CN105324521A - Anode and high-speed plating device provided with same - Google Patents
Anode and high-speed plating device provided with same Download PDFInfo
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- CN105324521A CN105324521A CN201480033953.6A CN201480033953A CN105324521A CN 105324521 A CN105324521 A CN 105324521A CN 201480033953 A CN201480033953 A CN 201480033953A CN 105324521 A CN105324521 A CN 105324521A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/12—Shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/005—Contacting devices
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/007—Current directing devices
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/06—Suspending or supporting devices for articles to be coated
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/10—Agitating of electrolytes; Moving of racks
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/08—Electroplating with moving electrolyte e.g. jet electroplating
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
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- Electroplating Methods And Accessories (AREA)
Abstract
Provided is an anode capable of favorably plating for a long period of time. The anode (10) is cylindrical, forms a space through which a plating solution flows between itself and an article (1) to be plated and positioned in the interior thereof, and has a positive voltage imparted thereto. The anode (10) is provided with a conductive outer-cylindrical section (11), and an inner-cylindrical section (12) comprising a platinum plate material (12A) welded so as to contact the inner surface of the outer-cylindrical section (11).
Description
Technical field
The present invention relates to a kind of anode and possess the high speed electrodeposition device of this anode.
Background technology
Patent Document 1 discloses a kind of existing high speed electrodeposition device.This high speed electrodeposition device possesses the encloses container be made up of metal cylinder and cover, and wherein, described metal cylinder is anode, and described cover is combined on the two ends of this metal cylinder integratedly.Metal cylinder is copper, and within it surface and end face substrates have platinum film.Two opposite covers be provided with for latch sliding freely inserted through inserted through hole.Latch is clamp plated body and the parts kept, and forms a part for holding device.In addition, latch is also for contact with plated body and to apply the power supply part of negative voltage.
In addition, this high speed electrodeposition device possesses supply unit, and described supply unit, to apply positive voltage to metal cylinder and to apply the mode of negative voltage to plated body, is energized to metal cylinder and latch.In addition, this high speed electrodeposition device possesses the circulation device be made up of the pump etc. making electroplate liquid carry out circulating in the mode making electroplate liquid flow in encloses container.
This high speed electrodeposition device is after receiving to encloses container by the plated body clamped by latch, and the mode flowed in encloses container to make electroplate liquid drives pump.And, by applying positive voltage to metal cylinder and applying negative voltage via latch to plated body, thus the shorter high speed electrodeposition of electroplating time can be implemented.
At first technical literature
Patent documentation
Patent documentation 1: Japanese Laid-Open Patent Publication 55-138097 publication
Summary of the invention
Invent problem to be solved
But because the high speed electrodeposition device of patent documentation 1 is compared with general electroplanting device, implement plating with larger current density, therefore the platinum film of galvanic deposit on the internal surface of metal cylinder can be peeled off at short notice or consume.Owing to cannot implement plating equably when the platinum film of galvanic deposit on the internal surface of metal cylinder is peeled off or consumed, therefore, in this high speed electrodeposition device, the replacement frequency of metal cylinder can increase, and the expense adding processing platinum film will improve.
The present invention is the invention in view of above-mentioned existing situation completes, and is as the problem that should solve, provide a kind of can for a long time between implement the anode electroplated well and possess the high speed electrodeposition device of this anode.
For solving the method for problem
Anode of the present invention is tubular, and between described anode and the plated body being configured in this anode interior, form the space that electroplate liquid is flowed, and described anode is applied in positive voltage, and the feature of described anode is to possess: outer cylindrical portion, and it has electroconductibility; Inner cylinder portion, it is soldered and be made up of the plate of platinum in the mode connected with the internal surface of this outer cylindrical portion.
Invention effect
Because the inner cylinder portion be made up of the plate of platinum to be welded on the internal surface of the outer cylindrical portion of electroconductibility, therefore, it is possible to make the inner cylinder portion be made up of the plate of platinum be close to securely in the outer cylindrical portion of electroconductibility by this anode.Therefore, it is possible to the situation that the inner cylinder portion that minimizing is made up of the plate of platinum is in the plating process peeled off from the internal surface of outer cylindrical portion.In addition, because the plate of inner cylinder portion by platinum is formed, the consumption produced owing to implementing plating can therefore be reduced compared with the platinum film of galvanic deposit.So, this anode can reduce replacement frequency, thus can reduce additional process cost.
Therefore, anode of the present invention and the high speed electrodeposition device that possesses this anode can implement plating for a long time well.
Accompanying drawing explanation
Fig. 1 represents the sectional view along the cross section of the travel direction of the second power supply part of the high speed electrodeposition device of embodiment.
Fig. 2 represents the sectional view along the cross section of the travel direction of the holding member of the high speed electrodeposition device of embodiment.
Fig. 3 represents the anode of embodiment, and (A) is the sectional view representing the state slab of titanium and the slab of platinum welded together, and (B) is rolled into cylindrical shape and the sectional view of state end face being docked and welds together for representing.
Fig. 4 represents the anode of embodiment and the sectional view of the first power supply part.
Fig. 5 is the sectional view part by the top compared with the top of anode of the high speed electrodeposition device of embodiment amplified.
Fig. 6 is the sectional view after amplifying around the bottom bearing part that carried out the antianode bottom of the high speed electrodeposition device of embodiment supporting.
Fig. 7 is the vertical view of the high speed electrodeposition device from top view embodiment.
The horizontal cross of the position residing for the second power supply part that Fig. 8 is embodiment.
Fig. 9 is the part sectioned view of the second power supply part of embodiment.
The horizontal cross of the position of Figure 10 residing for the holding member of embodiment.
Figure 11 represents cross section along the travel direction of the second power supply part of the high speed electrodeposition device of embodiment and to drop in anode front sectional view for plated body.
Figure 12 represents cross section along the travel direction of the holding member of the high speed electrodeposition device of embodiment and to drop in anode front sectional view for plated body.
Figure 13 is expression is inserted into the state in the recess of the upper end of support rod sectional view along the cross section of the travel direction of the second power supply part of the high speed electrodeposition device of embodiment and for the bottom of plated body.
Figure 14 represents cross section along the travel direction of the second power supply part of the high speed electrodeposition device of embodiment and drops to the sectional view of the state in anode for plated body.
Figure 15 is the sectional view representing the state that the top ends of the second power supply part of embodiment contacts with the periphery of plated body.
Figure 16 is that expression is along the cross section of the travel direction of the holding member of the high speed electrodeposition device of embodiment and for maintaining part is to the sectional view of the state that plated body keeps.
Figure 17 represents that maintaining part is to the horizontal cross of the state that plated body keeps.
Figure 18 has carried out amplification to the part by the top compared with the top of anode of the high speed electrodeposition device of embodiment and for representing that maintaining part is to the sectional view of the state that plated body keeps.
Embodiment
With reference to accompanying drawing, the embodiment specialized by the high speed electrodeposition device possessing anode of the present invention is described.
< embodiment >
As shown in Figures 1 and 2, the high speed electrodeposition device of embodiment possesses: anode 10; First power supply part 20, it contacts with anode 10 and applies positive voltage; Second power supply part 30, it contacts with the plated body 1 as workpiece and applies negative voltage; Holding device 40, it possesses the holding member 41 kept plated body 1; Pressurizing device 50, it sends into air and pressurizes in the holding chamber 45 being configured with holding member 41; Circulation device 60, it makes electroplate liquid circulate; Supply unit 70, its antianode 10 and the second power supply part 30 are energized.
Anode 10 is for cylindric and be configured in the mode extended in vertical direction.As shown in Figures 3 and 4, anode 10 has the outer cylindrical portion 11 formed by the plate of titanium and the inner cylinder portion 12 formed by the plate of platinum.In addition, as shown in Figures 1 and 2, anode 10 has the outer annular element 13 being embedded in the titanium in upper and lower end parts respectively.
This anode 10 is manufactured in next illustrated mode.First, the slab 12A of platinum is overlapped on the slab 11A of titanium, and is made by resistance welding surface be welded to one another together, thus manufacture the plate 10A (with reference to Fig. 3 (A)) of dual structure.Next, roll in the mode making the slab 12A of platinum become inner side, be shaped to become cylindric mode, and carry out welding (with reference to Fig. 3 (B)) in the mode making end face dock.And, periphery annular element 13 being welded on respectively the upper and lower end parts of anode 10 realizes integration.
So, due to the inner cylinder portion 12 be made up of the plate 12A of platinum is welded on the outer cylindrical portion 11 of the titanium with electroconductibility internal surface on thus form anode 10, therefore, it is possible to make the inner cylinder portion 12 be made up of the plate 12A of platinum be close to securely in the outer cylindrical portion 11 of electroconductibility.Therefore, it is possible to the situation that the inner cylinder portion 12 that minimizing is made up of the plate 12A of platinum is in the plating process peeled off from the internal surface of outer cylindrical portion 11.In addition, because the plate 12A of inner cylinder portion 12 by platinum is formed, the consumption produced owing to implementing plating can therefore be reduced compared with the platinum film of galvanic deposit.So, this anode 10 can reduce replacement frequency, thus can reduce additional process cost.
Therefore, the anode 10 of embodiment and the high speed electrodeposition device that possesses this anode 10 can implement plating for a long time well.
In addition, due to the slab 11A by making the slab 12A of platinum overlap titanium making after surface is welded to one another together, roll to become cylindric mode and end face is welded ground connection, thus anode 10 is shaped, therefore, can easily make cylindric anode 10 be shaped, the anode 10 of described cylindrical shape is consisted of the outer cylindrical portion 11 formed by the slab 11A of titanium and the outer cylindrical portion 11 formed by the slab 12A of platinum.
As shown in Figure 1, Figure 2 and shown in Fig. 4, the first power supply part 20 is formed by first component 21 and second component 22, and these parts are installed in respectively fitted between the annular element 13 in the upper and lower end parts of anode 10.First component 21 is copper coin, and second component 22 is by thinner copper coin is formed compared with first component 21.The rectangular flat board of lengthwise of first component 21 for extending in the vertical direction along anode 10, its left and right central part contacts with the periphery of the anode 10 extended on straight line in vertical direction.Second component 22 is the rectangular flat board of the lengthwise that the mode abutted with first component 21 with both ends extends in the vertical direction, and these both ends are screwed on first component 21 by multiple bolt.Second component 22 forwards to be bloated by the mode central part U-shaped ground covering anode 10 under the state that is screwed on first component 21, and its internal surface and anode 10 from first component 21 away from half circumferential contact.First power supply part 20 unscrews by making the bolt combined first component 21 and second component 22 thus dismantles anode 10 and change.
As shown in Figures 1 and 2, the upper end of anode 10 is supported by top bearing part 80, and bottom is supported by bottom bearing part 90.Top bearing part 80 be fixed on have for anode 10 inserted through opening flat first fixing part 100 on.Bottom bearing part 90 be fixed on have for support rod 15 described later inserted through opening flat second fixing part 101 on.Second fixing part 101 is linked to the below of the first fixing part 100 downwards by four connecting members 102 hanging down the lower surface from the first fixing part 100.
As shown in Figure 5, the outer shape of top bearing part 80 is rectangular shape, and have to the upper space 81 of vertical upper opening and with the lower end of this upper space 81 continuously and to the lower space 82 of vertical lower opening.The horizontal cross sectional geometry of the upper space 81 of top bearing part 80 and the respective inner peripheral surface of lower space 82 is formed concentric circles.Upper space 81 inserts from top for the bottom of base component 85 described later.In addition, be configured point-blank and top in upper space 81 on the lower compared with base component 85 the second opposite power supply part 30 with the center towards upper space 81, mode free to advance or retreat is configured.As shown in figures 2 and 5, upper space 81 has and to extend in the horizontal direction continuously and to the spout 83 of the electroplate liquid of the lateral opening of top bearing part 80.The spout 83 of electroplate liquid is connected with the outlet pipe 61 of L-shaped.
As shown in Figure 1, Figure 2 and shown in Fig. 5, in the lower space 82 of top bearing part 80, be inserted with the outer upper end being embedded with the anode 10 of annular element 13.Between the inner peripheral surface and the periphery of annular element 13 of lower space 82, there are two and there is corrosion proof O type ring R1.Thus, can prevent electroplate liquid from sewing from the lower space 82 of top bearing part 80 with anode 10 junction.
As shown in Figure 6, the outer shape of bottom bearing part 90 is rectangular shape, and has to the upper space 91 of vertical upper opening and the lower end continuous print lower space 92 with this upper space 91.The horizontal cross sectional geometry of the upper space 91 of bottom bearing part 90 and the respective inner peripheral surface of lower space 92 is formed concentric circles.The outer bottom being embedded with the anode 10 of annular element 13 is inserted with in upper space 91.Between the inner peripheral surface and the periphery of annular element 13 of upper space 91, there are two and there is corrosion proof O type ring R2.Thus, can prevent electroplate liquid from sewing from the upper space 91 of bottom bearing part 90 with the junction of anode 10.
As shown in Figure 1, Figure 2 and shown in Fig. 6, the lower space 92 of bottom bearing part 90 has and extends in the horizontal direction continuously and the influx 93 of the electroplate liquid of the lateral opening of lower portion bearing part 90.The influx 93 of electroplate liquid is connected with inflow pipe 62.In addition, lower space 92 have extend to vertical below continuously and the lower surface opening of lower portion bearing part 90 inserted through mouth 94.Horizontal cross sectional geometry inserted through the lower space 92 of mouth 94, bottom bearing part 90 and the respective inner peripheral surface of upper space 91 is formed concentric circles.The support rod 15 of cylindrical shape with lifting mode freely inserted through in this inserted through in mouth 94.
Support rod 15 has the recess 16 of the opening upward in upper end.This recess 16 inserts for the bottom of the plated body 1 of cylindrical shape.In addition, the bottom of support rod 15 and the piston rod of not shown cylinder link.Therefore, by driving this cylinder, thus support rod 15 can be made to be elevated on the central shaft of anode 10.Inserted through between the inner peripheral surface of mouth 94 and support rod 15, there are two and there is a corrosion proof O type ring R3 and dust seal S1.Thus, can prevent electroplate liquid from sewing from inserted through between mouth 94 and support rod 15, and prevent dust from entering from outside.
As shown in Fig. 1 and Fig. 8, in two through holes 84 run through towards the mode of upper space 81 with the two sides of the opposition side from top bearing part 80, be inserted with the second power supply part 30 separately point-blank.These second power supply parts 30 are configured point-blank as previously described, and top is opposite in upper space 81 on the lower compared with base component 85.In addition, as shown in Figure 7, each the second power supply part 30 rear end compared with the side of top bearing part 80 in the outer part place link with the piston rod 111 of cylinder 110 via holding parts 130.Each cylinder 110 is fixed on the fixation wall 103 that erects from the both ends of the first fixing part 100.Therefore, by driving cylinder 110, thus each second power supply part 30 is free to advance or retreat towards the center of upper space 81.That is, each second power supply part 30 is towards being configured in the plated body 1 of center of upper space 81 and free to advance or retreat between progressive position and going-back position.Each second power supply part 30 contacts at the periphery of its top ends of forward position with the plated body 1 of cylindrical shape, and is separated at the periphery of its top ends of going-back position place from plated body 1.In addition, on the holding parts 130 that the rearward end of the second power supply part 30 is held, an end of the power supply board made of copper 71 bending to roughly U-shaped is linked with.The other end of each power supply board 71 is linked by web 72 made of copper.Each power supply board 71 can be out of shape to follow the mode of the advance and retreat of each second power supply part 30.In addition, each power supply board 71 is connected with power supply 75.
Each second power supply part 30 is using the cylindrical shape axially as advance and retreat direction.In addition, as shown in Figure 8, between the periphery and the inner peripheral surface of each through hole 84 of each second power supply part 30, there are two and there is corrosion proof O type ring R4.Thus, can not from the condition sewed between each second power supply part 30 and the upper space 81 of top bearing part 80 at electroplate liquid, each second power supply part 30 can be retreated smoothly.
In addition, as shown in Figure 7 to 9, each second power supply part 30 is when carrying out top view from top, top is formed center V shape otch rearward compared with both sides.As shown in Figure 9, these second power supply parts 30 are configured by the central module made of copper 31 as cylindrical shape and the coating parts 32 to the titanium that the surrounding of central module 31 is coated to.The diameter of central module 31 be the external diameter of coating parts 32 90% ~ 50% between.Owing to being full of electroplate liquid in upper space 81 on the lower compared with base component 85, therefore, the position that electroplate liquid in the second power supply part 30 soaks is coated to by the coating parts 32 of titanium.This improves the solidity to corrosion of this second power supply part 30 for electroplate liquid.Therefore, it is possible to reduce the replacement frequency of this second power supply part 30.In addition, because this second power supply part 30 possesses the higher central module made of copper 31 of conductivity compared with titanium, therefore compared with the power supply part only formed by titanium, can heat dissipation capacity during power supply be suppressed, thus the temperature that can reduce electroplate liquid rises.
Therefore, the second power supply part 30 of embodiment and the high speed electrodeposition device that possesses this second power supply part 30 can implement plating for a long time well.
This second power supply part 30 is manufactured in next illustrated mode.First, as shown in Figure 9, coating parts 32 form the insertion space of cylindrical shape can inserted for central module 31, and side face forms ridge within it.With identical diameter of screw, central module 31 is processed into outside screw.And, central module 31 is screwed in the insertion space of coating parts 32, and by carrying out soldering at the insert port place of coating parts 32 thus manufacturing the second power supply part 30.The rearward end of the central module 31 of the second power supply part 30 is exposed from coating parts 32.The central module 31 that this exposes is utilized from the conducting parts of power supply 75 energising as via holding parts 130.
As shown in Fig. 2, Fig. 5 and Figure 10, holding device 40 has base component 85, and the bottom of described base component 85 is inserted in the upper space 81 of top bearing part 80 from top.The outer shape of the bottom of base component 85 is cylindrical shape, and the outer shape on top is rectangular shape.The outer shape of top bearing part 80 is also rectangular shape, and top bearing part 80 and base component 85, when carrying out top view from top, become parallel mode be grouped together to form each four limit outer peripheral.Between the upper surface of top bearing part 80 and the surface expanded from the upper end of the bottom of base component 85 in horizontal direction, exist and there is corrosion proof O type ring R5.Thus, can prevent electroplate liquid from sewing between top bearing part 80 and base component 85.
Base component 85 has incorporating section 86, and described incorporating section 86 is to vertical upper opening and have the connected entrance 87 of the opening downwards at lower central place.The horizontal cross sectional geometry of the inner peripheral surface of incorporating section 86 and connected entrance 87 is formed concentric circles.Connected entrance 87 is formed, less and bigger with the plated body 1 phase diameter group of cylindrical shape with the inner peripheral surface phase diameter group of incorporating section 86, thus can make plated body 1 inserted through.
Incorporating section 86 is received a pair holding member 41.Holding chamber 45 is formed by the incorporating section 86 of base component 85 and the sealing cover 88 closed by the upper opening of base component 85.The upper surface part 88A that sealing cover 88 has disc-shape and the 88B portion, side extended downwards from the edge of upper surface part 88A.Upper surface part 88A runs through and is provided with inlet mouth 89.Inlet mouth 89 is connected with an end of vent-pipe 52.The other end of vent-pipe 52 is connected to compressor 51.So, pressurizing device 50 has compressor 51 and vent-pipe 52.Sealing cover 88 can move to the position closed by the upper opening of base component 85 by not shown running gear, and becomes the state be pressed in this position downwards.Between the upper surface of base component 85 and the lower surface of the side surface part of sealing cover 88, there is an O type ring R6.Thus, can prevent air from spilling between base component 85 and sealing cover 88.
Each holding member 41 has maintaining part main body 42 and abutting part 43.Each maintaining part main body 42 is semi-cylindrical form, and is formed to be the recess 44A of semi-cylindrical form along the concavity in the axle portion of planar portions.This recess 44A is formed to be larger than the external diameter of the plated body 1 of cylindrical shape.Each maintaining part main body 42 is configured in the mode that planar portions 44B is opposed.
As shown in Figure 10, abutting part 43 is formed by being rectangle the sponge plate 46 of shape when carrying out top view from top.This sponge plate 46 is for having chemical-resistant elastomerics.At the central part place of the long leg of sponge plate 46, the recessed notch being cut into semi-circular shape is abutting part 43.Abutting part 43 is less than the external diameter of the plated body 1 of cylindrical shape mode with diameter is formed, and abuts with the periphery of plated body 1.That is, abutting part 43 is formed by carrying out recessed mode of cutting with less similar shape compared with the side view of abutted plated body 1 to sponge plate 46.Therefore, abutting part 43 seamlessly can abut with the periphery of plated body 1.
As shown in Figure 5, in each maintaining part main body 42, on opposed face and in the height direction away from two positions, be formed with groove portion 47A, 47B of extending in horizontal direction of clamping sponge plate 46.In the groove portion 47A of upside, insert two pieces of thinner sponge plates 46 overlappingly and it is clamped, in the groove portion 47B of downside, inserting one piece of thicker sponge plate 46 also it is clamped.
As shown in Figure 10, in base component 85, two sides orthogonal with the side of the top bearing part 80 inserting the second power supply part 30 are provided with cylinder 120.Base component 85 have to be through to from these two sides in incorporating section 86 and for each cylinder 120 piston rod 121 inserted through inserted through hole 85A.Between this inner peripheral surface inserted through hole 85A and periphery of piston rod 121, there is an O type ring R7.Thus, can prevent air from spilling from inserted through between hole and piston rod.
The top ends of the piston rod 121 of each cylinder 120 links with maintaining part main body 42 in the holding chamber 45 of base component 85.Each holding member 41 is free to advance or retreat between going-back position and progressive position, shown going-back position is, the planar portions 44B of maintaining part main body 42 and the end face of sponge plate 46 separated from one another, and the position that a part for the side of the arc-shaped of maintaining part main body 42 abuts with the inner peripheral surface of base component 85, described progressive position is, the opposed end face of sponge plate 46 contacts with each other, and the abutting part 43 of sponge plate 46 is seamlessly connected to the position clamped same periphery and to this plated body 1 from the both sides of plated body 1.
As shown in Figure 5, between the lower surface of maintaining part main body 42 and the bottom surface of the incorporating section 86 of base component 85, exist and there is corrosion proof O type ring R8.Thus, can prevent electroplate liquid from sewing between maintaining part main body 42 and base component 85.
As shown in Figures 1 and 2, circulation device 60 has circulation passage 63 and is arranged on the electroplate liquid management groove 64 and pump 65 of midway of this circulation passage 63, and described circulation passage 63 has: the outlet pipe 61 of the L-shaped be connected with the spout 83 of the electroplate liquid of the lateral opening at top bearing part 80 and the inflow pipe 62 be connected with the influx 93 of the electroplate liquid of the lateral opening at bottom bearing part 90.When driving pump 65, circulation device 60 can make the electroplate liquid in electroplate liquid management groove 64 carry at the influx 93 of the electroplate liquid of lower portion bearing part 90, be back to through the spout 83 of bottom bearing part 90, anode 10, top bearing part 80, electroplate liquid successively afterwards in the circulation passage 63 of electroplate liquid management groove 64 touring.
As shown in Figure 1, supply unit 70 is connected with power supply 75 as follows, that is, via the first power supply part 20, anode 10 applies positive voltage, and applies negative voltage via the second power supply part 30 to plated body 1.
Hereinafter, the electroplating work procedure of the high speed electrodeposition device with such structure is described.
First, as shown in FIG. 11 and 12, high speed electrodeposition device under the state that each second power supply part 30 and each holding member 41 are positioned at going-back position place and support rod 15 has risen, to upper end the decline of plated body 1 that held by chuck 5 await orders.Afterwards, plated body 1 is declined from the upper opening of base component 85, and as shown in figure 13, the bottom of plated body 1 is inserted in the recess 16 of the upper end of support rod 15 opening upward.
In addition, by making the chuck 5 to the upper end of plated body 1 holds decline, thus the piston rod of the not shown cylinder linked with the bottom of support rod 15 can decline, and then plated body 1 drops to electroplating site.That is, plated body 1 is configured to, between plated body and anode 10, forms the state in the space of flow of the electrolyte of powering.
In this condition, the piston rod 111 of the cylinder 110 linked with the rear end of the second power supply part 30 via holding parts 130 advances.That is, the second power supply part 30 moves to advanced position towards plated body 1, and as shown in Figure 14 and Figure 15, the top ends of the second power supply part 30 contacts with the periphery on the top of plated body 1 and keeps plated body 1.At this time point, each holding member 41 is still in going-back position.And chuck 5 is decontroled the upper end of plated body 1 and is risen.
Next, the piston rod 121 of the cylinder 120 linked with the maintaining part main body 42 of each holding member 41 advances.That is, as shown in FIG. 16 and 17, the abutting part 43 that each maintaining part main body 42 moves to sponge plate 46 is seamlessly connected to the progressive position clamped same periphery and to this plated body 1 from the both sides of plated body 1.In addition, other part of each sponge plate 46 also becomes following state, that is, opposed end face abuts and the state that contacts with each other of the opposed planar portions of maintaining part main body 42 from one another seamlessly mutually.
Next, as shown in Figure 1, Figure 2 and shown in Figure 18, sealing cover 88 becomes the position of the upper opening being moved to blocking base component 85 by running gear and the state be pressed in this position downwards.And, compressor 51 is driven, thus sends into air to the inlet mouth 89 of sealing cover 88 and pressurize in holding chamber 45.Now, in mode described later, electroplate liquid is circulated, and in the above mode of interior pressure pressure in holding chamber 45 being maintained the region (this region is equivalent to liquid bath) that electroplate liquid flows between plated body 1 and anode 10, compressor 51 is driven and air is sent in holding chamber 45.
In this condition, plated body 1 is configured on the axle of anode 10.That is, the inner peripheral surface of anode 10 is equally spaced separated with the periphery of plated body 1, and electroplate liquid flows in this space.
Next, the pump 65 of circulation device 60 is driven, thus makes the electroplate liquid in electroplate liquid management groove 64 carry at the influx 93 of the electroplate liquid of lower portion bearing part 90, be back to through the spout 83 of bottom bearing part 90, anode 10, top bearing part 80, electroplate liquid successively afterwards in the circulation passage 63 of electroplate liquid management groove 64 touring.Now, flow in anode 10 and between plated body 1 and have electroplate liquid.
And, by supply unit 70, first power supply part 20 and the second power supply part 30 are energized, and anode 10 applies positive voltage, applies negative voltage to plated body 1, thus perform high speed electrodeposition.
So, this high speed electrodeposition device, when performing high speed electrodeposition, the abutting part 43 of holding device 40 is seamlessly connected on the same periphery of the plated body 1 of cylindrical shape, and this abutting part 43 is formed by as having the elastomeric sponge plate 46 of chemical-resistant.In addition, compressor 51 is sent into air and pressurizes in holding chamber 45.Therefore, the abutting part 43 be made up of sponge plate 46 is pressed by air pressure, thus can be close-coupled on the periphery of plated body 1.In addition, by pressurizeing in holding chamber 45, thus for utilizing air pressure to the electroplate liquid that holding chamber 45 side leakage is let out from the boundary portion of abutting part 43 and plated body 1 or abutting part 43 boundary portion each other and be pushed back.Therefore, this holding device 40 can reliably prevent electroplate liquid from sewing in the incorporating section 86 of the lower direction base component 85 of base component 85.In addition, because this holding device 40 is by forming abutting part 43 as elastomeric sponge plate 46, even if therefore the periphery shape of plated body 1 changes abutting part 43 also can be made to be close-coupled on the periphery of plated body 1.Therefore, this holding device 40 can tackle multiple plated body 1.In addition, because the sponge plate 46 of the formation abutting part 43 of this holding device 40 has chemical resistant properties, therefore, it is possible to prevent the deterioration of the abutting part 43 caused due to electroplate liquid, thus sewing of electroplate liquid can be prevented for a long time.
Therefore, the holding device 40 of embodiment and the high speed electrodeposition device possessing this holding device 40 can keep multiple plated body 1, and can reliably prevent sewing of electroplate liquid.
When terminating high speed electrodeposition, this high speed electrodeposition device stops the energising from supply unit 70 to the first power supply part 20 and the second power supply part 30.In addition, the pump 65 of circulation device 60 also stops, and electroplate liquid is discharged in anode 10 and stores in electroplate liquid management groove 64.And sealing cover 88 is moved to retreating position from the position of the upper opening of blocking base component 85 by running gear.So each holding member 41 position of drawing back is moved, and the upper end of chuck 5 pairs of plated bodies 1 holds, and the second power supply part 30 is drawn back, position is moved.And chuck 5 is carried on plated body 1, and support rod 15 pushes away on plated body 1, thus makes plated body 1 extract out from the upper opening of base component 85 and terminate electroplating work procedure.
The present invention is not limited to by the embodiment illustrated by above-mentioned record and accompanying drawing, and such as ensuing embodiment is also comprised in technical scope of the present invention.
(1) although in an embodiment, anodic formation is made to be drum, as long as be formed as the shape conformed to its shape when electroplating the plated body of other shapes.
(2) although in an embodiment, the central module of the second power supply part and coating parts are screwed, but also can be in the following way, namely, the inner peripheral surface in insertion space of coating parts and the periphery of central module are set to cone shape, and by the insertion space of coating for central module press-in parts.
(3) although in an embodiment, the coating parts of the second power supply part are coated to central module, as long as the position that coating parts at least soak electroplate liquid is carried out coating with wide scope compared with the position of soaking with electroplate liquid.
(4) although in an embodiment, the central part otch of the long leg of sponge plate is formed as semi-circular shape and forms abutting part, as long as notch geometry meets the shape of plated body.In addition, also can be set to and there is no otch.
(5) although in an embodiment, from both direction, plated body is clamped by two holding members, also abutting part seamlessly can be connected on the same periphery of plated body by the holding member of more than three.
(6) although in an embodiment, maintaining part main body is provided with two places to sponge plate clamp in the height direction away from groove portion, also can a place be only set, also more than three places can be set.
(7) although in an embodiment, one piece or two pieces of sponge plates to be inserted into overlappingly in the groove portion of maintaining part main body and it is clamped, also more than three pieces can be inserted into overlappingly in the groove portion of maintaining part main body and it is clamped.
Nomenclature
1 ... plated body;
10 ... anode;
11 ... outer cylindrical portion;
11A ... the slab of titanium;
12 ... inner cylinder portion;
12A ... the plate of platinum;
30 ... second power supply part (power supply part);
60 ... circulation device;
70 ... supply unit.
Claims (3)
1. an anode, it is tubular, and forms the space of power supply flow of the electrolyte between this anode and the plated body being configured in its inside, and described anode is applied in positive voltage,
The feature of described anode is to possess: outer cylindrical portion, and it has electroconductibility; Inner cylinder portion, it is soldered and be made up of the plate of platinum in the mode connected with the internal surface of this outer cylindrical portion.
2. anode as claimed in claim 1, is characterized in that,
By making the slab of titanium, and the slab of platinum is overlapping and the structure of welding and being formed becomes inner side with the slab of described platinum mode bends to tubular, thus defines described outer cylindrical portion and described inner cylinder portion.
3. a high speed electrodeposition device, is characterized in that, possesses:
Anode described in claim 1 or 2;
Electric supply installation, it contacts with plated body and applies negative voltage to described plated body;
Circulation device, it makes electroplate liquid with at described anode and be configured in the mode flowed between the described plated body of the inside of this anode and circulate;
Supply unit, it is energized to described plated body via described anode and described power supply part.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013125552A JP6189655B2 (en) | 2013-06-14 | 2013-06-14 | Anode manufacturing method |
| JP2013-125552 | 2013-06-14 | ||
| PCT/JP2014/065049 WO2014199907A1 (en) | 2013-06-14 | 2014-06-06 | Anode and high-speed plating device provided with same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105324521A true CN105324521A (en) | 2016-02-10 |
Family
ID=52022203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480033953.6A Pending CN105324521A (en) | 2013-06-14 | 2014-06-06 | Anode and high-speed plating device provided with same |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20160108542A1 (en) |
| EP (1) | EP3009537A4 (en) |
| JP (1) | JP6189655B2 (en) |
| CN (1) | CN105324521A (en) |
| BR (1) | BR112015030429A2 (en) |
| MX (1) | MX2015016094A (en) |
| TW (1) | TWI646225B (en) |
| WO (1) | WO2014199907A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6193005B2 (en) | 2013-06-14 | 2017-09-06 | Ｋｙｂ株式会社 | Holding device and high-speed plating apparatus provided with the same |
| JP6189656B2 (en) | 2013-06-14 | 2017-08-30 | Ｋｙｂ株式会社 | Power supply member and high-speed plating apparatus including the same |
| US11542626B2 (en) | 2020-10-08 | 2023-01-03 | Honeywell International Inc. | Systems and methods for enclosed electroplating chambers |
| WO2023067864A1 (en) | 2021-10-19 | 2023-04-27 | 日立Astemo株式会社 | Rod production method and anode device |
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| JPS55138097A (en) * | 1979-04-13 | 1980-10-28 | Yamaha Motor Co Ltd | Plating device at high speed |
| EP0059481A1 (en) * | 1981-03-03 | 1982-09-08 | Yamaha Motor Co., Ltd. | High speed plating apparatus |
| CN1329969A (en) * | 2000-06-16 | 2002-01-09 | 德古萨加尔瓦诺技术股份公司 | Method for preparing one-sided platinum plated refractory metal plate and extended metal grid |
| JP2002256497A (en) * | 2001-03-05 | 2002-09-11 | Daiso Co Ltd | Insoluble anode |
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| CN101421441A (en) * | 2006-04-14 | 2009-04-29 | 大曹株式会社 | Hollow electrode with film for electrodeposition coating |
| JP2013060658A (en) * | 2011-08-25 | 2013-04-04 | Yuken Industry Co Ltd | Device for electroplating shaft, method for manufacturing shaft having plated film, and plating liquid for forming zinc-plated film on shaft |
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| DE3938160A1 (en) * | 1989-11-16 | 1991-05-23 | Peroxid Chemie Gmbh | ELECTROLYSIS CELL FOR PRODUCING PEROXO AND PERHALOGENATE COMPOUNDS |
| DE10102145B4 (en) * | 2000-01-19 | 2008-04-03 | Suzuki Motor Corp., Hamamatsu | Electroplating pretreatment device and plating treatment device |
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2013
- 2013-06-14 JP JP2013125552A patent/JP6189655B2/en active Active
-
2014
- 2014-06-06 WO PCT/JP2014/065049 patent/WO2014199907A1/en active Application Filing
- 2014-06-06 MX MX2015016094A patent/MX2015016094A/en unknown
- 2014-06-06 EP EP14810217.1A patent/EP3009537A4/en not_active Withdrawn
- 2014-06-06 BR BR112015030429A patent/BR112015030429A2/en not_active Application Discontinuation
- 2014-06-06 CN CN201480033953.6A patent/CN105324521A/en active Pending
- 2014-06-06 US US14/897,130 patent/US20160108542A1/en not_active Abandoned
- 2014-06-13 TW TW103120484A patent/TWI646225B/en active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55138097A (en) * | 1979-04-13 | 1980-10-28 | Yamaha Motor Co Ltd | Plating device at high speed |
| EP0059481A1 (en) * | 1981-03-03 | 1982-09-08 | Yamaha Motor Co., Ltd. | High speed plating apparatus |
| CN1329969A (en) * | 2000-06-16 | 2002-01-09 | 德古萨加尔瓦诺技术股份公司 | Method for preparing one-sided platinum plated refractory metal plate and extended metal grid |
| JP2002256497A (en) * | 2001-03-05 | 2002-09-11 | Daiso Co Ltd | Insoluble anode |
| CN101137772A (en) * | 2005-03-09 | 2008-03-05 | 德诺拉工业有限公司 | Cylindrical electrode |
| CN101421441A (en) * | 2006-04-14 | 2009-04-29 | 大曹株式会社 | Hollow electrode with film for electrodeposition coating |
| JP2013060658A (en) * | 2011-08-25 | 2013-04-04 | Yuken Industry Co Ltd | Device for electroplating shaft, method for manufacturing shaft having plated film, and plating liquid for forming zinc-plated film on shaft |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3009537A4 (en) | 2017-03-22 |
| JP2015001005A (en) | 2015-01-05 |
| TW201510292A (en) | 2015-03-16 |
| MX2015016094A (en) | 2016-05-31 |
| US20160108542A1 (en) | 2016-04-21 |
| TWI646225B (en) | 2019-01-01 |
| JP6189655B2 (en) | 2017-08-30 |
| WO2014199907A1 (en) | 2014-12-18 |
| EP3009537A1 (en) | 2016-04-20 |
| BR112015030429A2 (en) | 2017-08-29 |
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Application publication date: 20160210 |
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