CN105219156B - A kind of disposable thermometer High-performance ink and preparation method thereof - Google Patents
A kind of disposable thermometer High-performance ink and preparation method thereof Download PDFInfo
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- CN105219156B CN105219156B CN201510734989.3A CN201510734989A CN105219156B CN 105219156 B CN105219156 B CN 105219156B CN 201510734989 A CN201510734989 A CN 201510734989A CN 105219156 B CN105219156 B CN 105219156B
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Abstract
The invention discloses a kind of disposable thermometer High-performance ink, it is made after being mixed using following raw materials, it includes the component of following weight content：80 85 parts of epoxy modified acrylic resin, 10 15 parts of activated monomer, 20 parts of protein 10,10 20 parts of auxiliary agent, 1 10 parts of organic solvent.The invention also discloses the preparation method of the High-performance ink：After weighing epoxy modified acrylic resin, activated monomer, albumen, auxiliary agent mixing, take three-roll grinder to grind, Ink particle size D50 is reached 15 μm；Organic solvent is added, is uniformly dispersed using high speed dispersor, canned sealing is stand-by.The ink that the present invention prepares has the characteristics that solidification temperature is low, nontoxic, pollution-free, glass attachment power is strong, high conversion rate, monomer remnants amount is low, has biocompatibility and can arbitrarily adjust.
Description
Technical field
The present invention relates to a kind of High-performance ink, more particularly to a kind of disposable thermometer High-performance ink, while this
Invention further relates to the preparation method of the High-performance ink.
Background technology
World's environmental regulation it is increasingly perfect, the traditional solvent-borne coating of discharge volatile organic matter is greatly rushed
Hit, and using water paint, ultraviolet-curing paint, high solid coating and powdery paints as representative environment-friendly coating then
Arise at the historic moment, turn into the focus of people's research.
Three major types can be substantially divided into classify with ink：Water-based painting printing ink, dissolvant type spraying/drawing ink, UV-curing
Change painting printing ink.The characteristics of water-based painting printing ink is bright-colored, environmental protection, but is easy to fade, and color fidelity can only achieve
One month or so.The characteristics of dissolvant type spraying/drawing ink is light resistance, good waterproof performance, and printing species are wide；But used because it is a large amount of
Solvent（Including acetone, butanone, ethyl acetate, butyl acetate, alcohols etc.）, one side volatile organic matter（VOCs）Content height is right
Production environment causes seriously to pollute with air, has very big danger to production operation personnel and its subsequent product consumer's health
Evil, and potential safety hazard is brought to production process；On the other hand international oil price fluctuation is limited by there is also solvent cost to cause to turn
Paper transfer price improves.The characteristics of ultraviolet light solidification painting printing ink, is free from volatile solvent, film wink-dry, saves the energy,
And solidify after it is fast light, weather-proof, water proofing property is fine；But it contains a large amount of monomers, there is very strong excitant and corrosivity, easily burn and
Cause human allergy.
The content of the invention
Goal of the invention：The present invention provides a kind of disposable thermometer High-performance ink and preparation method thereof, ink tool
Have solidification temperature is low, nontoxic, pollution-free, glass attachment power is strong, high conversion rate, monomer remnants amount is low, have biocompatibility and
The features such as can arbitrarily adjusting.
Technical scheme：A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink
By following component by weight：
Epoxy modified acrylic resin 80-85 parts；
Activated monomer 10-15 parts；
- 20 parts of protein 10；
Auxiliary agent 10-20 parts；
Organic solvent 1-10 parts.
As optimization：The epoxy modified acrylic resin be with methyl methacrylate, acrylic acid, 2-ethyl hexyl acrylate,
Styrene, hydroxypropyl acrylate, trimethyol propane triacrylate are monomer, and benzoyl peroxide is initiator, E-44 rings
Oxygen tree fat is modifying agent, aggregated to obtain that thermoset epoxy is acrylic resin modified, has excellent adhesive property, wearability
The features such as energy, chemical stability, cheap cost.
As optimization：The activated monomer is acrylate monomer, specially methyl acrylate, ethyl acrylate, 2- first
Base methyl acrylate, ethyl 2-methacrylate, 1,6 hexanediol diacrylate, trimethylolpropane trimethacrylate, two
Contracting tripropylene glycol diacrylate and one kind in the acrylate of dipentaerythrite five or more person's mixtures.
As optimization：The albumen is selected from：One or more in bovine hemoglobin, globulin and Egg-white, are acted on
In the biocompatibility of enhancing ink.
As optimization：The auxiliary agent is that extinction machine, inorganic filler, levelling agent, styrax, defoamer and adhesive force promote
Agent.
As optimization：The organic solvent is one or both of terpinol, butyl carbitol.
A kind of preparation method of disposable thermometer High-performance ink described in basis, comprises the following steps：
a）Epoxy modified acrylic resin, activated monomer, albumen and auxiliary agent are weighed in proportion, are placed in mixing tank, it is fully mixed
Close；
b）Mixed material, when temperature be down to 40-60 DEG C, fineness reach 30-40 μm when, then ground by three-roller,
Coating particle size is set to reach less than 9 μm；
c）Material after grinding adjusts viscosity by organic solvent, packs and produces after being uniformly dispersed.
As optimization：The step（a）The time of middle each component mixing is 30-60 minutes, makes raw material mixing complete, nothing
Obvious bulk, coarse particulate matter occur.
As optimization：The step（b）In grinding pass be 10-20 times, after grinding material particular diameter D50 be 1-5 μm.
As optimization：The step（c）Remaining monomer can pass through low temperature in middle inorganic solvent and prepared ink
Solidification, the mode of vacuum filtration remove, and reduce monomer remnants amount.
Beneficial effect：The ink that the present invention prepares has that solidification temperature is low, nontoxic, pollution-free, glass attachment power is strong, turns
Rate is high, monomer remnants amount is low, has the characteristics that biocompatibility and can arbitrarily adjust.Specific advantage is as follows：
（1）The thermoset epoxy is acrylic resin modified, has excellent adhesive property, anti-wear performance, chemically stable
The features such as performance, cheap cost.
（2）The albumen effect is the biocompatibility for strengthening ink.
（3）Remaining monomer is removed by way of low-temperature setting, vacuum filtration in inorganic solvent and prepared ink,
Reduce monomer remnants amount.
Embodiment
With reference to specific embodiment, the present invention will be described in detail.
It is summarized as follows：In the present invention, the epoxy modified acrylic resin is with methyl methacrylate, acrylic acid, third
Olefin(e) acid monooctyl ester, styrene, hydroxypropyl acrylate, trimethyol propane triacrylate are monomer, and benzoyl peroxide is initiation
Agent, E-44 epoxy resin are modifying agent, aggregated to obtain that thermoset epoxy is acrylic resin modified, have excellent caking property
The features such as energy, anti-wear performance, chemical stability, cheap cost.
The activated monomer is acrylate monomer, specially methyl acrylate, ethyl acrylate, 2- methyl methacrylates
Ester, ethyl 2-methacrylate, 1,6 hexanediol diacrylate, trimethylolpropane trimethacrylate, tripropylene glycol
Diacrylate and one kind in the acrylate of dipentaerythrite five or more person's mixtures.
The albumen is selected from：One or more in bovine hemoglobin, globulin and Egg-white, effect are to strengthen ink
Biocompatibility.
The auxiliary agent is extinction machine, inorganic filler, levelling agent, styrax, defoamer and adhesion promoter.
The organic solvent is one or both of terpinol, butyl carbitol.
Specific embodiment one：
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is by following component
By weight：
80 parts of epoxy modified acrylic resin；
10 parts of activated monomer；
Protein 10 part；
10 parts of auxiliary agent；
1 part of organic solvent.
A kind of preparation method of disposable thermometer High-performance ink described in basis, comprises the following steps：
a）Epoxy modified acrylic resin, activated monomer, albumen and auxiliary agent are weighed in proportion, are placed in mixing tank, it is fully mixed
Close；
b）Mixed material, when temperature be down to 40 DEG C, fineness reach 30 μm when, then ground by three-roller, make coating
Granularity reaches less than 9 μm；
c）Material after grinding adjusts viscosity by organic solvent, packs and produces after being uniformly dispersed.
The step（a）The time of middle each component mixing is 30 minutes, makes raw material mixing complete, without obvious bulk, slightly
Particulate matter occurs.
The step（b）In grinding pass be 10 times, after grinding material particular diameter D50 be 1 μm.
The step（c）Remaining monomer can pass through low-temperature setting, vacuum in middle inorganic solvent and prepared ink
The mode of suction filtration removes, and reduces monomer remnants amount.
Specific embodiment two：
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is by following component
By weight：
85 parts of epoxy modified acrylic resin；
15 parts of activated monomer；
Protein 20 part；
20 parts of auxiliary agent；
10 parts of organic solvent.
A kind of preparation method of disposable thermometer High-performance ink described in basis, comprises the following steps：
a）Epoxy modified acrylic resin, activated monomer, albumen and auxiliary agent are weighed in proportion, are placed in mixing tank, it is fully mixed
Close；
b）Mixed material, when temperature be down to 60 DEG C, fineness reach 40 μm when, then ground by three-roller, make coating
Granularity reaches less than 9 μm；
c）Material after grinding adjusts viscosity by organic solvent, packs and produces after being uniformly dispersed.
The step（a）The time of middle each component mixing is 60 minutes, makes raw material mixing complete, without obvious bulk, slightly
Particulate matter occurs.
The step（b）In grinding pass be 20 times, after grinding material particular diameter D50 be 5 μm.
The step（c）Remaining monomer can pass through low-temperature setting, vacuum in middle inorganic solvent and prepared ink
The mode of suction filtration removes, and reduces monomer remnants amount.
Specific embodiment three：
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is by following component
By weight：
81 parts of epoxy modified acrylic resin；
13 parts of activated monomer；
Protein 15 part；
15 parts of auxiliary agent；
7 parts of organic solvent.
A kind of preparation method of disposable thermometer High-performance ink described in basis, comprises the following steps：
a）Epoxy modified acrylic resin, activated monomer, albumen and auxiliary agent are weighed in proportion, are placed in mixing tank, it is fully mixed
Close；
b）Mixed material, when temperature be down to 50 DEG C, fineness reach 34 μm when, then ground by three-roller, make coating
Granularity reaches less than 9 μm；
c）Material after grinding adjusts viscosity by organic solvent, packs and produces after being uniformly dispersed.
The step（a）The time of middle each component mixing is 40 minutes, makes raw material mixing complete, without obvious bulk, slightly
Particulate matter occurs.
The step（b）In grinding pass be 16 times, after grinding material particular diameter D50 be 3 μm.
The step（c）Remaining monomer can pass through low-temperature setting, vacuum in middle inorganic solvent and prepared ink
The mode of suction filtration removes, and reduces monomer remnants amount.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under the enlightenment of the present invention
The product of form, however, make any change in its shape or structure, it is every that there is skill identical or similar to the present application
Art scheme, is within the scope of the present invention.
Claims (5)
- A kind of 1. disposable thermometer High-performance ink, it is characterised in that：Described disposable thermometer High-performance ink By following component by weight：The epoxy modified acrylic resin is with methyl methacrylate, acrylic acid, 2-ethyl hexyl acrylate, styrene, acrylic acid Hydroxypropyl acrylate and trimethyol propane triacrylate are monomer, and benzoyl peroxide is initiator, and E-44 epoxy resin is modification Agent, aggregated to obtain thermoset epoxy acrylic resin modified；The activated monomer is acrylate monomer, specially methyl acrylate, ethyl acrylate, 2- methyl methacrylates, Ethyl 2-methacrylate, 1,6 hexanediol diacrylate, trimethylolpropane trimethacrylate, tripropylene glycol dipropyl Olefin(e) acid ester and one kind in the acrylate of dipentaerythrite five or more person's mixtures；The albumen is selected from：One or more in bovine hemoglobin, globulin and Egg-white；The auxiliary agent is delustering agent, inorganic filler, levelling agent, styrax, defoamer and adhesion promoter；The organic solvent is one or both of terpinol, butyl carbitol.
- 2. the preparation method of disposable thermometer High-performance ink according to claim 1, it is characterised in that：Including such as Lower step：A) epoxy modified acrylic resin, activated monomer, albumen and auxiliary agent are weighed in proportion, is placed in mixing tank, are sufficiently mixed；B) mixed material, when temperature be down to 40-60 DEG C, fineness reach 30-40 μm when, then ground by three-roller, make painting Material granularity reaches less than 9 μm；C) material after grinding adjusts viscosity by organic solvent, packs and produces after being uniformly dispersed.
- 3. the preparation method of disposable thermometer High-performance ink according to claim 2, it is characterised in that：The step Suddenly the time that each component mixes in (a) is 30-60 minutes, makes raw material mixing complete, goes out without obvious bulk, coarse particulate matter It is existing.
- 4. the preparation method of disposable thermometer High-performance ink according to claim 2, it is characterised in that：The step Suddenly the grinding pass in (b) is 10-20 times, and material particular diameter D50 is 1-5 μm after grinding.
- 5. the preparation method of disposable thermometer High-performance ink according to claim 2, it is characterised in that：The step Suddenly monomer remaining in organic solvent and prepared ink in (c) can be removed by way of low-temperature setting, vacuum filtration, Reduce monomer remnants amount.
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| CN201510734989.3A CN105219156B (en) | 2015-11-03 | 2015-11-03 | A kind of disposable thermometer High-performance ink and preparation method thereof |
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| CN201510734989.3A CN105219156B (en) | 2015-11-03 | 2015-11-03 | A kind of disposable thermometer High-performance ink and preparation method thereof |
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| CN105219156A CN105219156A (en) | 2016-01-06 |
| CN105219156B true CN105219156B (en) | 2017-12-29 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106398393A (en) * | 2016-08-31 | 2017-02-15 | 江门市阪桥电子材料有限公司 | Thermally curable white solder-resist material and preparation method thereof |
| CN113976881B (en) * | 2021-11-01 | 2024-03-08 | 南通天盛新能源股份有限公司 | Preparation method of high-tap-density silver-coated copper powder for synthesizing conductive paste in one pot |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5127948A (en) * | 1989-04-05 | 1992-07-07 | Eka Nobel Landskrona Ab | Water-based chemical compositions |
| WO2001062860A1 (en) * | 2000-02-22 | 2001-08-30 | Croda International Plc | Aqueous inkjet inks |
| CN102140110A (en) * | 2010-09-08 | 2011-08-03 | 上海飞凯光电材料股份有限公司 | High-adhesive force radiation curable activated monomer and preparation method and use thereof |
| CN104312273A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Special flexible environment-friendly printing ink containing modified collagen and preparation method of special flexible environment-friendly printing ink |
-
2015
- 2015-11-03 CN CN201510734989.3A patent/CN105219156B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5127948A (en) * | 1989-04-05 | 1992-07-07 | Eka Nobel Landskrona Ab | Water-based chemical compositions |
| WO2001062860A1 (en) * | 2000-02-22 | 2001-08-30 | Croda International Plc | Aqueous inkjet inks |
| CN102140110A (en) * | 2010-09-08 | 2011-08-03 | 上海飞凯光电材料股份有限公司 | High-adhesive force radiation curable activated monomer and preparation method and use thereof |
| CN104312273A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Special flexible environment-friendly printing ink containing modified collagen and preparation method of special flexible environment-friendly printing ink |
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| CN105219156A (en) | 2016-01-06 |
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Effective date of registration: 20230816 Address after: 226000 No. 9 Siyuan Road, Chongchuan District, Nantong City, Jiangsu Province Patentee after: Nantong University Technology Transfer Center Co.,Ltd. Address before: 226000 Jiangsu city of Nantong province sik Road No. 9 Patentee before: NANTONG University |