Simultaneously by the present invention containing humic acid surfactant and agricultural chemicals, fertilizer etc. composite, most of fertilizer, weed killer herbicide, insecticide can be significantly improved, the biologically active of bactericide and biopesticide etc., significantly improve the application effect of fertilizer, agricultural chemicals etc.
Embodiment
The present invention below will be further detailed by embodiment, but it is not limited to any one or similar example of these embodiments.
The technical scheme of the present invention containing humic acid surfactant is further illustrated below by specific embodiment.
The present invention is containing humic acid surfactant first embodiment
The constituent of following percentage by weight is comprised: purity is the fulvic acid 60% that polytrimethylene ether changes trisiloxanes 60%, fineness is 75 orders, purity is 50% of 50% containing humic acid surfactant.
The present invention is containing humic acid surfactant second embodiment
The constituent of following percentage by weight is comprised: purity is the fulvic acid 60% that polytrimethylene ether changes trisiloxanes 50%, fineness is 85 orders, purity is 50% of 60% containing humic acid surfactant.
The present invention is containing humic acid surfactant the 3rd embodiment
The constituent of following percentage by weight is comprised: purity is the fulvic acid 50% that polytrimethylene ether changes trisiloxanes 50%, fineness is 120 orders, purity is 65% of 70% containing humic acid surfactant.
The present invention is containing humic acid surfactant the 4th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 50% polytrimethylene ether changes trisiloxanes 60%, fineness is 70 object sodium fulvic acids 60%, in sodium fulvic acid, the percentage by weight of fulvic acid is 50%.
The present invention is containing humic acid surfactant the 5th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 60% polytrimethylene ether changes trisiloxanes 60%, fineness is 90 object sodium fulvic acids 70%, in sodium fulvic acid, the percentage by weight of fulvic acid is 50%.
The present invention is containing humic acid surfactant the 6th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 70% polytrimethylene ether changes trisiloxanes 60%, fineness is 160 object sodium fulvic acids 40%, in sodium fulvic acid, the percentage by weight of fulvic acid is 60%.
The present invention is containing humic acid surfactant the 7th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 70% polytrimethylene ether changes trisiloxanes 50%, fineness is 90 object fulvic acid potassiums 50%, in fulvic acid potassium, the percentage by weight of fulvic acid is 50%.
The present invention is containing humic acid surfactant the 8th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 50% polytrimethylene ether changes trisiloxanes 60%, fineness is 90 object fulvic acid potassiums 70%, in fulvic acid potassium, the percentage by weight of fulvic acid is 50%.
The present invention is containing humic acid surfactant the 9th embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 80% polytrimethylene ether changes trisiloxanes 50%, fineness is 180 object fulvic acid potassiums 50%, in fulvic acid potassium, the percentage by weight of fulvic acid is 70%.
The present invention is containing humic acid surfactant the tenth embodiment
Comprise the constituent of following percentage by weight containing humic acid surfactant: purity be 50% polytrimethylene ether changes trisiloxanes 60%, fineness is 70 object fulvic acid ammoniums 70%, in fulvic acid ammonium, the percentage by weight of fulvic acid is 50%.

Claims (6)

1., containing a humic acid surfactant, it is characterized in that, comprise the constituent of following percentage by weight: polytrimethylene ether changes trisiloxanes 20%-50%, containing humic acid compound 50%-70%.
2. according to claim 1 containing humic acid surfactant, it is characterized in that, the purity that described polytrimethylene ether changes trisiloxanes is more than 50%, and described is powder containing humic acid compound, and fineness is more than 75 orders.
3. according to claim 1 containing humic acid surfactant, it is characterized in that, described is any one or any combination of fulvic acid or fulvic acid salt containing humic acid compound.
4. according to claim 3 containing humic acid surfactant, it is characterized in that, described is fulvic acid containing humic acid compound, and the purity of described fulvic acid is more than 60%.
5. according to claim 3 containing humic acid surfactant, it is characterized in that, described is fulvic acid salt containing humic acid compound, in described fulvic acid salt, the percentage by weight of fulvic acid is more than 60%, and described fulvic acid salt is any one or any combination of sodium fulvic acid, fulvic acid potassium or fulvic acid ammonium.
6. prepare the preparation method containing humic acid surfactant described in arbitrary claim in claim 1-5 for one kind, it is characterized in that, comprising: by percentage by weight be 20%-50% that polytrimethylene ether changes trisiloxanes, percentage by weight is 50%-70% is even containing humic acid compound.
CN201410391477.7A 2014-08-11 2014-08-11 Surfactant containing humic acid Pending CN105325407A (en)

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Application Number Priority Date Filing Date Title
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CN105325407A true CN105325407A (en) 2016-02-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105944621A (en) * 2016-05-12 2016-09-21 广西融水闽兴树脂有限公司 Preparation method of special emulsifier for rosin emulsion
CN105970732A (en) * 2016-05-12 2016-09-28 广西融水闽兴树脂有限公司 Rosin emulsion

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105944621A (en) * 2016-05-12 2016-09-21 广西融水闽兴树脂有限公司 Preparation method of special emulsifier for rosin emulsion
CN105970732A (en) * 2016-05-12 2016-09-28 广西融水闽兴树脂有限公司 Rosin emulsion
CN105944621B (en) * 2016-05-12 2018-06-19 广西融水闽兴树脂有限公司 The preparation method of rosin milk emulsifier special

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Application publication date: 20160217