CN105218158A - A kind of happy ceramic tile - Google Patents

A kind of happy ceramic tile Download PDF

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Publication number
CN105218158A
CN105218158A CN201510533845.1A CN201510533845A CN105218158A CN 105218158 A CN105218158 A CN 105218158A CN 201510533845 A CN201510533845 A CN 201510533845A CN 105218158 A CN105218158 A CN 105218158A
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China
Prior art keywords
ceramic tile
happy
dry granular
charity
coat enamel
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CN201510533845.1A
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Chinese (zh)
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CN105218158B (en
Inventor
林家生
刘汉津
梁瑞平
石颍
李宣营
熊国锋
杨家进
朱志明
邓飞
涂伟明
吴云平
赵英
黄金保
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BOHUA CERAMIC Co Ltd GUANGDONG
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BOHUA CERAMIC Co Ltd GUANGDONG
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Publication of CN105218158B publication Critical patent/CN105218158B/en
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Abstract

<b> happy ceramic tile </b>, it is characterized in that the happy ceramic tile </b> of <b> realizes by the following method: be included in charity cover-coat enamel on ceramic tile blank, charity dry granular after charity cover-coat enamel, fire afterwards, aftertreatment obtains happy ceramic tile, dry granular is that a kind of high temperature viscosity is large, and transparency and the good frit of glossiness are formed by granulation.The present invention compared with the prior art, there is dry granular be evenly distributed, good with the bonding properties of bad body, finished product shows soft gloss under light, and there are the texture of " granulated sugar grain " and a stereoscopic sensation in surface, texture is lively simultaneously, color is true to nature, and luster effect is good, and fastness to rubbing is strong, anti-skid is good, the advantage that hardness is high.

Description

A kind of happy ceramic tile
Technical field:
The present invention relates to a kind of ceramic tile.
Background technology:
Happy ceramic tile is a kind of at billet surface charity one deck dry granular, fires a kind of combination with decorative surfaces having granulated sugar particle of rear generation, makes it have a kind of texture of solid.The dry granular size of current use is different, in order to make ceramic brick surface effect seem relatively more even, tries one's best dry granular size controlling within smaller scope.
Existing happy ceramic tile, also known as " candy glaze " on market, its manufacturing process mainly contains following several: one is apply dry granular in the mode of dry type cloth at ceramic brick surface by dry granular machine, its advantage is that dry granular granularity is controlled, shortcoming uses conventional material distributing machine cloth dry granular skewness, forms agglomeration sometimes; Two is get ready on ceramic brick surface with wet-format by getting rid of glaze cabinet, and its advantage is good with the associativity of base substrate, and shortcoming is dry granular poor fluidity, and easily stifled spray gun eye, produces bad control; Three is apply dry granular by half tone in the mode of silk screen printing, and its advantage is that dry granular is evenly distributed, and shortcoming is that half tone breakage rate is large, and cost is high, and the amount applying dry granular is few.
There is different defects in existing manufacturing process, cause the yield rate of happy ceramic tile lower, manufacturing cost is high.
Summary of the invention:
Goal of the invention of the present invention is to provide a kind of dry granular to be evenly distributed, good with the bonding properties of bad body, finished product shows soft gloss under light, there are the texture of " granulated sugar grain " and a stereoscopic sensation in surface, and texture is lively simultaneously, and color is true to nature, luster effect is good, fastness to rubbing is strong, and anti-skid is good, and hardness is high happy ceramic tile.
The present invention happy ceramic tilerealize by the following method: be included in charity cover-coat enamel on ceramic tile blank, after charity cover-coat enamel, charity dry granular, fires afterwards, and aftertreatment obtains happy ceramic tile, dry granular is that a kind of high temperature viscosity is large, and transparency and the good frit of glossiness are formed by granulation.Its main raw is:
Its composition is (unit is weight part):
Adopt first charity cover-coat enamel, then charity dry granular, can ensure under reliable, low cost dry granular can all with charity on ceramic tile surface, meanwhile, utilize the effect of cover-coat enamel, guarantee dry granular can be securely fixed in ceramic tile surface, to realize the goal of the invention of present patent application.
Further charity fixing agent after charity dry granular, fixing agent is the high molecular weight water soluble polymer of the wide model of a kind of purposes, and its performance, between plastics and rubber, is bonded at brick face with fixing dry granular, the main polyvinyl alcohol of its composition, molecule or be [C2H40]
Here, the charity of dry granular is that candy glaze comprises dry granular, suspension agent, and the weight ratio of dry granular and suspension agent is 1:2-4 with the form charity of candy glaze.
In order to ensure to have good flash effect, the particle diameter of dry granular is between 100 orders and 200 orders.
The consumption of the dry granular in dry granular glaze required on 330mm × 330mm ceramic tile blank is 20g ± 2.
What charity cover-coat enamel adopted is drench glaze mode: mainly adopt straight line slip shower and bell jar to drench glaze, drench glaze to require to drench glaze while stirring, drench glaze weight general control at 35 ~ 40 grams (300 × 300 standard plates), when drenching glaze, note the accurate of all even glaze volume of glaze curtain thickness.
Consisting of of cover-coat enamel: become glaze 900-1100 weight part, zirconium silicate 90-110 weight part, thickening material 1.2-1.4 weight part, tripoly phosphate sodium STPP 1.0-1.2 weight part, Sodium salts humic acids 1-3 weight part.
Glaze slip fineness is after 300g glaze slip crosses 325 mesh sieves, and tailing over is 0.8 ~ 1.6g.
Before charity dry granular, first ink-jet printed on cover-coat enamel, to enrich the pattern texture of ceramic tile surface.
The technological process of production: blank selection → by formula goals → ball milling → sizing material iron removing sieve → mist projection granulating → press-molding → biscuiting → pouring ground-coat enamel → pouring cover-coat enamel → side washing → ink-jet printed → pouring candy glaze → glaze firing → edging → classification → packaging is as storehouse.
The present invention compared with the prior art, there is dry granular be evenly distributed, good with the bonding properties of bad body, finished product shows soft gloss under light, and there are the texture of " granulated sugar grain " and a stereoscopic sensation in surface, texture is lively simultaneously, color is true to nature, and luster effect is good, and fastness to rubbing is strong, anti-skid is good, the advantage that hardness is high.
Embodiment:
Now the present invention is described in further detail in conjunction with the embodiments:
The present invention happy ceramic tilerealize by the following method: blank selection → by formula goals → ball milling → sizing material iron removing sieve → mist projection granulating → press-molding → biscuiting → pouring ground-coat enamel → pouring cover-coat enamel → side washing → ink-jet printed → pouring candy glaze → glaze firing → edging → classification → packaging is as storehouse.
The composition of dry granular is (unit is weight part):
Its composition is (unit is weight part)::
Candy glaze comprises dry granular, suspension agent, and the weight ratio of dry granular and suspension agent is 1:2-4.
Suspension agent: mainly a kind of mobility, suspension and the good high molecular polymer of viscosity, have polymolecularity and adhesivity, make dry granular not conglomeration in glaze, do not precipitate, can be suspended in glaze uniformly, thus after ensureing to drench glaze, the uniform particles of candy glaze is distributed in brick face.Suspension agent is a kind of interfacial agent simultaneously in molecule with lipophilicity and wetting ability two kinds of opposite nature, can homogeneous dispersion those be difficult to be dissolved in the inorganic of liquid, the solid particulate of pigment dyestuff, also can prevent sedimentation and the cohesion of solid particulate, its composition is simultaneously:
Title Ethylene glycol CH9 Xylo-Mucine Polypropylene Sodium Benzoate Water
Weight consumption ratio 15-25 180-250 30-50 0.4-0.5 30-45
After the special candy glaze of spray, spray fixing agent further, fixing agent is the high molecular weight water soluble polymer of the wide model of a kind of purposes, and its performance, between plastics and rubber, is bonded at brick face with fixing dry granular, the main polyvinyl alcohol of its composition, molecule or be [C2H40]
Time of drying of special dry granular glaze is extended with fixing dry granular.Fixing agent comprises polyethylene alcohol and water, and both weight consumptions are than being 1:2.5-3.5.
The particle diameter of dry granular is between 100 orders and 200 order orders.
The consumption of the dry granular in dry granular glaze required on 330mm × 330mm cement base substrate is 20g ± 2.
Before charity dry granular, first ink-jet printed on cover-coat enamel, to enrich the pattern texture of ceramic tile surface.
Consisting of of cover-coat enamel: become glaze, zirconium silicate, CH9 Xylo-Mucine, tripoly phosphate sodium STPP, Sodium salts humic acids.
Glaze slip fineness is after 300g glaze slip crosses 325 mesh sieves, and tailing over is 0.8 ~ 1.6g.
Dry granular glaze and cover-coat enamel component content following (unit is weight part):

Claims (10)

1. a kind of happy ceramic tile, it is characterized in that happy ceramic tilerealize by the following method: be included in charity cover-coat enamel on ceramic tile blank, after charity cover-coat enamel, charity dry granular, fires afterwards, and aftertreatment obtains happy ceramic tile, dry granular is that a kind of high temperature viscosity is large, and transparency and the good frit of glossiness are formed by granulation.
2. according to claim 1 happy ceramic tile, it is characterized in that each Ingredients Weight content forming dry granular is:
Its chemical weight content is:
3. according to claim 1 and 2 happy ceramic tile, it is characterized in that the particle diameter of dry granular is between 120 ~ 250 orders.
4. according to claim 1 and 2 happy ceramic tile, it is characterized in that the charity of dry granular is that candy glaze comprises dry granular, suspension agent, and the weight ratio of dry granular and suspension agent is 1:2-4 with the form charity of candy glaze.
5. according to claim 4 happy ceramic tile, it is characterized in that each Ingredients Weight content of composition suspension agent is:
Title Ethylene glycol Thickening material Polypropylene Sodium Benzoate Water Consumption 15-25 180-250 30-50 0.4-0.5 30-45
6. according to claim 3 happy ceramic tile, it is characterized in that the charity of dry granular is that candy glaze comprises dry granular, suspension agent, and the weight ratio of dry granular and suspension agent is 1:2-4 with the form charity of candy glaze.
7. according to claim 6 happy ceramic tile, each Ingredients Weight content of its feature composition suspension agent is:
Title Ethylene glycol Thickening material Polypropylene Sodium Benzoate Water Consumption 15-25 180-250 30-50 0.4-0.5 30-45
8. according to claim 1 or 2 or 5 or 7 happy ceramic tile, it is characterized in that the particle diameter of dry granular is between 100 orders and 200 orders.
9. according to claim 1 or 2 or 5 or 7 happy ceramic tile, it is characterized in that consisting of of cover-coat enamel: become glaze 900-1100 weight part, zirconium silicate 90-110 weight part, thickening material 1.2-1.4 weight part, tripoly phosphate sodium STPP 1.0-1.2 weight part, Sodium salts humic acids 1-3 weight part.
10. according to claim 1 or 2 or 5 or 7 happy ceramic tile, it is characterized in that before charity dry granular, first ink-jet printed on cover-coat enamel.
CN201510533845.1A 2015-08-27 2015-08-27 A kind of happy Ceramic Tiles Active CN105218158B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106431193A (en) * 2016-09-07 2017-02-22 安徽金生金世电子科技有限公司 Anti-skidding wall brick and preparation method thereof
CN106830686A (en) * 2017-01-03 2017-06-13 佛山石湾华鹏陶瓷有限公司 It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method
CN108911510A (en) * 2018-09-05 2018-11-30 安徽磐盛新型材料科技有限公司 A kind of the effect glaze and its application method of architectural pottery incrustation
CN111099923A (en) * 2019-12-30 2020-05-05 肇庆乐华陶瓷洁具有限公司 Colorful ceramic tile and preparation method thereof
CN113248144A (en) * 2021-05-06 2021-08-13 佛山市三水宏源陶瓷企业有限公司 Preparation method of matte and fine surface of dry grain glazed rock plate
CN115057728A (en) * 2022-08-19 2022-09-16 广东兴辉陶瓷集团有限公司 Production process of positioning stripping dry grain ceramic tile and product thereof

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CN102951928A (en) * 2012-10-16 2013-03-06 广东道氏技术股份有限公司 Microcrystal dry grain adhering agent
CN103113135A (en) * 2013-01-31 2013-05-22 星谊精密陶瓷科技(昆山)有限公司 Microbead-like dry granules, as well as preparation method and application thereof
CN203022284U (en) * 2012-11-27 2013-06-26 广东道氏技术股份有限公司 Inkjet microcrystal ceramic composite brick
CN103525184A (en) * 2013-09-30 2014-01-22 广州市溯达印章用品有限公司 Environmental-protection stamp-pad ink and preparation method thereof
CN103922815A (en) * 2014-03-25 2014-07-16 广东金意陶陶瓷有限公司 Manufacturing process of ceramic brick with candy effect
CN104016728A (en) * 2014-06-03 2014-09-03 广东蒙娜丽莎新型材料集团有限公司 Ceramic tile with bulged particle effect and preparation method of ceramic tile

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951928A (en) * 2012-10-16 2013-03-06 广东道氏技术股份有限公司 Microcrystal dry grain adhering agent
CN203022284U (en) * 2012-11-27 2013-06-26 广东道氏技术股份有限公司 Inkjet microcrystal ceramic composite brick
CN103113135A (en) * 2013-01-31 2013-05-22 星谊精密陶瓷科技(昆山)有限公司 Microbead-like dry granules, as well as preparation method and application thereof
CN103525184A (en) * 2013-09-30 2014-01-22 广州市溯达印章用品有限公司 Environmental-protection stamp-pad ink and preparation method thereof
CN103922815A (en) * 2014-03-25 2014-07-16 广东金意陶陶瓷有限公司 Manufacturing process of ceramic brick with candy effect
CN104016728A (en) * 2014-06-03 2014-09-03 广东蒙娜丽莎新型材料集团有限公司 Ceramic tile with bulged particle effect and preparation method of ceramic tile

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106431193A (en) * 2016-09-07 2017-02-22 安徽金生金世电子科技有限公司 Anti-skidding wall brick and preparation method thereof
CN106830686A (en) * 2017-01-03 2017-06-13 佛山石湾华鹏陶瓷有限公司 It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method
CN108911510A (en) * 2018-09-05 2018-11-30 安徽磐盛新型材料科技有限公司 A kind of the effect glaze and its application method of architectural pottery incrustation
CN111099923A (en) * 2019-12-30 2020-05-05 肇庆乐华陶瓷洁具有限公司 Colorful ceramic tile and preparation method thereof
CN113248144A (en) * 2021-05-06 2021-08-13 佛山市三水宏源陶瓷企业有限公司 Preparation method of matte and fine surface of dry grain glazed rock plate
CN115057728A (en) * 2022-08-19 2022-09-16 广东兴辉陶瓷集团有限公司 Production process of positioning stripping dry grain ceramic tile and product thereof
CN115057728B (en) * 2022-08-19 2022-11-01 广东兴辉陶瓷集团有限公司 Production process of positioning stripping dry grain ceramic tile and product thereof

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