CN106189108A - A kind of compound mould release membrance - Google Patents
A kind of compound mould release membrance Download PDFInfo
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- CN106189108A CN106189108A CN201610591003.6A CN201610591003A CN106189108A CN 106189108 A CN106189108 A CN 106189108A CN 201610591003 A CN201610591003 A CN 201610591003A CN 106189108 A CN106189108 A CN 106189108A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material: PET, TPX, PP, PE, 2 ethyl methacrylate, polyurethane, polyarylate, glass fibre, carbon fiber, organo montmorillonite, ethylene glycol, PP g MAH, PE g MAH, silane coupler, antioxidant, light stabilizer, defoamer, thickening agent;Described compound mould release membrance surfacing is bright and clean, has good peel strength and hot strength;Secondly, described compound mould release membrance possesses good heat stability and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Described compound mould release membrance combination property more equalizes, there is splendid resistance to water, solvent resistance, resistance to chemical reagents, corrosion resistance, temperature tolerance, weatherability and cohesive, in addition, the one that the present invention provides is combined mould release membrance environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.
Description
Technical field
The present invention relates to a kind of mould release membrance, be specifically related to a kind of compound mould release membrance.
Background technology
Mould release membrance, also known as stripping film, isolating membrane, separation film, adhesive block film, fractal film, thin film, plastic sheeting, masking hole film, silicon
Oil film, silicone oil paper, antiadhesion barrier, skidding film, that paper of sky, release paper, silliconfilm, release film, release.Logical
In order to increase the off-type force of plastic sheeting in the case of Chang, plastic sheeting can be done plasma treatment, or be coated with fluorine process, or be coated with silicon
(silicone) mould release is on the top layer of film material, such as PET, PE, OPP etc.;Allow it for various different organic pressures
Sense glue (such as hot melt adhesive, acrylic glue and the pressure sensitive adhesive of rubber series) can show the lightest and stable off-type force.
Owing to mould release membrance has isolation, fills, protects, the advantage such as is easily peeled off, therefore it is widely used in various electricity
In the fields such as son, communication, machinery.
Compound mould release membrance is to use relatively broad one in mould release membrance, it is common that be made up of two or more materials, but,
Due to the difference of composition material each performance, the compatibility is poor.The most current mould release membrance, Performance comparision is single, the most only uses
In isolation, fill.
Therefore, for expanding economy, it is necessary to develop a kind of new compound mould release membrance.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of compound mould release membrance, described compound release
Film surfacing is bright and clean, has good peel strength and hot strength;Secondly, described compound mould release membrance possesses good heat
Stability and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Described compound mould release membrance combination property more equalizes,
There is splendid resistance to water, solvent resistance, resistance to chemical reagents, corrosion resistance, temperature tolerance, weatherability and cohesive, additionally, this
The one of bright offer is combined mould release membrance environment-protecting asepsis, and synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industry metaplasia
Produce.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:60~70 parts, TPX:50~60 parts, PP:10~15 parts, PE:5~10 parts, ethyl 2-methacrylate: 3~5 parts,
Polyurethane: 2~5 parts, polyarylate: 2~3 parts, glass fibre: 1~3 part, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part,
Ethylene glycol: 10~20 parts, PP-g-MAH:0.5~1 part, PE-g-MAH:0.5~1 part, silane coupler: 2~3 parts, antioxidant:
0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening agent: 0.1~0.5 part.
Preferably, described thin layer includes following weight proportion raw material:
PET:62~68 parts, TPX:51~59 parts, PP:11~14 parts, PE:6~9 parts, ethyl 2-methacrylate: 3.4~4.7
Part, polyurethane: 2.8~4.2 parts, polyarylate: 2.2~2.8 parts, glass fibre: 1.5~2.5 parts, carbon fiber: 1.2~1.9 parts,
Organo montmorillonite: 1.6~2.4 parts, ethylene glycol: 12~18 parts, PP-g-MAH:0.6~0.9 part, PE-g-MAH:0.6~0.8
Part, silane coupler: 2.2~2.8 parts, antioxidant: 0.2~0.7 part, light stabilizer: 0.3~0.7 part, defoamer: 0.15~
0.45 part, thickening agent: 0.2~0.4 part.
Preferably, described thin layer includes following weight proportion raw material:
PET:64 part, TPX:55 part, PP:12.5 part, PE:7.8 part, ethyl 2-methacrylate: 4 parts, polyurethane: 3.5 parts, poly-
Aromatic ester: 2.48 parts, glass fibre: 2.2 parts, carbon fiber: 1.6 parts, organo montmorillonite: 2 parts, ethylene glycol: 16 parts, PP-g-MAH:
0.76 part, PE-g-MAH:0.72 part, silane coupler: 2.5 parts, antioxidant: 0.5 part, light stabilizer: 0.6 part, defoamer:
0.25 part, thickening agent: 0.3 part.
Further, described organo montmorillonite is hexadecyltrimethylammonium chloride.
Further, described silane coupler be VTES, γ aminopropyltriethoxy silane, β-
One in (3,4-expoxycyclohexyl) ethyl trimethoxy silane.
Further, the one during described antioxidant is antioxidant 1076, antioxidant 164.
Separately, described light stabilizer is light stabilizer 770.
Separately having, described defoamer is polyethers or silicone defoamer.
Again, described thickening agent is ethylhydroxyethylcellulose.
Further, the preparation method of described film layer material is specific as follows: weigh needed raw material according to weight proportion, then exist
Under nitrogen protection, by uniform for each raw material stirring weighed, 1~1.5 hs be stirred at room temperature, be then heated to 65~75 DEG C, stir 1.5
H, then temperature reduces by 45~50 DEG C, stirs 1.5 h, is finally cooled to the i.e. available required film layer material of room temperature.
The beneficial effects of the present invention is:
(1) described compound mould release membrance, improves the affinity between release layer and thin layer so that it is possess good stripping strong
Degree, it is possible to realize large area and peel off, possesses good separation property and fillibility, meanwhile, improves again release layer entirety
Hot strength.
(2) described compound mould release membrance, surfacing is bright and clean, possesses good heat stability and percent thermal shrinkage, also has meanwhile
There is heat radiation energy storage effect, being used for isolating, in filling process, if the apparatus overheat that institute isolates, fills, could be by waste heat
Absorption deposit gets up, and has reached quick heat radiating effect, and function is the most diversified.
(3) described compound mould release membrance, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is more
Height, be a kind of combination property more equalize, superior mould release membrance.
(4) described compound mould release membrance combination property more equalizes, have splendid resistance to water, solvent resistance, resistance to chemical reagents,
Corrosion resistance, temperature tolerance, weatherability and cohesive.
(5) described compound mould release membrance, environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industry
Metaplasia is produced.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection
Scope.
Embodiment one
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:64 part, TPX:55 part, PP:12.5 part, PE:7.8 part, ethyl 2-methacrylate: 4 parts, polyurethane: 3.5 parts, poly-
Aromatic ester: 2.48 parts, glass fibre: 2.2 parts, carbon fiber: 1.6 parts, organo montmorillonite: 2 parts, ethylene glycol: 16 parts, PP-g-MAH:
0.76 part, PE-g-MAH:0.72 part, silane coupler: 2.5 parts, antioxidant: 0.5 part, light stabilizer: 0.6 part, defoamer:
0.25 part, thickening agent: 0.3 part.
Embodiment two
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:62 part, TPX:60 part, PP:11 part, PE:9 part, ethyl 2-methacrylate: 5 parts, polyurethane: 4.2 parts, poly-virtue
Ester: 2.2 parts, glass fibre: 2.5 parts, carbon fiber: 1 part, organo montmorillonite: 2.4 parts, ethylene glycol: 18 parts, PP-g-MAH:0.5
Part, PE-g-MAH:0.6 part, silane coupler: 2.8 parts, antioxidant: 1 part, light stabilizer: 0.7 part, defoamer: 0.15 part, increase
Thick dose: 0.5 part.
Embodiment three
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:68 part, TPX:50 part, PP:15 part, PE:5 part, ethyl 2-methacrylate: 3.4 parts, polyurethane: 5 parts, poly-virtue
Ester: 2.8 parts, glass fibre: 1.5 parts, carbon fiber: 1.2 parts, organo montmorillonite: 3 parts, ethylene glycol: 20 parts, PP-g-MAH:1 part,
PE-g-MAH:0.8 part, silane coupler: 3 parts, antioxidant: 0.2 part, light stabilizer: 0.1 part, defoamer: 0.5 part, thickening
Agent: 0.1 part.
Embodiment four
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:60 part, TPX:59 part, PP:14 part, PE:10 part, ethyl 2-methacrylate: 3 parts, polyurethane: 2.8 parts, poly-virtue
Ester: 3 parts, glass fibre: 1 part, carbon fiber: 1.9 parts, organo montmorillonite: 1 part, ethylene glycol: 12 parts, PP-g-MAH:0.9 part,
PE-g-MAH:0.5 part, silane coupler: 2 parts, antioxidant: 0.7 part, light stabilizer: 1 part, defoamer: 0.1 part, thickening agent:
0.4 part.
Embodiment five
A kind of compound mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
PET:70 part, TPX:51 part, PP:10 part, PE:6 part, ethyl 2-methacrylate: 4.7 parts, polyurethane: 2 parts, poly-virtue
Ester: 2 parts, glass fibre: 1.9 parts, carbon fiber: 2 parts, organo montmorillonite: 1.6 parts, ethylene glycol: 10 parts, PP-g-MAH:0.6 part,
PE-g-MAH:1 part, silane coupler: 2.8 parts, antioxidant: 0.1 part, light stabilizer: 0.3 part, defoamer: 0.45 part, thickening
Agent: 0.2 part.
The preparation method of film layer material described in the embodiment of the present invention is specific as follows: weigh required former according to weight proportion
Material, the most under nitrogen protection, by uniform for each raw material stirring weighed, be stirred at room temperature 1~1.5 h, be then heated to 65~75
DEG C, stir 1.5 h, then temperature reduces by 45~50 DEG C, stirs 1.5 h, is finally cooled to the i.e. available required thin film of room temperature
Layer material.
The one that the present invention provides is combined mould release membrance, improves the affinity between release layer and thin layer so that it is possess
Good peel strength, it is possible to realize large area and peel off, possess good separation property and fillibility, meanwhile, improve again
The hot strength that release layer is overall.Secondly, described compound mould release membrance, surfacing is bright and clean, possesses good heat stability and heat
Shrinkage factor, meanwhile, also has heat radiation energy storage effect, being used for isolating, in filling process, if the equipment mistake that institute isolates, fills
Heat, can absorb deposit by waste heat, has reached quick heat radiating effect, and function is the most diversified.Of the present invention
Compound mould release membrance, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is higher, is a kind of comprehensive
Can more equalize, superior mould release membrance.Furthermore, described compound mould release membrance combination property more equalizes, have splendid resistance to water,
Solvent resistance, resistance to chemical reagents, corrosion resistance, temperature tolerance, weatherability and cohesive.Additionally, described compound mould release membrance, environmental protection without
Poison, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively
The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (10)
1. a compound mould release membrance, it is characterised in that include that thin layer, described thin layer include following weight proportion raw material:
PET:60~70 parts, TPX:50~60 parts, PP:10~15 parts, PE:5~10 parts, ethyl 2-methacrylate: 3~5 parts,
Polyurethane: 2~5 parts, polyarylate: 2~3 parts, glass fibre: 1~3 part, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part,
Ethylene glycol: 10~20 parts, PP-g-MAH:0.5~1 part, PE-g-MAH:0.5~1 part, silane coupler: 2~3 parts, antioxidant:
0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening agent: 0.1~0.5 part.
One the most according to claim 1 is combined mould release membrance, it is characterised in that described thin layer includes following weight proportion
Raw material:
PET:62~68 parts, TPX:51~59 parts, PP:11~14 parts, PE:6~9 parts, ethyl 2-methacrylate: 3.4~4.7
Part, polyurethane: 2.8~4.2 parts, polyarylate: 2.2~2.8 parts, glass fibre: 1.5~2.5 parts, carbon fiber: 1.2~1.9 parts,
Organo montmorillonite: 1.6~2.4 parts, ethylene glycol: 12~18 parts, PP-g-MAH:0.6~0.9 part, PE-g-MAH:0.6~0.8
Part, silane coupler: 2.2~2.8 parts, antioxidant: 0.2~0.7 part, light stabilizer: 0.3~0.7 part, defoamer: 0.15~
0.45 part, thickening agent: 0.2~0.4 part.
One the most according to claim 1 is combined mould release membrance, it is characterised in that described thin layer includes following weight proportion
Raw material:
PET:64 part, TPX:55 part, PP:12.5 part, PE:7.8 part, ethyl 2-methacrylate: 4 parts, polyurethane: 3.5 parts, poly-
Aromatic ester: 2.48 parts, glass fibre: 2.2 parts, carbon fiber: 1.6 parts, organo montmorillonite: 2 parts, ethylene glycol: 16 parts, PP-g-MAH:
0.76 part, PE-g-MAH:0.72 part, silane coupler: 2.5 parts, antioxidant: 0.5 part, light stabilizer: 0.6 part, defoamer:
0.25 part, thickening agent: 0.3 part.
4. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described organo montmorillonite is 16
Alkyl trimethyl ammonium chloride.
5. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described silane coupler is second
Thiazolinyl triethoxysilane, γ aminopropyltriethoxy silane, β-(3,4-expoxycyclohexyl) ethyl trimethoxy silane
In one.
6. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described antioxidant is antioxidant
1076, the one in antioxidant 164.
7. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described light stabilizer is that light is steady
Determine agent 770.
8. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described defoamer is polyethers
Or silicone defoamer.
9. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that described thickening agent is ethyl hydroxyl
Ethyl cellulose.
10. it is combined mould release membrance according to the one described in claim 1 or 2 or 3, it is characterised in that the system of described film layer material
Preparation Method is specific as follows: weigh needed raw material according to weight proportion, the most under nitrogen protection, by equal for each raw material stirring weighed
Even, 1~1.5 hs are stirred at room temperature, are then heated to 65~75 DEG C, stir 1.5 h, then temperature reduces by 45~50 DEG C, stirs 1.5
H, is finally cooled to the i.e. available required film layer material of room temperature.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI706853B (en) * | 2018-01-17 | 2020-10-11 | 南亞塑膠工業股份有限公司 | Polyolefin releasing film and method for manufacturing the same, and thermoplastic polyurethane composite structure |
Citations (2)
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CN103192578A (en) * | 2013-04-28 | 2013-07-10 | 恩斯盟防静电材料(镇江)有限公司(中外合资) | Fabrication method of anti-static release film with stable release force |
CN105440301A (en) * | 2015-12-14 | 2016-03-30 | 广东弘擎电子材料科技有限公司 | Method for improving adhesion between PET release film base material and release agent |
-
2016
- 2016-07-26 CN CN201610591003.6A patent/CN106189108A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103192578A (en) * | 2013-04-28 | 2013-07-10 | 恩斯盟防静电材料(镇江)有限公司(中外合资) | Fabrication method of anti-static release film with stable release force |
CN105440301A (en) * | 2015-12-14 | 2016-03-30 | 广东弘擎电子材料科技有限公司 | Method for improving adhesion between PET release film base material and release agent |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI706853B (en) * | 2018-01-17 | 2020-10-11 | 南亞塑膠工業股份有限公司 | Polyolefin releasing film and method for manufacturing the same, and thermoplastic polyurethane composite structure |
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Application publication date: 20161207 |