CN108782556A - A kind of surfactant containing humic acid - Google Patents
A kind of surfactant containing humic acid Download PDFInfo
- Publication number
- CN108782556A CN108782556A CN201710292209.3A CN201710292209A CN108782556A CN 108782556 A CN108782556 A CN 108782556A CN 201710292209 A CN201710292209 A CN 201710292209A CN 108782556 A CN108782556 A CN 108782556A
- Authority
- CN
- China
- Prior art keywords
- humic acid
- containing humic
- acid
- fulvic acid
- surfactant containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
Abstract
The present invention relates to a kind of surfactants containing humic acid, and surfactant containing humic acid includes the ingredient of following weight percent：Polytrimethylene ether changes trisiloxanes 20%-50%, the 50%-70% of compound containing humic acid.The preparation method of the surfactant containing humic acid includes：The polytrimethylene ether that weight percent is 20%-50% is changed into trisiloxanes, the compound containing humic acid that weight percent is 50%-70% is uniformly mixed.Present invention surfactant containing humic acid can make up the low defect of fulvic acid surface-active, and improve the effective rate of utilization and effect of fulvic acid；Simultaneously by the compoundings such as surfactant containing humic acid and pesticide, fertilizer of the invention, the injected volumes such as pesticide, fertilizer can be reduced, the application effect of fertilizer, pesticide etc. is significantly improved.
Description
Technical field
The present invention relates to a kind of surfactants containing humic acid, more particularly to a kind of fulvic acid surfactant.
Background technology
Humic acid is widely present in nature, is a kind of abundant natural resources, in soil, lake, river and ocean ring
It is distributed in border, the resource of humic acid for being mainly distributed on China in soil, peat, coal, weathered coal is particularly abundant.Humic acid
With acidity, hydrophily, interfacial activity, cation exchange capacity (CEC), complexing power, absorption dispersibility etc., humic acid and agricultural
Relationship it is the closest, be widely used in the fields such as soil, fertilizer, plant physiology and nutrition, plant protection, the ecological agriculture, have
There is fertilizer synergistic, improvement soil, stimulation plant growth, improve the functions such as agricultural product quality.
Fulvic acid is a kind of short carbon chain molecular structure substance extracted from natural humic acid, is water-soluble in humic acid
There are the major part that a preferable part and humic acid function controlling plant diseases, excitation plant microbiological to live
Property, improve chemical fertilizer and pesticide and utilize, promote plant growth, improve the functions such as soil texture, be often added into fertilizer, pesticide
In products such as (herbicide, insecticide, fungicide), but the surface-active of fulvic acid itself is not high so that fulvic acid
Effective rate of utilization is not high, while also resulting in fertilizer, pesticide etc. and being largely lost, effect unobvious.
Invention content
The object of the present invention is to provide a kind of surfactants containing humic acid, effectively overcome prior art fulvic acid surface
Activity is not high, effective rate of utilization is not high so that the technological deficiencies such as fertilizer, pesticide etc. be largely lost, effect unobvious.
To achieve the above object, the present invention provides a kind of surfactants containing humic acid, including following weight percent
Constituent：Polytrimethylene ether changes trisiloxanes 20%-50%, the 50%-70% of compound containing humic acid.
Based on the above technical solution, the purity that the polytrimethylene ether changes trisiloxanes is 50% or more, described containing corruption
Phytic acid compound is powder, and fineness is 75 mesh or more.
Further, the compound containing humic acid is any one or arbitrary group of fulvic acid or fulvic acid salt
It closes.
Preferably, the compound containing humic acid is fulvic acid, and the purity of the fulvic acid is 60% or more.It is described
Compound containing humic acid is fulvic acid salt, and the weight percent of fulvic acid is 60% or more in the fulvic acid salt, institute
State any one or arbitrary combination that fulvic acid salt is sodium fulvic acid, fulvic acid potassium or fulvic acid ammonium.
The present invention also provides a kind of preparation methods of surfactant containing humic acid, including：
The polytrimethylene ether that weight percent is 20%-50% is changed into trisiloxanes, weight percent be 50%-70% contain humic acid
Compound is uniformly mixed.
Based on the above technical solution, the purity that the polytrimethylene ether changes trisiloxanes is 50% or more, described containing corruption
Phytic acid compound is powder, and fineness is 75 mesh or more.
Further, the compound containing humic acid is any one or arbitrary group of fulvic acid or fulvic acid salt
It closes.
Preferably, the compound containing humic acid is fulvic acid, and the purity of the fulvic acid is 60% or more.It is described
Compound containing humic acid is fulvic acid salt, and the weight percent of fulvic acid is 60% or more in the fulvic acid salt, institute
State any one or arbitrary combination that fulvic acid salt is sodium fulvic acid, fulvic acid potassium or fulvic acid ammonium.
The present invention provides a kind of surfactants containing humic acid and preparation method thereof, have the following advantages：
1, high surface activity, effective rate of utilization are high.Polytrimethylene ether changes trisiloxanes and has in present invention surfactant containing humic acid
The characteristics such as surface tension, high extension and high permeability are reduced, polytrimethylene ether is changed into trisiloxanes and fulvic acid is organically combined one
It rises, the low defect of fulvic acid surface-active can be made up, and improve the effective rate of utilization of fulvic acid；The present invention is contained simultaneously
The compoundings such as humic acid surfactant and pesticide, fertilizer, can be such that liquid is sprawled rapidly on blade face, and penetrate wax coat, go directly
Target, hence it is evident that improve the effective rates of utilization such as pesticide, fertilizer, reduce the injected volumes such as pesticide, fertilizer, make fertilizer synergistic and reduce pesticide
Usage amount improves the safety for using pesticide, plays and reduces environmental pollution, improves the ecological environment and other effects.
2, obvious effect.Present invention surfactant containing humic acid changes having for trisiloxanes and fulvic acid by polytrimethylene ether
Machine combines so that the effective rate of utilization and obvious effect of fulvic acid improve, and fulvic acid has prevention plant pest, excitation
Plant microbiological activity improves soil texture, improvement chemical fertilizer and pesticide utilization, promotes plant growth, improve crop yield, change
Kind agricultural product quality and other effects；Simultaneously by the compoundings such as surfactant containing humic acid and pesticide, fertilizer of the invention, can significantly carry
The bioactivity of high most of fertilizer, herbicide, insecticide, fungicide and biological pesticide etc., significantly improves fertilizer, pesticide etc.
Application effect.
Below by embodiment, technical scheme of the present invention will be described in further detail.
Tool stops embodiment
In the following, the present invention will be further detailed with embodiment, but it be not limited to these examples any one
Or similar example.
The technical solution of the surfactant containing humic acid is further illustrated the present invention below by specific embodiment.
The present invention first embodiment of surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 50% changes three silica
The fulvic acid 60% that alkane 60%, fineness are 75 mesh, purity is 50%.
The present invention second embodiment of surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 60% changes three silica
The fulvic acid 60% that alkane 50%, fineness are 85 mesh, purity is 50%.
The present invention 3rd embodiment of surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 70% changes three silica
The fulvic acid 50% that alkane 50%, fineness are 120 mesh, purity is 65%.
The present invention fourth embodiment of surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 50% changes three silica
Alkane 60%, the sodium fulvic acid 60% that fineness is 70 mesh, the weight percent of fulvic acid is 50% in sodium fulvic acid.
The 5th embodiment of present invention surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 60% changes three silica
Alkane 60%, the sodium fulvic acid 70% that fineness is 90 mesh, the weight percent of fulvic acid is 50% in sodium fulvic acid.
The present invention sixth embodiment of surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 70% changes three silica
Alkane 60%, the sodium fulvic acid 40% that fineness is 160 mesh, the weight percent of fulvic acid is 60% in sodium fulvic acid.
The 7th embodiment of present invention surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 70% changes three silica
Alkane 50%, the fulvic acid potassium 50% that fineness is 90 mesh, the weight percent of fulvic acid is 50% in fulvic acid potassium.
The 8th embodiment of present invention surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 50% changes three silica
Alkane 60%, the fulvic acid potassium 70% that fineness is 90 mesh, the weight percent of fulvic acid is 50% in fulvic acid potassium.
The 9th embodiment of present invention surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 80% changes three silica
Alkane 50%, the fulvic acid potassium 50% that fineness is 180 mesh, the weight percent of fulvic acid is 70% in fulvic acid potassium.
The tenth embodiment of present invention surfactant containing humic acid
Surfactant containing humic acid includes the constituent of following weight percent：The polytrimethylene ether that purity is 50% changes three silica
Alkane 60%, the fulvic acid ammonium 70% that fineness is 70 mesh, the weight percent of fulvic acid is 50% in fulvic acid ammonium.
Claims (6)
1. a kind of surfactant containing humic acid, which is characterized in that include the constituent of following weight percent：Polytrimethylene ether changes
Trisiloxanes 20%-50%, the 50%-70% of compound containing humic acid.
2. according to the surfactant containing humic acid described in claim 1, which is characterized in that the polytrimethylene ether changes trisiloxanes
Purity be 50% or more, the compound containing humic acid is powder, and fineness is more than 75 mesh.
3. according to the surfactant containing humic acid described in claim 1, which is characterized in that the compound containing humic acid is
Any one or arbitrary combination of fulvic acid or fulvic acid salt.
4. according to the surfactant containing humic acid described in claim 3, which is characterized in that the compound containing humic acid is
The purity of fulvic acid, the fulvic acid is 60% or more.
5. according to the surfactant containing humic acid described in claim 3, which is characterized in that the compound containing humic acid is
Fulvic acid salt, the weight percent of fulvic acid is 60% or more in the fulvic acid salt, and the fulvic acid salt is Huang
Any one or arbitrary combination of sodium humate, fulvic acid potassium or fulvic acid ammonium.
6. a kind of preparation method preparing the surfactant containing humic acid described in any claim in claim 1-5,
It is characterized in that, including：The polytrimethylene ether that weight percent is 20%-50% is changed into trisiloxanes, weight percent 50%-70%
Compound containing humic acid be uniformly mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710292209.3A CN108782556A (en) | 2017-04-28 | 2017-04-28 | A kind of surfactant containing humic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710292209.3A CN108782556A (en) | 2017-04-28 | 2017-04-28 | A kind of surfactant containing humic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108782556A true CN108782556A (en) | 2018-11-13 |
Family
ID=64070451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710292209.3A Pending CN108782556A (en) | 2017-04-28 | 2017-04-28 | A kind of surfactant containing humic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108782556A (en) |
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2017
- 2017-04-28 CN CN201710292209.3A patent/CN108782556A/en active Pending
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181113 |