CN101913945A - Humic acid-containing surfactant and preparation method thereof - Google Patents
Humic acid-containing surfactant and preparation method thereof Download PDFInfo
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- CN101913945A CN101913945A CN2010102419257A CN201010241925A CN101913945A CN 101913945 A CN101913945 A CN 101913945A CN 2010102419257 A CN2010102419257 A CN 2010102419257A CN 201010241925 A CN201010241925 A CN 201010241925A CN 101913945 A CN101913945 A CN 101913945A
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Abstract
The invention relates to a humic acid-containing surfactant and a preparation method thereof. The humic acid-containing surfactant comprises the following components in percentage by weight: 40-60 percent of polyether modified trisiloxane, and 40-60 percent of humic acid-containing compound. The preparation method of the humic acid-containing surfactant comprises the following step of uniformly mixing the 40-60 percent by weight of the polyether modified trisiloxane and 40-60 percent by weight of the humic acid-containing compound. The humic acid-containing surfactant can overcome the defect of low surface activity of fulvic acid and improve the effective utilization ratio and the efficacy of the fulvic acid; meanwhile, by compounding with pesticides, fertilizers, and the like, the humic acid-containing surfactant can reduce the usage amount of the pesticides, the fertilizers, and the like, thereby remarkably improving the application effect of the pesticides, the fertilizers, and the like.
Description
Technical field
The present invention relates to a kind of humic acids tensio-active agent and preparation method thereof that contains, particularly relate to a kind of yellow humic acid tensio-active agent and preparation method thereof.
Background technology
Humic acids extensively is present in nature, is a kind of rich natural resource, and distribution is all arranged in soil, lake, river and ocean environment, and the resource of humic acid that mainly is distributed in China in soil, peat, coal, the weathered coal is particularly abundant.Humic acids has acidity, wetting ability, interfacial activity, cation exchange capacity (CEC), complex ability, absorption dispersive ability etc.; humic acids is the closest with the relation of agricultural; be widely used in fields such as soil, fertilizer, plant physiology and nutrition, plant protection, the ecological agriculture, have fertilizer synergistic, improve the soil, stimulate plant growth, improve functions such as agricultural product quality.
Yellow humic acid is a kind of short carbon chain molecular structure material that extracts from natural humic acid, it is a water-soluble part preferably in the humic acids, it also is the major portion of humic acids performance function, has controlling plant diseases, excite plant microcosmic biological activity, improve chemical fertilizer and agricultural chemicals utilization, promote plant-growth, improve functions such as Soil structure, often be added into fertilizer, agricultural chemicals (weedicide, sterilant, sterilant) etc. in the product, but the surfactivity of yellow humic acid itself is not high, make that the effective rate of utilization of yellow humic acid is not high, also cause simultaneously fertilizer, agricultural chemicals etc. are a large amount of to run off, and effect is not obvious.
Summary of the invention
The purpose of this invention is to provide a kind of humic acids tensio-active agent and preparation method thereof that contains, overcome effectively that prior art yellow humic acid surfactivity is not high, effective rate of utilization is not high, technological deficiency such as make fertilizer, agricultural chemicals etc. run off in a large number, effect is not obvious.
For achieving the above object, the invention provides a kind of humic acids tensio-active agent that contains, comprise the moiety of following weight percent: polytrimethylene ether changes trisiloxanes 40%-60%, contains humic acids compound 40%-60%.
On the basis of technique scheme, the purity that described polytrimethylene ether changes trisiloxanes is more than 60%, and the described humic acids compound that contains is a powder, and fineness is more than 80 orders.
Further, describedly contain any one or the arbitrary combination that the humic acids compound is yellow humic acid or fulvic acid salt.
Preferably, the described humic acids compound that contains is a yellow humic acid, and the purity of described yellow humic acid is more than 40%.The described humic acids compound that contains is a fulvic acid salt, and the weight percent of yellow humic acid is more than 40% in the described fulvic acid salt, and described fulvic acid salt is any one or an arbitrary combination of fulvic acid sodium, fulvic acid potassium or yellow humic acid ammonium.
The present invention also provides a kind of preparation method who contains the humic acids tensio-active agent, comprising:
With weight percent be the polytrimethylene ether of 40%-60% change trisiloxanes, weight percent be 40%-60% to contain the humic acids compound even.
On the basis of technique scheme, the purity that described polytrimethylene ether changes trisiloxanes is more than 60%, and the described humic acids compound that contains is a powder, and fineness is more than 80 orders.
Further, describedly contain any one or the arbitrary combination that the humic acids compound is yellow humic acid or fulvic acid salt.
Preferably, the described humic acids compound that contains is a yellow humic acid, and the purity of described yellow humic acid is more than 40%.The described humic acids compound that contains is a fulvic acid salt, and the weight percent of yellow humic acid is more than 40% in the described fulvic acid salt, and described fulvic acid salt is any one or an arbitrary combination of fulvic acid sodium, fulvic acid potassium or yellow humic acid ammonium.
The invention provides a kind of humic acids tensio-active agent and preparation method thereof that contains, have the following advantages:
1, surfactivity height, effective rate of utilization height.The present invention contains in the humic acids tensio-active agent polytrimethylene ether and changes trisiloxanes (organosilicon) and have characteristics such as the surface tension of reduction, high expansion and high permeability, polytrimethylene ether is changed trisiloxanes (organosilicon) and yellow humic acid organically combines, can remedy the low defective of yellow humic acid surfactivity, and improve the effective rate of utilization of yellow humic acid; It is composite simultaneously the present invention to be contained humic acids tensio-active agent and agricultural chemicals, fertilizer etc., soup is sprawled rapidly on the blade face, and penetrate wax layer, through target, obviously improve effective rates of utilization such as agricultural chemicals, fertilizer, reduce injected volumes such as agricultural chemicals, fertilizer, make fertilizer synergistic and reduce the agricultural chemicals usage quantity, improve the security of using agricultural chemicals, play effect such as reduce environmental pollution, improve the ecological environment.
2, effect is remarkable.The present invention contains the humic acids tensio-active agent changes trisiloxanes (organosilicon) and yellow humic acid by polytrimethylene ether combination, make the effective rate of utilization and the effect of yellow humic acid significantly improve, yellow humic acid has the control plant pest, excites plant microcosmic biological activity, improves Soil structure, improves chemical fertilizer and agricultural chemicals utilization, promotes plant-growth, improves crop yield, improves effect such as agricultural product quality; It is composite simultaneously the present invention to be contained humic acids tensio-active agent and agricultural chemicals, fertilizer etc., can significantly improve most of fertilizer, weedicide, sterilant, and the biological activity of sterilant and biological pesticide etc. significantly improves the application effect of fertilizer, agricultural chemicals etc.
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment
Further specify the technical scheme that the present invention contains the humic acids tensio-active agent below by specific embodiment.
The present invention contains humic acids tensio-active agent first embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is that 80 orders, purity are 40% yellow humic acid 60%.
The present invention contains humic acids tensio-active agent second embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is that 100 orders, purity are 60% yellow humic acid 50%.
The present invention contains humic acids tensio-active agent the 3rd embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is that 200 orders, purity are 80% yellow humic acid 40%.
The present invention contains humic acids tensio-active agent the 4th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is 80 purpose fulvic acid sodiums 60%, and the weight percent of yellow humic acid is 40% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 5th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is 100 purpose fulvic acid sodiums 50%, and the weight percent of yellow humic acid is 60% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 6th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is 200 purpose fulvic acid sodiums 40%, and the weight percent of yellow humic acid is 80% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 7th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is 80 purpose fulvic acid potassiums 60%, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 8th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is 100 purpose fulvic acid potassiums 50%, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 9th embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is 200 purpose fulvic acid potassiums 40%, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the tenth embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is 80 purpose yellow humic acid ammoniums 60%, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 11 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is 100 purpose yellow humic acid ammoniums 50%, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 12 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is 200 purpose yellow humic acid ammoniums 40%, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 13 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 60% polytrimethylene ether to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 30%, fineness are 80 purpose fulvic acid sodiums 30%, the weight percent of yellow humic acid is 40% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 14 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 70% polytrimethylene ether to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 25%, fineness are 100 purpose fulvic acid sodiums 25%, the weight percent of yellow humic acid is 60% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 15 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 80% polytrimethylene ether to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 20%, fineness are 200 purpose fulvic acid sodiums 20%, the weight percent of yellow humic acid is 80% in the fulvic acid sodium.
The present invention contains humic acids tensio-active agent the 16 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 60% polytrimethylene ether to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 30%, fineness are 80 purpose fulvic acid potassiums 30%, the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 17 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 70% polytrimethylene ether to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 25%, fineness are 100 purpose fulvic acid potassiums 25%, the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 18 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 80% polytrimethylene ether to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 20%, fineness are 200 purpose fulvic acid potassiums 20%, the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 19 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 60% polytrimethylene ether to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 30%, fineness are 80 purpose yellow humic acid ammoniums 30%, the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 20 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 70% polytrimethylene ether to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 25%, fineness are 100 purpose yellow humic acid ammoniums 25%, the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 21 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity be 80% polytrimethylene ether to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 20%, fineness are 200 purpose yellow humic acid ammoniums 20%, the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 22 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is that 80 purpose fulvic acid sodiums 30%, fineness are 80 purpose fulvic acid potassiums 30%, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 23 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is that 100 purpose fulvic acid sodiums 25%, fineness are 100 purpose fulvic acid potassiums 25%, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 24 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is that 200 purpose fulvic acid sodiums 20%, fineness are 200 purpose fulvic acid potassiums 20%, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 25 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is that 80 purpose fulvic acid sodiums 30%, fineness are 80 purpose yellow humic acid ammoniums 30%, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 26 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is that 100 purpose fulvic acid sodiums 25%, fineness are 100 purpose yellow humic acid ammoniums 25%, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 27 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is that 200 purpose fulvic acid sodiums 20%, fineness are 200 purpose yellow humic acid ammoniums 20%, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 28 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is that 80 purpose fulvic acid potassiums 30%, fineness are 80 purpose yellow humic acid ammoniums 30%, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 29 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is that 100 purpose fulvic acid potassiums 25%, fineness are 100 purpose yellow humic acid ammoniums 25%, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 30 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is that 200 purpose fulvic acid potassiums 20%, fineness are 200 purpose yellow humic acid ammoniums 20%, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent hentriaconta-embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 20%, fineness are that 80 purpose fulvic acid sodiums 20%, fineness are 80 purpose fulvic acid potassiums 20% for 60% polytrimethylene ether, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 32 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 17%, fineness are that 100 purpose fulvic acid sodiums 17%, fineness are 100 purpose fulvic acid potassiums 16% for 70% polytrimethylene ether, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 33 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 14%, fineness are that 200 purpose fulvic acid sodiums 13%, fineness are 200 purpose fulvic acid potassiums 13% for 80% polytrimethylene ether, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains humic acids tensio-active agent the 34 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 20%, fineness are that 80 purpose fulvic acid sodiums 20%, fineness are 80 purpose yellow humic acid ammoniums 20% for 60% polytrimethylene ether, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 35 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 17%, fineness are that 100 purpose fulvic acid sodiums 17%, fineness are 100 purpose yellow humic acid ammoniums 16% for 70% polytrimethylene ether, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 36 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 14%, fineness are that 200 purpose fulvic acid sodiums 13%, fineness are 200 purpose yellow humic acid ammoniums 13% for 80% polytrimethylene ether, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 37 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 20%, fineness are that 80 purpose fulvic acid potassiums 20%, fineness are 80 purpose yellow humic acid ammoniums 20% for 60% polytrimethylene ether, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 38 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 17%, fineness are that 100 purpose fulvic acid potassiums 17%, fineness are 100 purpose yellow humic acid ammoniums 16% for 70% polytrimethylene ether, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 39 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 14%, fineness are that 200 purpose fulvic acid potassiums 13%, fineness are 200 purpose yellow humic acid ammoniums 13% for 80% polytrimethylene ether, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 40 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 60% polytrimethylene ether changes trisiloxanes 40%, fineness is that 80 purpose fulvic acid sodiums 20%, fineness are that 80 purpose fulvic acid potassiums 20%, fineness are 80 purpose yellow humic acid ammoniums 20%, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 41 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 70% polytrimethylene ether changes trisiloxanes 50%, fineness is that 100 purpose fulvic acid sodiums 17%, fineness are that 100 purpose fulvic acid potassiums 17%, fineness are 100 purpose yellow humic acid ammoniums 16%, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 42 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that 80% polytrimethylene ether changes trisiloxanes 60%, fineness is that 200 purpose fulvic acid sodiums 14%, fineness are that 200 purpose fulvic acid potassiums 13%, fineness are 200 purpose yellow humic acid ammoniums 13%, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 43 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 40%, fineness be that 80 orders, purity are that 40% yellow humic acid 15%, fineness are that 80 purpose fulvic acid sodiums 15%, fineness are that 80 purpose fulvic acid potassiums 15%, fineness are 80 purpose yellow humic acid ammoniums 15% for 60% polytrimethylene ether, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 44 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 50%, fineness be that 100 orders, purity are that 60% yellow humic acid 13%, fineness are that 100 purpose fulvic acid sodiums 13%, fineness are that 100 purpose fulvic acid potassiums 12%, fineness are 100 purpose yellow humic acid ammoniums 12% for 70% polytrimethylene ether, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains humic acids tensio-active agent the 45 embodiment
Contain the moiety that the humic acids tensio-active agent comprises following weight percent: purity is that to change trisiloxanes 60%, fineness be that 200 orders, purity are that 80% yellow humic acid 10%, fineness are that 200 purpose fulvic acid sodiums 10%, fineness are that 200 purpose fulvic acid potassiums 10%, fineness are 200 purpose yellow humic acid ammoniums 10% for 80% polytrimethylene ether, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains the humic acids tensio-active agent and can be used as auxiliary agent adding sterilant, sterilant, and weedicide is in the spray mixing liquid of foliage fertilizer or biological pesticide.Using method: with the agricultural chemicals is example, earlier with agricultural chemicals (soup) dissolving, adds and adds the present invention after the 5-10 kg of water and contain the humic acids tensio-active agent, adds water to 15 kilograms behind the mixing, fully can use behind the mixing.
The present invention contains preparation method first embodiment of humic acids tensio-active agent
With weight percent be 40% polytrimethylene ether to change trisiloxanes, weight percent be that 60% yellow humic acid mixes, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is 80 orders, purity is 40%.
The present invention contains preparation method second embodiment of humic acids tensio-active agent
With weight percent be 50% polytrimethylene ether to change trisiloxanes, weight percent be that 50% yellow humic acid mixes, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is 100 orders, purity is 60%.
The present invention contains preparation method the 3rd embodiment of humic acids tensio-active agent
With weight percent be 60% polytrimethylene ether to change trisiloxanes, weight percent be that 40% yellow humic acid mixes, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is 200 orders, purity is 80%.
The present invention contains preparation method the 4th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 60% fulvic acid sodium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid sodium is 80 orders, and the weight percent of yellow humic acid is 40% in the fulvic acid sodium.
The present invention contains preparation method the 5th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 50% fulvic acid sodium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid sodium is 100 orders, and the weight percent of yellow humic acid is 60% in the fulvic acid sodium.
The present invention contains preparation method the 6th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 40% fulvic acid sodium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid sodium is 200 orders, and the weight percent of yellow humic acid is 80% in the fulvic acid sodium.
The present invention contains preparation method the 7th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 60% fulvic acid potassium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid potassium is 80 orders, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains preparation method the 8th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 50% fulvic acid potassium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid potassium is 100 orders, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains preparation method the 9th embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 40% fulvic acid potassium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid potassium is 200 orders, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains preparation method the tenth embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 60% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid ammonium is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 11 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 50% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid ammonium is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 12 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 40% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid ammonium is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 13 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% yellow humic acid, weight percent are that 30% fulvic acid sodium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of fulvic acid sodium is 80 orders, and the weight percent of yellow humic acid is 40% in the fulvic acid sodium.
The present invention contains preparation method the 14 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% yellow humic acid, weight percent are that 25% fulvic acid sodium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of fulvic acid sodium is 100 orders, and the weight percent of yellow humic acid is 60% in the fulvic acid sodium.
The present invention contains preparation method the 15 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% fulvic acid sodium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of fulvic acid sodium is 200 orders, and the weight percent of yellow humic acid is 80% in the fulvic acid sodium.
The present invention contains preparation method the 16 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% yellow humic acid, weight percent are that 30% fulvic acid potassium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of fulvic acid potassium is 80 orders, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains preparation method the 17 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% yellow humic acid, weight percent are that 25% fulvic acid potassium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of fulvic acid potassium is 100 orders, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains preparation method the 18 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% fulvic acid potassium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of fulvic acid potassium is 200 orders, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains preparation method the 19 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% yellow humic acid, weight percent are that 30% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of yellow humic acid ammonium is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 20 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% yellow humic acid, weight percent are that 25% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of yellow humic acid ammonium is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 21 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of yellow humic acid ammonium is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 22 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% fulvic acid sodium, weight percent are that 30% fulvic acid potassium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid sodium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of fulvic acid potassium is 80 orders, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains preparation method the 23 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% fulvic acid sodium, weight percent are that 25% fulvic acid potassium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid sodium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of fulvic acid potassium is 100 orders, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains preparation method the 24 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% fulvic acid sodium, weight percent are that 20% fulvic acid potassium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid sodium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of fulvic acid potassium is 200 orders, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains preparation method the 25 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% fulvic acid sodium, weight percent are that 30% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid sodium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 26 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% fulvic acid sodium, weight percent are that 25% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid sodium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 27 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% fulvic acid sodium, weight percent are that 20% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid sodium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 28 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 30% fulvic acid potassium, weight percent are that 30% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid potassium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 29 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 25% fulvic acid potassium, weight percent are that 25% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid potassium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 30 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% fulvic acid potassium, weight percent are that 20% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid potassium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method's hentriaconta-embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% fulvic acid sodium, weight percent are that 20% fulvic acid potassium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of fulvic acid sodium is 80 purposes, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of fulvic acid potassium is 80 purposes, and the weight percent of yellow humic acid is 40% in the fulvic acid potassium.
The present invention contains preparation method the 32 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 17% yellow humic acid, weight percent are that 17% fulvic acid sodium, weight percent are that 16% fulvic acid potassium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of fulvic acid sodium is 100 purposes, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of fulvic acid potassium is 100 purposes, and the weight percent of yellow humic acid is 60% in the fulvic acid potassium.
The present invention contains preparation method the 33 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 14% yellow humic acid, weight percent are that 13% fulvic acid sodium, weight percent are that 13% fulvic acid potassium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of fulvic acid sodium is 200 purposes, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of fulvic acid potassium is 200 purposes, and the weight percent of yellow humic acid is 80% in the fulvic acid potassium.
The present invention contains preparation method the 34 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% fulvic acid sodium, weight percent are that 20% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of fulvic acid sodium is 80 purposes, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 80 purposes, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 35 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 17% yellow humic acid, weight percent are that 17% fulvic acid sodium, weight percent are that 16% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of fulvic acid sodium is 100 purposes, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 100 purposes, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 36 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 14% yellow humic acid, weight percent are that 13% fulvic acid sodium, weight percent are that 13% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of fulvic acid sodium is 200 purposes, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of yellow humic acid ammonium is 200 purposes, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 37 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 20% yellow humic acid, weight percent are that 20% fulvic acid potassium, weight percent are that 20% yellow humic acid ammonium mixes for 40% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is that 80 orders, purity are 40%, the fineness of fulvic acid potassium is 80 purposes, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 80 purposes, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 38 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 17% yellow humic acid, weight percent are that 17% fulvic acid potassium, weight percent are that 16% yellow humic acid ammonium mixes for 50% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is that 100 orders, purity are 60%, the fineness of fulvic acid potassium is 100 purposes, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 100 purposes, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 39 embodiment of humic acids tensio-active agent
With weight percent is that to change trisiloxanes, weight percent be that 14% yellow humic acid, weight percent are that 13% fulvic acid potassium, weight percent are that 13% yellow humic acid ammonium mixes for 60% polytrimethylene ether, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is that 200 orders, purity are 80%, the fineness of fulvic acid potassium is 200 purposes, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 200 purposes, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 40 embodiment of humic acids tensio-active agent
With weight percent is that 40% polytrimethylene ether changes trisiloxanes, weight percent is 20% fulvic acid sodium, weight percent is 20% fulvic acid potassium, weight percent is that 20% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of fulvic acid sodium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of fulvic acid potassium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 41 embodiment of humic acids tensio-active agent
With weight percent is that 50% polytrimethylene ether changes trisiloxanes, weight percent is 17% fulvic acid sodium, weight percent is 17% fulvic acid potassium, weight percent is that 16% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of fulvic acid sodium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of fulvic acid potassium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 42 embodiment of humic acids tensio-active agent
With weight percent is that 60% polytrimethylene ether changes trisiloxanes, weight percent is 14% fulvic acid sodium, weight percent is 13% fulvic acid potassium, weight percent is that 13% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of fulvic acid sodium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of fulvic acid potassium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, the fineness of yellow humic acid ammonium is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention contains preparation method the 43 embodiment of humic acids tensio-active agent
With weight percent is that 40% polytrimethylene ether changes trisiloxanes, weight percent is 15% yellow humic acid, weight percent is 15% fulvic acid sodium, weight percent is 15% fulvic acid potassium, weight percent is that 15% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 60%, the fineness of yellow humic acid is 80 orders, purity is 40%, the fineness of fulvic acid sodium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid sodium, the fineness of fulvic acid potassium is 80 orders, the weight percent of yellow humic acid is 40% in the fulvic acid potassium, yellow humic acid ammonium fineness is 80 orders, and the weight percent of yellow humic acid is 40% in the yellow humic acid ammonium.
The present invention contains preparation method the 44 embodiment of humic acids tensio-active agent
With weight percent is that 50% polytrimethylene ether changes trisiloxanes, weight percent is 13% yellow humic acid, weight percent is 13% fulvic acid sodium, weight percent is 12% fulvic acid potassium, weight percent is that 12% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 70%, the fineness of yellow humic acid is 100 orders, purity is 60%, the fineness of fulvic acid sodium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid sodium, the fineness of fulvic acid potassium is 100 orders, the weight percent of yellow humic acid is 60% in the fulvic acid potassium, yellow humic acid ammonium fineness is 100 orders, and the weight percent of yellow humic acid is 60% in the yellow humic acid ammonium.
The present invention contains preparation method the 45 embodiment of humic acids tensio-active agent
With weight percent is that 60% polytrimethylene ether changes trisiloxanes, weight percent is 10% yellow humic acid, weight percent is 10% fulvic acid sodium, weight percent is 10% fulvic acid potassium, weight percent is that 10% yellow humic acid ammonium mixes, the purity that polytrimethylene ether changes trisiloxanes is 80%, the fineness of yellow humic acid is 200 orders, purity is 80%, the fineness of fulvic acid sodium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid sodium, the fineness of fulvic acid potassium is 200 orders, the weight percent of yellow humic acid is 80% in the fulvic acid potassium, yellow humic acid ammonium fineness is 200 orders, and the weight percent of yellow humic acid is 80% in the yellow humic acid ammonium.
The present invention who contains preparation method first embodiment to the 45 embodiment preparation of humic acids tensio-active agent by the invention described above contains the humic acids tensio-active agent and can be used as auxiliary agent and add sterilant, sterilant, weedicide is in the spray mixing liquid of foliage fertilizer or biological pesticide.Using method: with the agricultural chemicals is example, earlier with agricultural chemicals (soup) dissolving, adds and adds the present invention after the 5-10 kg of water and contain the humic acids tensio-active agent, adds water to 15 kilograms behind the mixing, fully can use behind the mixing.
With the wheat is example, and laboratory test data shows that the present invention contains the surface tension that the humic acids tensio-active agent can significantly reduce soup.After weight percent is 2500 times of 10% imidacloprid wettable powder dilutions, in soup, add the present invention again and contain the humic acids tensio-active agent, when the weight percent that contains the humic acids tensio-active agent as the present invention is 0.05%, can make the surface tension of soup drop to 20-25mNm
-1, droplet expanding area on wheat leaf blade obviously increases; When the weight percent that contains the humic acids tensio-active agent as the present invention was 0.001%, the contact angle of soup on wheat leaf blade promptly began significantly to reduce, and at the contact angle at the wheat back side less than contact angle in the front.The field test data show, at weight percent is that to add weight percent in the 10% imidacloprid wettable powder soup be after the present invention of 0.05% contains the humic acids tensio-active agent, use hand-held centrifugal low-gallonage spraying machine spraying, can significantly increase prevention effect wheat aphid.
The present invention contains in the humic acids tensio-active agent polytrimethylene ether and changes trisiloxanes (organosilicon) and have characteristics such as the surface tension of reduction, high expansion and high permeability, polytrimethylene ether is changed trisiloxanes (organosilicon) and yellow humic acid organically combines, can remedy the low defective of yellow humic acid surfactivity, and improving the effective rate of utilization of yellow humic acid, yellow humic acid has the control plant pest, excite plant microcosmic biological activity, improve Soil structure, improve chemical fertilizer and agricultural chemicals utilization, promote plant-growth, improve crop yield, improve effect such as agricultural product quality; Simultaneously the present invention is contained humic acids tensio-active agent and agricultural chemicals, fertilizer etc. are composite, soup is sprawled rapidly on the blade face, and penetrate wax layer, through target, obviously improve agricultural chemicals, effective rates of utilization such as fertilizer, reduce agricultural chemicals, injected volumes such as fertilizer, make fertilizer synergistic and reduce the agricultural chemicals usage quantity, improve the security of using agricultural chemicals, play and reduce environmental pollution, effect such as improve the ecological environment, in addition, the present invention contains the humic acids tensio-active agent can significantly improve most of fertilizer, weedicide, sterilant, the biological activity of sterilant and biological pesticide etc. significantly improves fertilizer, the application effect of agricultural chemicals etc.
It should be noted last that, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can make amendment or be equal to replacement technical scheme of the present invention, and not break away from the spirit and scope of technical solution of the present invention.
Claims (10)
1. one kind contains the humic acids tensio-active agent, it is characterized in that, comprises the moiety of following weight percent: polytrimethylene ether changes trisiloxanes 40%-60%, contains humic acids compound 40%-60%.
2. the humic acids tensio-active agent that contains according to claim 1 is characterized in that, the purity that described polytrimethylene ether changes trisiloxanes is more than 60%, and the described humic acids compound that contains is a powder, and fineness is more than 80 orders.
3. the humic acids tensio-active agent that contains according to claim 1 is characterized in that, describedly contains any one or the arbitrary combination that the humic acids compound is yellow humic acid or fulvic acid salt.
4. the humic acids tensio-active agent that contains according to claim 3 is characterized in that, the described humic acids compound that contains is a yellow humic acid, and the purity of described yellow humic acid is more than 40%.
5. the humic acids tensio-active agent that contains according to claim 3, it is characterized in that, the described humic acids compound that contains is a fulvic acid salt, the weight percent of yellow humic acid is more than 40% in the described fulvic acid salt, and described fulvic acid salt is any one or an arbitrary combination of fulvic acid sodium, fulvic acid potassium or yellow humic acid ammonium.
6. one kind prepares the described preparation method who contains the humic acids tensio-active agent of arbitrary claim among the claim 1-5, it is characterized in that, comprising:
With weight percent be the polytrimethylene ether of 40%-60% change trisiloxanes, weight percent be 40%-60% to contain the humic acids compound even.
7. the humic acids tensio-active agent that contains according to claim 6 is characterized in that, the purity that described polytrimethylene ether changes trisiloxanes is more than 60%, and the described humic acids compound that contains is a powder, and fineness is more than 80 orders.
8. the humic acids tensio-active agent that contains according to claim 6 is characterized in that, describedly contains any one or the arbitrary combination that the humic acids compound is yellow humic acid or fulvic acid salt.
9. humic acid surfactant according to claim 8 is characterized in that, the described humic acids compound that contains is a yellow humic acid, and the purity of described yellow humic acid is more than 40%.
10. humic acid surfactant according to claim 8, it is characterized in that, the described humic acids compound that contains is a fulvic acid salt, the weight percent of yellow humic acid is more than 40% in the described fulvic acid salt, and described fulvic acid salt is any one or an arbitrary combination of fulvic acid sodium, fulvic acid potassium or yellow humic acid ammonium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102419257A CN101913945A (en) | 2010-07-30 | 2010-07-30 | Humic acid-containing surfactant and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102419257A CN101913945A (en) | 2010-07-30 | 2010-07-30 | Humic acid-containing surfactant and preparation method thereof |
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| CN101913945A true CN101913945A (en) | 2010-12-15 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105936791A (en) * | 2016-05-27 | 2016-09-14 | 广西梧州龙鱼漆业有限公司 | Antirust automobile finishing paint |
| CN105969048A (en) * | 2016-05-27 | 2016-09-28 | 广西梧州龙鱼漆业有限公司 | Rustproof automobile finish preparation method |
| CN108552242A (en) * | 2018-05-21 | 2018-09-21 | 广州市淳淇新材料有限公司 | A kind of organic silicon pesticide synergist and its crops sterilizing insecticide |
-
2010
- 2010-07-30 CN CN2010102419257A patent/CN101913945A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105936791A (en) * | 2016-05-27 | 2016-09-14 | 广西梧州龙鱼漆业有限公司 | Antirust automobile finishing paint |
| CN105969048A (en) * | 2016-05-27 | 2016-09-28 | 广西梧州龙鱼漆业有限公司 | Rustproof automobile finish preparation method |
| CN108552242A (en) * | 2018-05-21 | 2018-09-21 | 广州市淳淇新材料有限公司 | A kind of organic silicon pesticide synergist and its crops sterilizing insecticide |
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Application publication date: 20101215 |