CN105219156A - A kind of disposable thermometer High-performance ink and preparation method thereof - Google Patents
A kind of disposable thermometer High-performance ink and preparation method thereof Download PDFInfo
- Publication number
- CN105219156A CN105219156A CN201510734989.3A CN201510734989A CN105219156A CN 105219156 A CN105219156 A CN 105219156A CN 201510734989 A CN201510734989 A CN 201510734989A CN 105219156 A CN105219156 A CN 105219156A
- Authority
- CN
- China
- Prior art keywords
- disposable thermometer
- performance ink
- monomer
- performance
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Dental Preparations (AREA)
Abstract
The invention discloses a kind of disposable thermometer High-performance ink, make after adopting following raw materials mixing, it comprises the component of following weight content: epoxy modified acrylic resin 80-85 part, reactive monomer 10-15 part, protein 10-20 parts, auxiliary agent 10-20 part, organic solvent 1-10 part.The invention also discloses the preparation method of this High-performance ink: after taking epoxy modified acrylic resin, reactive monomer, albumen, auxiliary agent mixing, take three-roll grinder to grind, make Ink particle size D50 reach 1-5 μm; Add organic solvent, adopt high speed dispersor to be uniformly dispersed, canned sealing is stand-by.The ink that the present invention prepares has that solidification value is low, nontoxic, pollution-free, glass attachment power is strong, transformation efficiency is high, monomer remnants amount is low, have biocompatibility and the feature such as can to regulate arbitrarily.
Description
Technical field
The present invention relates to a kind of High-performance ink, particularly relate to a kind of disposable thermometer High-performance ink, the invention still further relates to the preparation method of this High-performance ink simultaneously.
Background technology
World's environmental regulation day by day perfect, the traditional solvent-borne coating of discharge volatile organic matter is made to be subject to great impact, the environment-friendly coating being representative with water-borne coatings, ultraviolet-curing paint, high solid coating and powder coating then arises at the historic moment, and becomes the focus of people's research.
Classify with ink and substantially can be divided into three major types: water-based painting printing ink, dissolvant type spraying/drawing ink, ultraviolet light polymerization painting printing ink.The feature of water-based painting printing ink is bright-colored, environmental protection, but is easy to fade, and color fidelity can only reach about one month.The feature of dissolvant type spraying/drawing ink is photostabilization, good waterproof performance, and stock kind is wide; But because it uses solvent (to comprise acetone, butanone, vinyl acetic monomer in a large number, N-BUTYL ACETATE, alcohols etc.), volatile organic matter (VOCs) content is high on the one hand causes severe contamination to production environment and air, to production operation personnel and subsequent product human consumer is healthy very large harm, and potential safety hazard is brought to production process; Also there is on the other hand solvent cost to be limited by international oil price fluctuation and to cause transfer paper price to improve.The feature of ultraviolet light polymerization painting printing ink is not containing volatile solvent, film wink-dry, save energy, and fast light, weather-proof after solidification, water-repellancy is fine; But it, containing a large amount of monomer, has very strong pungency and corrodibility, easily burns and cause human allergy.
Summary of the invention
Goal of the invention: the invention provides a kind of disposable thermometer High-performance ink and preparation method thereof, this ink has that solidification value is low, nontoxic, pollution-free, glass attachment power is strong, transformation efficiency is high, monomer remnants amount is low, have biocompatibility and the feature such as can to regulate arbitrarily.
Technical scheme: a kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is made up of according to parts by weight following component:
Epoxy modified acrylic resin 80-85 part;
Reactive monomer 10-15 part;
Protein 10-20 parts;
Auxiliary agent 10-20 part;
Organic solvent 1-10 part.
As optimization: described epoxy modified acrylic resin is for monomer with methyl methacrylate, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, trimethyol propane triacrylate, benzoyl peroxide is initiator, E-44 epoxy resin is properties-correcting agent, through polymerization, to obtain thermoset epoxy acrylic resin modified, has excellent adhesive property, wear resisting property, chemical stability, the feature such as with low cost.
As optimization: described reactive monomer is acrylate monomer, be specially the one in methyl acrylate, ethyl propenoate, 2-methyl methacrylate, ethyl 2-methacrylate, 1,6 hexanediol diacrylate, Viscoat 295, tri (propylene glycol) diacrylate and dipentaerythritol five acrylate or many persons mixture.
As optimization: described albumen is selected from: one or more in bovine hemoglobin, sphaeroprotein and egg albumen, effect is the biocompatibility strengthening ink.
As optimization: described auxiliary agent is extinction machine, mineral filler, flow agent, st-yrax, defoamer and adhesion promoter.
As optimization: described organic solvent is one or both in Terpineol 350, diethylene glycol monobutyl ether.
A preparation method for disposable thermometer High-performance ink described in basis, comprises the steps:
A) take epoxy modified acrylic resin, reactive monomer, albumen and auxiliary agent in proportion, be placed in mixing tank, fully mix;
B) mixed material, until temperature be down to 40-60 DEG C, fineness reach 30-40 μm time, then to be ground by three-roller, make coating particle size reach less than 9 μm;
C) material after grinding, by organic solvent adjusting viscosity, is packed after being uniformly dispersed and get final product.
As optimization: in described step (a), the time of each component mixing is 30-60 minute, make starting material mix completely, occur without obvious bulk, coarse particulate matter.
As optimization: the grinding pass in described step (b) is 10-20 time, after grinding, material particular diameter D50 is 1-5 μm.
As optimization: in inorganic solvent and prepared ink, remaining monomer can be removed by the mode of low-temperature curing, vacuum filtration in described step (c), decreases monomer remnants amount.
Beneficial effect: the ink that the present invention prepares has that solidification value is low, nontoxic, pollution-free, glass attachment power is strong, transformation efficiency is high, monomer remnants amount is low, have biocompatibility and the feature such as can to regulate arbitrarily.Concrete advantage is as follows:
(1) described thermoset epoxy is acrylic resin modified, has excellent adhesive property, wear resisting property, chemical stability, the feature such as with low cost.
(2) described albumen effect is the biocompatibility strengthening ink.
(3) remaining in inorganic solvent and prepared ink monomer is removed by the mode of low-temperature curing, vacuum filtration, decreases monomer remnants amount.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
Be summarized as follows: in the present invention, described epoxy modified acrylic resin is for monomer with methyl methacrylate, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, trimethyol propane triacrylate, benzoyl peroxide is initiator, E-44 epoxy resin is properties-correcting agent, through polymerization, to obtain thermoset epoxy acrylic resin modified, has excellent adhesive property, wear resisting property, chemical stability, the feature such as with low cost.
Described reactive monomer is acrylate monomer, be specially the one in methyl acrylate, ethyl propenoate, 2-methyl methacrylate, ethyl 2-methacrylate, 1,6 hexanediol diacrylate, Viscoat 295, tri (propylene glycol) diacrylate and dipentaerythritol five acrylate or many persons mixture.
Described albumen is selected from: one or more in bovine hemoglobin, sphaeroprotein and egg albumen, and effect is the biocompatibility strengthening ink.
Described auxiliary agent is extinction machine, mineral filler, flow agent, st-yrax, defoamer and adhesion promoter.
Described organic solvent is one or both in Terpineol 350, diethylene glycol monobutyl ether.
Specific embodiment one:
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is made up of according to parts by weight following component:
Epoxy modified acrylic resin 80 parts;
Reactive monomer 10 parts;
Protein 10 part;
Auxiliary agent 10 parts;
Organic solvent 1 part.
A preparation method for disposable thermometer High-performance ink described in basis, comprises the steps:
A) take epoxy modified acrylic resin, reactive monomer, albumen and auxiliary agent in proportion, be placed in mixing tank, fully mix;
B) mixed material, until temperature be down to 40 DEG C, fineness reach 30 μm time, then to be ground by three-roller, make coating particle size reach less than 9 μm;
C) material after grinding, by organic solvent adjusting viscosity, is packed after being uniformly dispersed and get final product.
In described step (a), the time of each component mixing is 30 minutes, makes starting material mix completely, occurs without obvious bulk, coarse particulate matter.
Grinding pass in described step (b) is 10 times, and after grinding, material particular diameter D50 is 1 μm.
In inorganic solvent and prepared ink, remaining monomer can be removed by the mode of low-temperature curing, vacuum filtration in described step (c), decreases monomer remnants amount.
Specific embodiment two:
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is made up of according to parts by weight following component:
Epoxy modified acrylic resin 85 parts;
Reactive monomer 15 parts;
Protein 20 part;
Auxiliary agent 20 parts;
Organic solvent 10 parts.
A preparation method for disposable thermometer High-performance ink described in basis, comprises the steps:
A) take epoxy modified acrylic resin, reactive monomer, albumen and auxiliary agent in proportion, be placed in mixing tank, fully mix;
B) mixed material, until temperature be down to 60 DEG C, fineness reach 40 μm time, then to be ground by three-roller, make coating particle size reach less than 9 μm;
C) material after grinding, by organic solvent adjusting viscosity, is packed after being uniformly dispersed and get final product.
In described step (a), the time of each component mixing is 60 minutes, makes starting material mix completely, occurs without obvious bulk, coarse particulate matter.
Grinding pass in described step (b) is 20 times, and after grinding, material particular diameter D50 is 5 μm.
In inorganic solvent and prepared ink, remaining monomer can be removed by the mode of low-temperature curing, vacuum filtration in described step (c), decreases monomer remnants amount.
Specific embodiment three:
A kind of disposable thermometer High-performance ink, described disposable thermometer High-performance ink is made up of according to parts by weight following component:
Epoxy modified acrylic resin 81 parts;
Reactive monomer 13 parts;
Protein 15 part;
Auxiliary agent 15 parts;
Organic solvent 7 parts.
A preparation method for disposable thermometer High-performance ink described in basis, comprises the steps:
A) take epoxy modified acrylic resin, reactive monomer, albumen and auxiliary agent in proportion, be placed in mixing tank, fully mix;
B) mixed material, until temperature be down to 50 DEG C, fineness reach 34 μm time, then to be ground by three-roller, make coating particle size reach less than 9 μm;
C) material after grinding, by organic solvent adjusting viscosity, is packed after being uniformly dispersed and get final product.
In described step (a), the time of each component mixing is 40 minutes, makes starting material mix completely, occurs without obvious bulk, coarse particulate matter.
Grinding pass in described step (b) is 16 times, and after grinding, material particular diameter D50 is 3 μm.
In inorganic solvent and prepared ink, remaining monomer can be removed by the mode of low-temperature curing, vacuum filtration in described step (c), decreases monomer remnants amount.
The present invention is not limited to above-mentioned preferred forms; anyone can draw other various forms of products under enlightenment of the present invention; no matter but any change is done in its shape or structure; every have identical with the application or akin technical scheme, all drops within protection scope of the present invention.
Claims (10)
1. a disposable thermometer High-performance ink, is characterized in that: described disposable thermometer High-performance ink is made up of according to parts by weight following component:
Epoxy modified acrylic resin 80-85 part;
Reactive monomer 10-15 part;
Protein 10-20 parts;
Auxiliary agent 10-20 part;
Organic solvent 1-10 part.
2. disposable thermometer High-performance ink according to claim 1, it is characterized in that: described epoxy modified acrylic resin is for monomer with methyl methacrylate, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, trimethyol propane triacrylate, benzoyl peroxide is initiator, E-44 epoxy resin is properties-correcting agent, through polymerization, to obtain thermoset epoxy acrylic resin modified, has excellent adhesive property, wear resisting property, chemical stability, the feature such as with low cost.
3. disposable thermometer High-performance ink according to claim 1, it is characterized in that: described reactive monomer is acrylate monomer, be specially the one in methyl acrylate, ethyl propenoate, 2-methyl methacrylate, ethyl 2-methacrylate, 1,6 hexanediol diacrylate, Viscoat 295, tri (propylene glycol) diacrylate and dipentaerythritol five acrylate or many persons mixture.
4. disposable thermometer High-performance ink according to claim 1, is characterized in that: described albumen is selected from: one or more in bovine hemoglobin, sphaeroprotein and egg albumen, and effect is the biocompatibility strengthening ink.
5. disposable thermometer High-performance ink according to claim 1, is characterized in that: described auxiliary agent is extinction machine, mineral filler, flow agent, st-yrax, defoamer and adhesion promoter.
6. disposable thermometer High-performance ink according to claim 1, is characterized in that: described organic solvent is one or both in Terpineol 350, diethylene glycol monobutyl ether.
7. the preparation method of disposable thermometer High-performance ink according to claim 1, is characterized in that: comprise the steps:
A) take epoxy modified acrylic resin, reactive monomer, albumen and auxiliary agent in proportion, be placed in mixing tank, fully mix;
B) mixed material, until temperature be down to 40-60 DEG C, fineness reach 30-40 μm time, then to be ground by three-roller, make coating particle size reach less than 9 μm;
C) material after grinding, by organic solvent adjusting viscosity, is packed after being uniformly dispersed and get final product.
8. the preparation method of disposable thermometer High-performance ink according to claim 7, is characterized in that: in described step (a), the time of each component mixing is 30-60 minute, makes starting material mix completely, occurs without obvious bulk, coarse particulate matter.
9. the preparation method of disposable thermometer High-performance ink according to claim 7, is characterized in that: the grinding pass in described step (b) is 10-20 time, and after grinding, material particular diameter D50 is 1-5 μm.
10. the preparation method of disposable thermometer High-performance ink according to claim 7, it is characterized in that: in inorganic solvent and prepared ink, remaining monomer can be removed by the mode of low-temperature curing, vacuum filtration in described step (c), decreases monomer remnants amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510734989.3A CN105219156B (en) | 2015-11-03 | 2015-11-03 | A kind of disposable thermometer High-performance ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510734989.3A CN105219156B (en) | 2015-11-03 | 2015-11-03 | A kind of disposable thermometer High-performance ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105219156A true CN105219156A (en) | 2016-01-06 |
| CN105219156B CN105219156B (en) | 2017-12-29 |
Family
ID=54988456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510734989.3A Active CN105219156B (en) | 2015-11-03 | 2015-11-03 | A kind of disposable thermometer High-performance ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105219156B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398393A (en) * | 2016-08-31 | 2017-02-15 | 江门市阪桥电子材料有限公司 | Thermally curable white solder-resist material and preparation method thereof |
| CN113976881A (en) * | 2021-11-01 | 2022-01-28 | 南通天盛新能源股份有限公司 | Preparation method of high-compaction silver-coated copper powder for synthesizing conductive paste in one pot |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5127948A (en) * | 1989-04-05 | 1992-07-07 | Eka Nobel Landskrona Ab | Water-based chemical compositions |
| WO2001062860A1 (en) * | 2000-02-22 | 2001-08-30 | Croda International Plc | Aqueous inkjet inks |
| CN102140110A (en) * | 2010-09-08 | 2011-08-03 | 上海飞凯光电材料股份有限公司 | High-adhesive force radiation curable activated monomer and preparation method and use thereof |
| CN104312273A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Special flexible environment-friendly printing ink containing modified collagen and preparation method of special flexible environment-friendly printing ink |
-
2015
- 2015-11-03 CN CN201510734989.3A patent/CN105219156B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5127948A (en) * | 1989-04-05 | 1992-07-07 | Eka Nobel Landskrona Ab | Water-based chemical compositions |
| WO2001062860A1 (en) * | 2000-02-22 | 2001-08-30 | Croda International Plc | Aqueous inkjet inks |
| CN102140110A (en) * | 2010-09-08 | 2011-08-03 | 上海飞凯光电材料股份有限公司 | High-adhesive force radiation curable activated monomer and preparation method and use thereof |
| CN104312273A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Special flexible environment-friendly printing ink containing modified collagen and preparation method of special flexible environment-friendly printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398393A (en) * | 2016-08-31 | 2017-02-15 | 江门市阪桥电子材料有限公司 | Thermally curable white solder-resist material and preparation method thereof |
| CN113976881A (en) * | 2021-11-01 | 2022-01-28 | 南通天盛新能源股份有限公司 | Preparation method of high-compaction silver-coated copper powder for synthesizing conductive paste in one pot |
| CN113976881B (en) * | 2021-11-01 | 2024-03-08 | 南通天盛新能源股份有限公司 | Preparation method of high-tap-density silver-coated copper powder for synthesizing conductive paste in one pot |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105219156B (en) | 2017-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104004451B (en) | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof | |
| CN106752785B (en) | Aqueous UV silver powder coating and preparation method thereof | |
| CN103602224B (en) | A kind of white solvent-free finish paint and its preparation method and construction technology | |
| CN101348638B (en) | Efficient reflectorized paint | |
| CN104087127A (en) | Ultraviolet curing antique roller coating matt base coat and preparation method thereof | |
| CN102993908A (en) | UV (Ultraviolet) white primer for electrostatic spraying | |
| CN104087063A (en) | UV (ultraviolet) photo-curable dip-coating and coloring printing ink and preparation method thereof | |
| CN103224722A (en) | UV-curable fluorocarbon solar cell back-side protective film paint | |
| CN104559698B (en) | A kind of color inhibition UV transparent primings for electrostatic spraying | |
| CN101838505A (en) | Colored light-curing adhesive for adhering and sealing filled-words of metal keys and preparation method thereof | |
| CN102925052A (en) | Double-curing vacuum plating UV (Ultraviolet) coating finish | |
| CN103013275A (en) | Low-odor UV (Ultraviolet) roller painting primer | |
| CN104073040A (en) | UV-cured white curtaining paint and preparation method thereof | |
| CN105219156A (en) | A kind of disposable thermometer High-performance ink and preparation method thereof | |
| CN105885658A (en) | Water-based one-component automobile paint containing iron oxide pigment and preparation method of water-based one-component automobile paint | |
| CN104804525A (en) | UV curing transparent ink and preparation method thereof | |
| CN106366730A (en) | Ultraviolet light curing coating for steel tube | |
| CN103805007A (en) | Benzene-free spray paint and preparation method thereof | |
| CN103525293A (en) | Non-yellowing UV (Ultraviolet) gloss oil as well as preparation method thereof | |
| CN103834270A (en) | Smell and toxicity removing fragrant ultraviolet curing wood lacquer and preparation method thereof | |
| CN103436080A (en) | UV decorative ink used for PC/PMMA sheets and preparation method thereof | |
| CN102732137A (en) | Environment-friendly light-curing electrostatic spraying primer | |
| CN103834278B (en) | A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof | |
| CN103131303B (en) | A kind of powder coating containing Vanay | |
| CN102146244A (en) | Self-healing plastic coating primer with high durability and rubber hand feel as well as production method and application method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230816 Address after: 226000 No. 9 Siyuan Road, Chongchuan District, Nantong City, Jiangsu Province Patentee after: Nantong University Technology Transfer Center Co.,Ltd. Address before: 226000 Jiangsu city of Nantong province sik Road No. 9 Patentee before: NANTONG University |
|
| TR01 | Transfer of patent right |