CN106188899A - A kind of TPX mould release membrance - Google Patents

A kind of TPX mould release membrance Download PDF

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Publication number
CN106188899A
CN106188899A CN201610590984.2A CN201610590984A CN106188899A CN 106188899 A CN106188899 A CN 106188899A CN 201610590984 A CN201610590984 A CN 201610590984A CN 106188899 A CN106188899 A CN 106188899A
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China
Prior art keywords
parts
tpx
mould release
release membrance
thin layer
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CN201610590984.2A
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Chinese (zh)
Inventor
於险峰
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Ji Xiangbao (taicang) Material Science And Technology Development Co Ltd
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Ji Xiangbao (taicang) Material Science And Technology Development Co Ltd
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Priority to CN201610590984.2A priority Critical patent/CN106188899A/en
Publication of CN106188899A publication Critical patent/CN106188899A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08J2323/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2469/00Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material: TPX, PC, 2 ethyl methacrylate, polyurethane, polyimides, polyetheretherketonefiber fiber, carbon fiber, organo montmorillonite, ethylene glycol, silane coupler, antioxidant, light stabilizer, defoamer and thickening agent;Described TPX mould release membrance surfacing is bright and clean, has good peel strength and hot strength;Secondly, described TPX mould release membrance possesses good heat stability and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Additionally, a kind of TPX mould release membrance environment-protecting asepsis that the present invention provides, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.

Description

A kind of TPX mould release membrance
Technical field
The present invention relates to a kind of mould release membrance, be specifically related to a kind of TPX mould release membrance.
Background technology
Mould release membrance, also known as stripping film, isolating membrane, separation film, adhesive block film, fractal film, thin film, plastic sheeting, masking hole film, silicon Oil film, silicone oil paper, antiadhesion barrier, skidding film, that paper of sky, release paper, silliconfilm, release film, release.Logical In order to increase the off-type force of plastic sheeting in the case of Chang, plastic sheeting can be done plasma treatment, or be coated with fluorine process, or be coated with silicon (silicone) mould release is on the top layer of film material, such as PET, PE, OPP etc.;Allow it for various different organic pressures Sense glue (such as hot melt adhesive, acrylic glue and the pressure sensitive adhesive of rubber series) can show the lightest and stable off-type force.
Owing to mould release membrance has isolation, fills, protects, the advantage such as is easily peeled off, therefore it is widely used in various electricity In the fields such as son, communication, machinery.
TPX mould release membrance is of wide application, and main uses includes: medical treatment, cosmetics containers, physical and chemical experiment utensil, microwave With feeder, electrical/electronic part, industrial part, thin film, information equipment part, resin modification agent, electric insulation material etc., in addition The application such as the light internal memory of advanced person, optical communication equipment, water treatment facilities, air separation membrane are the most under development.
But existing TPX mould release membrance heat sealability is poor, and percent thermal shrinkage is low, being not easy to reclaim, mechanical performance can not expire The demand of foot industry.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of TPX mould release membrance, described TPX mould release membrance Surfacing is bright and clean, has good peel strength and hot strength;Secondly, described TPX mould release membrance possesses good heat surely Qualitative and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Additionally, described TPX mould release membrance environment-protecting asepsis, synthesis side Method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:100~110 parts, PC:10~15 parts, ethyl 2-methacrylate: 5~10 parts, polyurethane: 3~5 parts, polyamides is sub- Amine: 2~3 parts, polyetheretherketonefiber fiber: 2~4 parts, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part, ethylene glycol: 15~25 Part, silane coupler: 1~2 part, antioxidant: 0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening Agent: 0.1~0.5 part.
Preferably, described thin layer includes following weight proportion raw material:
TPX:102~108 parts, PC:11~14 parts, ethyl 2-methacrylate: 5.5~9.5 parts, polyurethane: 3.4~4.6 parts, Polyimides: 2.1~2.9 parts, polyetheretherketonefiber fiber: 2.6~3.7 parts, carbon fiber: 1.1~1.92 parts, organo montmorillonite: 1.4 ~2.5 parts, ethylene glycol: 17~23 parts, silane coupler: 1.2~1.8 parts, antioxidant: 0.15~0.95 part, light stabilizer: 0.2~0.9 part, defoamer: 0.14~0.46 part, thickening agent: 0.15~0.45 part.
Preferably, described thin layer includes following weight proportion raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti- Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
Further, described organo montmorillonite is hexadecyltrimethylammonium chloride.
Further, described silane coupler be VTES, γ aminopropyltriethoxy silane, β- One in (3,4-expoxycyclohexyl) ethyl trimethoxy silane.
Separately, the one during described antioxidant is antioxidant 1076, antioxidant 164.
Separately having, described light stabilizer is light stabilizer 770.
Again, described defoamer is polyethers or silicone defoamer.
Further, described thickening agent is ethylhydroxyethylcellulose.
The beneficial effects of the present invention is:
(1) described TPX mould release membrance, improves the affinity between release layer and thin layer so that it is possess good peel strength, It is capable of large area to peel off, meanwhile, improves again the hot strength that release layer is overall.
(2) described TPX mould release membrance, surfacing is bright and clean, possesses good heat stability and percent thermal shrinkage, also has meanwhile There is heat radiation energy storage effect, being used for isolating, in filling process, if the apparatus overheat that institute isolates, fills, could be by waste heat Absorption deposit gets up, and has reached quick heat radiating effect, and function is the most diversified.
(3) described TPX mould release membrance, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is more Height, be a kind of combination property more equalize, superior mould release membrance.
(4) described TPX mould release membrance, environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialization Produce.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection Scope.
Embodiment one
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti- Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
Embodiment two
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:106 part, PC:14 part, ethyl 2-methacrylate: 9.5 parts, polyurethane: 5 parts, polyimides: 2.7 parts, polyethers ether Ketone fiber: 3 parts, carbon fiber: 2 parts, organo montmorillonite: 2.5 parts, ethylene glycol: 19 parts, silane coupler: 1 part, antioxidant: 0.15 Part, light stabilizer: 1 part, defoamer: 0.14 part, thickening agent: 0.25 part.
Embodiment three
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:100 part, PC:12 part, ethyl 2-methacrylate: 5.5 parts, polyurethane: 3.4 parts, polyimides: 3 parts, polyethers ether Ketone fiber: 3.7 parts, carbon fiber: 1.1 parts, organo montmorillonite: 1 part, ethylene glycol: 23 parts, silane coupler: 1.4 parts, antioxidant: 1 part, light stabilizer: 0.1 part, defoamer: 0.46 part, thickening agent: 0.45 part.
Embodiment four
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:102 part, PC:10 part, ethyl 2-methacrylate: 10 parts, polyurethane: 4.6 parts, polyimides: 2.1 parts, polyethers Ether ketone fiber: 4 parts, carbon fiber: 1.45 parts, organo montmorillonite: 3 parts, ethylene glycol: 17 parts, silane coupler: 1.2 parts, antioxygen Agent: 0.7 part, light stabilizer: 0.2 part, defoamer: 0.5 part, thickening agent: 0.1 part.
Embodiment five
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:108 part, PC:15 part, ethyl 2-methacrylate: 5 parts, polyurethane: 3 parts, polyimides: 2.9 parts, polyether-ether-ketone Fiber: 2 parts, carbon fiber: 1 part, organo montmorillonite: 2.2 parts, ethylene glycol: 25 parts, silane coupler: 2 parts, antioxidant: 0.95 Part, light stabilizer: 0.9 part, defoamer: 0.3 part, thickening agent: 0.15 part.
Embodiment six
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:110 part, PC:11 part, ethyl 2-methacrylate: 7 parts, polyurethane: 3.8 parts, polyimides: 2 parts, polyether-ether-ketone Fiber: 2.6 parts, carbon fiber: 1.92 parts, organo montmorillonite: 1.4 parts, ethylene glycol: 15 parts, silane coupler: 1.8 parts, antioxygen Agent: 0.1 part, light stabilizer: 0.4 part, defoamer: 0.1 part, thickening agent: 0.5 part.
A kind of TPX mould release membrance that the present invention provides, described TPX mould release membrance, improve the parent between release layer and thin layer And power so that it is possess good peel strength, it is possible to realize large area and peel off, meanwhile, improve again release layer entirety Hot strength.Secondly, described TPX mould release membrance, surfacing is bright and clean, possesses good heat stability and percent thermal shrinkage, meanwhile, also There is heat radiation energy storage effect, being used for isolating, in filling process, if the apparatus overheat that institute isolates, fills, could be by many waste heat Amount absorbs deposit and gets up, and has reached quick heat radiating effect, and function is the most diversified.Furthermore, a kind of TPX provided by the present invention from Type film, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is higher, be a kind of combination property more Equilibrium, superior mould release membrance.Further, described TPX mould release membrance, environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition, It is applicable to industrialized production.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention In profit claimed range.

Claims (9)

1. a TPX mould release membrance, it is characterised in that include that thin layer, described thin layer include following weight proportion raw material:
TPX:100~110 parts, PC:10~15 parts, ethyl 2-methacrylate: 5~10 parts, polyurethane: 3~5 parts, polyamides is sub- Amine: 2~3 parts, polyetheretherketonefiber fiber: 2~4 parts, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part, ethylene glycol: 15~25 Part, silane coupler: 1~2 part, antioxidant: 0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening Agent: 0.1~0.5 part.
A kind of TPX mould release membrance the most according to claim 1, it is characterised in that described thin layer includes following weight proportion Raw material:
TPX:102~108 parts, PC:11~14 parts, ethyl 2-methacrylate: 5.5~9.5 parts, polyurethane: 3.4~4.6 parts, Polyimides: 2.1~2.9 parts, polyetheretherketonefiber fiber: 2.6~3.7 parts, carbon fiber: 1.1~1.92 parts, organo montmorillonite: 1.4 ~2.5 parts, ethylene glycol: 17~23 parts, silane coupler: 1.2~1.8 parts, antioxidant: 0.15~0.95 part, light stabilizer: 0.2~0.9 part, defoamer: 0.14~0.46 part, thickening agent: 0.15~0.45 part.
A kind of TPX mould release membrance the most according to claim 1, it is characterised in that described thin layer includes following weight proportion Raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti- Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
4. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described organo montmorillonite is 16 Alkyl trimethyl ammonium chloride.
5. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described silane coupler is ethylene In ethyl triethoxy silicane alkane, γ aminopropyltriethoxy silane, β-(3,4-expoxycyclohexyl) ethyl trimethoxy silane One.
6. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described antioxidant is antioxidant 1076, the one in antioxidant 164.
7. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described light stabilizer is that light is stable Agent 770.
8. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described defoamer be polyethers or Silicone defoamer.
9. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described thickening agent is ethyl hydroxyl second Base cellulose.
CN201610590984.2A 2016-07-26 2016-07-26 A kind of TPX mould release membrance Pending CN106188899A (en)

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CN201610590984.2A CN106188899A (en) 2016-07-26 2016-07-26 A kind of TPX mould release membrance

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108797200A (en) * 2018-07-02 2018-11-13 温州新意特种纸业有限公司 A kind of high temperature leather release paper
CN109466124A (en) * 2017-12-27 2019-03-15 宁波长阳科技股份有限公司 A kind of release film

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103464013A (en) * 2013-07-25 2013-12-25 烟台绿水赋膜材料有限公司 High-performance hybrid separation membrane and preparation method thereof
CN104945875A (en) * 2015-05-29 2015-09-30 吉翔宝(太仓)离型材料科技发展有限公司 Polycarbonate release film
CN104962043A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PET photodiffusion release film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103464013A (en) * 2013-07-25 2013-12-25 烟台绿水赋膜材料有限公司 High-performance hybrid separation membrane and preparation method thereof
CN104945875A (en) * 2015-05-29 2015-09-30 吉翔宝(太仓)离型材料科技发展有限公司 Polycarbonate release film
CN104962043A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PET photodiffusion release film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109466124A (en) * 2017-12-27 2019-03-15 宁波长阳科技股份有限公司 A kind of release film
CN109466124B (en) * 2017-12-27 2021-08-06 宁波长阳科技股份有限公司 Release film
CN108797200A (en) * 2018-07-02 2018-11-13 温州新意特种纸业有限公司 A kind of high temperature leather release paper

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