Anti-permeation concrete reduces diminishing waterproof compacting agent and production method thereof
Technical field
The present invention relates to a kind of be widely used in Highrise buildings vault, swimming pool, water channel, tunnel, cable trench engineering and building construction and building structure waterproof, seepage control Anti-permeation concrete reduce diminishing waterproof compacting agent.After using this product, other waterproof operation that it goes without doing.Concrete poured up at a time.
Background technology
The current waterproof product kind of China is more.There is inorganic salt water-repellent, also have organic water-resisting agent.Inorganic salt water-resisting agent is possibility Corrosion Reinforcement not only, and later stage waterproof effect is bad; Organic water-resisting agent, owing to having air-entraining effect, has detrimentally affect to concrete strength.In engineer applied, most water-resisting agent can strengthen contraction, and to shrink excessive be the one of the main reasons causing concrete cracking.See with physical condition, current product have a powdery with liquid, but be powder-like product mostly, this product volume is high, generally about 5%, have up to 8%-10%.
Open source literature reports some concrete diminishing water-resisting agents, takes passages as follows:
1, Chinese patent; title: a kind of polycarboxylate water-reducer and preparation method thereof; Application Number (patent): CN200910245171.X open (bulletin) number: CN101767952A application (patent right) people: Tianjin Feilong Concrete Additives Co., Ltd., invention (design) people: Shi Chun; Lee and Sheng summary: a kind of polycarboxylate water-reducer and preparation method thereof.The invention belongs to cement water reducing agent technical field.A kind of polycarboxylate water-reducer, its weight percent consists of: poly carboxylic acid 30-50, rust inhibitor Sodium Nitrite 15-30, air entrapment agent Sodium dodecylbenzene sulfonate 0.1-2.0, water-resisting agent sodium stearate 5-15, defoamer polyether glycol 0.1-0.5, volume stabilizer Tai-Ace S 150 15-40.Its preparation method: add poly carboxylic acid in a kettle., control temperature 45-80 DEG C, under agitation, rust inhibitor Sodium Nitrite, air entrapment agent Sodium dodecylbenzene sulfonate, water-resisting agent sodium stearate, defoamer polyether glycol, volume stabilizer Tai-Ace S 150, carries out building-up reactions, isothermal reaction 1.5-2.5 hour, obtains polycarboxylate water-reducer.Water reducer of the present invention has that water-reducing rate is high, concrete durability is high, consistency is good, adaptability is good, long service life, and technique has that flow process is simple, the reaction times is short, be convenient to the advantage such as suitability for industrialized production and safely cleaning.
2, Chinese patent; title: title: a kind of collapse protective poly-carboxylic acid water reducing agent and preparation method thereof Application Number (patent): CN201010185721.6 open (bulletin) number: CN101830663A application (patent right) people: Zhejiang Province Wulong Chemical Co., Ltd, invention (design) people: Zhu Yulian; Wang Jiafeng; Song Yongliang; Zhang Jianfeng; Yang Huifen; Li Qiuping, summary: a kind of collapse protective poly-carboxylic acid water reducing agent and preparation method thereof, is specifically related to a kind of with dimethylaminoethyl acrylate methyl ammonia ethyl ester, allyl polyglycol and maleic anhydride be raw material novel poly carboxylic acid series water reducer and synthetic method thereof.A kind of collapse protective poly-carboxylic acid water reducing agent, it for raw material, under the effect of initiator, obtains product by aqueous solution polymerization with dimethylaminoethyl acrylate methyl ammonia ethyl ester 5% ~ 60%, maleic anhydride 15% ~ 60%, allyl polyglycol 15%-70%.The invention also discloses above-mentioned collapse protective poly-carboxylic acid water reducing agent preparation method.Advantage of the present invention: 1. polymkeric substance water-reducing rate is high, slump retaining is good.2. preparation technology of the present invention is single stage method, and reaction conditions is easy to control, and reaction time is short, simple to operate, and is polymerized in aqueous, pollution-free.3. reaction conditions is gentle, low for equipment requirements.
3, Chinese patent, title: building concrete shrinkage type water reducer Application Number (patent): the CN201210526725.5 applying date: 2012.12.10 open (bulletin) number: CN102964529A application (patent right) people: Changshu Suzhou branch office of Jian Gong construction group company limited address: No. 183, Ting Lan lane, Suzhou City Industrial Park District, Jiangsu Province, summary: a kind of building concrete shrinkage type water reducer, it is a kind of polycarboxylate high-efficiency water-reducing agent, described building concrete shrinkage type water reducer first in water, adds maleic anhydride, diethylene glycol monobutyl ether, the trimethyl carbinol and catalyzer, then 120 DEG C are heated to, be incubated and be cooled to 80 DEG C after 4 hours, then initiator is added, methacrylic acid and isopentenol polyoxyethylene ether, then continue insulation and be cooled to 35 DEG C after 2 hours, use neutralizing agent neutralization solution again, be 7-8 to pH value and get final product.By the way, building concrete shrinkage type water reducer of the present invention can improve water-reducing rate and the dispersiveness of water reducer effectively, increase concrete intensity, make concrete have excellent slump retaining, mobility and impermeability, better with concrete consistency.
4, title: Chinese patent, composite polycarboxylic acid water reducing agent, Application Number (patent): CN201110147891.X open (bulletin) number: CN102249591A application (patent right) people: China State Construction Engineering Commercial Concrete; Commercial Concrete Co., Ltd.Of China Construction Third Engineering Bureau; China Construction. Third Engineering Bureau Corp., Ltd.) invention (design) people: Han Zhoubing; Zheng Guangjun; Xiong Xiaohui; Huang Bo; Liu Hangyu; Xiao Hongjun; Ji Xiaohui; Shen Hao; Jiang Xinfeng; Tai is big; Li Dong makes a summary: a kind of water reducer.Composite polycarboxylic acid water reducing agent, it is characterized in that: it is prepared from by high performance water reducing agent of polyocarboxy acid, retardant, functional agent, sanitas and water, mass percent shared by each component is: high performance water reducing agent of polyocarboxy acid 8-28.6%, retardant 0.5-7.36%, functional agent 0.001-0.15%, sanitas 0.01-0.65%, water are surplus, and mass percent sum shared by each component is 100%.Be applied in fresh concrete, after dismounting scribbles the template of used oil or rosined soap class, the concrete surface after sclerosis is smooth, and bubble obviously reduces, and meets construction requirement completely.The invention solves the difficult problem using interior formwork after the releasing agent such as used oil or rosined soap class more.
The raw material that above-mentioned disclosed the reinforcement of concrete shrinkage type water reducer has is complicated, and cost is higher, have through the impervious effect of overtesting be not fine.
Summary of the invention
In view of the deficiency that above-mentioned prior art exists, the object of this invention is to provide a kind ofly significantly improve impermeability, reducing property, impermeability, large, water-repellancy, closely knit effect the Anti-permeation concrete of water-reducing rate reduce diminishing waterproof compacting agent, and only need add this product repeatedly need not add admixture in concrete.Product is liquid, is convenient to add, and low alkalinity, does not corrode, without inflammable and explosive property, and nontoxicity.
The object of the present invention is achieved like this:
A kind of Anti-permeation concrete reduces diminishing waterproof compacting agent, and it comprises the raw material of following parts by weight, and wherein, it comprises the raw material of following parts by weight, wherein, and high-performance polycarboxylic acids water reducing agent 48-54 part; Iron trichloride 13-21 part; Sunmorl N 60S 5-10 part; Sucrose 3-5 part; Water 10-15 part; Also comprise the defoamer of 0.05-0.5 part and the air entrapment agent of 0.1-2.0 part.
Described high-performance polycarboxylic acids water reducing agent is polyester type structure; Or polyether-type structure; Solid content is 40%.
Described defoamer is silicone oil.
Described air entrapment agent is black liquid and molasses reaction solution, and its preparation method is: solid content is that the strong sulfuric acid response 0.5-1 hour that black liquid weight 1 part and the cane molasses weight 1 part of 30-60% adds the 70-90% of weight 1 part obtains.
Anti-permeation concrete of the present invention reduces the production method of diminishing waterproof compacting agent, first iron trichloride is put into water, make it to be dissolved in the water completely under whipped state, allow after its naturally cooling and add Sunmorl N 60S and sucrose, add high-performance polycarboxylic acids water reducing agent again, mix, enter in finished product packing tank, test package, obtains product.
Anti-permeation concrete of the present invention reduces the production method of diminishing waterproof compacting agent, also can be first iron trichloride is put into water, make it to be dissolved in the water completely under whipped state, allow after its naturally cooling and add Sunmorl N 60S and sucrose, add high-performance polycarboxylic acids water reducing agent again, finally add air entrapment agent and defoamer mixes, enter in finished product packing tank, test package, obtains product.
High-performance polycarboxylic acids water reducing agent of the present invention (PolycarboxylateSuperplasticizer), it is a kind of cement dispersants during cement concrete uses, the present invention adopts the high-performance polycarboxylic acids water reducing agent of two types, a kind of is methacrylic acid with main chain, side chain is hydroxy-acid group and MPEG (Methoxypolyethyleneglycol), polyester type structure; Another for main chain be polyacrylic acid, side chain is Vinylalcoholpolyethyleneglycol, polyether-type structure; The solid content of high-performance polycarboxylic acids water reducing agent is 40%.
Anti-permeation concrete of the present invention reduces the beneficial effect of diminishing waterproof compacting agent:
1, can significantly improve that impermeability, reducing property, impermeability, water-reducing rate are large, water-repellancy, closely knit effect.In concrete, only need add this product need not repeatedly add other admixture.Product is that liquid is convenient to interpolation and can is effectively stoped water molecules to permeate, significantly improve intensity, impervious rank reaches 12 grades, can make to bond between concrete particle more closely and form parcel and reach impervious while can reduce contraction more than 30%, especially in the presence of a harsh environment, can reduce contraction, this is very important for effectively controlling cracking; Volume can be increased and decreased as requested.This product, by different labels concrete and different slump requirement, recommends volume to be the 0.21%-0.22% of gelling material, and detecting volume is 0.21% of gelling material.It is a kind of compound product, has several functions.
2, the air entrapment agent selected of the present invention and defoamer effect good, particularly adopt black liquid and molasses reaction solution, cost is low, can carry out utilization of waste material.Containing a large amount of xylogen in black liquid, can obtain resisting the material that water molecules permeate after adding sulfuric acid reaction with molasses, make concrete produce certain dope in addition, be not easy to ftracture.
Embodiment:
Below in conjunction with embodiment, the present invention is made the following instructions.
Air entrapment agent black liquid and molasses reaction solution embodiment: preparation method is: solid content is that the strong sulfuric acid response 0.5-1 hour that black liquid weight 1 part and the cane molasses weight 1 part of 30-60% adds the 70-90% of weight 1 part obtains.
Anti-permeation concrete reduces diminishing waterproof compacting agent embodiment:
Embodiment 1:
(1) raw material and weight:
High-performance polycarboxylic acids water reducing agent 50 weight part of polyether-type solid content 40%; Iron trichloride 15 weight part, Sunmorl N 60S 5 weight part; Sucrose 3 weight part; Water 15 weight part; Black liquor and molasses reaction solution total amount are 1 weight part.
(2) make
First iron trichloride is put into water, under agitation, make it to be dissolved in the water completely, allow after its naturally cooling and add Sunmorl N 60S and sucrose, then add high-performance polycarboxylic acids water reducing agent, finally add air entrapment agent.Drop in container to enter by the metering of said sequence proportioning raw materials and mix to whole dissolving, enter in finished product packing tank, test package, obtains product.
Embodiment 2:
(1) raw material and weight:
High-performance polycarboxylic acids water reducing agent 25 weight part of polyester type solid content 40%; High-performance polycarboxylic acids water reducing agent 28 weight part of polyether-type solid content 40%; Iron trichloride 15 weight part, Sunmorl N 60S 5 weight part; Sucrose 3 weight part; Water 15 weight part; Defoamer silicone oil 0.3 weight part; Black liquor and molasses reaction solution total amount are 1.5 weight parts.
(2) make
First iron trichloride is put into water, make it under agitation to be dissolved in the water completely, allow after its naturally cooling and add Sunmorl N 60S and sucrose, then add high-performance polycarboxylic acids water reducing agent, finally add air entrapment agent and defoamer.Drop in container to enter by the metering of said sequence proportioning raw materials and mix to whole dissolving, enter in finished product packing tank, test package, obtains product.
Embodiment 3:
(1) raw material and weight:
High-performance polycarboxylic acids water reducing agent 51 weight part of polyester type solid content 40%; Iron trichloride 16 weight part; Sunmorl N 60S 6 weight part; Sucrose 4 weight part; Water 15 weight part; Black liquor and molasses reaction solution total amount are 2 weight parts.
(2) make
First iron trichloride is put into water, make it under agitation to be dissolved in the water completely, allow after its naturally cooling and add Sunmorl N 60S and sucrose, then add high-performance polycarboxylic acids water reducing agent, finally add air entrapment agent.Drop in container to enter by the metering of said sequence proportioning raw materials and mix to whole dissolving, enter in finished product packing tank, test package, obtains product.
Embodiment 4:
(1) raw material and weight:
High-performance polycarboxylic acids water reducing agent 52 weight part of polyester type solid content 40%; Iron trichloride 16 weight part; Sunmorl N 60S 5 weight part; Sucrose 3 weight part; Water 15 weight part.
(2) make
First iron trichloride is put into water, make it under agitation to be dissolved in the water completely, allow after its naturally cooling and add Sunmorl N 60S and sucrose, then add high-performance polycarboxylic acids water reducing agent.Drop in container to enter by the metering of said sequence proportioning raw materials and mix to whole dissolving, enter in finished product packing tank, test package, obtains product.
Of the present invention can according to site operation require allocate, consumption also adds according to concrete situation.
Application Example 1(waterproof):
The present inventor is by embodiment 1,2,3,4 and buy the DH-HPWR high performance water proof agent of producing of sea, Guangxi building materials company limited and test, acetonideexample 1,2 better than the concrete waterproofer of sea, Guangxi building materials company limited production; 3 water resistancees are the same with the agent of DH-HPWR high performance water proof, and embodiment 4 water resistance is poorer than the agent of DH-HPWR high performance water proof.
Application Example 2(diminishing):
The cement water reducing agent that embodiment 1,2,3 and purchase sea, Guangxi building materials company limited are produced is tested by the present inventor, and the cement water reducing agent that the water-reducing effect of acetonideexample 1,2,3 is produced than sea, Guangxi building materials company limited is good.
Application Example 3:
Guigang, Guangxi unit builds 25 floor height buildings near river bank, basement construction have employed the embodiment of the present invention 1, 2, the Anti-permeation concrete of 3 and 5 reduce diminishing waterproof compacting agent (vault three little between waterproof face wall body adopt different embodiments), the house owed by a citizen of 6 floor has also been built on the side in this building by peasant, also vault is had, two building foundation dried up line height are identical, but house owed by a citizen uses common concrete, there is no admixture, build up latter 1 year, meet rainy season, the vault of the house owed by a citizen of 6 layers finds that there is Seepage, but the vault in 25 floor height buildings does not have Seepage, illustrate that Anti-permeation concrete of the present invention reduces diminishing waterproof compacting agent effective.
Illustrate, the compressive strength rate of concrete of the present invention or mortar, shrinkage ratio, infiltration all meet national standard and industry standard from technical indicators such as degree ratios.