CN105252858A - 3D imaging film and application thereof - Google Patents

3D imaging film and application thereof Download PDF

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Publication number
CN105252858A
CN105252858A CN201510655049.5A CN201510655049A CN105252858A CN 105252858 A CN105252858 A CN 105252858A CN 201510655049 A CN201510655049 A CN 201510655049A CN 105252858 A CN105252858 A CN 105252858A
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China
Prior art keywords
layer
tack coat
dimensional imaging
mass fraction
mentioned
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CN201510655049.5A
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Chinese (zh)
Inventor
吕晓义
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SHANGHAI BEIXIANG CHEMICAL ENGINEERING Co Ltd
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SHANGHAI BEIXIANG CHEMICAL ENGINEERING Co Ltd
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Publication of CN105252858A publication Critical patent/CN105252858A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/12—Polyvinylhalogenides containing fluorine
    • B32B2327/18—PTFE, i.e. polytetrafluoroethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2355/00—Specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of index codes B32B2323/00 - B32B2333/00
    • B32B2355/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2369/00—Polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2379/00—Other polymers having nitrogen, with or without oxygen or carbon only, in the main chain
    • B32B2379/08—Polyimides

Abstract

The invention discloses a 3D imaging film. The 3D imaging film comprises a protective layer, a 3D imaging layer and a carrier layer. The protective layer is made from resin materials or composite materials of the resin materials; the 3D imaging layer is made from macromolecule photopolymer imaging materials or silver salt materials; the carrier layer is made from resin materials; one plane of the 3D imaging layer is connected with the protective layer through a first adhering layer, another plane of the 3D imaging layer is connected with the carrier layer through a second adhering layer, and the first adhering layer and the second adhering layer are made from adhering agents without solvents. Due to the arrangement and selection of the first adhering layer and the second adhering layer, the problem that the 3D imaging layer is not resistant to solvents in the processes of in-mold injection molding, in-mold blow molding, 3D card manufacturing, sealing gasket manufacturing, 3C product protective film manufacturing and outdoor label manufacturing is solved, the 3D imaging layer can effectively adhere to different plastic materials instantly under high temperature and high pressure, and the problem that the 3D imaging layer is not resistant to high temperature is solved due to the arrangement of a heat insulating and resisting layer.

Description

A kind of 3D three-dimensional imaging film and application thereof
The application is submission on December 24th, 2012, application number is 201210566161.8, denomination of invention is: the divisional application of the Chinese invention patent application of " a kind of 3D three-dimensional imaging film and application thereof ".
Technical field
The present invention relates to a kind of 3D three-dimensional imaging film and application thereof.
Background technology
So-called high-molecular optical polymer image forming material, a kind of on very thin planar materials, the material of the 3D three-dimensional image effect having the degree of depth can be shown, it is mainly used on the field of antifalsification label at present, but level phenomenon can be formed with affixed object in use, there is the as easy as rolling off a log shortcoming be lifted.And it is directly applied in the manufacture process in the field such as blowing, fabrication in in-mould injection, mould manufacture with the integrated stereo-picture of product identify time, then can run into the not solvent-proof problem of high-molecular optical polymer image forming material in whole processing procedure, and in some processing procedure, need the high temperature and high pressure problem of resistance to about 270 DEG C, and need instantaneously under elevated temperature and pressure conditions to bond from different plastic material and adhesive strength need reach the problem of professional standard.In addition, also there are these problems in the silver salt material for imaging.At present for these problems, the solution that there is no.
Summary of the invention
The object of this invention is to provide a kind of 3D three-dimensional imaging film, to solve in prior art, high-molecular optical polymer image forming material is directly applied in the manufacture process in the field such as blowing, fabrication in in-mould injection, mould, the not solvent-proof problem of high-molecular optical polymer image forming material in whole processing procedure run into, and need the high temperature and high pressure problem of resistance to about 270 DEG C, and need instantaneously under elevated temperature and pressure conditions to bond from different plastic material and adhesive strength need reach the problem of professional standard.The present invention also provides the purposes of above-mentioned 3D three-dimensional imaging film inflation film, 3D Antiforge card, seal gasket, 3C Product diaphragm and outdoor label in making in-mould injection film, mould.
Technical scheme of the present invention is as follows:
A kind of 3D three-dimensional imaging film, it comprises:
Protective layer, adopts resin material or its composite to make; Usual protective layer contacts with external environment, certainly also can arrange the layer of other types thereon, make its not with extraneous contact;
3D three-dimensional imaging layer, adopts high-molecular optical polymer image forming material or silver salt material to make;
Carrier layer, adopts resin material to make; The selection of carrier layer does not limit, any suitable resin material can be selected as required with actual conditions, such as ABS, PC, PET, PE, PP, and there is the resin material of various property, such as surperficial release PETG, polyimides or the Merlon etc. processed through process;
One plane of described 3D three-dimensional imaging layer is connected with described protective layer by the first tack coat; another plane of described 3D three-dimensional imaging layer is connected with described carrier layer by the second tack coat, and the material of described first tack coat and the second tack coat is not solvent-laden adhesive.
Preferably, the material of described first tack coat and the second tack coat is selected from one or more in silica gel, UV glue, polyurethane or acryloid cement, those adhesives are not containing solvent, and caking property is good, can meet the requirement of 3D three-dimensional imaging film about adhesion strength.
Preferably, the high-molecular optical polymer image forming material of described 3D three-dimensional imaging layer is selected from one or more in acrylic acid, polyurethane, polyester or carbonic ester, the silver salt material of described 3D three-dimensional imaging layer be selected from silver bromide or silver iodide one or both, the 3D three-dimensional imaging layer be made up of these materials has good 3D rendering effect.
Preferably, described protective layer is selected from common protective layer, enhanced protection layer or uvioresistant protective layer, wherein
The material of described common protective layer is selected from one or more of PETG, polyimides or Merlon;
Wherein one or more the composite of the group that the material of described enhanced protection layer is selected from PETG, acryl, Merlon are formed, and cure process is done on the surface of described enhanced protection layer;
The matrix material of described uvioresistant protective layer is selected from one or more of Merlon, polytetrafluoroethylene (PTFE) or PETG.The selection of protective layer can be carried out according to the actual needs of product, also can select the existing or conventional protective layer with various different defencive function except above-mentioned several protective layer.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for in-mould injection film, and this in-mould injection film comprises following each layer:
1. enhanced protection layer: cure process is done on described enhanced protection layer surface, its percetage by weight is determined according to common method in the industry, and be preferably 17 ~ 19%, its material is selected from resin material or its composite, can preferably from wherein one or more the composite of the group that PETG, acryl, Merlon are formed;
2. the first tack coat: be connected to described enhanced protection layer, percetage by weight 7 ~ 17%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 6 ~ 16%, adopts high-molecular optical polymer image forming material or silver salt material to make;
4. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 10 ~ 14%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
5. heat insulation heat-resistant layer: be connected to described second tack coat, percetage by weight 35 ~ 41%, its material is selected from one or more of polyimides, PETG or Merlon;
6. articulamentum: be connected to described heat insulation heat-resistant layer, percetage by weight 5 ~ 9%, its material is selected from one or more of special I MF ink or chlorinated polypropylene compound oil ink;
7. following layer: be connected to described articulamentum, percetage by weight 1 ~ 3%, its material is selected from one or more of special I MF PUR, EVA hot-melt adhesive or polyurethane PUR;
Described following layer is connected with carrier layer.Carrier layer adopts resin material to make; The Material selec-tion of carrier layer does not limit, and can select any suitable resin material as required, such as ABS, PC, PET, PE, PP etc. with actual conditions.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for inflation film in mould, and in this mould, inflation film comprises following each layer:
1. common protective layer: its percetage by weight is determined according to common method in the industry, and be preferably 9 ~ 11%, its material is selected from resin material or its composite, and can preferably from one or more of PETG, polyimides or Merlon;
2. the first tack coat: be connected to described common protective layer, percetage by weight 19 ~ 21%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 13 ~ 23%, adopts high-molecular optical polymer image forming material or silver salt material to make;
4. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 19 ~ 21%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
5. heat insulation heat-resistant layer: be connected to described second tack coat, percetage by weight 12 ~ 16%, its material is selected from one or more of PETG, polyimides or Merlon;
6. tack coat: be connected to described heat insulation heat-resistant layer, its percetage by weight is determined according to common method in the industry, and is preferably 1 ~ 3%, and its material can preferably from one or more of polyurethane or polyether resin;
7. following layer: be connected to described tack coat, its percetage by weight is determined according to common method in the industry, and is preferably 5 ~ 7%, and its material can preferred one or more in polyethylene, polystyrene or acrylic resin system free;
Described following layer is connected with carrier layer, and carrier layer adopts resin material to make; The Material selec-tion of carrier layer does not limit, and can select any suitable resin material as required, such as ABS, PC, PET, PE, PP etc. with actual conditions.The thickness of described common protective layer, tack coat and following layer or weight fraction arrange according to conventional method in the industry and choose.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for 3D card, and this 3D card comprises following each layer:
1. the first following layer: be connected to the first carrier layer, its percetage by weight is determined according to common method in the industry, and is preferably 9 ~ 11%, and its material can preferably from one or more of Corvic, polypropylene or polystyrene resin;
2. tack coat one: be connected to described first following layer, its percetage by weight is determined according to common method in the industry, and is preferably 9 ~ 11%, and its material can preferably from one or more of polyurethane or polyether resin;
3. common protective layer: be connected to described tack coat one, its percetage by weight is determined according to common method in the industry, and being preferably 9 ~ 11%, its material is selected from resin material or its composite, and can preferably from one or more of PETG, polyimides or Merlon;
4. the first tack coat: be connected to described common protective layer, percetage by weight 19 ~ 21%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
5. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 12 ~ 22%, adopts high-molecular optical polymer image forming material or silver salt material to make;
6. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 19 ~ 21%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
7. heat insulation heat-resistant layer: be connected to described second tack coat, percetage by weight 11 ~ 15%, its material is selected from one or more of PETG, polyimides or Merlon;
8. tack coat two: be connected to described heat insulation heat-resistant layer, its percetage by weight is determined according to common method in the industry, and is preferably 1 ~ 3%, and its material can preferably from one or more of polyurethane or polyether resin;
9. the second following layer: be connected to described tack coat two, its percetage by weight is determined according to common method in the industry, and is preferably 5 ~ 7%, and its material can preferably from one or more of Corvic, polypropylene or polystyrene resin;
Described second following layer is connected with Second support layer, and described first carrier layer and Second support layer adopt resin material to make; The Material selec-tion of carrier layer does not limit, and can select any suitable resin material as required, such as ABS, PC, PET, PE, PP etc. with actual conditions.The thickness of described first following layer, adhesive linkage one, common protective layer, tack coat two and the second following layer or weight fraction arrange according to conventional method in the industry and choose.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for seal gasket, and this seal gasket comprises following each layer:
1. common protective layer: its percetage by weight is determined according to common method in the industry, and be preferably 6 ~ 8%, its material is selected from resin material or its composite, and can preferably from one or more of PETG, polyimides or Merlon;
2. the first tack coat: be connected to described common protective layer, percetage by weight 19 ~ 21%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 15 ~ 25%, adopts high-molecular optical polymer image forming material or silver salt material to make;
4. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 19 ~ 21%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
5. electromagnetic wave induction layer: be connected to described second tack coat, its percetage by weight is determined according to common method in the industry, and is preferably 6 ~ 8%, and its material can preferably from one or more of aluminium foil, tinfoil paper or Copper Foil;
6. tack coat: be connected to described electromagnetic wave induction layer, its percetage by weight is determined according to common method in the industry, and is preferably 5 ~ 7%, and its material can preferably from one or more of polyurethane or polyether resin;
7. following layer: be connected to described tack coat, its percetage by weight is determined according to common method in the industry, and is preferably 19 ~ 21%, and its material can one or more preferably in polyethylene, polystyrene or acrylic resin system;
Described following layer is connected with carrier layer, and described carrier layer adopts resin material to make; The Material selec-tion of carrier layer does not limit, and can select any suitable resin material as required, such as ABS, PC, PET, PE, PP etc. with actual conditions.The thickness of described common protective layer, electromagnetic wave induction layer, tack coat and following layer or weight fraction arrange according to conventional method in the industry and choose.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for 3C Product diaphragm, and this 3C Product diaphragm comprises following each layer:
1. enhanced protection layer: cure process is done on described enhanced protection layer surface, its percetage by weight is determined according to common method in the industry, and be preferably 29 ~ 31%, its material is selected from resin material or its composite, and can preferably from wherein one or more the composite of the group that PETG, acryl, Merlon are formed;
2. the first tack coat: be connected to described enhanced protection layer, percetage by weight 9 ~ 11%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 20 ~ 30%, adopts high-molecular optical polymer image forming material or silver salt material to make;
4. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 4 ~ 6%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
5. carrier layer: be connected to described second tack coat, its percetage by weight is determined according to common method in the industry, and is preferably 29 ~ 31%, and its material can preferably from one or more of PETG, polyimides or Merlon;
6. following layer: be connected to described carrier layer, percetage by weight can be preferably 1 ~ 3%, and this layer has degassing function, and its material can preferably from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement.The thickness of described enhanced protection layer, carrier layer, following layer or weight fraction all can arrange according to conventional method in the industry and choose.
Above-mentioned 3D three-dimensional imaging film is for making a purposes for outdoor label, and this outdoor label comprises following each layer:
1. uvioresistant protective layer: its percetage by weight is determined according to common method in the industry, and be preferably 19 ~ 21%, its material is selected from the resin material or its composite with anti-ultraviolet function, and its matrix material can one or more of preferably self-polycarbonate, polytetrafluoroethylene (PTFE), polyvinyl fluoride or PETG;
2. the first tack coat: be connected to described uvioresistant protective layer, percetage by weight 6 ~ 8%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 15 ~ 25%, adopts high-molecular optical polymer image forming material or silver salt material to make;
4. ink layer: be connected to described 3D three-dimensional imaging layer, percetage by weight 4 ~ 6%, its material is selected from water color ink;
5. the second tack coat: be connected to described ink layer, percetage by weight 19 ~ 21%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
6. carrier layer: be connected to described second tack coat, its percetage by weight is determined according to common method in the industry, and be preferably 27 ~ 29%, its material can preferably from surface release PETG, polyimides or the Merlon processed one or more.The thickness of described uvioresistant protective layer, carrier layer or weight fraction can arrange according to conventional method in the industry and choose.
Compared with prior art, beneficial effect of the present invention is as follows:
First, the present invention is by arranging the up and down tack coat bonding with 3D three-dimensional imaging layer, i.e. the first tack coat and the second tack coat, and by select silica gel, UV glue, polyurethane or acryloid cement etc. containing the adhesive of solvent composition as the material of the first tack coat and the second tack coat, successfully solve high-molecular optical polymer image forming material or the not solvent-proof problem of silver salt material;
The second, in in-mould injection film, mould inflation film and 3D Antiforge card making in, the heat insulation heat-resistant layer that the exotic materials such as use polyimides, PETG or Merlon are made, as main thermal insulation layer, solves the problem of the high temperature and high pressure of not resistance to about 270 DEG C of high-molecular optical polymer image forming material;
Three, in the making of in-mould injection film, be selected from articulamentum that special I MF ink or chlorinated polypropylene compound oil ink etc. make and be selected from following layer that special I MF PUR, EVA hot-melt adhesive or polyurethane PUR etc. make as buffering cooling layer, solve the problem of the high temperature and high pressure of not resistance to about 270 DEG C of high-molecular optical polymer image forming material further;
Four, in the making of in-mould injection film, use and be selected from the special adhesives such as special I MF PUR, EVA hot-melt adhesive or polyurethane PUR or plastic film solve as following layer the problem that high-molecular optical polymeric material can need to bond from different plastic material at high temperature and pressure instantaneously simultaneously;
Five, the expansion of the application of high-molecular optical polymer image forming material successfully extends on the industry fields such as IMF (in-mould injection), IML (in mould blowing), fabrication, seal gasket, the diaphragm of 3C Product, outdoor label use by the present invention.
Certainly, implement arbitrary product of the present invention might not need to reach above-described all advantages simultaneously.
Accompanying drawing explanation
Fig. 1 is each Rotating fields schematic diagram of 3D three-dimensional imaging film of embodiment of the present invention 1-3.
Detailed description of the invention
See Fig. 1,3D three-dimensional imaging film of the present invention comprises:
Protective layer 1, adopts resin material or its composite to make;
3D three-dimensional imaging layer 3, adopts high-molecular optical polymer image forming material or silver salt material to make;
Carrier layer 5, adopts resin material to make;
One plane of 3D three-dimensional imaging layer 3 is connected with protective layer 1 by the first tack coat 2, and another plane of 3D three-dimensional imaging layer 3 is connected with carrier layer 5 by the second tack coat 4, and the material of the first tack coat 2 and the second tack coat 4 is not solvent-laden adhesive.
Wherein, protective layer 1 can be selected as required, more preferably can select common protective layer, enhanced protection layer or uvioresistant protective layer, wherein
Common protective layer used in insulation blocking under normal circumstances, its material can select any suitable resin material, such as, be selected from PETG, polyimides or Merlon;
Enhanced protection layer is for needing the insulation blocking that scratch-resistant, hardness are higher, its material can select any suitable resin material, such as be selected from PETG, wherein one or more the composite of group that acryl, Merlon are formed, and cure process is done on the surface of described enhanced protection layer, make it possess anti-scratchly to wipe, the effect of friction resistant;
Uvioresistant is protective layer used resists ultraviolet insulation blocking in needs; such as often be exposed to the product under outdoor daylight; its matrix material can select any suitable resin material, such as, be selected from Merlon, polytetrafluoroethylene (PTFE) or PETG.
The material of the first tack coat 2 and the second tack coat 4 is not solvent-laden adhesive, can one or more preferably in silica gel, UV glue, polyurethane or acryloid cement.
The high-molecular optical polymer image forming material that 3D three-dimensional imaging layer 3 adopts can be selected from all suitable macromolecule image forming materials in the industry, one or more preferably in acrylic acid, polyurethane, polyester or carbonic ester, one or both preferably in silver bromide or silver iodide of the silver salt material that 3D three-dimensional imaging layer 3 adopts.
In addition, according to actual needs, such as can also need high temperature high voltage resistant etc., heat insulation heat-resistant layer is set between the second tack coat 4 and carrier layer 5; Need Electromagnetic Heating, then electromagnetic induction layer is set between the second tack coat 4 and carrier layer 5; And when needing abundant image, between 3D three-dimensional imaging layer 3 and the second tack coat 4, patterned layer can be set, such as ink design layer.
Mass fraction above shared by each layer, those skilled in the art can carry out arranging and adjusting according to its practical situations.
3D three-dimensional imaging film of the present invention can be used for anti-counterfeit field, also can be used for 3D film applications, can produce the product with 3D rendering true to nature.
Below in conjunction with specific embodiment, set forth the present invention further.Should be appreciated that, these embodiments only for illustration of the present invention, and are not intended to limit the scope of the invention.The improvement made according to the present invention of those skilled in the art and adjustment, still belong to protection scope of the present invention in actual applications.
Embodiment 1
The 3D three-dimensional imaging film of the present embodiment comprises:
Common protective layer, adopts PETG to make;
3D three-dimensional imaging layer, adopt high-molecular optical polymer image forming material to make, high-molecular optical polymer imaging matrix material is acrylic acid;
Carrier layer, adopts PP to make;
One plane of 3D three-dimensional imaging layer is connected with common protective layer by the first tack coat, and another plane of 3D three-dimensional imaging layer is connected with carrier layer by the second tack coat, and the material of the first tack coat and the second tack coat is silica gel.
Embodiment 2
The 3D three-dimensional imaging film of the present embodiment comprises:
Enhanced protection layer, adopts PETG to make, cure process is done on the surface of this enhanced protection layer, makes it possess anti-scratchly to wipe, the effect of friction resistant;
3D three-dimensional imaging layer, adopt high-molecular optical polymer image forming material to make, high-molecular optical polymer image forming material is carbonic ester;
Carrier layer, adopts PC to make;
One plane of 3D three-dimensional imaging layer is connected with enhanced protection layer by the first tack coat, and another plane of 3D three-dimensional imaging layer is connected with carrier layer by the second tack coat, and the material of the first tack coat and the second tack coat is UV glue.
Embodiment 3
The 3D three-dimensional imaging film of the present embodiment comprises:
Uvioresistant protective layer, its matrix adopts polytetrafluoroethylene (PTFE) to make;
3D three-dimensional imaging layer, adopts silver bromide to make;
Carrier layer, adopts PC to make;
One plane of 3D three-dimensional imaging layer is connected with enhanced protection layer by the first tack coat, and another plane of 3D three-dimensional imaging layer is connected with carrier layer by the second tack coat, and the material of the first tack coat and the second tack coat is polyurethane.
Above, because the first tack coat of the embodiment of the present invention and the second tack coat have employed not solvent-laden adhesive, so fundamentally solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure.
In following examples 4-21, E.I.Du Pont Company all selected by the material of 3D three-dimensional imaging layer product.
Embodiment 4
The present embodiment be 3D three-dimensional imaging film for making the purposes of in-mould injection film, this in-mould injection film comprises following each layer:
1. enhanced protection layer: be exposed in external environment condition, mass fraction 18%, its material is the composite of PETG, acryl, Merlon, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 12%, its material is silica gel;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 11%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 12%, its material is silica gel;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 38%, its material is polyimides;
6. articulamentum: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 7%, its material is special I MF ink;
7. following layer: be connected to above-mentioned articulamentum, mass fraction 2%, its material is special I MF PUR;
Wherein, combination between enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, articulamentum, following layer is coating machine coating or abutted equipment laminating; following layer is connected by injection machine injection moulding with carrier layer, and this carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment have employed not solvent-laden first tack coat and the second tack coat, so well solve 3D three-dimensional imaging film not solvent resistant problem in whole processing procedure, and owing to have employed resistant to elevated temperatures polyimides as heat insulation heat-resistant layer and the buffering cooling effect adopting the articulamentum of special I MF ink and the following layer of special I MF PUR, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional, resulting product clear patterns, appearance profile are complete, do not have depredation; And reach moment under elevated temperature and pressure conditions by the special I MF PUR of selecting adhesion strength to reach industry requirement standard as following layer and to bond from different plastic material and adhesive strength reaches the object of professional standard.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 5
The present embodiment be 3D three-dimensional imaging film for making the purposes of in-mould injection film, this in-mould injection film comprises following each layer:
1. enhanced protection layer: be exposed in external environment condition, mass fraction 20%, its material is PETG composite, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 7%, its material is UV glue;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 16%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 10%, its material is UV glue;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 41%, its material is PETG;
6. articulamentum: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 5%, its material is chlorinated polypropylene compound oil ink;
7. following layer: be connected to above-mentioned articulamentum, mass fraction 1%, its material is EVA hot-melt adhesive;
Described following layer is connected with carrier layer.
Wherein, combination between enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, articulamentum, following layer is coating machine coating or abutted equipment laminating; following layer is connected by injection machine injection moulding with carrier layer, and this carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment have employed not solvent-laden first tack coat and the second tack coat, so well solve 3D three-dimensional imaging film not solvent resistant problem in whole processing procedure, and owing to have employed resistant to elevated temperatures PETG as heat insulation heat-resistant layer and the buffering cooling effect adopting the articulamentum of chlorinated polypropylene compound oil ink and the following layer of EVA hot-melt adhesive, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional, resulting product clear patterns, appearance profile are complete, do not have depredation; And reach moment under elevated temperature and pressure conditions by the EVA hot-melt adhesive of selecting adhesion strength to reach industry requirement standard as following layer and to bond from different plastic material and adhesive strength reaches the object of professional standard.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 6
The present embodiment be 3D three-dimensional imaging film for making the purposes of in-mould injection film, this in-mould injection film comprises following each layer:
1. enhanced protection layer: be not exposed in external environment condition, mass fraction 16%, its material is acryl, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 17%, its material is polyurethane;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 6%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 14%, its material is acryloid cement;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 35%, its material is Merlon;
6. articulamentum: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 9%, its material is special I MF ink;
7. following layer: be connected to above-mentioned articulamentum mass fraction 3%, its material is polyurethane PUR;
Described following layer is connected with carrier layer.
Wherein, combination between enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, articulamentum, following layer is coating machine coating or abutted equipment laminating; following layer is connected by injection machine injection moulding with carrier layer, and this carrier layer can be the plastic products such as ABS, PC or PET.
Because the present embodiment have employed not solvent-laden first tack coat and the second tack coat, so well solve 3D three-dimensional imaging film not solvent resistant problem in whole processing procedure, and owing to have employed resistant to elevated temperatures Merlon as heat insulation heat-resistant layer and the buffering cooling effect adopting the articulamentum of special I MF ink and the following layer of polyurethane PUR, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional, resulting product clear patterns, appearance profile are complete, do not have depredation; And reach moment under elevated temperature and pressure conditions by the polyurethane PUR of selecting adhesion strength to reach industry requirement standard as following layer and to bond from different plastic material and adhesive strength reaches the object of professional standard.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 7
The present embodiment be 3D three-dimensional imaging film for making the purposes of inflation film in mould, in this mould, inflation film comprises following each layer:
1. common protective layer: be exposed in external environment condition, mass fraction 10%, its material is PETG;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 20%, its material is UV glue;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 18%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 20%, its material is pressure sensitive adhesive;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 14%, its material is polyimides;
6. tack coat: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 2%, its material is polyether resin;
7. following layer: be connected to above-mentioned tack coat, mass fraction 6%, its material is polyethylene;
Described following layer is connected with carrier layer.
Wherein, combination between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, tack coat, following layer is coating machine coating or abutted equipment laminating; following layer is connected by in-mold injection molding machine injection moulding with carrier layer, and this carrier layer can be PE, PP or PET product.
Because the present embodiment have employed not solvent-laden first tack coat and the second tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures polyimides as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 8
The present embodiment be 3D three-dimensional imaging film for making the purposes of inflation film in mould, in this mould, inflation film comprises following each layer:
1. common protective layer: be not exposed in external environment condition, mass fraction 11%, its material is polyimides;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 19%, its material is polyurethane;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 13%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 19%, its material is acryloid cement;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 16%, its material is Merlon;
6. tack coat: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 3%, its material is polyurethane;
7. following layer: be connected to above-mentioned tack coat, mass fraction 7%, its material is polystyrene;
Described following layer is connected with carrier layer.
Wherein, combination between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, tack coat, following layer is coating machine coating or abutted equipment laminating; following layer is connected by in-mold injection molding machine injection moulding with carrier layer, and this carrier layer can be PE, PP or PET product.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures Merlon as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 9
The present embodiment be 3D three-dimensional imaging film for making the purposes of inflation film in mould, in this mould, inflation film comprises following each layer:
1. common protective layer: be exposed in external environment condition, mass fraction 9%, its material is Merlon;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 21%, its material is acryloid cement;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 23%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 21%, its material is silica gel;
5. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 12%, its material is Merlon;
6. tack coat: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 1%, its material is polyurethane;
7. following layer: be connected to above-mentioned tack coat, mass fraction 5%, its material is polypropylene;
Described following layer is connected with carrier layer.
Wherein, combination between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer, tack coat, following layer is coating machine coating or abutted equipment laminating; following layer is connected by in-mold injection molding machine injection moulding with carrier layer, and this carrier layer can be PE, PP or PET product.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures polyimides as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 10
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3D card, this 3D card comprises following each layer:
1. the first following layer: be connected to the first carrier layer, mass fraction 10%, its material is Corvic;
2. tack coat one: be connected to above-mentioned first following layer, mass fraction 2%, its material is polyurethane;
3. common protective layer: be connected to above-mentioned tack coat one, mass fraction 10%, its material is PETG;
4. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 20%, its material is acryloid cement;
5. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 17%;
6. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 20%, its material is silica gel;
7. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 13%, its material is Merlon;
8. tack coat two: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 2%, its material is polyurethane;
9. the second following layer: be connected to above-mentioned tack coat two, mass fraction 6%, its material is polystyrene resin; Above-mentioned second following layer is connected with Second support layer, and above-mentioned first carrier layer and Second support layer adopt resin material to make; The material of the first carrier layer and Second support layer can select ABS, PC, PET, PE, PP etc.
Wherein, linked together by hot press pressure-bearing mode between first following layer, tack coat one, common protective layer; to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer or abutted equipment is fitted and connected together, to be linked together by hot press pressure-bearing mode between heat insulation heat-resistant layer, tack coat two, second following layer.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures Merlon as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 11
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3D card, this 3D card comprises following each layer:
1. the first following layer: be connected to the first carrier layer, mass fraction 11%, its material is polypropylene;
2. tack coat one: be connected to above-mentioned first following layer, mass fraction 2%, its material is polyether resin;
3. common protective layer: be connected to above-mentioned tack coat one, mass fraction 11%, its material is polyimides;
4. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 19%, its material is UV glue;
5. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 12%;
6. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 19%, its material is silica gel;
7. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 11%, its material is PETG;
8. tack coat two: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 3%, its material is polyether resin;
9. the second following layer: be connected to above-mentioned tack coat two, mass fraction 7%, its material is Corvic; Above-mentioned second following layer is connected with Second support layer, and above-mentioned first carrier layer and Second support layer adopt resin material to make; The material of the first carrier layer and Second support layer can select ABS, PC, PET, PE, PP etc.
Wherein, linked together by hot press pressure-bearing mode between first following layer, tack coat one, common protective layer; to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer or abutted equipment is fitted and connected together, to be linked together by hot press pressure-bearing mode between heat insulation heat-resistant layer, tack coat two, second following layer.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures PETG as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 12
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3D card, this 3D card comprises following each layer:
1. the first following layer: be connected to the first carrier layer, mass fraction 9%, its material is polystyrene resin;
2. tack coat one: be connected to above-mentioned first following layer, mass fraction 2%, its material is polyurethane;
3. common protective layer: be connected to above-mentioned tack coat one, mass fraction 9%, its material is Merlon;
4. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 21%, its material is polyurethane;
5. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 22%;
6. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 21%, its material is pressure sensitive adhesive;
7. heat insulation heat-resistant layer: be connected to above-mentioned second tack coat, mass fraction 15%, its material is PETG;
8. tack coat two: be connected to above-mentioned heat insulation heat-resistant layer, mass fraction 1%, its material is polyether resin;
9. the second following layer: be connected to above-mentioned tack coat two, mass fraction 5%, its material is polypropylene;
Above-mentioned second following layer is connected with Second support layer, and above-mentioned first carrier layer and Second support layer adopt resin material to make; The material of the first carrier layer and Second support layer can select ABS, PC, PET, PE, PP etc.
Wherein, linked together by hot press pressure-bearing mode between first following layer, tack coat one, common protective layer; to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, heat insulation heat-resistant layer or abutted equipment is fitted and connected together, to be linked together by hot press pressure-bearing mode between heat insulation heat-resistant layer, tack coat two, second following layer.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and owing to have employed resistant to elevated temperatures Merlon as heat insulation heat-resistant layer, the in-mould injection film of the present embodiment high temperature and high pressure of resistance to about 270 DEG C in whole processing procedure is functional.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 13
The present embodiment be 3D three-dimensional imaging film for making the purposes of seal gasket, this seal gasket comprises following each layer:
1. common protective layer: be not exposed in external environment condition, mass fraction 7%, its material is polyimides;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 20%, its material is silica gel;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 20%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 20%, its material is silica gel;
5. electromagnetic wave induction layer: be connected to above-mentioned second tack coat, mass fraction 7%, its material is aluminium foil, and it act as and accepts electromagnetic energy generation heat with following layer and the carrier layer of boning;
6. tack coat: be connected to above-mentioned electromagnetic wave induction layer, mass fraction 6%, its material is polyether resin;
7. following layer: be connected to above-mentioned tack coat, mass fraction 20%, its material is polypropylene;
Wherein, to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, electromagnetic wave induction layer, tack coat or abutted equipment is fitted and connected together; following layer is connected with carrier layer and is connected by electromagnetic wave device thermoinduction processing mode, and this carrier layer is selected from PE, PP or PET product.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and solving by arranging electromagnetic wave induction layer the problem utilizing electromagnetic wave energy to make following layer to be connected with carrier layer, the material selecting adhesive strength to reach professional standard by adhesive linkage ensure that the adhesion strength under using state.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 14
The present embodiment be 3D three-dimensional imaging film for making the purposes of seal gasket, this seal gasket comprises following each layer:
1. common protective layer: be exposed in external environment condition, mass fraction 8%, its material is PETG;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 19%, its material is UV glue;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 15%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 19%, its material is UV glue;
5. electromagnetic wave induction layer: be connected to above-mentioned second tack coat, mass fraction 8%, its material is tinfoil paper, and it act as and accepts electromagnetic energy generation heat with following layer and the carrier layer of boning;
6. tack coat: be connected to above-mentioned electromagnetic wave induction layer, mass fraction 7%, its material is polyurethane;
7. following layer: be connected to above-mentioned tack coat, mass fraction 21%, its material is polystyrene;
Wherein, to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, electromagnetic wave induction layer, tack coat or abutted equipment is fitted and connected together; following layer is connected with carrier layer and is connected by electromagnetic wave device thermoinduction processing mode, and this carrier layer is selected from PE, PP or PET product.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and solving by arranging electromagnetic wave induction layer the problem utilizing electromagnetic wave energy to make following layer to be connected with carrier layer, the material selecting adhesive strength to reach professional standard by adhesive linkage ensure that the adhesion strength under using state.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 15
The present embodiment be 3D three-dimensional imaging film for making the purposes of seal gasket, this seal gasket comprises following each layer:
1. common protective layer: be exposed in external environment condition, mass fraction 6%, its material is Merlon;
2. the first tack coat: be connected to above-mentioned common protective layer, mass fraction 21%, its material is polyurethane;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 25%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 21%, its material is acryloid cement;
5. electromagnetic wave induction layer: be connected to above-mentioned second tack coat, mass fraction 6%, its material is Copper Foil, and it act as and accepts electromagnetic energy generation heat with following layer and the carrier layer of boning;
6. tack coat: be connected to above-mentioned electromagnetic wave induction layer, mass fraction 5%, its material is polyether resin;
7. following layer: be connected to above-mentioned tack coat, mass fraction 19%, its material is polyethylene;
Wherein, to be coated with by coating machine between common protective layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, electromagnetic wave induction layer, tack coat or abutted equipment is fitted and connected together; following layer is connected with carrier layer and is connected by electromagnetic wave device thermoinduction processing mode, and this carrier layer is selected from PE, PP or PET product.
Because the present embodiment have employed not solvent-laden tack coat, so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure, and solving by arranging electromagnetic wave induction layer the problem utilizing electromagnetic wave energy to make following layer to be connected with carrier layer, the material selecting adhesive strength to reach professional standard by adhesive linkage ensure that the adhesion strength under using state.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 16
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3C Product diaphragm, this 3C Product diaphragm comprises following each layer:
1. enhanced protection layer: be exposed in external environment condition, mass fraction 30%, its material is PETG, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 10%, its material is polyurethane;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 25%, its material is high-molecular optical polymer image forming material acrylic acid;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 5%, its material is polyurethane;
5. carrier layer: be connected to above-mentioned second tack coat, mass fraction 29%, its material is PETG;
6. following layer: be connected to above-mentioned carrier layer, percetage by weight can be preferably 1%, and this layer has degassing function, and for being pasted on 3C Product screen, its material is pressure sensitive adhesive.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, to be coated with by coating machine between carrier layer and following layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging enhanced protection layer on the surface of itself and extraneous contact, make it possess anti-scratchly to wipe, the effect of friction resistant.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 17
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3C Product diaphragm, this 3C Product diaphragm comprises following each layer:
1. enhanced protection layer: be not exposed in external environment condition, mass fraction 31%, its material is acryl, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 9%, its material is pressure sensitive adhesive;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 20%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 4%, its material is UV glue;
5. carrier layer: be connected to above-mentioned second tack coat, mass fraction 31%, its material is polyimides;
6. following layer: be connected to above-mentioned carrier layer, percetage by weight can be preferably 2%, and this layer has degassing function, and for being pasted on 3C Product screen, its material is silica gel.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, to be coated with by coating machine between carrier layer and following layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging enhanced protection layer on the surface of itself and extraneous contact, make it possess anti-scratchly to wipe, the effect of friction resistant.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 18
The present embodiment be 3D three-dimensional imaging film for making the purposes of 3C Product diaphragm, this 3C Product diaphragm comprises following each layer:
1. enhanced protection layer: be exposed in external environment condition, mass fraction 30%, its material is polycarbonate composite material, and cure process is done on this enhanced protection layer surface, makes it possess anti-scratchly to wipe, the effect of friction resistant;
2. the first tack coat: be connected to above-mentioned enhanced protection layer, mass fraction 10%, its material is acryloid cement;
3. 3D three-dimensional imaging layer: be connected to above-mentioned first tack coat, mass fraction 25%;
4. the second tack coat: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 5%, its material is acryloid cement;
5. carrier layer: be connected to above-mentioned second tack coat, mass fraction 30%, its material is polyimides;
6. following layer: be connected to above-mentioned carrier layer, percetage by weight can be preferably 3%, and this layer has degassing function, and for being pasted on 3C Product screen, its material is silica gel.
Wherein, enhanced protection layer, the first tack coat, 3D three-dimensional imaging layer, the second tack coat, to be coated with by coating machine between carrier layer and following layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging enhanced protection layer on the surface of itself and extraneous contact, make it possess anti-scratchly to wipe, the effect of friction resistant.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 19
The present embodiment be 3D three-dimensional imaging film for making the purposes of outdoor label, this outdoor label comprises following each layer:
1. uvioresistant protective layer: be exposed in external environment condition, mass fraction 20%, its material is selected from polyvinyl fluoride thin film, is preferably the Tedlar light film of E.I.Du Pont Company;
2. the first tack coat: be connected to above-mentioned uvioresistant protective layer, mass fraction 7%, its material is pressure sensitive adhesive;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, mass fraction 20%;
4. ink layer: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 5%, its material is water color ink;
5. the second tack coat: be connected to above-mentioned ink layer, mass fraction 20%, its material is pressure sensitive adhesive;
6. carrier layer: be connected to above-mentioned second tack coat, mass fraction 28%, its material is the release Merlon processed in surface.
Wherein, to be coated with by coating machine between uvioresistant protective layer, the first tack coat, 3D three-dimensional imaging layer, ink layer, the second tack coat, carrier layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging uvioresistant protective layer on the surface of itself and extraneous contact, make it prolonged application have in a large amount of sun-exposed environment in open air.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 20
The present embodiment be 3D three-dimensional imaging film for making the purposes of outdoor label, this outdoor label comprises following each layer:
1. uvioresistant protective layer: be exposed in external environment condition, mass fraction 19%, its material is selected from polyvinyl fluoride thin film, is preferably the Tedlar light film of E.I.Du Pont Company;
2. the first tack coat: be connected to above-mentioned uvioresistant protective layer, mass fraction 8%, its material is polyurethane;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, mass fraction 25%;
4. ink layer: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 6%, its material is water color ink;
5. the second tack coat: be connected to above-mentioned ink layer, mass fraction 21%, its material is acryloid cement;
6. carrier layer: be connected to above-mentioned second tack coat, mass fraction 27%, its material is the release polyimides processed in surface.
Wherein, to be coated with by coating machine between uvioresistant protective layer, the first tack coat, 3D three-dimensional imaging layer, ink layer, the second tack coat, carrier layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging uvioresistant protective layer on the surface of itself and extraneous contact, make it prolonged application have in a large amount of sun-exposed environment in open air.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
Embodiment 21
The present embodiment be 3D three-dimensional imaging film for making the purposes of outdoor label, this outdoor label comprises following each layer:
1. uvioresistant protective layer: be not exposed in external environment condition, mass fraction 21%, its material is selected from polyvinyl fluoride thin film, is preferably the Tedlar light film of E.I.Du Pont Company;
2. the first tack coat: be connected to above-mentioned uvioresistant protective layer, mass fraction 6%, its material is silica gel;
3. 3D three-dimensional imaging layer: be connected to described first tack coat, mass fraction 15%;
4. ink layer: be connected to above-mentioned 3D three-dimensional imaging layer, mass fraction 4%, its material is water color ink;
5. the second tack coat: be connected to above-mentioned ink layer, mass fraction 19%, its material is UV glue;
6. carrier layer: be connected to above-mentioned second tack coat, mass fraction 29%, its material is the release PETG processed in surface.
Wherein, to be coated with by coating machine between uvioresistant protective layer, the first tack coat, 3D three-dimensional imaging layer, ink layer, the second tack coat, carrier layer or abutted equipment is fitted and connected together.
Because the present embodiment have employed not solvent-laden tack coat; so well solve the solvent resistant problem of 3D three-dimensional imaging film in whole processing procedure; and by arranging uvioresistant protective layer on the surface of itself and extraneous contact, make it prolonged application have in a large amount of sun-exposed environment in open air.The product prepared according to the present embodiment is tested according to professional standard, found that these products reach the requirement of professional standard.
These are only several specific embodiment of the present invention, any equivalent replacement that any those skilled in the art does under the prerequisite without prejudice to spirit of the present invention and distortion, all in protection scope of the present invention.

Claims (1)

1. 3D three-dimensional imaging film is for making a purposes for 3D card, it is characterized in that, described 3D three-dimensional imaging film comprises: protective layer, adopts resin material or its composite to make;
3D three-dimensional imaging layer, adopts high-molecular optical polymer image forming material to make;
Carrier layer, adopts resin material to make;
Wherein, described high-molecular optical polymer image forming material is selected from one or more in acrylic acid, polyurethane, polyester or carbonic ester, and described protective layer is common protective layer; Wherein,
Described 3D card comprises following each layer:
1. the first following layer: be connected to the first carrier layer;
2. tack coat one: be connected to described first following layer;
3. common protective layer: be connected to described tack coat one, its material is selected from resin material or its composite;
4. the first tack coat: be connected to described common protective layer, percetage by weight 19 ~ 21%, its material is selected from one or more of silica gel, UV glue, polyurethane or acryloid cement;
5. 3D three-dimensional imaging layer: be connected to described first tack coat, percetage by weight 12 ~ 22%, adopts high-molecular optical polymer image forming material to make;
6. the second tack coat: be connected to described 3D three-dimensional imaging layer, percetage by weight 19 ~ 21%, its material is selected from one or more of pressure sensitive adhesive, silica gel, UV glue, polyurethane or acryloid cement;
7. heat insulation heat-resistant layer: be connected to described second tack coat, percetage by weight 11 ~ 15%, its material is selected from one or more of PETG, polyimides or Merlon;
8. tack coat two: be connected to described heat insulation heat-resistant layer;
9. the second following layer: be connected to described tack coat two;
Described second following layer is connected with Second support layer.
CN201510655049.5A 2012-12-24 2012-12-24 3D imaging film and application thereof Pending CN105252858A (en)

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Publication number Priority date Publication date Assignee Title
US6180228B1 (en) * 1998-03-02 2001-01-30 3M Innovative Properties Company Outdoor advertising system
TW575223U (en) * 2002-02-08 2004-02-01 In Chang Technic Print Co Ltd Label for in-mold labeling
CN101439603A (en) * 2007-11-20 2009-05-27 健盟印刷企业有限公司 Label for in-mold labeling and article with the label
CN102774047A (en) * 2011-05-12 2012-11-14 中钞特种防伪科技有限公司 Anti-fake film structure of optical window

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CN202306124U (en) * 2011-09-15 2012-07-04 张保平 Transparent multidimensional stereo holographic projection imaging membrane

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Publication number Priority date Publication date Assignee Title
US6180228B1 (en) * 1998-03-02 2001-01-30 3M Innovative Properties Company Outdoor advertising system
TW575223U (en) * 2002-02-08 2004-02-01 In Chang Technic Print Co Ltd Label for in-mold labeling
CN101439603A (en) * 2007-11-20 2009-05-27 健盟印刷企业有限公司 Label for in-mold labeling and article with the label
CN102774047A (en) * 2011-05-12 2012-11-14 中钞特种防伪科技有限公司 Anti-fake film structure of optical window

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CN105216411A (en) 2016-01-06
CN105235339A (en) 2016-01-13
CN105365312B (en) 2017-10-31
CN105365312A (en) 2016-03-02
CN102991052B (en) 2016-01-13
CN105252859A (en) 2016-01-20
CN105235339B (en) 2017-06-23

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