CN105235339B - A kind of 3D three-dimensional imagings film and its application - Google Patents

A kind of 3D three-dimensional imagings film and its application Download PDF

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CN105235339B
CN105235339B CN201510654431.4A CN201510654431A CN105235339B CN 105235339 B CN105235339 B CN 105235339B CN 201510654431 A CN201510654431 A CN 201510654431A CN 105235339 B CN105235339 B CN 105235339B
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layer
tack coat
dimensional imagings
mass fraction
mentioned
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CN105235339A (en
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吕晓义
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SHANGHAI BEIXIANG CHEMICAL ENGINEERING Co Ltd
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SHANGHAI BEIXIANG CHEMICAL ENGINEERING Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/12—Polyvinylhalogenides containing fluorine
    • B32B2327/18—PTFE, i.e. polytetrafluoroethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2355/00—Specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of index codes B32B2323/00 - B32B2333/00
    • B32B2355/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2369/00—Polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2379/00—Other polymers having nitrogen, with or without oxygen or carbon only, in the main chain
    • B32B2379/08—Polyimides

Abstract

The invention discloses a kind of 3D three-dimensional imagings film, it includes：Protective layer, is made of resin material or its composite；3D three-dimensional imagings layer, is made of high-molecular optical polymer image forming material or silver salt material；Carrier layer, is made of resin material；One plane of 3D three-dimensional imagings layer is connected by the first tack coat with protective layer, and another plane of 3D three-dimensional imagings layer is connected by the second tack coat with carrier layer, and the material of the first tack coat and the second tack coat is not solvent-laden adhesive.The present invention solves the 3D three-dimensional imagings not solvent-proof problem of layer run into during blowing, the making of 3D blockings work, seal gasket, 3C Product protect film production and outdoor label fabrication process in in-mould injection, mould by the setting and selection of the first tack coat and the second tack coat; make its at high temperature under high pressure moment effectively bonded from different plastic materials, and further by the setting of heat-insulated heat-resistant layer solve the problems, such as 3D three-dimensional imagings layer non-refractory.

Description

A kind of 3D three-dimensional imagings film and its application
The application is the submission of on December 24th, 2012, Application No. 201210566161.8, entitled：It is " a kind of The divisional application of the Chinese invention patent application of 3D three-dimensional imagings film and its application ".
Technical field
The present invention relates to a kind of 3D three-dimensional imagings film and its application.
Background technology
So-called high-molecular optical polymer image forming material, is a kind of on very thin planar materials, can be shown great The material of the 3D three-dimensional image effects of depth, at present its be mainly used on the field of antifalsification label, but when in use with pasted Thing can form level phenomenon, have the shortcomings that to be easy to be lifted.And it is directly applied in in-mould injection, mould and be blow molded, make When manufacture is identified with the integrally formed stereo-picture of product in the manufacturing processes in field such as card, then can run into high in whole processing procedure The not solvent-proof problem of molecule photopolymer image forming material, and the high temperature and high pressure that resistance to 270 DEG C or so are needed in some processing procedures Problem, and moment need to bond from different plastic materials and adhesive strength need to reach professional standard under elevated temperature and pressure conditions Problem.Additionally, the silver salt material for being imaged there is also these problems.At present for these problems, the solution party that there is no Case.
The content of the invention
It is an object of the invention to provide a kind of 3D three-dimensional imagings film, to solve in the prior art by high-molecular optical polymer Image forming material is directly applied in in-mould injection, mould in the manufacturing process in field such as blowing, fabrication, run into whole processing procedure The not solvent-proof problem of high-molecular optical polymer image forming material, and resistance to 270 DEG C or so of high temperature and high pressure problem is needed, and in height Gentle condition of high voltage lower moment need to be bonded from different plastic materials and adhesive strength need to reach the problem of professional standard.The present invention Also provide above-mentioned 3D three-dimensional imagings film make inflation film in in-mould injection film, mould, 3D Antiforge cards, seal gasket, The purposes of 3C Product diaphragm and outdoor label.
Technical scheme is as follows：
A kind of 3D three-dimensional imagings film, it includes：
Protective layer, is made of resin material or its composite；Usual protective layer is contacted with external environment, also may be used certainly Other kinds of layer is set thereon, it is not contacted with the external world；
3D three-dimensional imagings layer, is made of high-molecular optical polymer image forming material or silver salt material；
Carrier layer, is made of resin material；The selection of carrier layer is not limited, and can be selected with actual conditions as needed With any suitable resin material, such as ABS, PC, PET, PE, PP, and process resin of the treatment with various properties The release treated polyethylene terephthalate of material, such as surface, polyimides or makrolon etc.；
One plane of the 3D three-dimensional imagings layer is connected by the first tack coat with the protective layer, the 3D three-dimensional imagings Another plane of layer is connected by the second tack coat with the carrier layer, and the material of first tack coat and the second tack coat is Not solvent-laden adhesive.
Preferably, the material of first tack coat and the second tack coat is viscous selected from silica gel, UV glue, polyurethane or acrylic acid One or more in mixture, those adhesives are free of solvent, and caking property is good, can meet 3D three-dimensional imagings film on bonding The requirement of intensity.
Preferably, the high-molecular optical polymer image forming material of the 3D three-dimensional imagings layer is selected from acrylic acid, polyurethane, polyester Or one or more in carbonic ester, the silver salt material of 3D three-dimensional imagings layer be selected from one kind in silver bromide or silver iodide or Two kinds, the 3D three-dimensional imagings layer being made up of these materials has good 3D rendering effect.
Preferably, the protective layer is selected from common protective layer, enhanced protection layer or uvioresistant protective layer, wherein
The material of the common protective layer is selected from one kind of polyethylene terephthalate, polyimides or makrolon Or it is several；
The material of the enhanced protection layer is selected from polyethylene terephthalate, acryl, makrolon and is constituted The composite of the wherein one or more of group, and do cure process on the surface of enhanced protection layer；
The matrix material of the uvioresistant protective layer is selected from makrolon, polytetrafluoroethylene (PTFE) or poly terephthalic acid second One or more of diol ester.The selection of protective layer can be carried out according to being actually needed for product, it is also possible to which selection is except above-mentioned several The existing or conventional protective layer with various different defencive functions outside protective layer.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of in-mould injection film, and the in-mould injection film includes Following each layer：
1. enhanced protection layer：The enhanced protection layer surface does cure process, and its percetage by weight is according to side commonly used in the trade Method determination, and preferably 17~19%, its material is selected from resin material or its composite, preferably from poly terephthalic acid second The composite of the wherein one or more of the group that diol ester, acryl, makrolon are constituted；
2. the first tack coat：The enhanced protection layer is connected to, percetage by weight 7~17%, its material is selected from silica gel, UV One or more of glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 6~16% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
4. the second tack coat：The 3D three-dimensional imagings layer is connected to, percetage by weight 10~14%, its material is selected from silicon One or more of glue, UV glue, polyurethane or acryloid cement；
5. heat-insulated heat-resistant layer：Second tack coat, percetage by weight 35~41% are connected to, its material is selected from polyamides Asia One or more of amine, polyethylene terephthalate or makrolon；
6. articulamentum：The heat-insulated heat-resistant layer is connected to, percetage by weight 5~9%, its material is selected from special IMF ink Or one or more of chlorinated polypropylene compound oil ink；
7. following layer：Be connected to the articulamentum, percetage by weight 1~3%, its material be selected from special IMF PURs, One or more of EVA hot-melt adhesive or polyurethane PUR；
The following layer is connected with carrier layer.Carrier layer is made of resin material；The material selection of carrier layer is without limit System, can select any suitable resin material, such as ABS, PC, PET, PE, PP etc. with actual conditions as needed.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of inflation film in mould, and inflation film includes in the mould Following each layer：
1. common protective layer：Its percetage by weight determines according to method commonly used in the trade, and preferably 9~11%, its material Selected from resin material or its composite, and preferably from polyethylene terephthalate, polyimides or makrolon One or more；
2. the first tack coat：Be connected to the common protective layer, percetage by weight 19~21%, its material be selected from silica gel, One or more of UV glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 13~23% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
4. the second tack coat：The 3D three-dimensional imagings layer is connected to, percetage by weight 19~21%, its material is selected from pressure-sensitive One or more of glue, silica gel, UV glue, polyurethane or acryloid cement；
5. heat-insulated heat-resistant layer：Second tack coat, percetage by weight 12~16% are connected to, its material is selected from poly- to benzene One or more of naphthalate, polyimides or makrolon；
6. tack coat：The heat-insulated heat-resistant layer is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably Be 1~3%, its material preferably from polyurethane or polyether resin one or more；
7. following layer：The tack coat is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably 5 ~7%, its material preferably free one or more from polyethylene, polystyrene or acrylic resin system；
The following layer is connected with carrier layer, and carrier layer is made of resin material；The material selection of carrier layer is without limit System, can select any suitable resin material, such as ABS, PC, PET, PE, PP etc. with actual conditions as needed.It is described general The thickness or weight fraction of logical protective layer, tack coat and following layer set and choose according to industry routine method.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of 3D cards, and the 3D cards include following each layer：
1. the first following layer：First vector layer is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably Be 9~11%, its material preferably from Corvic, polypropylene or polystyrene resin one or more；
2. tack coat one：First following layer is connected to, its percetage by weight determines according to method commonly used in the trade, and excellent Elect 9~11% as, its material preferably from polyurethane or polyether resin one or more；
3. common protective layer：The tack coat one is connected to, its percetage by weight determines according to method commonly used in the trade, and excellent Elect 9~11% as, its material is selected from resin material or its composite, and preferably from polyethylene terephthalate, poly- One or more of acid imide or makrolon；
4. the first tack coat：Be connected to the common protective layer, percetage by weight 19~21%, its material be selected from silica gel, One or more of UV glue, polyurethane or acryloid cement；
5. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 12~22% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
6. the second tack coat：The 3D three-dimensional imagings layer is connected to, percetage by weight 19~21%, its material is selected from pressure-sensitive One or more of glue, silica gel, UV glue, polyurethane or acryloid cement；
7. heat-insulated heat-resistant layer：Second tack coat, percetage by weight 11~15% are connected to, its material is selected from poly- to benzene One or more of naphthalate, polyimides or makrolon；
8. tack coat two：The heat-insulated heat-resistant layer is connected to, its percetage by weight determines according to method commonly used in the trade, and excellent Elect 1~3% as, its material preferably from polyurethane or polyether resin one or more；
9. the second following layer：The tack coat two is connected to, its percetage by weight determines according to method commonly used in the trade, and excellent Elect 5~7% as, its material preferably from Corvic, polypropylene or polystyrene resin one or more；
Second following layer is connected with Second support layer, and the first vector layer and Second support layer use resin material It is made；The material selection of carrier layer can select any suitable resin material with actual conditions as needed without limitation, than Such as ABS, PC, PET, PE, PP.First following layer, adhesive linkage one, common protective layer, the following layer of tack coat two and second Thickness or weight fraction according to industry routine method set and choose.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of seal gasket, and the seal gasket includes following each Layer：
1. common protective layer：Its percetage by weight determines according to method commonly used in the trade, and preferably 6~8%, the choosing of its material From resin material or its composite, and preferably from the one of polyethylene terephthalate, polyimides or makrolon Plant or several；
2. the first tack coat：Be connected to the common protective layer, percetage by weight 19~21%, its material be selected from silica gel, One or more of UV glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 15~25% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
4. the second tack coat：The 3D three-dimensional imagings layer is connected to, percetage by weight 19~21%, its material is selected from silicon One or more of glue, UV glue, polyurethane or acryloid cement；
5. electromagnetic wave induction layer：Second tack coat is connected to, its percetage by weight determines according to method commonly used in the trade, And preferably 6~8%, its material preferably from aluminium foil, tinfoil paper or Copper Foil one or more；
6. tack coat：The electromagnetic wave induction layer is connected to, its percetage by weight determines according to method commonly used in the trade, and excellent Elect 5~7% as, its material preferably from polyurethane or polyether resin one or more；
7. following layer：The tack coat is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably 19 ~21%, one or more of its material preferably from polyethylene, polystyrene or acrylic resin system；
The following layer is connected with carrier layer, and the carrier layer is made of resin material；The material selection of carrier layer does not have It is restricted, any suitable resin material, such as ABS, PC, PET, PE, PP etc. can be selected with actual conditions as needed.Institute The thickness or weight fraction for stating common protective layer, electromagnetic wave induction layer, tack coat and following layer are set according to industry routine method And selection.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of 3C Product diaphragm, and the 3C Product diaphragm includes Following each layer：
1. enhanced protection layer：The enhanced protection layer surface does cure process, and its percetage by weight is according to side commonly used in the trade Method determination, and preferably 29~31%, its material is selected from resin material or its composite, and preferably from poly terephthalic acid The composite of the wherein one or more of the group that glycol ester, acryl, makrolon are constituted；
2. the first tack coat：Be connected to enhanced protection layer, percetage by weight 9~11%, its material be selected from pressure sensitive adhesive, One or more of silica gel, UV glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 20~30% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
4. the second tack coat：Be connected to 3D three-dimensional imagings layer, percetage by weight 4~6%, its material be selected from silica gel, One or more of UV glue, polyurethane or acryloid cement；
5. carrier layer：Second tack coat is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably Be 29~31%, its material preferably from polyethylene terephthalate, polyimides or makrolon one or more；
6. following layer：The carrier layer is connected to, percetage by weight is preferably 1~3%, and this layer has degassing function, Its material preferably from pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement one or more.The enhanced protection Layer, carrier layer, the thickness of following layer or weight fraction can set and choose according to industry routine method.
A kind of above-mentioned 3D three-dimensional imagings film is used to make the purposes of outdoor label, and the outdoor label includes following each Layer：
1. uvioresistant protective layer：Its percetage by weight determines according to method commonly used in the trade, and preferably 19~21%, its Material is selected from resin material or its composite with anti-ultraviolet function, the preferable self-polycarbonate of its matrix material, poly- One or more of tetrafluoroethene, polyvinyl fluoride or polyethylene terephthalate；
2. the first tack coat：The uvioresistant protective layer is connected to, percetage by weight 6~8%, its material is selected from pressure-sensitive One or more of glue, silica gel, UV glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：First tack coat is connected to, percetage by weight 15~25% is poly- using high-molecular optical Compound image forming material or silver salt material are made；
4. ink layer：The 3D three-dimensional imagings layer is connected to, percetage by weight 4~6%, its material is selected from water-based ink；
5. the second tack coat：The ink layer is connected to, percetage by weight 19~21%, its material is selected from pressure sensitive adhesive, silicon One or more of glue, UV glue, polyurethane or acryloid cement；
6. carrier layer：Second tack coat is connected to, its percetage by weight determines according to method commonly used in the trade, and preferably It is 27~29%, its material is preferably from the release treated polyethylene terephthalate in surface, polyimides or poly- carbon One or more of acid esters.The uvioresistant protective layer, the thickness of carrier layer or weight fraction can be according to industry routine methods Set and choose.
Compared with prior art, beneficial effects of the present invention are as follows：
First, the present invention is by setting the up and down tack coat Nian Jie with 3D three-dimensional imagings layer, i.e. the first tack coat and second Tack coat, and the adhesive containing solvent composition is not used as first by selecting silica gel, UV glue, polyurethane or acryloid cement etc. The material of tack coat and the second tack coat, successfully solves high-molecular optical polymer image forming material or silver salt material is not solvent-proof Problem；
Secondth, in in-mould injection film, the mould in the making of inflation film and 3D Antiforge cards, using polyimides, poly- right The heat-insulated heat-resistant layer that the exotic material such as PET or makrolon is made solves height as main thermal insulation layer Problem of the molecule photopolymer image forming material intolerant to 270 DEG C or so of high temperature and high pressure；
3rd, in the making of in-mould injection film, it is made selected from special IMF ink or chlorinated polypropylene compound oil ink etc. Articulamentum and the following layer that is made selected from special IMF PURs, EVA hot-melt adhesive or polyurethane PUR etc. lower the temperature as buffering Layer, further solves the problems, such as high-molecular optical polymer image forming material intolerant to 270 DEG C or so of high temperature and high pressure；
4th, in the making of in-mould injection film, using selected from special IMF PURs, EVA hot-melt adhesive or polyurethane heat The special adhesive such as melten gel or plastic film solve high-molecular optical polymeric material simultaneously as following layer can be in high temperature The problem that need to be bonded from different plastic materials with high pressure lower moment；
5th, the extension of the application field of high-molecular optical polymer image forming material is successfully extended to IMF (in mould by the present invention Injection), IML (mould in blowing), fabrication, seal gasket, the diaphragm of 3C Product, outdoor label used etc. on industry field.
Certainly, implement any product of the invention to it is not absolutely required to while reaching all the above advantage.
Brief description of the drawings
Fig. 1 is each Rotating fields schematic diagram of 3D three-dimensional imaging films of embodiment of the present invention 1-3.
Specific embodiment
Referring to Fig. 1,3D three-dimensional imagings film of the invention includes：
Protective layer 1, is made of resin material or its composite；
3D three-dimensional imagings layer 3, is made of high-molecular optical polymer image forming material or silver salt material；
Carrier layer 5, is made of resin material；
One plane of 3D three-dimensional imagings layer 3 is connected by the first tack coat 2 with protective layer 1,3D three-dimensional imagings layers 3 it is another Plane is connected by the second tack coat 4 with carrier layer 5, and the material of the first tack coat 2 and the second tack coat 4 is not solvent-laden viscous Mixture.
Wherein, protective layer 1 can be selected as needed, more preferably can be from common protective layer, enhanced protection layer Or uvioresistant protective layer, wherein
Common protective layer used in insulation blocking under normal circumstances, its material can select any suitable resin material, example Such as it is selected from polyethylene terephthalate, polyimides or makrolon；
For needing the insulation blocking higher of scratch-resistant, hardness, its material can select any suitable tree to enhanced protection layer Fat material, is selected from the one of which or of the group that polyethylene terephthalate, acryl, makrolon are constituted The composite of kind of the above, and cure process is done on the surface of enhanced protection layer, make it possess it is anti-scratch wipe, friction resistant Effect；
Uvioresistant is protective layer used in needing to anti-ultraviolet insulation blocking, such as to be commonly exposed under outdoor daylight Product, its matrix material can select any suitable resin material, be selected from makrolon, polytetrafluoroethylene (PTFE) or poly- to benzene Naphthalate.
The material of the first tack coat 2 and the second tack coat 4 is not solvent-laden adhesive, preferably from silica gel, UV glue, is gathered One or more in ammoniacum or acryloid cement.
3D three-dimensional imagings layer 3 use high-molecular optical polymer image forming material may be selected from the industry all suitable macromolecules into As material, one or more in acrylic acid, polyurethane, polyester or carbonic ester, the silver salt that 3D three-dimensional imagings layer 3 is used preferably are selected from Material preferably is selected from one or two in silver bromide or silver iodide.
Further, it is also possible to according to actual needs, such as high temperature high voltage resistant etc. is needed, between the second tack coat 4 and carrier layer 5 Heat-insulated heat-resistant layer is set；Electromagnetic Heating is needed, then electromagnetic induction layer is set between the second tack coat 4 and carrier layer 5；And need During the image to be enriched, patterned layer, such as ink design layer can be set between 3D three-dimensional imagings layer 3 and the second tack coat 4.
Mass fraction shared by each layer of the above, those skilled in the art can be configured and adjust according to its practical situations It is whole.
3D three-dimensional imagings film of the invention can be used for anti-counterfeit field, it can also be used to 3D film applications, it is possible to produce tool There is the product of 3D rendering true to nature.
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate this hair It is bright, rather than limit protection scope of the present invention.Those skilled in the art are according to changing that the present invention makes in actual applications Enter and adjust, still fall within protection scope of the present invention.
Embodiment 1
The 3D three-dimensional imaging films of the present embodiment include：
Common protective layer, is made of polyethylene terephthalate；
3D three-dimensional imagings layer, is made of high-molecular optical polymer image forming material, high-molecular optical polymer imaging matrix material Expect to be acrylic acid；
Carrier layer, is made of PP；
One plane of 3D three-dimensional imagings layer is connected by the first tack coat with common protective layer, 3D three-dimensional imagings layer it is another Plane is connected by the second tack coat with carrier layer, and the material of the first tack coat and the second tack coat is silica gel.
Embodiment 2
The 3D three-dimensional imaging films of the present embodiment include：
Enhanced protection layer, is made of polyethylene terephthalate, is done at hardening on the surface of enhanced protection layer Reason, make it possess it is anti-scratch wipe, the effect of friction resistant；
3D three-dimensional imagings layer, is made of high-molecular optical polymer image forming material, and high-molecular optical polymer image forming material is Carbonic ester；
Carrier layer, is made of PC；
One plane of 3D three-dimensional imagings layer is connected by the first tack coat and enhanced protection layer, 3D three-dimensional imagings layer it is another Plane is connected by the second tack coat with carrier layer, and the material of the first tack coat and the second tack coat is UV glue.
Embodiment 3
The 3D three-dimensional imaging films of the present embodiment include：
Uvioresistant protective layer, its matrix is made of polytetrafluoroethylene (PTFE)；
3D three-dimensional imagings layer, is made of silver bromide；
Carrier layer, is made of PC；
One plane of 3D three-dimensional imagings layer is connected by the first tack coat and enhanced protection layer, 3D three-dimensional imagings layer it is another Plane is connected by the second tack coat with carrier layer, and the material of the first tack coat and the second tack coat is polyurethane.
More than, because first tack coat and the second tack coat of the embodiment of the present invention employ not solvent-laden adhesive, So fundamentally solving the problems, such as solvent resistant of the 3D three-dimensional imagings film in whole processing procedure.
In example 4 below -21, the material of 3D three-dimensional imagings layer is from E.I.Du Pont CompanyProduct.
Embodiment 4
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make in-mould injection film, and the in-mould injection film includes Following each layer：
1. enhanced protection layer：It is externally exposed in environment, mass fraction 18%, its material is polyethylene terephthalate Ester, acryl, the composite of makrolon, the enhanced protection layer surface do cure process, make it possess it is anti-scratch wipe, friction resistant Effect；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 12%, its material is silica gel；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 11%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 12%, its material is silica gel；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 38% are connected to, its material is polyimides；
6. articulamentum：Above-mentioned heat-insulated heat-resistant layer, mass fraction 7% are connected to, its material is special IMF ink；
7. following layer：Above-mentioned articulamentum, mass fraction 2% are connected to, its material is special IMF PURs；
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, articulamentum, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is molded by injection machine with carrier layer and connected Connect, the carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment employs not solvent-laden first tack coat and the second tack coat, so solving 3D well Three-dimensional imaging film in whole processing procedure intolerant to Solvent, and as a result of resistant to elevated temperatures polyimides as heat-insulated resistance to The buffering cooling effect of the following layer of the articulamentum and special IMF PURs of warm layer and the special IMF ink of use, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional, resulting product clear patterns, profile Profile is complete, does not have depredation；And be used as by the special IMF PURs for selecting adhesion strength to reach industry requirement standard and connect Layer and reach that moment under elevated temperature and pressure conditions bonds from different plastic materials and adhesive strength reaches the mesh of professional standard 's.To being tested according to professional standard according to product manufactured in the present embodiment, as a result find that these products have reached industry mark Accurate requirement.
Embodiment 5
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make in-mould injection film, and the in-mould injection film includes Following each layer：
1. enhanced protection layer：It is externally exposed in environment, mass fraction 20%, its material is polyethylene terephthalate Ester composite, the enhanced protection layer surface does cure process, make it possess it is anti-scratch wipe, the effect of friction resistant；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 7%, its material is UV glue；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 16%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 10%, its material is UV glue；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 41% are connected to, its material is poly terephthalic acid second Diol ester；
6. articulamentum：Above-mentioned heat-insulated heat-resistant layer, mass fraction 5% are connected to, its material is chlorinated polypropylene compound oil ink；
7. following layer：Above-mentioned articulamentum, mass fraction 1% are connected to, its material is EVA hot-melt adhesive；
The following layer is connected with carrier layer.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, articulamentum, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is molded by injection machine with carrier layer and connected Connect, the carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment employs not solvent-laden first tack coat and the second tack coat, so solving 3D well Three-dimensional imaging film in whole processing procedure intolerant to Solvent, and as a result of resistant to elevated temperatures polyethylene terephthalate Ester is lowered the temperature as heat-insulated heat-resistant layer and using the buffering of the following layer of the articulamentum and EVA hot-melt adhesive of chlorinated polypropylene compound oil ink Effect, the in-mould injection film of the present embodiment resistance to 270 DEG C or so of the high temperature and high pressure in whole processing procedure is functional, gained system Product clear patterns, appearance profile are complete, do not have depredation；And reach the EVA of industry requirement standard by selecting adhesion strength PUR reaches that moment under elevated temperature and pressure conditions bonds from different plastic materials and adhesive strength reaches as following layer The purpose of professional standard.To being tested according to professional standard according to product manufactured in the present embodiment, these products are as a result found The requirement of professional standard is reached.
Embodiment 6
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make in-mould injection film, and the in-mould injection film includes Following each layer：
1. enhanced protection layer：Without exposure in external environment condition, mass fraction 16%, its material is acryl, the reinforcing Protective layer does cure process, make it possess it is anti-scratch wipe, the effect of friction resistant；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 17%, its material is polyurethane；3. 3D stands Body imaging layer：It is connected to above-mentioned first tack coat, mass fraction 6%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 14%, its material is bonded for acrylic acid Agent；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 35% are connected to, its material is makrolon；
6. articulamentum：Above-mentioned heat-insulated heat-resistant layer, mass fraction 9% are connected to, its material is special IMF ink；
7. following layer：Above-mentioned articulamentum mass fraction 3% is connected to, its material is polyurethane PUR；
The following layer is connected with carrier layer.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, articulamentum, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is molded by injection machine with carrier layer and connected Connect, the carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment employs not solvent-laden first tack coat and the second tack coat, so solving 3D well Three-dimensional imaging film in whole processing procedure intolerant to Solvent, and as a result of resistant to elevated temperatures makrolon as heat-insulated resistance to The buffering cooling effect of the following layer of the articulamentum and polyurethane PUR of warm layer and the special IMF ink of use, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional, resulting product clear patterns, profile Profile is complete, does not have depredation；And be used as by the polyurethane PUR for selecting adhesion strength to reach industry requirement standard and connect Layer and reach that moment under elevated temperature and pressure conditions bonds from different plastic materials and adhesive strength reaches the mesh of professional standard 's.To being tested according to professional standard according to product manufactured in the present embodiment, as a result find that these products have reached industry mark Accurate requirement.
Embodiment 7
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make inflation film in mould, and inflation film includes in the mould Following each layer：
1. common protective layer：It is externally exposed in environment, mass fraction 10%, its material is polyethylene terephthalate Ester；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 20% are connected to, its material is UV glue；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 18%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 20%, its material is pressure sensitive adhesive；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 14% are connected to, its material is polyimides；
6. tack coat：Above-mentioned heat-insulated heat-resistant layer, mass fraction 2% are connected to, its material is polyether resin；
7. following layer：Above-mentioned tack coat, mass fraction 6% are connected to, its material is polyethylene；
The following layer is connected with carrier layer.
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, tack coat, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is noted with carrier layer by in-mold injection molding machine Modeling connection, the carrier layer can be PE, PP or PET product.
Because the present embodiment employs not solvent-laden first tack coat and the second tack coat, so solving 3D well Solvent resistant problem of the three-dimensional imaging film in whole processing procedure, and as a result of resistant to elevated temperatures polyimides as heat-insulated resistance to Warm layer, the in-mould injection film of the present embodiment resistance to 270 DEG C or so of the high temperature and high pressure in whole processing procedure is functional.To basis Product manufactured in the present embodiment is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 8
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make inflation film in mould, and inflation film includes in the mould Following each layer：
1. common protective layer：Without exposure in external environment condition, mass fraction 11%, its material is polyimides；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 19% are connected to, its material is polyurethane；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 13%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 19%, its material is bonded for acrylic acid Agent；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 16% are connected to, its material is makrolon；
6. tack coat：Above-mentioned heat-insulated heat-resistant layer, mass fraction 3% are connected to, its material is polyurethane；
7. following layer：Above-mentioned tack coat, mass fraction 7% are connected to, its material is polystyrene；
The following layer is connected with carrier layer.
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, tack coat, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is noted with carrier layer by in-mold injection molding machine Modeling connection, the carrier layer can be PE, PP or PET product.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and as a result of resistant to elevated temperatures makrolon as heat-insulated heat-resistant layer, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional.To according to manufactured in the present embodiment Product is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 9
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make inflation film in mould, and inflation film includes in the mould Following each layer：
1. common protective layer：It is externally exposed in environment, mass fraction 9%, its material is makrolon；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 21% are connected to, its material is acryloid cement；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 23%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 21%, its material is silica gel；
5. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 12% are connected to, its material is makrolon；
6. tack coat：Above-mentioned heat-insulated heat-resistant layer, mass fraction 1% are connected to, its material is polyurethane；
7. following layer：Above-mentioned tack coat, mass fraction 5% are connected to, its material is polypropylene；
The following layer is connected with carrier layer.
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, heat-insulated heat-resistant layer, tack coat, Combination between following layer is coating machine coating or abutted equipment laminating, and following layer is noted with carrier layer by in-mold injection molding machine Modeling connection, the carrier layer can be PE, PP or PET product.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and as a result of resistant to elevated temperatures polyimides as heat-insulated heat-resistant layer, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional.To according to manufactured in the present embodiment Product is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 10
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3D cards, and the 3D cards include following each layer：
1. the first following layer：First vector layer is connected to, mass fraction 10%, its material is Corvic；
2. tack coat one：Above-mentioned first following layer, mass fraction 2% are connected to, its material is polyurethane；
3. common protective layer：Above-mentioned tack coat one, mass fraction 10% are connected to, its material is poly terephthalic acid second two Alcohol ester；
4. the first tack coat：Above-mentioned common protective layer, mass fraction 20% are connected to, its material is acryloid cement；
5. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 17%；
6. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 20%, its material is silica gel；
7. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 13% are connected to, its material is makrolon；
8. tack coat two：Above-mentioned heat-insulated heat-resistant layer, mass fraction 2% are connected to, its material is polyurethane；
9. the second following layer：Above-mentioned tack coat two, mass fraction 6% are connected to, its material is polystyrene resin；It is above-mentioned Second following layer is connected with Second support layer, and above-mentioned first vector layer and Second support layer are made of resin material；First carries The material of body layer and Second support layer can be from ABS, PC, PET, PE, PP etc..
Wherein, linked together by hot press pressure-bearing mode between the first following layer, tack coat one, common protective layer, Common protective layer, the first tack coat, 3D three-dimensional imagings layer, between the second tack coat, heat-insulated heat-resistant layer by coating machine coating or Abutted equipment is fitted and connected together, is connected by hot press pressure-bearing mode between heat-insulated heat-resistant layer, tack coat two, the second following layer It is connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and as a result of resistant to elevated temperatures makrolon as heat-insulated heat-resistant layer, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional.To according to manufactured in the present embodiment Product is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 11
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3D cards, and the 3D cards include following each layer：
1. the first following layer：First vector layer is connected to, mass fraction 11%, its material is polypropylene；
2. tack coat one：Above-mentioned first following layer, mass fraction 2% are connected to, its material is polyether resin；
3. common protective layer：Above-mentioned tack coat one, mass fraction 11% are connected to, its material is polyimides；
4. the first tack coat：Above-mentioned common protective layer, mass fraction 19% are connected to, its material is UV glue；
5. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 12%；
6. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 19%, its material is silica gel；
7. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 11% are connected to, its material is poly terephthalic acid second Diol ester；
8. tack coat two：Above-mentioned heat-insulated heat-resistant layer, mass fraction 3% are connected to, its material is polyether resin；
9. the second following layer：Above-mentioned tack coat two, mass fraction 7% are connected to, its material is Corvic；It is above-mentioned Second following layer is connected with Second support layer, and above-mentioned first vector layer and Second support layer are made of resin material；First carries The material of body layer and Second support layer can be from ABS, PC, PET, PE, PP etc..
Wherein, linked together by hot press pressure-bearing mode between the first following layer, tack coat one, common protective layer, Common protective layer, the first tack coat, 3D three-dimensional imagings layer, between the second tack coat, heat-insulated heat-resistant layer by coating machine coating or Abutted equipment is fitted and connected together, is connected by hot press pressure-bearing mode between heat-insulated heat-resistant layer, tack coat two, the second following layer It is connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and as a result of resistant to elevated temperatures polyethylene terephthalate as heat-insulated heatproof Layer, the in-mould injection film of the present embodiment resistance to 270 DEG C or so of the high temperature and high pressure in whole processing procedure is functional.To according to this Product prepared by embodiment is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 12
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3D cards, and the 3D cards include following each layer：
1. the first following layer：First vector layer is connected to, mass fraction 9%, its material is polystyrene resin；
2. tack coat one：Above-mentioned first following layer, mass fraction 2% are connected to, its material is polyurethane；
3. common protective layer：Above-mentioned tack coat one, mass fraction 9% are connected to, its material is makrolon；
4. the first tack coat：Above-mentioned common protective layer, mass fraction 21% are connected to, its material is polyurethane；
5. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 22%；
6. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 21%, its material is pressure sensitive adhesive；
7. heat-insulated heat-resistant layer：Above-mentioned second tack coat, mass fraction 15% are connected to, its material is poly terephthalic acid second Diol ester；
8. tack coat two：Above-mentioned heat-insulated heat-resistant layer, mass fraction 1% are connected to, its material is polyether resin；
9. the second following layer：Above-mentioned tack coat two, mass fraction 5% are connected to, its material is polypropylene；
Above-mentioned second following layer is connected with Second support layer, and above-mentioned first vector layer and Second support layer use resin material It is made；The material of first vector layer and Second support layer can be from ABS, PC, PET, PE, PP etc..
Wherein, linked together by hot press pressure-bearing mode between the first following layer, tack coat one, common protective layer, Common protective layer, the first tack coat, 3D three-dimensional imagings layer, between the second tack coat, heat-insulated heat-resistant layer by coating machine coating or Abutted equipment is fitted and connected together, is connected by hot press pressure-bearing mode between heat-insulated heat-resistant layer, tack coat two, the second following layer It is connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and as a result of resistant to elevated temperatures makrolon as heat-insulated heat-resistant layer, the present embodiment In-mould injection film resistance to 270 DEG C or so of high temperature and high pressure in whole processing procedure is functional.To according to manufactured in the present embodiment Product is tested according to professional standard, as a result finds that these products have reached the requirement of professional standard.
Embodiment 13
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make seal gasket, and the seal gasket includes following each Layer：
1. common protective layer：Without exposure in external environment condition, mass fraction 7%, its material is polyimides；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 20% are connected to, its material is silica gel；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 20%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 20%, its material is silica gel；
5. electromagnetic wave induction layer：Above-mentioned second tack coat is connected to, mass fraction 7%, its material is aluminium foil, and it act as Receive electromagnetic energy and produce heat to bond following layer and carrier layer；
6. tack coat：Above-mentioned electromagnetic wave induction layer is connected to, mass fraction 6%, its material is polyether resin；
7. following layer：Above-mentioned tack coat, mass fraction 20% are connected to, its material is polypropylene；
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, electromagnetic wave induction layer, bonding It is fitted and connected together by coating machine coating or abutted equipment between layer, following layer connects through electromagnetic wave device with carrier layer Thermoinduction processing mode is connected, and the carrier layer is selected from PE, PP or PET product.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and make following layer and carry using electromagnetic wave energy by setting electromagnetic wave induction layer and solving The problem of body layer connection, selects the material that adhesive strength reaches professional standard to ensure that the bonding under use state by adhesive linkage Intensity.To being tested according to professional standard according to product manufactured in the present embodiment, as a result find that these products have reached industry The requirement of standard.
Embodiment 14
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make seal gasket, and the seal gasket includes following each Layer：
1. common protective layer：It is externally exposed in environment, mass fraction 8%, its material is polyethylene terephthalate Ester；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 19% are connected to, its material is UV glue；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 15%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 19%, its material is UV glue；
5. electromagnetic wave induction layer：Above-mentioned second tack coat is connected to, mass fraction 8%, its material is tinfoil paper, and it act as Receive electromagnetic energy and produce heat to bond following layer and carrier layer；
6. tack coat：Above-mentioned electromagnetic wave induction layer is connected to, mass fraction 7%, its material is polyurethane；
7. following layer：Above-mentioned tack coat, mass fraction 21% are connected to, its material is polystyrene；
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, electromagnetic wave induction layer, bonding It is fitted and connected together by coating machine coating or abutted equipment between layer, following layer connects through electromagnetic wave device with carrier layer Thermoinduction processing mode is connected, and the carrier layer is selected from PE, PP or PET product.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and make following layer and carry using electromagnetic wave energy by setting electromagnetic wave induction layer and solving The problem of body layer connection, selects the material that adhesive strength reaches professional standard to ensure that the bonding under use state by adhesive linkage Intensity.To being tested according to professional standard according to product manufactured in the present embodiment, as a result find that these products have reached industry The requirement of standard.
Embodiment 15
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make seal gasket, and the seal gasket includes following each Layer：
1. common protective layer：It is externally exposed in environment, mass fraction 6%, its material is makrolon；
2. the first tack coat：Above-mentioned common protective layer, mass fraction 21% are connected to, its material is polyurethane；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 25%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 21%, its material is bonded for acrylic acid Agent；
5. electromagnetic wave induction layer：Above-mentioned second tack coat is connected to, mass fraction 6%, its material is Copper Foil, and it act as Receive electromagnetic energy and produce heat to bond following layer and carrier layer；
6. tack coat：Above-mentioned electromagnetic wave induction layer is connected to, mass fraction 5%, its material is polyether resin；
7. following layer：Above-mentioned tack coat, mass fraction 19% are connected to, its material is polyethylene；
Wherein, common protective layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, electromagnetic wave induction layer, bonding It is fitted and connected together by coating machine coating or abutted equipment between layer, following layer connects through electromagnetic wave device with carrier layer Thermoinduction processing mode is connected, and the carrier layer is selected from PE, PP or PET product.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and make following layer and carry using electromagnetic wave energy by setting electromagnetic wave induction layer and solving The problem of body layer connection, selects the material that adhesive strength reaches professional standard to ensure that the bonding under use state by adhesive linkage Intensity.To being tested according to professional standard according to product manufactured in the present embodiment, as a result find that these products have reached industry The requirement of standard.
Embodiment 16
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3C Product diaphragm, and the 3C Product diaphragm includes Following each layer：
1. enhanced protection layer：It is externally exposed in environment, mass fraction 30%, its material is polyethylene terephthalate Ester, the enhanced protection layer surface does cure process, make it possess it is anti-scratch wipe, the effect of friction resistant；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 10%, its material is polyurethane；
3. 3D three-dimensional imagings layer：Above-mentioned first tack coat is connected to, mass fraction 25%, its material is polymerized for high-molecular optical Thing image forming material acrylic acid；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 5%, its material is polyurethane；
5. carrier layer：Above-mentioned second tack coat, mass fraction 29% are connected to, its material is polyethylene terephthalate Ester；
6. following layer：Above-mentioned carrier layer is connected to, percetage by weight is preferably 1%, and this layer has degassing function, is used for It is pasted on 3C Product screen, its material is pressure sensitive adhesive.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, between carrier layer and following layer It is coated with by coating machine or abutted equipment is fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and enhanced protection layer is set with the extraneous surface for contacting by it, possess it anti-scratch Wipe, the effect of friction resistant.To being tested according to professional standard according to product manufactured in the present embodiment, these products are as a result found The requirement of professional standard is reached.
Embodiment 17
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3C Product diaphragm, and the 3C Product diaphragm includes Following each layer：
1. enhanced protection layer：Without exposure in external environment condition, mass fraction 31%, its material is acryl, the reinforcing Protective layer does cure process, make it possess it is anti-scratch wipe, the effect of friction resistant；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 9%, its material is pressure sensitive adhesive；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 20%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 4%, its material is UV glue；
5. carrier layer：Above-mentioned second tack coat, mass fraction 31% are connected to, its material is polyimides；
6. following layer：Above-mentioned carrier layer is connected to, percetage by weight is preferably 2%, and this layer has degassing function, is used for It is pasted on 3C Product screen, its material is silica gel.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, between carrier layer and following layer It is coated with by coating machine or abutted equipment is fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and enhanced protection layer is set with the extraneous surface for contacting by it, possess it anti-scratch Wipe, the effect of friction resistant.To being tested according to professional standard according to product manufactured in the present embodiment, these products are as a result found The requirement of professional standard is reached.
Embodiment 18
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make 3C Product diaphragm, and the 3C Product diaphragm includes Following each layer：
1. enhanced protection layer：It is externally exposed in environment, mass fraction 30%, its material is polycarbonate composite material, The enhanced protection layer surface does cure process, make it possess it is anti-scratch wipe, the effect of friction resistant；
2. the first tack coat：Above-mentioned enhanced protection layer is connected to, mass fraction 10%, its material is acryloid cement；
3. 3D three-dimensional imagings layer：It is connected to above-mentioned first tack coat, mass fraction 25%；
4. the second tack coat：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 5%, its material is acryloid cement；
5. carrier layer：Above-mentioned second tack coat, mass fraction 30% are connected to, its material is polyimides；
6. following layer：Above-mentioned carrier layer is connected to, percetage by weight is preferably 3%, and this layer has degassing function, is used for It is pasted on 3C Product screen, its material is silica gel.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imagings layer, the second tack coat, between carrier layer and following layer It is coated with by coating machine or abutted equipment is fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and enhanced protection layer is set with the extraneous surface for contacting by it, possess it anti-scratch Wipe, the effect of friction resistant.To being tested according to professional standard according to product manufactured in the present embodiment, these products are as a result found The requirement of professional standard is reached.
Embodiment 19
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make outdoor label, and the outdoor label includes following each Layer：
1. uvioresistant protective layer：It is externally exposed in environment, mass fraction 20%, it is thin that its material is selected from polyvinyl fluoride Film, it is therefore preferable to the Tedlar light films of E.I.Du Pont Company；
2. the first tack coat：Above-mentioned uvioresistant protective layer, mass fraction 7% are connected to, its material is pressure sensitive adhesive；
3. 3D three-dimensional imagings layer：It is connected to first tack coat, mass fraction 20%；
4. ink layer：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 5%, its material is water-based ink；
5. the second tack coat：Above-mentioned ink layer, mass fraction 20% are connected to, its material is pressure sensitive adhesive；
6. carrier layer：Above-mentioned second tack coat, mass fraction 28% are connected to, its material is that surface is release treated to be gathered Carbonic ester.
Wherein, uvioresistant protective layer, the first tack coat, 3D three-dimensional imagings layer, ink layer, the second tack coat, carrier layer Between by coating machine be coated with or abutted equipment be fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and by itself and the extraneous surface setting uvioresistant protective layer for contact, making it can be with Prolonged application has in the environment of a large amount of solar radiations in open air.To being carried out according to professional standard according to product manufactured in the present embodiment Test, as a result finds that these products have reached the requirement of professional standard.
Embodiment 20
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make outdoor label, and the outdoor label includes following each Layer：
1. uvioresistant protective layer：It is externally exposed in environment, mass fraction 19%, it is thin that its material is selected from polyvinyl fluoride Film, it is therefore preferable to the Tedlar light films of E.I.Du Pont Company；
2. the first tack coat：Above-mentioned uvioresistant protective layer, mass fraction 8% are connected to, its material is polyurethane；
3. 3D three-dimensional imagings layer：It is connected to first tack coat, mass fraction 25%；
4. ink layer：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 6%, its material is water-based ink；
5. the second tack coat：Above-mentioned ink layer, mass fraction 21% are connected to, its material is acryloid cement；
6. carrier layer：Above-mentioned second tack coat, mass fraction 27% are connected to, its material is that surface is release treated to be gathered Acid imide.
Wherein, uvioresistant protective layer, the first tack coat, 3D three-dimensional imagings layer, ink layer, the second tack coat, carrier layer Between by coating machine be coated with or abutted equipment be fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and by itself and the extraneous surface setting uvioresistant protective layer for contact, making it can be with Prolonged application has in the environment of a large amount of solar radiations in open air.To being carried out according to professional standard according to product manufactured in the present embodiment Test, as a result finds that these products have reached the requirement of professional standard.
Embodiment 21
The present embodiment is the purposes that 3D three-dimensional imagings film is used to make outdoor label, and the outdoor label includes following each Layer：
1. uvioresistant protective layer：Without exposure in external environment condition, mass fraction 21%, its material is selected from polyvinyl fluoride Film, it is therefore preferable to the Tedlar light films of E.I.Du Pont Company；
2. the first tack coat：Above-mentioned uvioresistant protective layer, mass fraction 6% are connected to, its material is silica gel；
3. 3D three-dimensional imagings layer：It is connected to first tack coat, mass fraction 15%；
4. ink layer：Above-mentioned 3D three-dimensional imagings layer is connected to, mass fraction 4%, its material is water-based ink；
5. the second tack coat：Above-mentioned ink layer, mass fraction 19% are connected to, its material is UV glue；
6. carrier layer：Above-mentioned second tack coat, mass fraction 29% are connected to, its material is that surface is release treated to be gathered Ethylene glycol terephthalate.
Wherein, uvioresistant protective layer, the first tack coat, 3D three-dimensional imagings layer, ink layer, the second tack coat, carrier layer Between by coating machine be coated with or abutted equipment be fitted and connected together.
Because the present embodiment employs not solvent-laden tack coat, so solving 3D three-dimensional imaging films whole well Solvent resistant problem in individual processing procedure, and by itself and the extraneous surface setting uvioresistant protective layer for contact, making it can be with Prolonged application has in the environment of a large amount of solar radiations in open air.To being carried out according to professional standard according to product manufactured in the present embodiment Test, as a result finds that these products have reached the requirement of professional standard.
Several specific embodiments of the invention are these are only, any those skilled in the art is spiritual without prejudice to the present invention On the premise of any equivalent for being done and deformation, within the scope of the present invention.

Claims (1)

1. a kind of 3D three-dimensional imagings film is used to make the purposes of 3C Product diaphragm, it is characterised in that the 3D three-dimensional imagings Film includes：
Protective layer, is made of resin material or its composite；
3D three-dimensional imagings layer, is made of high-molecular optical polymer image forming material；
Carrier layer, is made of resin material；
Wherein, the high-molecular optical polymer image forming material is selected from the one kind or several in acrylic acid, polyurethane, polyester or carbonic ester Kind, the protective layer is enhanced protection layer；Wherein,
The 3C Product diaphragm includes following each layer：
1. enhanced protection layer：Its material is selected from resin material or its composite, and the enhanced protection layer surface does cure process；
2. the first tack coat：The enhanced protection layer is connected to, percetage by weight 9~11%, its material is selected from pressure sensitive adhesive, silicon One or more of glue, UV glue, polyurethane or acryloid cement；
3. 3D three-dimensional imagings layer：It is connected to first tack coat, percetage by weight 20~30%, using high-molecular optical polymer Image forming material is made；
4. the second tack coat：Be connected to 3D three-dimensional imagings layer, percetage by weight 4~6%, its material be selected from silica gel, UV glue, One or more of polyurethane or acryloid cement；
5. carrier layer：It is connected to second tack coat；
6. following layer：It is connected to the carrier layer, the material that this layer of use has degassing function is made.
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Publication number Priority date Publication date Assignee Title
TW575223U (en) * 2002-02-08 2004-02-01 In Chang Technic Print Co Ltd Label for in-mold labeling
CN202306124U (en) * 2011-09-15 2012-07-04 张保平 Transparent multidimensional stereo holographic projection imaging membrane
CN102774047A (en) * 2011-05-12 2012-11-14 中钞特种防伪科技有限公司 Anti-fake film structure of optical window

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US6180228B1 (en) * 1998-03-02 2001-01-30 3M Innovative Properties Company Outdoor advertising system
CN101439603A (en) * 2007-11-20 2009-05-27 健盟印刷企业有限公司 Label for in-mold labeling and article with the label

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW575223U (en) * 2002-02-08 2004-02-01 In Chang Technic Print Co Ltd Label for in-mold labeling
CN102774047A (en) * 2011-05-12 2012-11-14 中钞特种防伪科技有限公司 Anti-fake film structure of optical window
CN202306124U (en) * 2011-09-15 2012-07-04 张保平 Transparent multidimensional stereo holographic projection imaging membrane

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