CN105238527B - Oil emulsion and application thereof - Google Patents
Oil emulsion and application thereof Download PDFInfo
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- CN105238527B CN105238527B CN201510681159.9A CN201510681159A CN105238527B CN 105238527 B CN105238527 B CN 105238527B CN 201510681159 A CN201510681159 A CN 201510681159A CN 105238527 B CN105238527 B CN 105238527B
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Abstract
The present invention relates to a kind of oil emulsions and application thereof, mainly solve the problem of that the prior art can generate the dust floated in air there are solid wire drawing powder product in use and have adverse effect to human respiratory.The present invention is made of the following components by using based on parts by weight：A) 1~5 part of extreme pressure anti-wear additives；B) 5~15 parts of surfactants；C) 5~15 parts of antirust agent；D) 5~15 parts of oiliness improvers；E) 0.01~0.1 part of defoaming agent；F) 0.1~1.0 part of fungicide；G) 5~10 parts of water；H) technical solution of 60~80 parts of refined mineral oils preferably solves the problems, such as this, can be used in the industrial production of ordinary low-carbon steel wire drawing oil emulsion.
Description
Technical field
The present invention relates to a kind of oil emulsions and application thereof.
Background technique
Ordinary low-carbon steel wire drawing oil emulsion is mainly used for the lubrication in the production of common low carbon steel wire between blank and mold.By
In metal wire material in drawing, it is radially and circumferentially compression, the stress shape that longitudinal direction is tensile stress that the metal in deformed area, which is in,
State, when tensile stress numerical value of the product on orifice exit section is greater than the strength degree of material, material will be pulled off.Cause
This, using effective technology lubricant for strengthening drawing production process, improves production efficiency in silk material drawing production process
Have great importance with product quality.
According to ordinary low-carbon steel drawing process situation, wire drawing oil emulsion needs following property：Good pole
Pressure lubricating performance can reduce the frictional force between blank and mold；Good cooling performance can rapidly take away working face heat,
Prevent metal superheat from sticking together；Good rustless property can prevent product from corroding, it is easy to produce in keeping and turnover.
The solid wire drawing powder product of relative low price, such as lime, molybdenum disulfide are used on domestic market mostly
Deng.Since such product can generate the dust particles floated in air in use, there is adverse effect to human respiratory.
Summary of the invention
The first technical problem to be solved by the present invention is that there are solid wire drawing powder products can produce in use for the prior art
The raw dust floated in air, has the problem of adverse effect to human respiratory, provides a kind of new oil emulsion.The emulsification
Oil had both been able to satisfy ordinary low-carbon steel wire drawing manufacturing technique requirent, guaranteed engineering safety, improved the quality of common low carbon steel wire, and right
Human body is harmless, using simple and direct efficient.The second technical problem to be solved by the present invention be to provide it is a kind of with solve technical problem it
The purposes of oil emulsion corresponding to one.
One of to solve above-mentioned technical problem, the technical solution adopted by the present invention is as follows：A kind of oil emulsion, with parts by weight
Meter, is made of the following components：
A) 1~5 part of extreme pressure anti-wear additives；
B) 5~15 parts of surfactants；
C) 5~15 parts of antirust agent；
D) 5~15 parts of oiliness improvers；
E) 0.01~0.1 part of defoaming agent；
F) 0.1~1.0 part of fungicide；
G) 5~10 parts of water；
H) 60~80 parts of refined mineral oils；
The extreme pressure anti-wear additives are selected from phosphate, vulcanization at least one of vegetable and animals oils or chlorinated paraffin；
The surfactant is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether or sorbitan fatty acid
At least one of ester；
The antirust agent is selected from least one of inorganic base, hydramine, carboxylate or sulfonate；
The oiliness improver is selected from vegetable oil acid；
The defoaming agent is selected from silicone based defoaming agents；
The fungicide is selected from least one of triazines or morpholine bactericide；
The refined mineral oil is selected from least one of I class low viscosity base oil, machinery oil or technical white oil.
In above-mentioned technical proposal, it is preferable that the extreme pressure anti-wear additives are selected from phosphate, vulcanization vegetable and animals oils or chlorinated paraffin
In at least two.
In above-mentioned technical proposal, it is preferable that the extreme pressure anti-wear additives are selected from phosphate and vulcanize the mixture of vegetable and animals oils；
In mixture, the weight ratio of phosphate and vulcanization vegetable and animals oils is 0.2~0.9.
In above-mentioned technical proposal, it is preferable that the surfactant is selected from fatty alcohol polyoxyethylene ether and anhydrous sorbitol
The mixture of aliphatic ester；In mixture, the weight ratio of fatty alcohol polyoxyethylene ether and sorbitan fatty acid ester is 0.1~
0.6。
In above-mentioned technical proposal, it is preferable that the mixture selected from inorganic base or hydramine and sulfonate of the antirust agent；It is mixed
It closes in object, the weight ratio of inorganic base or hydramine and sulfonate is 0.1~1.0.
To solve above-mentioned technical problem two, the technical solution adopted by the present invention is as follows：The oil emulsion is for common
Lubrication in mild steel wire production between blank and mold.
The preparation method of the present composition includes the following steps：
A) water and inorganic base or alcamines antirust agent investment reconciliation kettle, stirring are warming up to 40 DEG C and maintained；
B) oiliness improver and refined mineral oil is added, stirs evenly；
C) Sulfonates antirust agent and surfactant are added, is stirred evenly；
D) extreme pressure anti-wear additives, fungicide and defoaming agent are finally sequentially added, stir and stops heating, is gradually cooled to room
Temperature stops stirring to get the oil emulsion.
In the present composition, extreme pressure anti-wear additives selected from phosphate, vulcanization vegetable and animals oils or chlorinated paraffin at least one
Kind will be, it is preferable to use phosphate and the mixture for vulcanizing vegetable and animals oils, wire drawing oil will have better extreme pressure and antiwear behavior；Mixture
The weight ratio of middle phosphate and vulcanization vegetable and animals oils is 0.2~0.9.
In the present composition, surfactant is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether or dehydration
At least one of Span, it is preferable to use fatty alcohol polyoxyethylene ether and sorbitan fatty acid ester mixing
Object, wire drawing oil will have better emulsifiability and stable emulsifying performance；Fatty alcohol polyoxyethylene ether and dehydration in mixture
The weight ratio of Span is 0.1~0.6.
In the present composition, antirust agent is selected from least one of inorganic base, hydramine, carboxylate or sulfonate.It is preferred that
Using inorganic base or the mixture of hydramine and sulfonate, wire drawing oil will have better rustless property and anti-corrupt performance；Mixing
The weight ratio of inorganic base or hydramine and sulfonate is 0.1~1.0 in object.
In the present composition, fungicide is selected from least one of triazines, morpholine bactericide.Fungicide can be prevented
Only wire drawing oil emulsion is in use because of service performance decline caused by breeding the microorganisms such as bacterium, fungi.
In the present composition, defoaming agent is selected from silicone based defoaming agents.If emulsion generates bubble in use
Foam will destroy film strength and stability, influence lubricant effect, cause the secondary abrasion that rubs, therefore to prevent ordinary low-carbon steel
The emulsion of wire drawing oil emulsion configuration generates foam in use, needs that defoaming agent is added.
In the present composition, refined mineral oil in I class low viscosity base oil, machinery oil, technical white oil at least
It is a kind of.
Ordinary low-carbon steel wire drawing oil emulsion of the present invention using when be diluted with water to mass fraction be 5~15% emulsion,
Common low carbon steel wire drawing process requirement can either be met, guarantee engineering safety, improve the quality of common low carbon steel wire；With pole
High extreme boundary lubrication performance, preferable stable emulsifying performance；With good rustless property, there is the usage mode of safety, both
Guarantee being normally carried out for wire drawing, reduces energy consumption, improve the surface quality of product, and will not generate in use and float on sky
Dust in gas achieves preferable technical effect on human respiratory without influence.
Below with reference to embodiment, the invention will be further elaborated.
Specific embodiment
【Examples 1 to 5】
Deionized water and inorganic base or alcamines antirust agent investment reconciliation kettle, stirring are warming up to 40 DEG C and maintain this
A temperature；Oiliness improver and refined mineral oil is added, stirs evenly；Sulfonates antirust agent and surfactant are added, is stirred
Uniformly；Extreme pressure anti-wear additives, fungicide and defoaming agent are finally sequentially added, stir and stops heating, is gradually cooled to room temperature, is stopped
Stirring is to get the oil emulsion.The type and dosage of each component, are specifically shown in Table 1 in oil emulsion.
In table 1, AEO is fatty alcohol polyoxyethylene ether；SP is sorbitan fatty acid ester；OP is alkylphenol-polyethenoxy
Ether；BK is triazines fungicide；MBM is morpholine bactericide.
【Comparative example 1~7】
【Comparative example 1】Wire drawing oil Drawing oil 6268K (trade name) is produced for company of South Korea.
【Comparative example 2】It is the comparative example of phosphate for extreme pressure anti-wear additives list in embodiment 1.
【Comparative example 3】It is the comparative example of fatty alcohol polyoxyethylene ether for surfactant list in embodiment 3.
【Comparative example 4】It is the comparative example of carboxylate for antirust agent list in embodiment 5.
【Comparative example 5】It is the comparative example of olefine sulfide for extreme pressure anti-wear additives list in comparative example 2.
【Comparative example 6】It is the comparative example of poly resin acid monoethylene glycol ester for surfactant list in comparative example 3.
【Comparative example 7】It is the comparative example of dodecenylsuccinic acid for antirust agent list in comparative example 4.
The ordinary low-carbon steel wire drawing oil prepared respectively to each embodiment and comparative example is tested for the property, and test method is this
Known to domain engineering technical staff.Test result is shown in Table 2.
As can be seen from Table 2, ordinary low-carbon steel wire drawing oil of the present invention has excellent greasy property and stable emulsifying performance,
With good rustless property, prevent product from corroding, it is easy to produce in keeping and turnover.In addition, ordinary low-carbon steel of the present invention
Wire drawing oil has the usage mode of safety, has both guaranteed being normally carried out for wire drawing, reduces energy consumption, improves the surface matter of product
Amount, and the dust floated in air will not be generated in use, on human respiratory without influence.
Claims (3)
1. a kind of oil emulsion is made of the following components based on parts by weight：
A) 1~5 part of extreme pressure anti-wear additives；
B) 5~15 parts of surfactants；
C) 5~15 parts of antirust agent；
D) 5~15 parts of oiliness improvers；
E) 0.01~0.1 part of defoaming agent；
F) 0.1~1.0 part of fungicide；
G) 5~10 parts of water；
H) 60~80 parts of refined mineral oils；
The extreme pressure anti-wear additives are selected from phosphate and vulcanize the mixture of vegetable and animals oils；In mixture, phosphate and the dynamic plant of vulcanization
The weight ratio of object oil is 0.2~0.9；
The surfactant is selected from the mixture of fatty alcohol polyoxyethylene ether and sorbitan fatty acid ester；In mixture,
Fatty alcohol polyoxyethylene ether and the weight ratio of sorbitan fatty acid ester are 0.1~0.6；
The antirust agent is selected from the mixture of inorganic base or hydramine and sulfonate；
The oiliness improver is selected from vegetable oil acid；
The defoaming agent is selected from silicone based defoaming agents；
The fungicide is selected from least one of triazines or morpholine bactericide；
The refined mineral oil is selected from least one of I class low viscosity base oil, machinery oil or technical white oil.
2. oil emulsion according to claim 1, it is characterised in that in the antirust agent composition, inorganic base or hydramine and sulfonic acid
The weight ratio of salt is 0.1~1.0.
3. any oil emulsion of claim 1~2 is for the lubrication in the production of common low carbon steel wire between blank and mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510681159.9A CN105238527B (en) | 2015-10-19 | 2015-10-19 | Oil emulsion and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510681159.9A CN105238527B (en) | 2015-10-19 | 2015-10-19 | Oil emulsion and application thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105238527A CN105238527A (en) | 2016-01-13 |
| CN105238527B true CN105238527B (en) | 2018-11-20 |
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| CN201510681159.9A Active CN105238527B (en) | 2015-10-19 | 2015-10-19 | Oil emulsion and application thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108410557B (en) * | 2018-03-30 | 2021-01-22 | 南京工程学院 | Steel pipe drawing emulsified oil with ultrahigh lubricating property and preparation method thereof |
| CN109518192A (en) * | 2018-12-29 | 2019-03-26 | 南京派诺金属表面处理技术有限公司 | Emulsion-type antirust agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2151171C1 (en) * | 1999-02-04 | 2000-06-20 | Открытое акционерное общество "Чебоксарский завод кабельных изделий "Чувашкабель" | Lubricant for cold drawing of aluminium wire |
| CN101747988A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Copper and aluminum wire drawing oil and preparation method and use method thereof |
| CN101812361A (en) * | 2009-12-18 | 2010-08-25 | 益田润石（北京）化工有限公司 | Stainless steel wire drawing liquid composition |
| CN102010779A (en) * | 2010-12-20 | 2011-04-13 | 南京工程学院 | Steel cord drawing lubricant and preparation method thereof |
| CN102839038A (en) * | 2012-09-13 | 2012-12-26 | 济南库伦特科技有限公司 | Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition |
-
2015
- 2015-10-19 CN CN201510681159.9A patent/CN105238527B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2151171C1 (en) * | 1999-02-04 | 2000-06-20 | Открытое акционерное общество "Чебоксарский завод кабельных изделий "Чувашкабель" | Lubricant for cold drawing of aluminium wire |
| CN101812361A (en) * | 2009-12-18 | 2010-08-25 | 益田润石（北京）化工有限公司 | Stainless steel wire drawing liquid composition |
| CN101747988A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Copper and aluminum wire drawing oil and preparation method and use method thereof |
| CN102010779A (en) * | 2010-12-20 | 2011-04-13 | 南京工程学院 | Steel cord drawing lubricant and preparation method thereof |
| CN102839038A (en) * | 2012-09-13 | 2012-12-26 | 济南库伦特科技有限公司 | Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition |
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