CN105236354B - A kind of implementation method for the device that tritium is reclaimed from tritiated water - Google Patents
A kind of implementation method for the device that tritium is reclaimed from tritiated water Download PDFInfo
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- CN105236354B CN105236354B CN201510557495.2A CN201510557495A CN105236354B CN 105236354 B CN105236354 B CN 105236354B CN 201510557495 A CN201510557495 A CN 201510557495A CN 105236354 B CN105236354 B CN 105236354B
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Abstract
The invention discloses it is a kind of from tritiated water reclaim tritium device, including be sequentially connected by pipeline gas circulator, the surge tank equipped with inert carrier gas, the tritiated water storage tank equipped with tritiated water, be filled with iron powder the first water decomposition bed, be filled with the first adsorbent bed of 5A molecular sieves and be filled with zirconium base hydrogen storage alloy the first hydrogen storage bed;The first hydrogen storage bed, which is returned, is connected in gas circulator.Compact conformation of the present invention, with low cost, simple operation, can be carried out continuously the recovery operation of tritium in tritiated water, and not produce solid waste, therefore, and it has very high practical value and promotional value.
Description
Technical field
The present invention relates to a kind of implementation method for the device that tritium is reclaimed from tritiated water.
Background technology
Tritium technological experiment room can all produce the tritium of different activity under normal operating conditions or tritium leakage emergency processing state
Change water (HTO).Tritium in tritiated water can not be used directly, it is necessary to be translated into elemental tritium (HT), could be used as nuclear fuel
Re-used.Also, tritiated water is easier to be absorbed by human organ relative to elemental tritium, and this can cause bigger radiation
Dosage, its dose factor is 25000 times of simple substance tritium.Therefore, from the aspect of the utilization of resources and Environmental security two, it is necessary to will
Tritiated water is converted into elemental tritium, to realize the recovery of tritium.
At present, the method for tritium is reclaimed from tritiated water mainly following several:Electrolysis, isotope are exchanged, thermometal is decomposed
Method.HTO directly can be converted into HT by electrolysis, and its principle is that water decomposition reaction directly occurs under electric field action:2HTO=
2HT+O2.Represent developing direction mainly includes polymer electrolytic (SPE) and refractory ceramics electrolysis (SOEC) two class, and this method is needed
High performance proton membrane and electrode are wanted, technology maturity is not high, also in developing stage.Isotope exchange method uses catalysis
Membrane reactor (PERMCAT) is exchanged, is made up of Pd alloys permeable membrane and catalyst bed.Using isotope exchange principle, containing HTO's
Gas enters catalyst bed, and H2Or CO enters permeable membrane side with counter-flow pattern, per-meate side maintains negative pressure, and reaction principle is:H2+
HTO=H2O+HT or CO+HTO=HT+CO2;HT is enriched in the osmos tube port of export, so as to realize recovery.This method needs high-performance
Permeable membrane and catalyst, cost is higher, and running-course control is complex.
Thermometal method uses the metal or alloy with reproducibility, and its reaction principle is:XM+HTO=MxO+HT.Contain
After HTO gas is by reaction bed, the oxygen in water in the form of metal oxide to be trapped within metal bed, and the hydrogen in water is same
Position element is changed into HT.This method need not introduce the mechanical systems of complexity, low and safe and reliable with small volume, initial input cost
The advantages of.Therefore consider that this method is suitable for from tritiated water reclaiming tritium from economy and technology maturity.But using tradition
Active metal (Mg, Zr etc.) or alloy packing (ZrNi, ZrMnFe etc.), bed body failure after can form solid tritiated waste, increase
Plus subsequent treatment burden;It is therefore desirable to optimize design to this method, and tritium recovery scheme in tritiated water is carried out overall
Design, so as to be not only able to realize the high efficiente callback of tritium, and can avoid producing solid waste.
The content of the invention
For the deficiency of above-mentioned technology, the invention provides a kind of device that tritium is reclaimed from tritiated water, with can be high
Effect reclaims tritium and does not produce the advantage of solid waste.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of implementation method for the device that tritium is reclaimed from tritiated water, described device includes what is be sequentially connected by pipeline
Gas circulator, the surge tank equipped with inert carrier gas, the tritiated water storage tank equipped with tritiated water, the first moisture for being filled with iron powder
The the first hydrogen storage bed for solve bed, being filled with the first adsorbent bed of 5A molecular sieves and be filled with zirconium base hydrogen storage alloy;First storage
Hydrogen bed, which is returned, is connected in gas circulator;The tritiated water storage tank is bubbler structure;Described implementation method then includes following
Step:
(1) the first water decomposition bed, the first adsorbent bed and the first hydrogen storage respective input of bed and output end are separately turned on
Valve, closes the second water decomposition bed, the second adsorbent bed and the respective input of the second hydrogen storage bed and the valve of output end;
(2) gas circulator is opened, the inert carrier gas in surge tank is sent in tritiated water storage tank by gas circulator;
(3) tritiated water in tritiated water storage tank is with bubbling mode shifts into carrier gas, and liquid tritiated water changes into tritiated
Water vapour, then carrier gas is entered in the first water decomposition bed, and the first water decomposition bed tempertaure is heated into 400 DEG C, made in carrier gas
With iron powder redox reaction, generation ferroso-ferric oxide and gas containing hydrogen tritide occur for most of tritiated water vapour;
(4) gas containing hydrogen tritide is entered in the first adsorbent bed, and remaining water vapour is adsorbed by the first adsorbent bed, obtains drying
Gas containing hydrogen tritide;
(5) gas containing hydrogen tritide dried is entered in the first hydrogen storage bed, and is adsorbed by zirconium base hydrogen storage alloy therein;
(6) circulation step (2)~(5).
To realize the continuous processing of water decomposition bed, present invention additionally comprises in parallel and be also filled with the first water decomposition bed
The second water decomposition bed of iron powder;The first water decomposition bed and the respective input of the second water decomposition bed are equipped with valve with output end
Door.
To realize the continuous processing of adsorbent bed, present invention additionally comprises in parallel with the first adsorbent bed and be also filled with 5A point
Second adsorbent bed of son sieve;The respective input of first adsorbent bed and the second adsorbent bed is also equipped with valve with output end.
Yet further, valve, and the valve also are provided with the pipeline between surge tank and the tritiated water storage tank
Both sides are equipped with the branch road as regeneration of adsorbent beds loop, wherein, close to surge tank branch road simultaneously with the first adsorbent bed and the
The respective gas outlet connection of two adsorbent beds, and then adsorbed simultaneously with the first adsorbent bed and second close to the branch road of tritiated water storage tank
The respective air inlet connection of bed.
To realize the continuous processing of hydrogen storage bed, present invention additionally comprises in parallel and be also filled with zirconium system with the first hydrogen storage bed
The second hydrogen storage bed of hydrogen bearing alloy;The first hydrogen storage bed and the respective input of the second hydrogen storage bed are also equipped with valve with output end
Door.
Further, in the step (6), if the iron powder in the first water decomposition bed all generates ferroso-ferric oxide, cause
First water decomposition bed failure, then close the first water decomposition bed input and the respective valve of output end, opens the second water decomposition bed
Input and the respective valve of output end, make carrier gas enter in the second water decomposition bed and proceed redox reaction;Meanwhile,
First water decomposition bed tempertaure is heated to more than 500 DEG C, then to the first water decomposition bed in be continually fed into high-purity hydrogen, make its with
Reduction reaction occurs for ferroso-ferric oxide, generates metallic iron, makes the first water decomposition bed regeneration.
Yet further, in the step (6), if the first adsorbent bed adsorption saturation, the first adsorbent bed input is closed
With the respective valve of output end, the second adsorbent bed input and the respective valve of output end are opened, gas containing hydrogen tritide is entered the
In two adsorbent beds, continued to adsorb water vapour by the second adsorbent bed;Meanwhile, open the valve on the regenerative circuit of the first adsorbent bed of connection
Door, the valve closed on the pipeline between surge tank and tritiated water storage tank, by the first absorption bed tempertaure be heated to 300 DEG C with
On, dry inert carrier gas is entered the first adsorbent bed with opposite airflow direction, the tritiated water desorbed is sent to tritiated
In storage tank, while making the first regeneration of adsorbent beds.
Further, in the step (6), if the bed adsorption saturation of the first hydrogen storage, the first hydrogen storage bed input is closed
With the respective valve of output end, the second hydrogen storage bed input and the respective valve of output end are opened, enters the gas containing hydrogen tritide of drying
Enter into the second hydrogen storage bed, continue to adsorb gas containing hydrogen tritide by the second hydrogen storage bed;Meanwhile, the first hydrogen storage bed tempertaure is heated to 300
~500 DEG C, it is gaseous state gas containing hydrogen tritide to make the thermal desorption of aspiration containing hydrogen tritide, then will contain hydrogen tritide gas and outwards turn from the first hydrogen storage bed
Move, make the bed regeneration of the first hydrogen storage.
Compared with prior art, the invention has the advantages that:
(1) present invention is simple in construction, reasonable in design, which employs gas-solid reaction principle, by effective structure design,
Tritiated water is directly decomposed into gas containing hydrogen tritide, this is for electrolysis, hydrogen isotopic exchange method, and device fabrication is easy to manufacture
Realize, operation control is also simpler, therefore have construction cost low and the low advantage of operating cost.
(2) present invention takes full advantage of the reversible reaction characteristic of iron, oxidation stage metal using iron as water decomposition material
The raw ferroso-ferric oxide of iron and tritiated water reaction and gas containing hydrogen tritide, reduction phase ferroso-ferric oxide and hydrogen reaction generation metallic iron and
Water, filler, without changing, can not be produced solid waste, reduce the input of cost with Reusability.
(3) tritiated water storage tank uses bubbler structure design in the present invention, and carrier gas enters liquid internal, and carrier gas is follow-up
In flow process, it will be escaped in the form of bubble from liquid, tritiated water can be transferred in carrier gas, consequently, it is possible to can be true
While protecting processing safety, liquid tritiated water can be converted into tritiated water vapour well, so that tritium therein can be very
Decomposed and absorbed by follow-up fixed bed well.
(4) present invention uses enclosed system, and the product of device output is the isotope gas containing hydrogen tritide of pure component;Ran
Inert carrier gas uses circulation pattern in journey, will not be to environmental emission waste containing tritium gas, therefore safe, operating flexibility is big,
Tritium in various concentrations tritiated water can be met and reclaim demand.
(5) present invention has been arranged in parallel water decomposition bed, adsorbent bed and hydrogen storage bed, using the alternate mode of operation of double bed, energy
Enough realize the continuous recovery of tritium.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Fig. 2 is a kind of use state figure of the invention.
Fig. 3 is another use state figure of the invention.
Wherein, the corresponding parts title of reference is:
1- gas circulators, 2- flow controllers, 3- surge tanks, 4- tritiated water storage tanks, the water decompositions of 5- first bed, 6- the
Two water decompositions bed, the adsorbent beds of 7- first, the adsorbent beds of 8- second, the hydrogen storages of 9- first bed, the hydrogen storages of 10- second bed.
Embodiment
The invention will be further described with reference to the accompanying drawings and examples, and embodiments of the present invention include but is not limited to
The following example.
Embodiment
As shown in figure 1, the device of tritium can be reclaimed from tritiated water the invention provides a kind of, nuclear facilities is mainly used in
In tritiated and tritium technique.The present invention include be sequentially connected by pipeline gas circulator 1, flow controller 2, surge tank 3,
Tritiated water storage tank 4, the first water decomposition the 5, first adsorbent bed 7 of bed and the first hydrogen storage bed 9;And 9 companies of returning of the first hydrogen storage bed
In gas circulator 1.
Inert carrier gas is housed, under the driving of gas circulator 1, inert carrier gas can be entered in described surge tank 3
In tritiated water storage tank 4, and flow controller 2 is then used for the flow and flow velocity for controlling carrier gas, it is ensured that the safety of operation.Described
Tritiated water storage tank 4 uses bubbler structure design, and tank body and inlet and outlet piping are stainless steel tube, and inlet duct extend into tank body
Bottom, port of export road is located at the top of tank body.Tritiated water is housed, when carrier gas enters tritiated water storage tank 4 in tritiated water storage tank 4
When, under the bubble structure effect of tritiated water storage tank, it will be escaped in the form of bubble from liquid, tritiated water is transferred to carrier gas
In.
Iron powder is filled with the first water decomposition bed 5 as filler, it is used for water decomposition tritiated water, obtains and contains hydrogen tritide
Gas.5A molecular sieves are filled with first adsorbent bed 7 as filler, it is used to remove the water vapour in gas containing hydrogen tritide.It is described
Zirconium base hydrogen storage alloy is filled with first hydrogen storage bed 9, it is used to adsorb the hydrogen isotope gas in gas containing hydrogen tritide.
In addition, the present invention has also been arranged in parallel the second water decomposition the 6, second adsorbent bed 8 of bed and the second hydrogen storage bed 10, the second water
Decompose in bed 6, the second adsorbent bed 8 and the second hydrogen storage bed 10 and be equally filled with iron powder, 5A molecular sieves and zirconium base hydrogen storage alloy successively.
In order to be able to realize that alternate run works two-by-two between water decomposition bed, adsorbent bed and hydrogen storage bed, i.e., be so designed that purpose is:When one
While bed body is in running order, another bed body is in reproduced state, just can so realize the continuous operation of whole device.
Specifically, the first water decomposition bed 5 and the second water decomposition 6 respective inputs of bed are equipped with valve with output end;First
The respective input of 7 and second adsorbent bed of adsorbent bed 8 is equipped with valve with output end;First hydrogen storage bed 9 and the second hydrogen storage bed 10
Respective input is also equipped with valve with output end.By the control of respective valves, just can realize two water decompositions bed, two
The switching of adsorbent bed and two hydrogen storage beds.
The process that the present invention reclaims tritium from tritiated water is as follows:
The first water decomposition the 5, first adsorbent bed 7 of bed and the first hydrogen storage 9 pairs of tritiated waters of bed are needed to use to enter as shown in Fig. 2 working as
During row processing, the flow control of flow controller 2 is regulated first, the moisture of gas circulator 1 and first is then separately turned on
Solution bed 5, the first adsorbent bed 7 and the first hydrogen storage 9 respective inputs of bed and the valve of output end, and the second water decomposition of closing bed 6,
Second adsorbent bed 8 and the second hydrogen storage 10 respective inputs of bed and the valve of output end.
Under the driving of gas circulator 1, the inert carrier gas in surge tank 3 is pumped into tritiated water storage tank 4, due to
Tritiated water storage tank 4 employs the design of bubbler structure, thus carrier gas enters after tritiated water storage tank 4, and tritiated water is just with drum
The mode of bubble is transferred in carrier gas, and liquid tritiated water changes into tritiated water vapour, enters the first water together then as carrier gas
Decompose in bed 5.
Carrier gas enters after the first water decomposition bed 5, and the first water decomposition 5 temperature of bed are heated into 400 DEG C, make the big portion in carrier gas
(about 90%) tritiated water is divided to occur redox reaction, generation ferroso-ferric oxide and gas containing hydrogen tritide with iron powder.Then, gas containing hydrogen tritide
Enter in the first adsorbent bed 7, the remaining water vapour of small part is adsorbed by the first adsorbent bed 7, the gas containing hydrogen tritide of drying is obtained.
Finally, the gas containing hydrogen tritide dried is entered in the first hydrogen storage bed 9, is absorbed by zirconium base hydrogen storage alloy therein, so that
Realize the recovery of tritium.
When plant running for a period of time after, the first water decomposition the 5, first adsorbent bed 7 of bed and the first hydrogen storage bed 9 fail,
At this time, it may be necessary to carry out regeneration treatments to three bed bodies, while, it is necessary to being switched to the second water decomposition the 6, second adsorbent bed 7 of bed and the
On two hydrogen storages bed 10, device is set continuously to work.As shown in figure 3, specific mode of operation is as follows:
First water decomposition bed regeneration
The first water decomposition 5 inputs of bed and the respective valve of output end are closed, the second water decomposition 6 inputs of bed are opened and defeated
Go out and hold respective valve, carrier gas is entered in the second water decomposition bed 6 and proceed oxidation reaction.Meanwhile, by the first water decomposition
5 temperature of bed are heated to more than 500 DEG C, are then continually fed into high-purity hydrogen into the first water decomposition bed 5 from the A2 pipelines in Fig. 3,
It is occurred reduction reaction with ferroso-ferric oxide, generate metallic iron, gas is discharged by A1 pipelines.A1 pipelines are provided with humidity sensor
Device, when water content is less than 10ppm, shows that the regeneration of the first water decomposition bed 5 is completed, now, just can stop being passed through for high-purity hydrogen.
First regeneration of adsorbent beds
In the present invention, adsorbent bed using be heated at high temperature and be passed through inert carrier gas purging by the way of regenerated, specifically set
Putting is:Valve also is provided with pipeline between surge tank 3 and tritiated water storage tank 4, and the valve both sides are equipped with as suction
The branch road of attached bed regenerative circuit, wherein, the branch road close to surge tank 3 is simultaneously respective with the first adsorbent bed 7 and the second adsorbent bed 8
Gas outlet is connected, and close to tritiated water storage tank 4 branch road then simultaneously with the first adsorbent bed 7 and the second adsorbent bed 8 it is respective enter
Gas port is connected.
When the first adsorbent bed 7 needs regeneration, the input of the first adsorbent bed 7 and the respective valve of output end are closed, is opened
The input of second adsorbent bed 8 and the respective valve of output end, make gas containing hydrogen tritide enter in the second adsorbent bed 8, by the second absorption
Bed 8 continues to adsorb water vapour.Meanwhile, open connection the first adsorbent bed regenerative circuit on valve, close surge tank 3 with it is tritiated
Valve between water storage tank 4 on main pipeline, is heated to more than 300 DEG C by the first absorption bed tempertaure, makes dry inert carrier gas
First adsorbent bed (the B2 pipelines in Fig. 3 enter, B1 pipelines go out) is entered with opposite airflow direction, the tritiated water feeding desorbed
Into tritiated storage tank 4, while regenerating it.The water content in the pipeline of inert carrier gas circulation is detected using humidity sensor,
When water content is less than 10ppm, then shows the regeneration completion of the first adsorbent bed 7, stop the infeed of inert carrier gas.
The bed regeneration of first hydrogen storage
The first hydrogen storage 9 inputs of bed and the respective valve of output end are closed, the second hydrogen storage 10 inputs of bed and output is opened
Respective valve is held, the gas containing hydrogen tritide of drying is entered in the second hydrogen storage bed 10, continuing absorption by the second hydrogen storage bed 10 contains tritium
Hydrogen.Meanwhile, the first hydrogen storage 9 temperature of bed are heated to 300~500 DEG C, it is gaseous state gas containing hydrogen tritide to make the thermal desorption of aspiration containing hydrogen tritide,
Maintenance system pressure is less than 1atm, then by the C pipelines in Fig. 3, and hydrogen is outwards shifted from the first hydrogen storage bed 9, makes the
One hydrogen storage bed 9 regenerates.
In the present embodiment, gas circulator 1 selects membrane pump, and drives load pattern using positive displacement multiple layer metal diaphragm, no
Process gas can be polluted, and can avoided containing tritium gas leakage.Flow controller 2 selects all-metal mass flow control
Device processed, will not equally be polluted to process gas, and can also be avoided containing tritium gas leakage.Surge tank 3 selects stainless steel
Pressure vessel, rated operating pressure meets the leak rate requirement of tritium system part up to 5atm, and provided with gas transport line.Institute
Some water decomposition beds, adsorbent bed and hydrogen storage bed select fixed bed reactors.And the valve of each pipeline is connected then from pneumatic
Two-way valve, can realize gas path on-off control automatically by prime solenoid-driven.
The present invention uses fixed-bed structure, and carries out water decomposition using iron powder as filler, for being limited not by reaction balance
The remaining water vapour decomposed completely, is absorbed in rear end using molecular sieve, finally again by hydrogen bearing alloy by hydrogen isotope gas
Absorption, you can realize the recovery of tritium.One aspect of the present invention does not use penetration mode to extract gas containing hydrogen tritide, it is to avoid use palladium tube,
System building cost can effectively be reduced;The technology maturation of another aspect molecular sieve water removal, it is cheap, simple to operate.Therefore, originally
Invention is by cleverly structure design, and while ensureing high efficiente callback tritium and not producing solid waste, the system of also reducing is built
The cost made, simplifies the flow of technological operation.
Above-described embodiment is only the preferred embodiments of the present invention, is not construed as limiting the scope of the present invention, as long as adopting
With the design principle of the present invention, and the change for carrying out non-creativeness work on this basis and making, the present invention all should be belonged to
Protection domain within.
Claims (8)
1. a kind of implementation method for the device that tritium is reclaimed from tritiated water, it is characterised in that described device includes passing through pipeline
The gas circulator (1) being sequentially connected, the surge tank (3) equipped with inert carrier gas, the tritiated water storage tank (4) equipped with tritiated water,
The first water decomposition bed (5) of iron powder is filled with, the first adsorbent bed (7) of 5A molecular sieves is filled with and is filled with the hydrogen storage conjunction of zirconium system
The first hydrogen storage bed (9) of gold;The first hydrogen storage bed (9), which is returned, is connected in gas circulator (1);The tritiated water storage tank (4)
For bubbler structure;Described implementation method then comprises the following steps:
(1) the first water decomposition bed, the first adsorbent bed and the respective input of the first hydrogen storage bed and the valve of output end are separately turned on,
Close the second water decomposition bed, the second adsorbent bed and the respective input of the second hydrogen storage bed and the valve of output end;
(2) gas circulator is opened, the inert carrier gas in surge tank is sent in tritiated water storage tank by gas circulator;
(3) tritiated water in tritiated water storage tank is with bubbling mode shifts into carrier gas, and liquid tritiated water changes into tritiated water steaming
Vapour, then carrier gas is entered in the first water decomposition bed, and the first water decomposition bed tempertaure is heated into 400 DEG C, makes the big portion in carrier gas
Tritiated water vapour is divided to occur redox reaction, generation ferroso-ferric oxide and gas containing hydrogen tritide with iron powder;
(4) gas containing hydrogen tritide is entered in the first adsorbent bed, and remaining water vapour is adsorbed by the first adsorbent bed, and obtain drying contains tritium
Hydrogen;
(5) gas containing hydrogen tritide dried is entered in the first hydrogen storage bed, and is adsorbed by zirconium base hydrogen storage alloy therein;
(6) circulation step (2)~(5).
2. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 1, it is characterised in that also wrap
Include the second water decomposition bed (6) that is in parallel with the first water decomposition bed (5) and being also filled with iron powder;The first water decomposition bed (5)
With the second water decomposition bed (6) respective input valve is equipped with output end.
3. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 2, it is characterised in that also wrap
Include the second adsorbent bed (8) that is in parallel with the first adsorbent bed (7) and being also filled with 5A molecular sieves;First adsorbent bed (7) and
Second adsorbent bed (8) respective input is also equipped with valve with output end.
4. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 3, it is characterised in that described
Valve also is provided with pipeline between surge tank (3) and tritiated water storage tank (4), and the valve both sides are equipped with as absorption
The branch road of bed regenerative circuit, wherein, the branch road close to surge tank (3) is simultaneously each with the first adsorbent bed (7) and the second adsorbent bed (8)
From gas outlet connection, and close to tritiated water storage tank (4) branch road then simultaneously with the first adsorbent bed (7) and the second adsorbent bed
(8) respective air inlet connection.
5. a kind of implementation method of device that tritium is reclaimed from tritiated water according to claim 3 or 4, it is characterised in that
Also include the second hydrogen storage bed (10) that is in parallel with the first hydrogen storage bed (9) and being also filled with zirconium base hydrogen storage alloy;First storage
Hydrogen bed (9) and the second hydrogen storage bed (10) respective input are also equipped with valve with output end.
6. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 5, it is characterised in that described
In step (6), if the iron powder in the first water decomposition bed all generates ferroso-ferric oxide, cause the first water decomposition bed failure, then close
The first water decomposition bed input and the respective valve of output end are closed, the second water decomposition bed input and the respective valve of output end is opened
Door, makes carrier gas enter in the second water decomposition bed and proceeds redox reaction;Meanwhile, the first water decomposition bed tempertaure is heated
To more than 500 DEG C, high-purity hydrogen then is continually fed into the first water decomposition bed, it is occurred reduction with ferroso-ferric oxide anti-
Should, metallic iron is generated, makes the first water decomposition bed regeneration.
7. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 6, it is characterised in that described
In step (6), if the first adsorbent bed adsorption saturation, the first adsorbent bed input and the respective valve of output end are closed, is opened
Second adsorbent bed input and the respective valve of output end, make gas containing hydrogen tritide enter in the second adsorbent bed, by the second adsorbent bed
Continue to adsorb water vapour;Meanwhile, the valve on the regenerative circuit of the first adsorbent bed of connection is opened, surge tank is closed and is deposited with tritiated water
The valve on pipeline between storage tank, is heated to more than 300 DEG C by the first absorption bed tempertaure, makes dry inert carrier gas with opposite
Airflow direction enter the first adsorbent bed, the tritiated water desorbed is sent in tritiated storage tank, while making the first adsorbent bed
Regeneration.
8. the implementation method of a kind of device that tritium is reclaimed from tritiated water according to claim 6, it is characterised in that described
In step (6), if the bed adsorption saturation of the first hydrogen storage, closes the first hydrogen storage bed input and the respective valve of output end, opens
Second hydrogen storage bed input and the respective valve of output end, make the gas containing hydrogen tritide of drying enter in the second hydrogen storage bed, by second
Hydrogen storage bed continues to adsorb gas containing hydrogen tritide;Meanwhile, the first hydrogen storage bed tempertaure is heated to 300~500 DEG C, aspiration containing hydrogen tritide is pyrolyzed
Inhale for gaseous state gas containing hydrogen tritide, then will contain hydrogen tritide gas and outwards be shifted from the first hydrogen storage bed, make the bed regeneration of the first hydrogen storage.
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KR20070040304A (en) * | 2005-10-11 | 2007-04-16 | 스페셜 세퍼레이션스 어플리케이션스 아이엔씨. | A process for tritium removal from water by transfer of tritium from water to an elemental hydrogen stream, followed by membrane diffusion tritium stripping and enrichment, and final tritium enrichment by thermal diffusion |
CN103936219B (en) * | 2014-04-28 | 2016-03-30 | 四川材料与工艺研究所 | A kind of for making device and its implementation of going tritiate containing HTO |
CN104167233A (en) * | 2014-06-16 | 2014-11-26 | 中国工程物理研究院核物理与化学研究所 | Tritium water collecting device |
CN104318968A (en) * | 2014-08-21 | 2015-01-28 | 中国工程物理研究院核物理与化学研究所 | Process and device for treating tritium-containing water in nuclear power plant based on electrolysis and low-temperature distillation cascade process |
CN204897393U (en) * | 2015-09-02 | 2015-12-23 | 中国工程物理研究院材料研究所 | Retrieve device of tritium in follow tritiated water |
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