CN102951928A - Microcrystal dry grain adhering agent - Google Patents

Microcrystal dry grain adhering agent Download PDF

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Publication number
CN102951928A
CN102951928A CN2012103918603A CN201210391860A CN102951928A CN 102951928 A CN102951928 A CN 102951928A CN 2012103918603 A CN2012103918603 A CN 2012103918603A CN 201210391860 A CN201210391860 A CN 201210391860A CN 102951928 A CN102951928 A CN 102951928A
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China
Prior art keywords
dry granular
agent
crystallite
microcrystal
caking agent
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CN2012103918603A
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Chinese (zh)
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CN102951928B (en
Inventor
石教艺
李向钰
张翼
黄国花
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广东道氏技术股份有限公司
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Priority to CN201210391860.3A priority Critical patent/CN102951928B/en
Publication of CN102951928A publication Critical patent/CN102951928A/en
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Publication of CN102951928B publication Critical patent/CN102951928B/en

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Abstract

The invention discloses a microcrystal dry grain adhering agent which comprises the following components in percentage by mass of 2.7-3.6 percent of alkali swelling type thickening agent, 1.2-1.8 percent of bentonite and 1.4-2.7 percent of assistant, a pH regulating agent for regulating the pH of a system to be 8.0-9.0, and the balance of solvent. During use, microcrystal dry grains are uniformly mixed with microcrystal dry grain adhering agent and then the mixture is applied to the surface of a blank body. The microcrystal dry grain adhering agent disclosed by the invention is suitable for microcrystal dry grains with a grain size of 100-250 meshes; in a process of preparing a microcrystal brick, the microcrystal dry grains are prevented from being taken away by low negative pressure of a preheating band of a kiln if the microcrystal dry grains are too small in grain size, therefore, flaws such as a large quantity of pinholes and bubbles in the surface of the microcrystal brink are avoided. After being mixed with the adhering agent provided by the invention, the microcrystal dry grains are good in suspension property, stability and flowability, do not easily precipitate, and cannot generate bubbles after being continuously used.

Description

A kind of crystallite dry granular caking agent
Technical field
The invention belongs to architectural ceramic industry, be specifically related to a kind of crystallite dry granular caking agent.
Background technology
Crystallite brick is the crystallite composite brick of a kind of alternative stone material of in recent years ceramic industry development, the flaw that it has not only avoided lithotome to exist, and integrate glass, pottery, stone material advantage, compact product structure, clean mark, glittering and translucent, stereoscopic sensation is strong, has the sensation as the beautiful matter.Crystallite brick is that after polished finish, the lines of stone material is life-like at the thick transparent layer of surface decoration 2~5 mm of general Antique Imitation Tiles, and specular brightness reaches 95 to 97, has reappeared a kind of as beautiful in the gentle effect as the amber.At present, crystallite brick mainly is to cover certain thickness dry granular (size of dry granular is at 20~100 orders) on the glaze upper berth by cloth system, and spray one deck fixing agent is being fixed on billet surface with dry granular, burn till and rear glaze is polished, the quality of dry granular has directly determined the quality of crystallite brick decorative effect, in the production, too little particle is introduced easily pin hole and bubble when burning till, what is more important fine particle (particle diameter is not more than 100 orders) since lighter weight easily in the preheating zone of kiln owing to lower negative pressure is sucked away.
Along with the crystallite dry granular of various decorative effects arises at the historic moment, its market of bringing also is inestimable.But impact grinding is adopted in the processing of dry granular at present, dry granular is directly fallen into the rotating disk of high speed rotating by machine top, under the effect of high speed centrifugation power, the target stone of shunting around rotating disk in the umbellate form mode with another part produces high-speed bump and highdensity pulverizing, building stones are after hitting mutually, can between rotating disk and casing, form vortex motion again and cause repeatedly mutual strike, friction, pulverizing, the straight-through discharge from the bottom.This processing mode has produced part can't adapt to the small dry granular (particle diameter is not more than 100 orders) of existing cloth system, thereby has caused the wasting of resources.Common small dry granular (particle diameter is not more than 100 orders) is difficult to directly be fixed on the surface of base substrate, therefore is difficult to directly be applied.If by in dry granular, adding caking agent again to drench the mode of glaze, then can realize small dry granular is fixed on equably the surface of base substrate, thereby reach good application.So, be badly in need of a kind of dry granular caking agent of research and connect small dry granular, adopt modes such as drenching glaze that small dry granular is applied to actual production, thereby turn waste into wealth, both can reduce the waste of resource, can bring considerable economic benefit for enterprise again.
Glaze pouring require to add the crystallite dry granular and mixes with caking agent afterwards that flow velocity is lower than 50s(30 ℃, is coated with-4 glasss), and can not precipitate, the solid content of crystallite dry granular is higher than 60%, but this to be common glue or caking agent be difficult to realize.Domestic research and comparison to crystallite dry granular caking agent is few at present, and the rare product that occurs on the market also presents various limitation.So work out and add good fluidity behind the crystallite dry granular, suspension excellence and the high caking agent of solid holdup and will have wide market outlook.
Summary of the invention
The object of the present invention is to provide a kind of crystallite dry granular caking agent.
For existing deficiency in the prior art, the technical solution adopted in the present invention is:
A kind of crystallite dry granular caking agent, by mass percentage, contain following component: alkali swelling type thickening material 2.7~3.6%, wilkinite 1.2~1.8%, auxiliary agent 1.4~2.7% are 8.0~9.0 with the pH of pH adjusting agent regulation system, and surplus is solvent.
Preferably, auxiliary agent is dispersion agent, defoamer, and the quality percentage composition of dispersion agent is 1.0~2.2% in the system, the quality percentage composition of defoamer is 0.2~0.5%.
Preferably, alkali swelling type thickening material is the multipolymer of acrylate and methacrylic ester.
Preferably, dispersion agent is at least a among tripoly phosphate sodium STPP, sodium polyacrylate, the polycarboxylate sodium.
Preferably, defoamer is polymethyl siloxane.
Preferably, solvent is at least a in water, the ethylene glycol.
Preferably, pH adjusting agent is at least a in sodium hydroxide, the ammoniacal liquor.
The preparation method of above-mentioned crystallite dry granular caking agent may further comprise the steps:
1) alkali swelling type thickening material is dissolved in the partial solvent, stirs;
2) continue to add dispersion agent, polymethyl siloxane, stir;
3) adding pH adjusting agent regulation system pH value is 8.0~9.0;
4) add wilkinite, residual solvent, stir, get crystallite dry granular caking agent.
The using method of above-mentioned crystallite dry granular caking agent may further comprise the steps: crystallite dry granular and crystallite dry granular caking agent are mixed, impose on billet surface.
Preferably, the granular size of crystallite dry granular is 100~250 orders.
Preferably, mixed crystallite dry granular pouring is imposed on billet surface.In the production, in the mode of drenching glaze mixed crystallite dry granular is drenched on the surface of base substrate, viscosity can require to regulate according to glaze pouring.
The invention has the beneficial effects as follows:
Crystallite dry granular caking agent of the present invention is applicable to the less crystallite dry granular of particle (100~250 order), in the process of preparation crystallite brick, avoid the crystallite dry granular to be sucked away by the lower negative pressure of kiln preheating zone owing to particle is too little, thereby avoided the crystallite brick surface flaws such as a large amount of pin holes and bubble to occur.
Crystallite dry granular caking agent of the present invention has solved suspension, stability and the flowability problem of crystallite dry granular.After using crystallite dry granular caking agent of the present invention, the crystallite dry granular can reach 60% above solid content, and flow velocity is lower than 50s(30 ℃, is coated with-4 glasss), suspension, stability and good fluidity, lasting use bubble can not occur.
Crystallite dry granular caking agent of the present invention is only produced with the mode of simple mix and blend, only needs at normal temperatures and pressures stirring in 1~2 hour can finish whole preparation process, and production unit and technique are fairly simple, meet the requirement of current energy-saving and emission-reduction.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment, but do not limit to so.
Used per-cent among the embodiment if no special instructions, is mass percent.
Embodiment 1
The component of every 100kg crystallite dry granular caking agent: alkali swelling type thickening material (U.S. Rhom and Hass, model ASE-60) 3.4kg, (wilkinite mixes formation to 6% wilkinite hydrogel with water, wherein the wilkinite mass concentration is 6%, together lower) 25kg, tripoly phosphate sodium STPP 1.0kg, polymethyl siloxane 0.4kg, with 30% NaOH aqueous solution regulation system pH value to 8.0, surplus is water.
The preparation method of above-mentioned crystallite dry granular caking agent may further comprise the steps: 1) that alkali swelling type thickening material is soluble in water, stir; 2) continue to add tripoly phosphate sodium STPP, polymethyl siloxane, stir; 3) the NaOH aqueous solution regulation system pH value of adding 30% is 8.0; 4) add the wilkinite hydrogel, stir, obtain crystallite dry granular caking agent, surveying its flow velocity is 16.8s(30 ℃, is coated with-4 glasss).
(Guangdong Dowstone Technologies Co., Ltd. provides with 600g crystallite dry granular, granular size is 100~250 orders, together lower) add in the above-mentioned crystallite dry granular of the 400g caking agent, mix, get crystallite dry granular suspension, it does not have macroscopic bubble, recording its flow velocity is 46.5s(30 ℃, is coated with-4 glasss), leave standstill a week also without precipitation, as seen, crystallite dry granular caking agent good stability of the present invention.
Above-mentioned crystallite dry granular suspension is drenched surface at base substrate in the mode of drenching glaze, the thickness of control billet surface crystallite dry granular suspension is 2.5mm, in kiln behind 1150~1230 ℃ of calcination 1.5h, and polishing, get the crystallite brick finished product, finished product is without macroscopic bubble and pin hole.
Embodiment 2
The component of every 100kg crystallite dry granular caking agent: alkali swelling type thickening material (U.S. Rhom and Hass, model ASE-60) 2.7kg, 6% wilkinite hydrogel 30kg, sodium polyacrylate 1.7kg, polymethyl siloxane 0.2kg, ethylene glycol 5kg, with ammonia soln (28% mass concentration) regulation system pH value to 8.5, surplus is water.
The preparation method of above-mentioned crystallite dry granular caking agent may further comprise the steps: 1) alkali swelling type thickening material, ethylene glycol, water are mixed, stir; 2) continue to add sodium polyacrylate, polymethyl siloxane, stir; 3) adding ammonia soln regulation system pH value is 8.5; 4) add the wilkinite hydrogel, stir, obtain crystallite dry granular caking agent, gained crystallite dry granular caking agent flow velocity is 18.5s(30 ℃, is coated with-4 glasss).
600g crystallite dry granular is added in the 400g crystallite dry granular caking agent, mix, get crystallite dry granular suspension, it does not have macroscopic bubble, and recording its flow velocity is 49.5s(30 ℃, is coated with-4 glasss), leave standstill a week also without precipitation, as seen, crystallite dry granular caking agent good stability of the present invention.
Above-mentioned crystallite dry granular suspension is drenched surface at base substrate in the mode of drenching glaze, the thickness of control billet surface crystallite dry granular suspension is 2mm, in kiln behind 1150~1230 ℃ of calcination 1h, and polishing, get the crystallite brick finished product, finished product is without macroscopic bubble and pin hole.
Embodiment 3
The component of every 100kg crystallite dry granular caking agent: alkali swelling type thickening material (U.S. Rhom and Hass, model ASE-60) 3.6kg, 6% wilkinite hydrogel 20kg, polycarboxylate sodium 2.2kg, polymethyl siloxane 0.5kg, ethylene glycol 4kg, with 30% NaOH aqueous solution regulation system pH value to 9.0, surplus is water.
The preparation method of above-mentioned crystallite dry granular caking agent may further comprise the steps: 1) alkali swelling type thickening material, ethylene glycol, water are mixed, stir; 2) continue to add polycarboxylate sodium, polymethyl siloxane, stir; 3) the NaOH aqueous solution regulation system pH value of adding 30% is 9.0; 4) add the wilkinite hydrogel, stir, obtain crystallite dry granular caking agent, gained crystallite dry granular caking agent flow velocity is 17.0s(30 ℃, is coated with-4 glasss).
600g crystallite dry granular is added in the 400g crystallite dry granular caking agent, mix, get crystallite dry granular suspension, it does not have macroscopic bubble, and recording its flow velocity is 45.6s(30 ℃, is coated with-4 glasss), leave standstill a week also without precipitation, as seen, crystallite dry granular caking agent good stability of the present invention.
Above-mentioned crystallite dry granular suspension is drenched surface at base substrate in the mode of drenching glaze, the thickness of control billet surface crystallite dry granular suspension is 3mm, in kiln behind 1150~1230 ℃ of calcination 2h, and polishing, get the crystallite brick finished product, finished product is without macroscopic bubble and pin hole.

Claims (7)

1. crystallite dry granular caking agent, by mass percentage, contain following component: alkali swelling type thickening material 2.7~3.6%, wilkinite 1.2~1.8%, auxiliary agent 1.4~2.7% are 8.0~9.0 with the pH of pH adjusting agent regulation system, and surplus is solvent.
2. a kind of crystallite dry granular caking agent according to claim 1, it is characterized in that: auxiliary agent is dispersion agent, defoamer, the quality percentage composition of dispersion agent is 1.0~2.2% in the system, the quality percentage composition of defoamer is 0.2~0.5%.
3. a kind of crystallite dry granular caking agent according to claim 1, it is characterized in that: described alkali swelling type thickening material is the multipolymer of acrylate and methacrylic ester.
4. a kind of crystallite dry granular caking agent according to claim 2 is characterized in that: dispersion agent is at least a among tripoly phosphate sodium STPP, sodium polyacrylate, the polycarboxylate sodium.
5. a kind of crystallite dry granular caking agent according to claim 2, it is characterized in that: defoamer is polymethyl siloxane.
6. a kind of crystallite dry granular caking agent according to claim 1 is characterized in that: solvent is at least a in water, the ethylene glycol.
7. a kind of crystallite dry granular caking agent according to claim 1 is characterized in that: pH adjusting agent is at least a in sodium hydroxide, the ammoniacal liquor.
CN201210391860.3A 2012-10-16 2012-10-16 Microcrystal dry grain adhering agent CN102951928B (en)

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CN104230393A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Green brick of single-firing glass ceramic composite board
CN104230396A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Method for producing glazed ceramic tiles
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CN104230390A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Production method of pattern glazed ceramic tile
CN104230394A (en) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 Production process of microcrystalline glass ceramic composite board
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CN107162602A (en) * 2017-06-07 2017-09-15 景德镇陶瓷大学 A kind of formula of glaze base bonding agent and preparation method thereof

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