CN105218060A - A kind of self-styled closed form acid resisting material and preparation method - Google Patents

A kind of self-styled closed form acid resisting material and preparation method Download PDF

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Publication number
CN105218060A
CN105218060A CN201510520714.XA CN201510520714A CN105218060A CN 105218060 A CN105218060 A CN 105218060A CN 201510520714 A CN201510520714 A CN 201510520714A CN 105218060 A CN105218060 A CN 105218060A
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component
self
water glass
mixture
aggregate
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姚俊海
章荣会
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Beijing Associating Rong Great Building Materials Co Ltd
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Beijing Associating Rong Great Building Materials Co Ltd
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  • Adhesives Or Adhesive Processes (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Abstract

A kind of self-styled closed form acid resisting material and preparation method, for industry storage pond technical field of anticorrosion.For A, B and C three components composition, component A is water glass; B component is epoxide modified furane resin; Component C is the acidproof aggregate of grating, water glass curing agent; Concrete proportioning weight ratio is as follows: component A: water glass 60 ~ 95; B component: epoxide modified furane resin 5 ~ 20; Component C: the acidproof aggregate 70 ~ 128 of grating; Water glass curing agent 3 ~ 12.Three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all self-enclosed layer can be formed in the certain limit of top layer, the material ultimate compression strength >=35MPa after shaping, there is higher physical strength, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life.

Description

A kind of self-styled closed form acid resisting material and preparation method
Technical field
The present invention relates to a kind of self-styled closed form acid resisting material and preparation method, for industry storage pond technical field of anticorrosion.
Background technology
The effect of the factors such as the flowing of industry storage pond for a long time by the chemical such as soda acid, industrial sewage, industrial gasses, ultraviolet, solid particulate is worn and torn, wash away, all loading ends all also exist the multiple comparatively complicated etch state such as physical erosion, microbiological corrosion of acid and alkali corrosion, atomospheric corrosion, infiltration type spalling, have a strong impact on its work-ing life, therefore, in order to ensure the operation that industry storage pond is permanently effective, the anti-corrosive treatment of its loading end is particularly crucial.
Traditional anticorrosive, mostly is the system such as water glass acid-proof material, furans or modification furans acid resisting material, acid resisting brick, " three cloth five oil " formula resinous material.
Water glass acid-proof Material Thermodynamics is well-behaved, has great resistance to corrosion to some aggressive substances, but its impermeabilisation, water-alkali resistance are poor, thus uses and is restricted.And put into practice explanation in a large number, concrete system of comparing, water glass acid-proof material is in use, due to the impact of the factors such as outside temperature, gravity laod, External Force Acting, more easy to crack, along with the expansion in crack, corrosive fluid invasion, Seepage happen occasionally, and affect structure function time serious.
Furans or modification furans acid resisting material are a kind of excellent resist chemical materials.Except to the acid with oxidisability, outside the sulfuric acid as more than 60%, nitric acid etc., it is to general conventional strong acid, and highly basic and many agricultural chemicals all have resistance to corrosion.But epoxide modified furane resin solidifying product fragility is large, and cohesiveness and construction technology are all poor.
Acid resisting brick resistance to corrosion is comparatively strong, but its whole structure is determined by the state of the art of adhesives and workmen.Adhesives is durable, long service life, but based on above-mentioned bi-material on selecting.The state of the art of workmen is high, long service life, if there is deviation, may produce local shedding phenomenon at position devious.
" three cloth five oil " formula resinous material is an individual system comparatively multiplex at present, and its corrosion resistance is undoubted, but comparatively obvious by the impact of concrete reactive force, therefore, on its work-ing life, needs regular maintenance, and construction and maintenance cost higher.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of self-styled closed form acid resisting material and preparation method.
The present invention relates to a kind of self-styled closed form acid resisting material, is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
As follows with the concrete proportioning of weight ratio:
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
As follows with the concrete proportioning of weight ratio:
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping with promoting that liquid or high temperature or acidification can realize self-enclosed, can effectively stop that acid solution invades.
Described water glass system is sodium silicate, the one of potash water glass or its mixture;
Preparation method is as follows for described B component epoxide modified furane resin: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 15 ~ 20min is stirred within the scope of 60 DEG C ~ 80 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is Sodium Silicofluoride, condensation of aluminum phosphate, the one of silicon phosphate or its mixture, and its addition is 6% ~ 15% of component C.
The invention has the beneficial effects as follows in moulding process, epoxide modified furane resin can progressively migrate in the certain limit of top layer, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
Advantage of the present invention is in self-styled closed form acid resisting material curing molding process, because the consistency of resin material and water glass is poor, then to top layer migration, and assembles in the certain limit of top layer; After self-enclosed property acid resisting material curing molding, under curing fluid capable or high temperature or acidulated condition, the resin within the scope of top layer produces crosslinking curing, thus forms tight network structure, reduces porosity, improves degree of compactness, thus realization stops the object that acid solution invades.
In order to prepare effectively and permanent stronger erosion-resisting material, overcome water glass impermeabilisation, anti-diluted acid poor performance and epoxide modified furane resin solidifying product fragility large, the shortcoming of cohesiveness and construction technology difference the invention provides a kind of novel self-enclosed acid resisting material, this acid resisting material overcomes water glass and epoxide modified furane resin shortcoming, Bound moisture glass and epoxide modified furane resin advantage separately, make material of the present invention have better anticorrosion effect simultaneously.
Accompanying drawing explanation
When considered in conjunction with the accompanying drawings, by referring to detailed description below, more completely can understand the present invention better and easily learn wherein many adjoint advantages, but accompanying drawing described herein is used to provide a further understanding of the present invention, form a part of the present invention, schematic description and description of the present invention, for explaining the present invention, does not form inappropriate limitation of the present invention.
Fig. 1 is schematic flow sheet of the present invention.
Below in conjunction with drawings and Examples, the present invention is further described.
Embodiment
Obviously, the many modifications and variations that those skilled in the art do based on aim of the present invention belong to protection scope of the present invention.
Embodiment 1: as shown in Figure 1,
A kind of self-styled closed form acid resisting material is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning following (weight ratio):
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
Concrete proportioning following (weight ratio):
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping can be able to realize self-enclosed by curing fluid capable or high temperature or acidification, can effectively stop that acid solution invades.
Water glass system is the mixture of sodium silicate, potash water glass, blending ratio sodium silicate: potash water glass=1:1;
Performance index: material ultimate compression strength=37MPa, better mechanical property; The erosion of the acid solution of different concns can be stopped, antiseptic property test passes.
Preparation method is as follows for described B component epoxide modified furane resin: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 20min is stirred within the scope of 70 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is mixture, and the mixture of its inside is Sodium Silicofluoride, condensation of aluminum phosphate, silicon phosphate, Sodium Silicofluoride: condensation of aluminum phosphate: silicon phosphate=1:3:6, and water glass curing agent is its addition is 10% of component C.
Embodiment 2:
A kind of self-styled closed form acid resisting material is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning following (weight ratio):
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
Concrete proportioning following (weight ratio):
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping can be able to realize self-enclosed by curing fluid capable or high temperature or acidification, can effectively stop that acid solution invades.
Described water glass system is sodium silicate, the one of potash water glass or its mixture; Performance index: material ultimate compression strength=35MPa, better mechanical property; The erosion of the acid solution of different concns can be stopped, antiseptic property test passes.
Preparation method is as follows for described B component epoxide modified furane resin:
Organic ester, diepoxides, reactive toughening agent and liquid-state epoxy resin are placed in reaction vessel, 18min is stirred within the scope of 80 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
Described water glass curing agent is mixture, and the mixture of its inside is Sodium Silicofluoride, condensation of aluminum phosphate, silicon phosphate, Sodium Silicofluoride: condensation of aluminum phosphate: silicon phosphate=1:3:6, and water glass curing agent is its addition is 10% of component C.
Water glass system is the mixture of sodium silicate, potash water glass, blending ratio sodium silicate: potash water glass=1:1.
Embodiment 3:
A kind of self-styled closed form acid resisting material is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning following (weight ratio):
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
As follows with the concrete proportioning of weight ratio:
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping can be able to realize self-enclosed by curing fluid capable or high temperature or acidification, can effectively stop that acid solution invades.
Described water glass system is sodium silicate, the one of potash water glass or its mixture;
Described b componentepoxide modified furane resin preparation method is as follows: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 15 ~ 20min is stirred within the scope of 60 DEG C ~ 80 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is mixture, and the mixture of its inside is Sodium Silicofluoride, condensation of aluminum phosphate, silicon phosphate, Sodium Silicofluoride: condensation of aluminum phosphate: silicon phosphate=2:3:5, and water glass curing agent is its addition is 10% of component C
Described water glass curing agent is Sodium Silicofluoride, condensation of aluminum phosphate, the one of silicon phosphate or its mixture, and its addition is 6% ~ 15% of component C.
Water glass system is the mixture of sodium silicate, potash water glass, blending ratio sodium silicate: potash water glass=3:7.
Embodiment 4:
A kind of self-styled closed form acid resisting material is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning following (weight ratio):
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
Concrete proportioning following (weight ratio):
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping with promoting that liquid or high temperature or acidification can realize self-enclosed, can effectively stop that acid solution invades.
Described water glass system is sodium silicate, the one of potash water glass or its mixture;
Preparation method is as follows for described B component epoxide modified furane resin: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 20min is stirred within the scope of 68 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is Sodium Silicofluoride, condensation of aluminum phosphate, the one of silicon phosphate or its mixture, and its addition is 8% of component C.
Embodiment 5:
A kind of self-styled closed form acid resisting material is A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning following (weight ratio):
During application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
A kind of self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
Concrete proportioning following (weight ratio):
During use:
Step 1), first the component A of 2/3 is mixed with component C, and to stir, obtain mixture;
Step 2), B component is joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Step 3), then by step 2) mixture that obtains joins step 1) in the mixture that obtains, stir and can construct;
Through construction curing molding, the material surface after shaping with promoting that liquid or high temperature or acidification can realize self-enclosed, can effectively stop that acid solution invades.
Described water glass system is sodium silicate, the one of potash water glass or its mixture;
Preparation method is as follows for described B component epoxide modified furane resin: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 17min is stirred within the scope of 70 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is Sodium Silicofluoride, condensation of aluminum phosphate, the one of silicon phosphate or its mixture, and its addition is 6% ~ 15% of component C.
As mentioned above, embodiments of the invention are explained, but as long as do not depart from inventive point of the present invention in fact and effect can have a lot of distortion, this will be readily apparent to persons skilled in the art.Therefore, such variation is also all included within protection scope of the present invention.

Claims (4)

1. a self-styled closed form acid resisting material, is characterized in that for A, B and C three components composition,
Component A is water glass;
B component is epoxide modified furane resin;
Component C is the acidproof aggregate of grating, water glass curing agent;
Concrete proportioning weight ratio is as follows:
2. the self-styled closed form acid resisting material of one according to claim 1, when it is characterized in that application, three components stirs according to a certain percentage, in moulding process, epoxide modified furane resin can progressively migrate in the top layer certain limit of self-styled closed form acid resisting material, then through curing fluid capable or high temperature or acidification, all can form self-enclosed layer in the certain limit of top layer, material ultimate compression strength >=35MPa after shaping, there is higher physical strength, and self-enclosed layer is resin web network crosslinking structure, and be closely connected with aggregate, porosity is little, can effectively stop that acid solution invades, thus protection is formed to other base material, increase the service life further.
3. a self-enclosed acid resisting material preparation method, containing following steps:
Component A is water glass system; B component is the epoxide modified furane resin of self-control; Component C is the acidproof aggregate of grating, water glass curing agent.
Concrete proportioning following (weight ratio):
During use:
Step is 1.: first the component A of 2/3 mixed with component C, and stir, obtain mixture;
Step is 2.: B component joined in remaining 1/3A component, and high-speed stirring, obtain mixture;
Then 3. the mixture that 2. step obtains join in the mixture that 1. step obtain by step, stirs and can construct;
Through construction curing molding, the material surface after shaping can be able to realize self-enclosed by curing fluid capable or high temperature or acidification, can effectively stop that acid solution invades;
Described water glass system is sodium silicate, the one of potash water glass or its mixture.
4. the self-enclosed acid resisting material preparation method of one according to claim 3, it is characterized in that described B component epoxide modified furane resin preparation method is as follows: organic ester, diepoxides, response type toughner and liquid-state epoxy resin are placed in reaction vessel, 15 ~ 20min is stirred within the scope of 60 DEG C ~ 80 DEG C, then under agitation furane resin are added, and drip a small amount of fatty amine curing agent, continue 30min, finally add defoamer, coupling agent, emulsifying agent a be down to room temperature;
In described component C, the acidproof aggregate of grating coordinates when auxiliary material following (weight ratio):
Described water glass curing agent is Sodium Silicofluoride, condensation of aluminum phosphate, the one of silicon phosphate or its mixture, and its addition is 6% ~ 15% of component C.
CN201510520714.XA 2015-08-21 2015-08-21 A kind of self-styled closed form acid resisting material and preparation method Pending CN105218060A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN109437808A (en) * 2018-11-06 2019-03-08 中国神华能源股份有限公司 A kind of silicate composite mortar and preparation method thereof that furane resins are modified
CN110698166A (en) * 2019-11-19 2020-01-17 白雨婷 Sulfuric acid tower plugging agent and preparation and use methods thereof
CN113150691A (en) * 2021-05-12 2021-07-23 伍翠云 Acid-resistant non-cured waterproof coating and preparation process thereof
CN113698802A (en) * 2021-08-24 2021-11-26 成都新柯力化工科技有限公司 Graphene hybridized organic-inorganic anticorrosive paint and preparation method thereof

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CN101445346A (en) * 2008-12-19 2009-06-03 周建国 Compact light acid resistant pouring material for chimneys and preparation method thereof
CN101823865A (en) * 2010-01-12 2010-09-08 江西萍乡龙发实业股份有限公司 Compact acid resistant adhesive mortar

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109437808A (en) * 2018-11-06 2019-03-08 中国神华能源股份有限公司 A kind of silicate composite mortar and preparation method thereof that furane resins are modified
CN110698166A (en) * 2019-11-19 2020-01-17 白雨婷 Sulfuric acid tower plugging agent and preparation and use methods thereof
CN113150691A (en) * 2021-05-12 2021-07-23 伍翠云 Acid-resistant non-cured waterproof coating and preparation process thereof
CN113698802A (en) * 2021-08-24 2021-11-26 成都新柯力化工科技有限公司 Graphene hybridized organic-inorganic anticorrosive paint and preparation method thereof

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