CN105238527A - Emulsified oil and application thereof - Google Patents
Emulsified oil and application thereof Download PDFInfo
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- CN105238527A CN105238527A CN201510681159.9A CN201510681159A CN105238527A CN 105238527 A CN105238527 A CN 105238527A CN 201510681159 A CN201510681159 A CN 201510681159A CN 105238527 A CN105238527 A CN 105238527A
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Abstract
The invention relates to emulsified oil and application thereof. The problems that in the prior art, solid wire drawing powder can produce dust floating in air in the use process and bad affects are caused to human respiratory systems are mainly solved. The emulsified oil is prepared from, by weight, 1-5 parts of anti-wear reagents at extreme pressure, 5-15 parts of surface active agent, 5-15 parts of antirust agent, 5-15 parts of oiliness agent, 0.01-0.1 part of antifoaming agent, 0.1-1.0 part of bactericide, 5-10 parts of water and 60-80 parts of refined mineral oil. By means of the technical scheme, the problems are well solved, and the emulsified oil can be used for industrial production of ordinary low-carbon steel wire drawing emulsified oil.
Description
Technical field
The present invention relates to a kind of oil in water emulsion and uses thereof.
Background technology
Ordinary low-carbon steel wire drawing oil in water emulsion is mainly used in the lubrication in the production of common low carbon steel wire between blank and mould.Because metal wire material is when drawing, the metal in distorted area is in radial and circumference and is stress, is longitudinally the stressed condition of tensile stress, and when the tensile stress numerical value of goods on orifice exit section is greater than the breakdown point of material, material will be pulled off.Therefore, in silk material drawing production process, adopt effective technology lubricant for strengthening drawing production process, improve production efficiency and product quality has great importance.
According to ordinary low-carbon steel drawing process situation, wire drawing oil in water emulsion needs some property following: good extreme boundary lubrication performance, can reduce the frictional force between blank and mould; Good cooling performance, can take away working face heat rapidly, prevent metal superheat from sticking together; Good rustless property, can prevent goods corrosion, is convenient to the keeping in producing and turnover.
Domestic market uses mostly the solid wire drawing powder product of relative low price, such as lime, molybdenumdisulphide etc.Because this series products in use can produce the dust granules floated in air, there is detrimentally affect to human respiratory.
Summary of the invention
One of technical problem to be solved by this invention is that prior art exists solid wire drawing powder product and in use can produce the dust floated in air, has dysgenic problem, provide a kind of new oil in water emulsion to human respiratory.This oil in water emulsion can meet ordinary low-carbon steel wire drawing manufacturing technique requirent, ensures engineering safety, improves the quality of common low carbon steel wire, harmless again, uses efficiently simple and direct.Two of technical problem to be solved by this invention is to provide a kind of purposes of the oil in water emulsion corresponding with one of technical solution problem.
For one of solving the problems of the technologies described above, the technical scheme that the present invention takes is as follows: a kind of oil in water emulsion, with weight parts, is made up of following component:
A) 1 ~ 5 part of extreme pressure anti-wear additives;
B) 5 ~ 15 parts of tensio-active agents;
C) 5 ~ 15 parts of rust-preventive agent;
D) 5 ~ 15 parts of oiliness improvers;
E) 0.01 ~ 0.1 part of defoamer;
F) 0.1 ~ 1.0 part of sterilant;
G) 5 ~ 10 parts of water;
H) 60 ~ 80 parts of refined mineral oils;
Described extreme pressure anti-wear additives is selected from least one in phosphoric acid ester, sulfuration vegetable and animals oils or clorafin;
Described tensio-active agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene or sorbitan fatty acid ester;
Described rust-preventive agent is selected from least one in mineral alkali, hydramine, carboxylate salt or sulfonate;
Described oiliness improver is selected from vegetable oil acid;
Described defoamer is selected from silicone based defoaming agents;
Described sterilant is selected from least one in triazines or morpholine bactericide;
Described refined mineral oil is selected from least one in I class low viscosity base oil, machinery oil or industrial white oil.
In technique scheme, preferably, described extreme pressure anti-wear additives is selected from least two kinds in phosphoric acid ester, sulfuration vegetable and animals oils or clorafin.
In technique scheme, preferably, described extreme pressure anti-wear additives is selected from the mixture of phosphoric acid ester and sulfuration vegetable and animals oils; In mixture, the weight ratio of phosphoric acid ester and sulfuration vegetable and animals oils is 0.2 ~ 0.9.
In technique scheme, preferably, described tensio-active agent is selected from the mixture of fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester; In mixture, the weight ratio of fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester is 0.1 ~ 0.6.
In technique scheme, preferably, the mixture being selected from mineral alkali or hydramine and sulfonate of described rust-preventive agent; In mixture, the weight ratio of mineral alkali or hydramine and sulfonate is 0.1 ~ 1.0.
For solve the problems of the technologies described above two, the technical scheme that the present invention takes is as follows: described oil in water emulsion be used for common low carbon steel wire produce in lubrication between blank and mould.
The preparation method of the present composition comprises the following steps:
A) water and mineral alkali or alcamines rust-preventive agent are dropped into be in harmonious proportion still, stir, be warming up to 40 DEG C and maintain;
B) add oiliness improver and refined mineral oil, stir;
C) add Sulfonates rust-preventive agent and tensio-active agent again, stir;
D) finally add extreme pressure anti-wear additives, sterilant and defoamer successively, stir and stop heating, being progressively cooled to room temperature, stop stirring, obtain described oil in water emulsion.
In the present composition, extreme pressure anti-wear additives is selected from least one in phosphoric acid ester, sulfuration vegetable and animals oils or clorafin, and preferably use the mixture of phosphoric acid ester and sulfuration vegetable and animals oils, wire drawing oil will have better extreme pressure and antiwear behavior; In mixture, the weight ratio of phosphoric acid ester and sulfuration vegetable and animals oils is 0.2 ~ 0.9.
In the present composition, tensio-active agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene or sorbitan fatty acid ester, the mixture of preferred use fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester, wire drawing oil will have better emulsifying property and stable emulsifying performance; In mixture, the weight ratio of fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester is 0.1 ~ 0.6.
In the present composition, rust-preventive agent is selected from least one in mineral alkali, hydramine, carboxylate salt or sulfonate.The mixture of preferred use mineral alkali or hydramine and sulfonate, wire drawing oil will have better rustless property and anti-corrupt performance; In mixture, the weight ratio of mineral alkali or hydramine and sulfonate is 0.1 ~ 1.0.
In the present composition, sterilant is selected from least one in triazines, morpholine bactericide.The use properties that sterilant can prevent wire drawing oil emulsion from use causing because of the microorganism such as breed bacteria, fungi declines.
In the present composition, defoamer is selected from silicone based defoaming agents.If emulsion in use produces foam, oil film strength and stability will be destroyed, affect lubricant effect, cause friction pair to wear and tear, therefore the emulsion for preventing ordinary low-carbon steel wire drawing oil in water emulsion from configuring in use produces foam, needs to add defoamer.
In the present composition, refined mineral oil is selected from least one in I class low viscosity base oil, machinery oil, industrial white oil.
Ordinary low-carbon steel wire drawing oil in water emulsion of the present invention is diluted with water to the emulsion that massfraction is 5 ~ 15% when using, and can either meet the requirement of common low carbon steel wire drawing process, ensures engineering safety, improves the quality of common low carbon steel wire; There is high extreme boundary lubrication performance, good stable emulsifying performance; There is good rustless property, there is safe use-pattern, both ensured normally carrying out of Wire Drawing, reduce energy consumption, improve the surface quality of goods, can not in use produce the dust floated in air again, on human respiratory without impact, achieve good technique effect.
Below in conjunction with embodiment, the invention will be further elaborated.
Embodiment
[embodiment 1 ~ 5]
Deionized water and mineral alkali or alcamines rust-preventive agent are dropped into and is in harmonious proportion still, stir, be warming up to 40 DEG C and maintain this temperature; Add oiliness improver and refined mineral oil, stir; Add Sulfonates rust-preventive agent and tensio-active agent again, stir; Finally add extreme pressure anti-wear additives, sterilant and defoamer successively, stir and stop heating, being progressively cooled to room temperature, stop stirring, obtain described oil in water emulsion.The kind of each component and consumption in oil in water emulsion, specifically in table 1.
In table 1, AEO is fatty alcohol-polyoxyethylene ether; SP is sorbitan fatty acid ester; OP is alkylphenol polyoxyethylene; BK is triazines sterilant; MBM is morpholine bactericide.
[comparative example 1 ~ 7]
[comparative example 1] is company of Korea S product wire drawing oil Drawingoil6268K (trade(brand)name).
[comparative example 2] for extreme pressure anti-wear additives list in embodiment 1 be the comparative example of phosphoric acid ester.
[comparative example 3] for tensio-active agent list in embodiment 3 be the comparative example of fatty alcohol-polyoxyethylene ether.
[comparative example 4] for rust-preventive agent list in embodiment 5 be the comparative example of carboxylate salt.
[comparative example 5] for extreme pressure anti-wear additives list in comparative example 2 be the comparative example of olefine sulfide.
[comparative example 6] is the comparative example of tensio-active agent Dan Weiju resinous acid monoethylene glycol ester in comparative example 3.
[comparative example 7] for rust-preventive agent list in comparative example 4 be the comparative example of dodecenylsuccinic acid.
Carry out performance test to ordinary low-carbon steel wire drawing oil prepared by each embodiment and comparative example respectively, testing method is known by the engineering technical personnel of this area.Test-results is in table 2.
As can be seen from Table 2, ordinary low-carbon steel wire drawing oil of the present invention has excellent lubricity and stable emulsifying performance, has good rustless property, prevents goods corrosion, is convenient to the keeping in producing and turnover.In addition, ordinary low-carbon steel wire drawing oil of the present invention has safe use-pattern, has both ensured normally carrying out of Wire Drawing, has reduced energy consumption, improved the surface quality of goods, can not in use produce the dust floated in air, on human respiratory without impact again.
Claims (6)
1. an oil in water emulsion, with weight parts, is made up of following component:
A) 1 ~ 5 part of extreme pressure anti-wear additives;
B) 5 ~ 15 parts of tensio-active agents;
C) 5 ~ 15 parts of rust-preventive agent;
D) 5 ~ 15 parts of oiliness improvers;
E) 0.01 ~ 0.1 part of defoamer;
F) 0.1 ~ 1.0 part of sterilant;
G) 5 ~ 10 parts of water;
H) 60 ~ 80 parts of refined mineral oils;
Described extreme pressure anti-wear additives is selected from least one in phosphoric acid ester, sulfuration vegetable and animals oils or clorafin;
Described tensio-active agent is selected from least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene or sorbitan fatty acid ester;
Described rust-preventive agent is selected from least one in mineral alkali, hydramine, carboxylate salt or sulfonate;
Described oiliness improver is selected from vegetable oil acid;
Described defoamer is selected from silicone based defoaming agents;
Described sterilant is selected from least one in triazines or morpholine bactericide;
Described refined mineral oil is selected from least one in I class low viscosity base oil, machinery oil or industrial white oil.
2. oil in water emulsion according to claim 1, is characterized in that described extreme pressure anti-wear additives is selected from least two kinds in phosphoric acid ester, sulfuration vegetable and animals oils or clorafin.
3. oil in water emulsion according to claim 2, is characterized in that described extreme pressure anti-wear additives is selected from the mixture of phosphoric acid ester and sulfuration vegetable and animals oils; In mixture, the weight ratio of phosphoric acid ester and sulfuration vegetable and animals oils is 0.2 ~ 0.9.
4. oil in water emulsion according to claim 1, is characterized in that described tensio-active agent is selected from the mixture of fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester; In mixture, the weight ratio of fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester is 0.1 ~ 0.6.
5. oil in water emulsion according to claim 1, is characterized in that the mixture being selected from mineral alkali or hydramine and sulfonate of described rust-preventive agent; In mixture, the weight ratio of mineral alkali or hydramine and sulfonate is 0.1 ~ 1.0.
6. the arbitrary described oil in water emulsion of claim 1 ~ 6 is used for the lubrication in the production of common low carbon steel wire between blank and mould.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510681159.9A CN105238527B (en) | 2015-10-19 | 2015-10-19 | Oil emulsion and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510681159.9A CN105238527B (en) | 2015-10-19 | 2015-10-19 | Oil emulsion and application thereof |
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| CN105238527A true CN105238527A (en) | 2016-01-13 |
| CN105238527B CN105238527B (en) | 2018-11-20 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108410557A (en) * | 2018-03-30 | 2018-08-17 | 南京工程学院 | A kind of steel pipe drawing oil emulsion and preparation method thereof with superelevation greasy property |
| CN109518192A (en) * | 2018-12-29 | 2019-03-26 | 南京派诺金属表面处理技术有限公司 | Emulsion-type antirust agent and preparation method thereof |
Citations (5)
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| RU2151171C1 (en) * | 1999-02-04 | 2000-06-20 | Открытое акционерное общество "Чебоксарский завод кабельных изделий "Чувашкабель" | Lubricant for cold drawing of aluminium wire |
| CN101747988A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Copper and aluminum wire drawing oil and preparation method and use method thereof |
| CN101812361A (en) * | 2009-12-18 | 2010-08-25 | 益田润石（北京）化工有限公司 | Stainless steel wire drawing liquid composition |
| CN102010779A (en) * | 2010-12-20 | 2011-04-13 | 南京工程学院 | Steel cord drawing lubricant and preparation method thereof |
| CN102839038A (en) * | 2012-09-13 | 2012-12-26 | 济南库伦特科技有限公司 | Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition |
-
2015
- 2015-10-19 CN CN201510681159.9A patent/CN105238527B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2151171C1 (en) * | 1999-02-04 | 2000-06-20 | Открытое акционерное общество "Чебоксарский завод кабельных изделий "Чувашкабель" | Lubricant for cold drawing of aluminium wire |
| CN101812361A (en) * | 2009-12-18 | 2010-08-25 | 益田润石（北京）化工有限公司 | Stainless steel wire drawing liquid composition |
| CN101747988A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Copper and aluminum wire drawing oil and preparation method and use method thereof |
| CN102010779A (en) * | 2010-12-20 | 2011-04-13 | 南京工程学院 | Steel cord drawing lubricant and preparation method thereof |
| CN102839038A (en) * | 2012-09-13 | 2012-12-26 | 济南库伦特科技有限公司 | Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108410557A (en) * | 2018-03-30 | 2018-08-17 | 南京工程学院 | A kind of steel pipe drawing oil emulsion and preparation method thereof with superelevation greasy property |
| CN108410557B (en) * | 2018-03-30 | 2021-01-22 | 南京工程学院 | Steel pipe drawing emulsified oil with ultrahigh lubricating property and preparation method thereof |
| CN109518192A (en) * | 2018-12-29 | 2019-03-26 | 南京派诺金属表面处理技术有限公司 | Emulsion-type antirust agent and preparation method thereof |
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| CN105238527B (en) | 2018-11-20 |
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