CN101439603A - Label for in-mold labeling and article with the label - Google Patents
Label for in-mold labeling and article with the label Download PDFInfo
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- CN101439603A CN101439603A CNA2007101927626A CN200710192762A CN101439603A CN 101439603 A CN101439603 A CN 101439603A CN A2007101927626 A CNA2007101927626 A CN A2007101927626A CN 200710192762 A CN200710192762 A CN 200710192762A CN 101439603 A CN101439603 A CN 101439603A
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Abstract
An in-mold labeling label comprises a first substrate, a surface treatment layer, a printing layer, a first adhesive layer and a protective film. The first substrate is provided with a front face and a rear face, the surface treatment layer is formed on the front face of the first substrate, the printing layer is provided with images, formed on the front face of the first substrate and positioned on the surface treatment layer, the first adhesive layer is formed on the printing layer, the protective film is adhered to the printing layer by the first adhesive layer, the adhesive force between the printing layer and the first substrate is enhanced by forming the surface treatment layer on the front face of the first substrate, and the printing layer is not stripped due to the influence of the pressure or high temperature during the in-mold labeling process of the label, thus enhancing yield of the label molding, high temperature resistance and recycling property, and providing a special pattern design effect.
Description
[technical field]
The present invention relates to a kind of label of in-mold label, particularly relate to a kind of moulding yield height, reuse is good and high temperature resistant and wear-resisting and have a label of the in-mold label of special design effect.
[background technology]
The processing procedure of general in-mold label (in-mold labelling) is that the label with a polymerizable material places in the mould, and in the mode that blows out moulding (blowing molding) or ejection formation (injection molding) or vacuum forming (vaccum molding) in the article of this in-mold molding one polymerizable material, make that the article after the moulding can combine with the label of polymerizable material.
As shown in Figure 1, it is the disclosed a kind of label that is used for in-mold label of No. the 575223rd, TaiWan, China patent announcement (No. 91221606 application case) patent case, label 1 is to place a mould 101, and in mould 101, behind the forming polymer spare 102, make label 1 be incorporated on the polymer member 102.Label 1 comprises coating 12, an adhesive layer 13 and a cuticula 14 that is incorporated on the polymer member 102 and forms for the base material 11, of polymerizable material image; coating 12 is the fronts that are formed at base material 11; and cuticula 14 is to be affixed on the positive of base material 11 and to cover on the coating 12 by heat-resisting, solvent-free adhesive layer 13; by the configuration of cuticula 14, can protect the label 1 that is molded on the polymer member 102 to avoid producing problems such as scratch or wearing and tearing because of friction.
Yet, because special surface treatment process is not passed through in base material 11 fronts, so the adhesive force that coating 12 is attached on the base material 11 is not good, therefore easy influence in forming process because of pressure and high temperature, or under temperature spread variation environmental factor greatly, make coating 12 produce the phenomenon of peeling off, cause the not good and shortage reuse of yield of label 1 moulding.Moreover polymer member 102 in use also can cause using the misgivings of security because of the factor that coating 12 is easily peeled off.
[summary of the invention]
A purpose of the present invention is the label that is to provide good and the high temperature resistant and wear-resisting in-mold label of a kind of moulding yield height, reuse.
Another object of the present invention is that the article with label that provide a kind of safety in utilization good are provided.
The invention provides a kind of label of in-mold label, comprise one first base material, a surface-treated layer, a printed layers, one first adhesive layer and a cuticula.
First base material has a positive and back side, surface-treated layer is formed at the front of first base material, and printed layers has image, and is formed at the positive of first base material and is positioned on the surface-treated layer, first adhesive layer is formed on the printed layers, and cuticula is covered on the printed layers with first adhesive layer.
Another feature of the present invention is that label comprises that also one is formed at the cold wave film between the printed layers and first adhesive layer.
Another feature of the present invention is, label comprises that also one is formed at printed layers and the second intermembranous adhesive layer of cold wave, and second adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
Another feature of the present invention is that surface-treated layer can be sided corona treatment or flame treatment or plate gravure coating method or relief printing plate coating method or gentle version coating method or half tone coating method.
Another feature of the present invention is, printed layers is to be formed by lithographic printing or intaglio printing or letterpress or flexographic printing or screen painting or ink jet printing or numerical digit printshop.
Another feature of the present invention is, first adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
Another feature of the present invention is that first base material can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
Another feature of the present invention is that cuticula is a grating film, and the grating film can be polypropylene or PET or polyvinyl chloride or the inferior ethene of polychlorostyrene or polystyrene or Merlon or acryl material.
Another feature of the present invention is that cuticula can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
The present invention also provides a kind of article with described label, comprise a body and a label, this body comprises an outer surface, it is characterized in that: this label is formed at this outer surface of this body in the in-mold label mode, this label comprises one first base material, one surface-treated layer, one printed layers, one first adhesive layer and a cuticula, this first base material has a positive and back side, this surface-treated layer is formed at this front of this first base material, this printed layers has an image, and be formed at this front of this first base material and be positioned on this surface-treated layer, this first adhesive layer is formed on this printed layers, and this cuticula is covered on this printed layers with this first adhesive layer.
The beneficial effect of the label of in-mold label of the present invention is, be formed at the front of first base material by surface-treated layer, increase the adhesive force between the printed layers and first base material, make label in the forming process of in-mold label, be difficult for the phenomenon that the influence because of pressure or high temperature causes printed layers to peel off.In addition, under temperature spread changes big environmental factor, also be difficult for Yin Gaowen and cause peeling off of printed layers, whereby, can promote yield, heat-resisting quantity and the reuse of label shaping, the configuration of the cuticula of arranging in pairs or groups simultaneously can promote wearability.
[description of drawings]
Fig. 1 is a cross-sectional schematic that generally is used for the label of in-mold label.
Fig. 2 is the cross-sectional schematic of first preferred embodiment of the label of in-mold label of the present invention, and care label is that the back side with first base material is the outer surface that is formed at body.
Fig. 3 is the cross-sectional schematic of first preferred embodiment of the label of in-mold label of the present invention, and care label is the outer surface that is formed at body with cuticula.
Fig. 4 is the cross-sectional schematic of second preferred embodiment of the label of in-mold label of the present invention.
Fig. 5 is the cross-sectional schematic of the 3rd preferred embodiment of the label of in-mold label of the present invention.
Fig. 6 is the cross-sectional schematic of the 4th preferred embodiment of the label of in-mold label of the present invention.
Fig. 7 is the cross-sectional schematic of the 5th preferred embodiment of the label of in-mold label of the present invention.
Fig. 8 is the cross-sectional schematic of the 6th preferred embodiment of the label of in-mold label of the present invention.
[specific embodiment]
The present invention is described in detail below in conjunction with drawings and Examples:
Before the present invention is described in detail, be noted that in the following description content similar elements is to represent with identical numbering.
As shown in Figures 2 and 3, it is first preferred embodiment of the label of in-mold label of the present invention, this label 200 is that the mode with in-mold label is formed on the article 3, in the present embodiment, article 3 are to be that example explains with a container, anyly need indicate and be on the object of polymerizable material with label 200 but also can be.
First adhesive layer 24 is formed on the printed layers 23, it mainly is with so that cuticula 25 can be covered on printed layers 23, first adhesive layer 24 is for transparent material and can keep good light transmittance, it is formed by a resistant to elevated temperatures ultraviolet solidified adhesive, electronic beam curing adhesive, solvent-borne type (Solvent Type) adhesive, thermoplastic adhesive or hot setting adhesive, by first adhesive layer, 24 resistant to elevated temperatures characteristics, make that label 200 can Yin Gaowen in the process of in-mold label and produce bubble.Cuticula 25 is to see through first adhesive layer 24 to be covered on the printed layers 23; it is mainly in order to protection printed layers 23; make image energies such as pattern that printed layers 23 presents or literal avoid factor because of friction or external force; and problems such as generation scratch or wearing and tearing; cuticula 25 can be polyethylene (PE) or polypropylene (PP) or extension type polypropylene (OPP) or biaxial stretched polypropylene film (BOPP) or chlorinated polypropylene film (CPP) or PET (PET) or K type PET (KPET) or ethylene-vinyl alcohol copolymer (EVOH) or nylon (NYLON) or aluminium foil or polyvinyl chloride (PVC) or the inferior ethene (PVDC) of polychlorostyrene or Merlon (PC) or extensibility polystyrene (OPS) or PLA (PLA) or foaming heat insulation material or polyester film (Mylar) or acryl or paper wood matter; wherein the foaming heat insulation material is polyurethanes (PU), and the surface of cuticula 25 can be smooth and has bright or cloudy surface of gloss.
In addition, in the process of in-mold label, label 200 is to place earlier in the mould 4, and to blow out moulding (blowing molding), mode contoured body 31 in mould 4 of ejection formation (injection molding) or vacuum forming (vaccum molding), the direction that label 200 is formed on the body 31 of article 3 has two kinds, a kind of is as shown in Figure 2, the one side that cuticula 25 is not formed with first adhesive layer 24 is to contact with mould 4, and the back side 212 of first base material 21 is outer surfaces 311 that are formed at body 31, therefore after moulding, label 200 is that the back side 212 with first base material 21 is formed on the outer surface 311 of body 31.When label 200 is that the back side 212 with first base material 21 is when being formed on the outer surface 311 of body 31 in design, then cuticula 25 can be designed to a grating film that can present stereo-picture, whereby with the aesthetic property that increases article 3 and make article 3 present the visual effect of special pattern or literal.
Another kind is as shown in Figure 3, the one side that cuticula 25 is not formed with first adhesive layer 24 is to contact with the outer surface 311 of body 31, and the back side 212 of first base material 21 is to contact with mould 4, and therefore after moulding, label 200 is to be formed on the outer surface 311 of body 31 with cuticula 25, in other words, compare down with Fig. 2, label 200 is whole upset aftershaping outer surfaces 311 in body 31, whereby, label 200 is when moulding, and is more flexible in the design of its each interlayer directionality.
By the configuration of surface-treated layer 22, increase the adhesive force of 21 of the printed layers 23 and first base materials, make label 200 in the forming process of in-mold label, be difficult for the phenomenon that the influence because of pressure or high temperature causes printed layers 23 to peel off.In addition, change under the big environmental factor (as thermophilic digestion article 3), also be difficult for Yin Gaowen and cause peeling off of printed layers 23, make article 3 not have the misgivings of security in the use in temperature spread.Whereby, can promote yield, heat-resisting quantity and the reuse of label 200 moulding, the configuration of the cuticula 25 of arranging in pairs or groups simultaneously can promote the wearability of label 200.
As shown in Figure 4, be second preferred embodiment of the label of in-mold label of the present invention, the molding mode of this label 210 is identical with first preferred embodiment, but the composition member of label 210 and first preferred embodiment are different.
As shown in Figure 5, be the 3rd preferred embodiment of the label of in-mold label of the present invention, the molding mode of this label 220 is identical with second preferred embodiment, but the composition member of label 220 and second preferred embodiment are different.
As shown in Figure 6, be the 4th preferred embodiment of the label of in-mold label of the present invention, the molding mode of this label 230 is identical with first preferred embodiment, but the composition member of label 230 and first preferred embodiment are different.
Because first base material 21 is the design of aluminium foil or foaming heat insulation material material, make when label 230 is formed on the body 31, body 31 can reach the effect of insulation, whereby, label 230 can be applied on the edible container, certainly, label 230 is whole when being coated on the outer surface 311 of body 31, can reach best heat insulation effect.In addition, the direction that label 230 is formed on the body 31 also can have two kinds, a kind of is the outer surface 311 that is formed at body 31 with the face that second base material 29 is not formed with the 3rd adhesive layer 28, another kind is the outer surface 311 that is formed at body 31 with cuticula 25, wherein, when the face that label 230 is not formed with the 3rd adhesive layer 28 with second base material 29 is formed at the outer surface 311 of body 31, cuticula 25 can be designed to a grating film that can present stereo-picture, makes label 230 present the design effect of special pattern or literal whereby.
As shown in Figure 7, be the 5th preferred embodiment of the label of in-mold label of the present invention, the molding mode of this label 240 is identical with the 4th preferred embodiment, but the composition member of label 240 and the 4th preferred embodiment are different.
Label 240 comprises that also one is formed at the cold wave film 26 of 24 of printed layers 23 and first adhesive layers, cold wave film 26 is formed on the printed layers 23 by the mode of transfer printing, whereby, can make label 240 present diversified metal color, in addition, because of first base material 21 is the design of aluminium foil or foaming heat insulation material material, make body 31 can reach the effect of insulation.
As shown in Figure 8, be the 6th preferred embodiment of the label of in-mold label of the present invention, the molding mode of this label 250 is identical with the 4th preferred embodiment, but the composition member of label 250 and the 5th preferred embodiment are different.
Conclude above-mentioned, be formed at the front 211 of first base material 21 by surface-treated layer 22, increase the adhesive force of 21 of the printed layers 23 and first base materials, make label 200,210,220,230,240,250 in the forming process of in-mold label, be difficult for the phenomenon that the influence because of pressure or high temperature causes printed layers 23 to peel off.In addition, under temperature spread variation environmental factor greatly, also be difficult for Yin Gaowen and cause peeling off of printed layers 23, whereby, can promote yield, heat-resisting quantity and the reuse of label 200,210,220,230,240,250 moulding, arrange in pairs or groups the simultaneously configuration of cuticula 25 can promote wearability, so can reach the purpose of institute of the present invention demand really.
Claims (32)
1. the label of an in-mold label is characterized in that:
This label comprises one first base material, a surface-treated layer, a printed layers, one first adhesive layer and a cuticula, this first base material has a positive and back side, this surface-treated layer is formed at this front of this first base material, this printed layers has an image, and be formed at this front of this first base material and be positioned on this surface-treated layer, this first adhesive layer is formed on this printed layers, and this cuticula is covered on this printed layers with this first adhesive layer.
2. the label of in-mold label as claimed in claim 1, it is characterized in that: this label comprises that also one is formed at the cold wave film between this printed layers and this first adhesive layer.
3. the label of in-mold label as claimed in claim 2, it is characterized in that: this label comprises that also one is formed at this printed layers and the second intermembranous adhesive layer of this cold wave, and this second adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
4. as the label of claim 1 or 2 or 3 described in-mold labels, it is characterized in that: this surface-treated layer can be sided corona treatment or flame treatment or plate gravure coating method or relief printing plate coating method or gentle version coating method or half tone coating method.
5. the label of in-mold label as claimed in claim 4 is characterized in that: this printed layers is to be formed by lithographic printing or intaglio printing or letterpress or flexographic printing or screen painting or ink jet printing or numerical digit printshop.
6. the label of in-mold label as claimed in claim 5 is characterized in that: this first adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
7. the label of in-mold label as claimed in claim 6 is characterized in that: this first base material can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
8. the label of in-mold label as claimed in claim 7, it is characterized in that: this cuticula is a grating film, this grating film can be polypropylene or PET or polyvinyl chloride or the inferior ethene of polychlorostyrene or polystyrene or Merlon or acryl material.
9. the label of in-mold label as claimed in claim 7 is characterized in that: this cuticula can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
10. the label of in-mold label as claimed in claim 6, it is characterized in that: this label comprises that also one is formed at the 3rd adhesive layer at this back side of this first base material, and one is covered on second base material at this back side of this first base material with the 3rd adhesive layer.
11. the label of in-mold label as claimed in claim 10, it is characterized in that: this first base material is aluminium foil or foaming heat insulation material material, and this second base material can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
12. the label of in-mold label as claimed in claim 11 is characterized in that: the 3rd adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
13. the label of in-mold label as claimed in claim 12 is characterized in that: this cuticula is a grating film, and this grating film can be polypropylene or PET or polyvinyl chloride or the inferior ethene of polychlorostyrene or polystyrene or Merlon or acryl material.
14. the label of in-mold label as claimed in claim 12 is characterized in that: this cuticula can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
15. the article with label comprise a body and a label, this body comprises an outer surface, it is characterized in that:
This label is formed at this outer surface of this body in the in-mold label mode, this label comprises one first base material, a surface-treated layer, a printed layers, one first adhesive layer and a cuticula, this first base material has a positive and back side, this surface-treated layer is formed at this front of this first base material, this printed layers has an image, and be formed at this front of this first base material and be positioned on this surface-treated layer, this first adhesive layer is formed on this printed layers, and this cuticula is covered on this printed layers with this first adhesive layer.
16. the article with label as claimed in claim 15 is characterized in that: this label comprises that also one is formed at the cold wave film between this printed layers and this first adhesive layer.
17. the article with label as claimed in claim 16, it is characterized in that: this label comprises that also one is formed at this printed layers and the second intermembranous adhesive layer of this cold wave, and this second adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
18. as claim 15 or 16 or 17 described article with label, it is characterized in that: this surface-treated layer can be sided corona treatment or flame treatment or plate gravure coating method or relief printing plate coating method or gentle version coating method or half tone coating method.
19. the article with label as claimed in claim 18 is characterized in that: this printed layers is to be formed by lithographic printing or intaglio printing or letterpress or flexographic printing or screen painting or ink jet printing or numerical digit printshop.
20. the article with label as claimed in claim 19 is characterized in that: this first adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
21. the article with label as claimed in claim 20 is characterized in that: this first base material can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
22. the article with label as claimed in claim 21, it is characterized in that: this back side of this first base material is formed at this outer surface of this body, this cuticula is a grating film, and this grating film can be polypropylene or PET or polyvinyl chloride or the inferior ethene of polychlorostyrene or polystyrene or Merlon or acryl material.
23. the article with label as claimed in claim 21 is characterized in that: this cuticula can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
24. the article with label as claimed in claim 23 is characterized in that: this back side of this first base material is formed at this outer surface of this body.
25. the article with label as claimed in claim 23 is characterized in that: this cuticula is formed at this outer surface of this body.
26. the article with label as claimed in claim 20 is characterized in that: this label comprises that also one is formed at the 3rd adhesive layer at this back side of this first base material, and one is covered on second base material at this back side of this first base material with the 3rd adhesive layer.
27. the article with label as claimed in claim 26, it is characterized in that: this first base material is aluminium foil or foaming heat insulation material material, and this second base material can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
28. the article with label as claimed in claim 27 is characterized in that: the 3rd adhesive layer is formed with ultraviolet solidified adhesive or electronic beam curing adhesive or solvent-based adhesive or thermoplastic adhesive or hot setting adhesive.
29. the article with label as claimed in claim 28, it is characterized in that: the face that this second base material is not formed with the 3rd adhesive layer is formed at this outer surface of this body, this cuticula is a grating film, and this grating film can be polypropylene or PET or polyvinyl chloride or the inferior ethene of polychlorostyrene or polystyrene or Merlon or acryl material.
30. the article with label as claimed in claim 28 is characterized in that: this cuticula can be polyethylene or polypropylene or extension type polypropylene or biaxial stretched polypropylene film or chlorinated polypropylene film or PET or K type PET or ethylene-vinyl alcohol copolymer or nylon or aluminium foil or polyvinyl chloride or the inferior ethene of polychlorostyrene or Merlon or extensibility polystyrene or PLA or foaming heat insulation material or polyester film or acryl or paper wood matter.
31. the article with label as claimed in claim 30 is characterized in that: the face that this second base material is not formed with the 3rd adhesive layer is formed at this outer surface of this body.
32. the article with label as claimed in claim 30 is characterized in that: this cuticula is formed at this outer surface of this body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101927626A CN101439603A (en) | 2007-11-20 | 2007-11-20 | Label for in-mold labeling and article with the label |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101927626A CN101439603A (en) | 2007-11-20 | 2007-11-20 | Label for in-mold labeling and article with the label |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101439603A true CN101439603A (en) | 2009-05-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101927626A Pending CN101439603A (en) | 2007-11-20 | 2007-11-20 | Label for in-mold labeling and article with the label |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101439603A (en) |
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| CN102097034A (en) * | 2010-12-01 | 2011-06-15 | 中山国安火炬科技发展有限公司 | Label jumping resistance label |
| CN102129813A (en) * | 2010-01-20 | 2011-07-20 | 锣洋科技股份有限公司 | Decoration element and manufacturing method thereof |
| CN102745007A (en) * | 2012-06-21 | 2012-10-24 | 杜晴婷 | Intramode decoration process for manufacturing 2D color changing pattern or 3D stereo multi-color pattern |
| CN102991052A (en) * | 2012-12-24 | 2013-03-27 | 上海贝橡化工有限公司 | 3D (3-dimensional) stereo imaging film and application thereof |
| CN103247230A (en) * | 2013-05-31 | 2013-08-14 | 四川汇利实业有限公司 | Temperature-resistant and pressure-resistant in-mold label |
| CN104476899A (en) * | 2014-11-29 | 2015-04-01 | 桐城市福润包装材料有限公司 | Printing process of non-setting adhesive film label |
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| CN102129813A (en) * | 2010-01-20 | 2011-07-20 | 锣洋科技股份有限公司 | Decoration element and manufacturing method thereof |
| CN102097034A (en) * | 2010-12-01 | 2011-06-15 | 中山国安火炬科技发展有限公司 | Label jumping resistance label |
| CN102745007A (en) * | 2012-06-21 | 2012-10-24 | 杜晴婷 | Intramode decoration process for manufacturing 2D color changing pattern or 3D stereo multi-color pattern |
| CN105252859B (en) * | 2012-12-24 | 2017-06-23 | 上海贝橡化工有限公司 | A kind of 3D three-dimensional imagings film and its application |
| CN102991052A (en) * | 2012-12-24 | 2013-03-27 | 上海贝橡化工有限公司 | 3D (3-dimensional) stereo imaging film and application thereof |
| CN105365312B (en) * | 2012-12-24 | 2017-10-31 | 上海贝橡化工有限公司 | A kind of 3D three-dimensional imagings film and its application |
| CN102991052B (en) * | 2012-12-24 | 2016-01-13 | 上海贝橡化工有限公司 | A kind of 3D three-dimensional imaging film and application thereof |
| CN105252859A (en) * | 2012-12-24 | 2016-01-20 | 上海贝橡化工有限公司 | 3D imaging film and application thereof |
| CN105252858A (en) * | 2012-12-24 | 2016-01-20 | 上海贝橡化工有限公司 | 3D imaging film and application thereof |
| CN105365312A (en) * | 2012-12-24 | 2016-03-02 | 上海贝橡化工有限公司 | Three-dimensional imaging thin film and application thereof |
| CN103247230A (en) * | 2013-05-31 | 2013-08-14 | 四川汇利实业有限公司 | Temperature-resistant and pressure-resistant in-mold label |
| CN104476899A (en) * | 2014-11-29 | 2015-04-01 | 桐城市福润包装材料有限公司 | Printing process of non-setting adhesive film label |
| CN107507509A (en) * | 2017-08-30 | 2017-12-22 | 广州市挚联数码科技有限公司 | A kind of 3D stereo anti-fakes logo and its preparation method and application |
| CN108154793A (en) * | 2017-12-30 | 2018-06-12 | 东莞市安德标签材料有限公司 | label paper and preparation method thereof |
| CN110802978A (en) * | 2019-12-05 | 2020-02-18 | 漳州金马百虹金葱粉有限公司 | Preparation process of water-based degradable glitter powder |
| CN114687218A (en) * | 2020-12-30 | 2022-07-01 | 浙江凯瑞博科技有限公司 | Environment-friendly label material |
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