CN105220011A - A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof - Google Patents
A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof Download PDFInfo
- Publication number
- CN105220011A CN105220011A CN201510728638.1A CN201510728638A CN105220011A CN 105220011 A CN105220011 A CN 105220011A CN 201510728638 A CN201510728638 A CN 201510728638A CN 105220011 A CN105220011 A CN 105220011A
- Authority
- CN
- China
- Prior art keywords
- high strength
- base alloy
- alloy material
- copper base
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 68
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000010949 copper Substances 0.000 title claims abstract description 66
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 66
- 239000002245 particle Substances 0.000 title claims abstract description 60
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 59
- 239000010936 titanium Substances 0.000 title claims abstract description 59
- 238000010000 carbonizing Methods 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 55
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000002844 melting Methods 0.000 claims abstract description 12
- 230000008018 melting Effects 0.000 claims abstract description 12
- 238000005266 casting Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003723 Smelting Methods 0.000 claims description 5
- 238000009749 continuous casting Methods 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000000630 rising effect Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 10
- 229910052793 cadmium Inorganic materials 0.000 description 5
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000007669 thermal treatment Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010791 quenching Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
The present invention relates to a kind of high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline and preparation method thereof, this high strength carbonizing titanium particle enhanced copper base alloy material is made up of the component of following volume percent: nano titanium carbide 5.5-9%, copper alloy ZCuSn
3zn
11pb
491-94.5%.High strength carbonizing titanium particle enhanced copper base alloy material for the preparation of Nuclear steam pipeline passes through the steps such as stirring, melting, casting.High strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline provided by the invention, the features such as utilize titanium carbide hardness high, chemically stable is good, is not hydrolyzed, and high-temperature oxidation resistance is good, make copper alloy ZCuSn
3zn
11pb
4while its original solidity to corrosion of guarantee and good casting property, improve its intensity, hardness and working life, thus extend the application of high strength carbonizing titanium particle enhanced copper base alloy material at Nuclear steam pipeline.
Description
Technical field
The present invention relates to a kind of copper-base alloy composite material and preparation method thereof, particularly relate to a kind of high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline.
Background technology
The standard system of GB GB/T1176-2013 obtains copper alloy ZCuSn
3zn
11pb
4be a kind of polycomponent cast bronze material, it has easy processing, good casting property, the characteristic such as corrosion-resistant; Be mainly used in the tube fittings being manufactured on and working in seawater, light water and steam.But, due to the insufficient strength of its material self, make it drive the application in steam system to be subject to larger restriction at core.Only under the prerequisite ensureing its primary characteristic, promote this copper alloy ZCuSn further
3zn
11pb
4the intensity of material could expand the requirement that this material is applied in core steam propulsion system.
It is high that nano titanium carbide has fusing point, good heat conductivity, and hardness is large, the series of advantages such as chemically stable is good, is not hydrolyzed, and high-temperature oxidation resistance is good.Highly purified nano silicon carbide ti powder is a kind of by TiO
2in the carbon tube furnace or frequency modulation vacuum oven of logical hydrogen, under 1600 DEG C of-1800 DEG C of high temperature, obtained a kind of starting material are reacted with carbon black.Because nano titanium carbide hardness is large, have good mechanical property, therefore it is the important source material of CEMENTED CARBIDE PRODUCTION, can be used for manufacturing high-abrasive material, cutter material, mechanical component etc., also can make the crucible of the metals such as melting tin, lead, cadmium, zinc.
To sum up, by nano titanium carbide and copper alloy ZCuSn
3zn
11pb
4the high strength carbonizing titanium particle enhanced copper base alloy material that the two advantage combines can at guarantee copper alloy ZCuSn
3zn
11pb
4improve its intensity and hardness while original solidity to corrosion and good casting property, thus extend the application of high strength carbonizing titanium particle enhanced copper base alloy material in core driving steam system.
Summary of the invention
The object of the invention is to, by improving nano titanium carbide and copper alloy ZCuSn
3zn
11pb
4between volume proportion and preparation condition, provide a kind of and effectively improve copper alloy ZCuSn
3zn
11pb
4intensity, hardness and and the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline and preparation method thereof of working life.
For achieving the above object, technical scheme provided by the present invention is:
For a high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline, be made up of the component of following volume percent: nano titanium carbide 5.5-9%, copper alloy ZCuSn
3zn
11pb
491-94.5%.
Preferably, the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the present invention, is made up of the component of following volume percent: nano titanium carbide 5.5%, copper alloy ZCuSn
3zn
11pb
494.5%.
Preferably, the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the present invention, is characterized in that, be made up of the component of following volume percent: nano titanium carbide 7%, copper alloy ZCuSn
3zn
11pb
493%.
Preferably, the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the present invention, is characterized in that, be made up of the component of following volume percent: nano titanium carbide 9%, copper alloy ZCuSn
3zn
11pb
491%.
Further, described nano titanium carbide particle diameter is 300 μm-500 μm.
Further, described copper alloy ZCuSn
3zn
11pb
4be made up of the component of following mass percent: tin slab 2-4%, lead pig 3.0-6.0%, zinc 9.0-13.0%, impurity is less than 1.0, and all the other are copper.
The invention provides a kind of preparation method of the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline, there are following steps:
1) copper alloy ZCuSn is prepared
3zn
11pb
4: electrolytic copper, tin slab, lead pig, zinc are put into electric furnace melting according to above-mentioned part by weight, and in melting, copper alloy liquid volume is less than 99% of electric furnace volume; Smelting temperature is 1050-1100 DEG C, and the time is 4-5h;
2) use Spike direct-reading spectrometer to the copper alloy ZCuSn of preparation
3zn
11pb
4liquid carries out composition detection, to determine that its chemical constitution is within above-mentioned scope;
3) by nano titanium carbide by volume per-cent 5.5-9% put into above-mentioned copper alloy ZCuSn
3zn
11pb
4the surface of liquid, opens the shaking device of main frequency furnace and stirs with graphite rod simultaneously, makes the two Homogeneous phase mixing; Further rising furnace temperature is to 1200-1300 DEG C and keep 20-30min;
4) be incubated in electric furnace by the high strength carbonizing titanium particle enhanced copper base alloy material completed, the time is 1-1.5h; Adopt the mode of continuous casting that this high strength carbonizing titanium particle enhanced copper base alloy material is cast as high strength carbonizing titanium particle reinforced copper base alloy composite bar afterwards, casting temp is 1000-1100 DEG C;
5) the high strength carbonizing titanium particle reinforced copper base alloy composite bar after having cast is carried out surperficial Vehicle Processing process, and pack according to factory calibration.
Further, in step 3, the volume percent of described nano titanium carbide is 5.5%.
Further, in step 3, the volume percent of described nano titanium carbide is 7%.
Further, in step 3, the volume percent of described nano titanium carbide is 9%.
Adopt technique scheme, beneficial effect of the present invention has:
1. nano titanium carbide material is evenly distributed on copper alloy ZCuSn by certain technique means by the present invention
3zn
11pb
4in material, utilize the features such as nano level titanium carbide hardness is high, and chemically stable is good, is not hydrolyzed, and high-temperature oxidation resistance is good, compensate for copper alloy ZCuSn
3zn
11pb
4the shortcomings such as the hardness of material is low, intensity difference, realize copper alloy ZCuSn
3zn
11pb
4the hardness of material and the further lifting of strength property.
2. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline that obtains of the present invention, by changing nano titanium carbide and copper alloy ZCuSn
3zn
11pb
4volume ratio, effectively can improve the intensity of final titanium carbide granule reinforced copper base alloy material, hardness and working life, thus make high strength carbonizing titanium particle enhanced copper base alloy material can drive application in steam system at core.
Accompanying drawing explanation
Fig. 1 is the schema of the method for the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the present invention.
Embodiment
Below in conjunction with drawings and Examples, high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline provided by the invention and preparation method thereof is described further, but and unrestricted range of application of the present invention.
embodiment 1
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 1, is made up of the component of following volume percent: nano titanium carbide 5.5%, copper alloy ZCuSn
3zn
11pb
494.5%; Wherein nano titanium carbide particle diameter is 300 μm-500 μm; Copper alloy ZCuSn
3zn
11pb
4be made up of the component of following mass percent: tin slab 2-4%, lead pig 3.0-6.0%, zinc 9.0-13.0%, impurity is less than 1.0, and all the other are copper.
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 1, has following steps (as shown in Figure 1):
1) copper alloy ZCuSn is prepared
3zn
11pb
4: electrolytic copper, tin slab, lead pig, zinc are put into electric furnace melting according to above-mentioned part by weight, and in melting, copper alloy liquid volume is less than 99% of electric furnace volume; Smelting temperature is 1050 DEG C, and the time is 4h;
2) use Spike direct-reading spectrometer to the copper alloy ZCuSn of preparation
3zn
11pb
4liquid carries out composition detection, to determine that its chemical constitution is within above-mentioned scope;
3) by nano titanium carbide by volume per-cent 5.5% put into above-mentioned copper alloy ZCuSn
3zn
11pb
4the surface of liquid, opens the shaking device of main frequency furnace and stirs with graphite rod simultaneously, makes the two Homogeneous phase mixing; Further rising furnace temperature to 1200 DEG C also keeps 20min;
4) be incubated in electric furnace by the high strength carbonizing titanium particle enhanced copper base alloy material completed, the time is 1h; Adopt the mode of continuous casting that this high strength carbonizing titanium particle enhanced copper base alloy material is cast as high strength carbonizing titanium particle reinforced copper base alloy composite bar afterwards, casting temp is 1000 DEG C;
5) the high strength carbonizing titanium particle reinforced copper base alloy composite bar after having cast is carried out surperficial Vehicle Processing process, and pack according to factory calibration.
embodiment 2
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 2, is made up of the component of following volume percent: nano titanium carbide 7%, copper alloy ZCuSn
3zn
11pb
493%; Wherein nano titanium carbide particle diameter is 300 μm-500 μm; Copper alloy ZCuSn
3zn
11pb
4be made up of the component of following mass percent: tin slab 2-4%, lead pig 3.0-6.0%, zinc 9.0-13.0%, impurity is less than 1.0, and all the other are copper.
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 2, has following steps (as shown in Figure 1):
1) copper alloy ZCuSn is prepared
3zn
11pb
4: electrolytic copper, tin slab, lead pig, zinc are put into electric furnace melting according to above-mentioned part by weight, and in melting, copper alloy liquid volume is less than 99% of electric furnace volume; Smelting temperature is 1075 DEG C, and the time is 4.5h;
2) use Spike direct-reading spectrometer to the copper alloy ZCuSn of preparation
3zn
11pb
4liquid carries out composition detection, to determine that its chemical constitution is within above-mentioned scope;
3) by nano titanium carbide by volume per-cent 7% put into above-mentioned copper alloy ZCuSn
3zn
11pb
4the surface of liquid, opens the shaking device of main frequency furnace and stirs with graphite rod simultaneously, makes the two Homogeneous phase mixing; Further rising furnace temperature to 1250 DEG C also keeps 25min;
4) be incubated in electric furnace by the high strength carbonizing titanium particle enhanced copper base alloy material completed, the time is 1.25h; Adopt the mode of continuous casting that this high strength carbonizing titanium particle enhanced copper base alloy material is cast as high strength carbonizing titanium particle reinforced copper base alloy composite bar afterwards, casting temp is 1050 DEG C;
5) the high strength carbonizing titanium particle reinforced copper base alloy composite bar after having cast is carried out surperficial Vehicle Processing process, and pack according to factory calibration.
embodiment 3
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 3, is made up of the component of following volume percent: nano titanium carbide 9%, copper alloy ZCuSn
3zn
11pb
491%; Wherein nano titanium carbide particle diameter is 300 μm-500 μm; Copper alloy ZCuSn
3zn
11pb
4be made up of the component of following mass percent: tin slab 2-4%, lead pig 3.0-6.0%, zinc 9.0-13.0%, impurity is less than 1.0, and all the other are copper.
The high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the embodiment of the present invention 3, has following steps (as shown in Figure 1):
1) copper alloy ZCuSn is prepared
3zn
11pb
4: electrolytic copper, tin slab, lead pig, zinc are put into electric furnace melting according to above-mentioned part by weight, and in melting, copper alloy liquid volume is less than 99% of electric furnace volume; Smelting temperature is 1100 DEG C, and the time is 5h;
2) use Spike direct-reading spectrometer to the copper alloy ZCuSn of preparation
3zn
11pb
4liquid carries out composition detection, to determine that its chemical constitution is within above-mentioned scope;
3) by nano titanium carbide by volume per-cent 9% put into above-mentioned copper alloy ZCuSn
3zn
11pb
4the surface of liquid, opens the shaking device of main frequency furnace and stirs with graphite rod simultaneously, makes the two Homogeneous phase mixing; Further rising furnace temperature to 1300 DEG C also keeps 30min;
4) be incubated in electric furnace by the high strength carbonizing titanium particle enhanced copper base alloy material completed, the time is 1.5h; Adopt the mode of continuous casting that this high strength carbonizing titanium particle enhanced copper base alloy material is cast as high strength carbonizing titanium particle reinforced copper base alloy composite bar afterwards, casting temp is 1100 DEG C;
5) the high strength carbonizing titanium particle reinforced copper base alloy composite bar after having cast is carried out surperficial Vehicle Processing process, and pack according to factory calibration.
comparative example 1
Add the Cu alloy material of traditional element cadmium, titanium, composed of the following components: the cadmium accounting for alloy material gross weight 1.5%, account for the titanium of alloy material gross weight 4%, account for the copper alloy ZCuSn of alloy material gross weight 94.5%
3zn
11pb
4.By traditional thermal treatment process, namely repeatedly to anneal, tempering and the thermal treatment process such as to quench, prepare above-mentioned Cu alloy material.
comparative example 2
Add the Cu alloy material of traditional element cadmium, titanium, composed of the following components: the cadmium accounting for alloy material gross weight 3%, account for the titanium of alloy material gross weight 6%, account for the copper alloy ZCuSn of alloy material gross weight 91%
3zn
11pb
4.By traditional thermal treatment process, namely repeatedly to anneal, tempering and the thermal treatment process such as to quench, prepare above-mentioned Cu alloy material.
The embodiment of high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline of the present invention and the mechanical property of traditional copper alloy material of above-mentioned comparative example 1 and 2 and the parts of manufacture as shown in table 1 as the working life of accessory in core steam propulsion system.
Table 1
Data according to above-mentioned table 1 can be found out, the high strength carbonizing titanium particle enhanced copper base alloy material mechanical property after interpolation nano titanium carbide and the parts of manufacture thereof obtain significant raising as the working life of accessory in core steam propulsion system.
The above embodiment only have expressed embodiments of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (10)
1., for a high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline, it is characterized in that, be made up of the component of following volume percent: nano titanium carbide 5.5-9%, copper alloy ZCuSn
3zn
11pb
491-94.5%.
2. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline according to claim 1, is characterized in that, be made up of the component of following volume percent: nano titanium carbide 5.5%, copper alloy ZCuSn
3zn
11pb
494.5%.
3. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline according to claim 1, is characterized in that, be made up of the component of following volume percent: nano titanium carbide 7%, copper alloy ZCuSn
3zn
11pb
493%.
4. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline according to claim 1, is characterized in that, be made up of the component of following volume percent: nano titanium carbide 9%, copper alloy ZCuSn
3zn
11pb
491%.
5. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline as claimed in one of claims 1-4, it is characterized in that, described nano titanium carbide particle diameter is 300 μm-500 μm.
6. the high strength carbonizing titanium particle enhanced copper base alloy material for Nuclear steam pipeline according to claim 1-4, is characterized in that, described copper alloy ZCuSn
3zn
11pb
4be made up of the component of following mass percent: tin slab 2-4%, lead pig 3.0-6.0%, zinc 9.0-13.0%, impurity is less than 1.0, and all the other are copper.
7., for a preparation method for the high strength carbonizing titanium particle enhanced copper base alloy material of Nuclear steam pipeline, it is characterized in that there are following steps:
1) copper alloy ZCuSn is prepared
3zn
11pb
4: electrolytic copper, tin slab, lead pig, zinc are put into electric furnace melting according to part by weight according to claim 6, and in melting, copper alloy liquid volume is less than 99% of electric furnace volume; Smelting temperature is 1050-1100 DEG C, and the time is 4-5h;
2) use Spike direct-reading spectrometer to the copper alloy ZCuSn of preparation
3zn
11pb
4liquid carries out composition detection, to determine that its chemical constitution is within scope according to claim 6;
3) by nano titanium carbide by volume per-cent 5.5-9% put into above-mentioned copper alloy ZCuSn
3zn
11pb
4the surface of liquid, opens the shaking device of main frequency furnace and stirs with graphite rod simultaneously, makes the two Homogeneous phase mixing; Further rising furnace temperature is to 1200-1300 DEG C and keep 20-30min;
4) be incubated in electric furnace by the high strength carbonizing titanium particle enhanced copper base alloy material completed, the time is 1-1.5h; Adopt the mode of continuous casting that this high strength carbonizing titanium particle enhanced copper base alloy material is cast as high strength carbonizing titanium particle reinforced copper base alloy composite bar afterwards, casting temp is 1000-1100 DEG C;
5) the high strength carbonizing titanium particle reinforced copper base alloy composite bar after having cast is carried out surperficial Vehicle Processing process, and pack according to factory calibration.
8. preparation method according to claim 7, is characterized in that, in step 3, the volume percent of described nano titanium carbide is 5.5%.
9. preparation method according to claim 7, is characterized in that, in step 3, the volume percent of described nano titanium carbide is 7%.
10. preparation method according to claim 7, is characterized in that, in step 3, the volume percent of described nano titanium carbide is 9%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510728638.1A CN105220011A (en) | 2015-10-30 | 2015-10-30 | A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510728638.1A CN105220011A (en) | 2015-10-30 | 2015-10-30 | A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105220011A true CN105220011A (en) | 2016-01-06 |
Family
ID=54989276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510728638.1A Pending CN105220011A (en) | 2015-10-30 | 2015-10-30 | A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105220011A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57164955A (en) * | 1981-04-06 | 1982-10-09 | Mitsubishi Metal Corp | Alloy with 2-phase structure for decoration and lock |
| JPS609604A (en) * | 1983-06-30 | 1985-01-18 | Agency Of Ind Science & Technol | Cutter blade made of ceramics formed of plural layers of super hard material group and oxide group |
| CN103305742A (en) * | 2013-06-26 | 2013-09-18 | 苏州金仓合金新材料有限公司 | Method for preparing nanoscale silicon carbide copper alloy material |
| CN104372196A (en) * | 2014-10-09 | 2015-02-25 | 河海大学 | In situ reaction method for generating TiC dispersion strengthened Cu alloy |
| CN104630544A (en) * | 2015-01-27 | 2015-05-20 | 苏州金仓合金新材料有限公司 | Novel composite copper-based alloy material for high speed railway and preparation method of novel composite copper-based alloy material |
-
2015
- 2015-10-30 CN CN201510728638.1A patent/CN105220011A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57164955A (en) * | 1981-04-06 | 1982-10-09 | Mitsubishi Metal Corp | Alloy with 2-phase structure for decoration and lock |
| JPS609604A (en) * | 1983-06-30 | 1985-01-18 | Agency Of Ind Science & Technol | Cutter blade made of ceramics formed of plural layers of super hard material group and oxide group |
| CN103305742A (en) * | 2013-06-26 | 2013-09-18 | 苏州金仓合金新材料有限公司 | Method for preparing nanoscale silicon carbide copper alloy material |
| CN104372196A (en) * | 2014-10-09 | 2015-02-25 | 河海大学 | In situ reaction method for generating TiC dispersion strengthened Cu alloy |
| CN104630544A (en) * | 2015-01-27 | 2015-05-20 | 苏州金仓合金新材料有限公司 | Novel composite copper-based alloy material for high speed railway and preparation method of novel composite copper-based alloy material |
Non-Patent Citations (1)
| Title |
|---|
| 宋德军: "《中华人民共和国国家标准，GB/T 1176-2013，铸造铜及铜合金》", 18 September 2013 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103305742A (en) | Method for preparing nanoscale silicon carbide copper alloy material | |
| CN102134444A (en) | Temperature-resistance thermal-insulation heavy-duty anticorrosion coating | |
| CN101117723A (en) | Method for preparing Gd-Mg master alloy by co-electrodeposition of fluorinated system | |
| CN105177348A (en) | High-strength titanium carbide copper-based composite material and preparation method thereof | |
| WO2017070806A1 (en) | High-strength titanium carbide particle-reinforced copper-based composite material and preparation method therefor | |
| CN107164657B (en) | A kind of preparation method of graphene/La-Fe-B systems low temperature hydrogen storage composite material | |
| CN105420533A (en) | New high-strength titanium carbide particle reinforced copper-based alloy material for oceanographic engineering | |
| CN104372209A (en) | Aluminum-base powder-metallurgy composite material and preparation method thereof | |
| CN104294133A (en) | A kind of ZrO2 ceramic particle reinforced molybdenum-based composite material and preparation method thereof | |
| CN101914706B (en) | Zinc-aluminum-neodymium alloy and its molten salt electrolytic preparation method | |
| CN101696509B (en) | 4000A-electrolytic furnace for producing oxide molten salt through electrolysis | |
| CN101497446B (en) | Method for producing calcium boride with high purity | |
| CN105220011A (en) | A kind of high strength carbonizing titanium particle enhanced copper base alloy material and preparation method thereof | |
| CN105256169A (en) | High-strength nanometer silicon carbide strengthening copper-based composite material and preparing method thereof | |
| CN105200264A (en) | High-strength titanium diboride particle enhanced copper-based composite and preparation method thereof | |
| CN105220000A (en) | A kind of high strength titanium diboride particle enhanced copper-based composite material and preparation method thereof | |
| CN107587168A (en) | The method that molten-salt electrolysis prepares Titanium | |
| CN103498091B (en) | The preparation method of niobium ferro-titanium and niobium ferro-titanium | |
| CN105177349A (en) | High-strength nano titanium carbide copper-based corrosion-resisting alloy material and preparation method thereof | |
| CN105219988A (en) | A kind of titanium carbide granule reinforced copper base composite alloy material and manufacture method thereof | |
| CN102492962A (en) | Preparation method for tellurium electrolyte | |
| CN104561728A (en) | Iron-chromium-aluminum alloy smelting method | |
| CN103204486B (en) | Grapheme lithium iron phosphate in composite polycrystalline structure and preparation method thereof | |
| CN103074643B (en) | The method of different Ni-Tb intermetallic compound is prepared in fused salt electrolysis | |
| CN108070736A (en) | A kind of ocean engineering high-strength nano grade carborundum acid bronze alloy new material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160106 |
|
| RJ01 | Rejection of invention patent application after publication |