CN101735550A - Low-smell furan resin - Google Patents
Low-smell furan resin Download PDFInfo
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- CN101735550A CN101735550A CN200910273342A CN200910273342A CN101735550A CN 101735550 A CN101735550 A CN 101735550A CN 200910273342 A CN200910273342 A CN 200910273342A CN 200910273342 A CN200910273342 A CN 200910273342A CN 101735550 A CN101735550 A CN 101735550A
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- furane resin
- resin
- acid resistance
- curing agent
- resistance filler
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Abstract
The invention relates to a furan resin with low smell and no volatile substance, which is used in anti-corrosion engineering. The furan resin is formed by adding an aldehyde arresting agent, an acid resistance filler and an active curing agent into the traditional furan resin and mixing the components, wherein the aldehyde arresting agent mainly adopts melamine, urea, borax and ethylene urea; the acid resistance filler is quartz sand; and the active curing agent is a mixture of paratoluensulfonyl chloride and sulfamic acid (the mass ratio of the paratoluensulfonyl chloride to the sulfamic acid is 1:1). The use quantity of the invention is as follows: 9-66% of furan resin, 1-13% of aldehyde arresting agent, 0-89% of acid resistance filler and 1-17% of active curing agent. The product not only has favorable antiseptic property and physical property but also has low smell and no volatile substance in construction.
Description
Technical field
The invention belongs to chemical field, be specifically related to a kind of ideal impregnating material.
Background technology
Furane resin are to be raw material synthetic superpolymer with furfuryl alcohol, furfural.Uncured furane resin dissolve in general organic solvent.Furane resin can be mixed with clay, mortar, concrete and glass reinforced plastic sizing material by a certain percentage with acid-resistant powder, have excellent acid, alkaline-resisting, anti-solvent and resistance toheat after the curing.1970 back China import, digestion and absorption West Germany furane resin utilisation technologies are succeeded in developing YJ type furane resin.Along with YJ type furane resin use range constantly enlarges,, need to improve its cohesive strength and relevant technical feature as the development of whole furane resin glass reinforced plastic and whole furan resin concrete utilisation technology.Corrosion-resistant maintenance of works quantities increases, basic unit is subjected to problems such as corrosive medium pollution, humidity height serious, do not reach the requirement of job specifications defined, make that the cohesive strength of YJ type furane resin glue material is undesirable, influence construction quality, press for the cohesive strength that improves resin, to guarantee its corrosion-resistant effect.XLZ type furane resin were developed in the Huibo Anticorrosive Technology Co., Ltd., Huangshi City in 1993, its technical feature has surpassed the state of the art of later stage eighties Germany product of the same type.In various types of corrosion-resistant engineerings, use, obtained good effect.
XLZ type furane resin are the same with YJ type furane resin, all belong to furfuryl alcohol furfural type furane resin.But its technical feature is greatly improved than YJ type furane resin:
1, cohesive strength increases substantially.The cohesive strength of XLZ type furane resin clay and acid-proof ceramic tile and grouan can reach 2.5～12MPa, and its bonding strength test can make acid-proof ceramic tile and the fracture of grouan matrix, shows the tensile strength of its cohesive strength greater than acid-proof ceramic tile and grouan itself.
2, resistance to compression, tensile strength improve.The ultimate compression strength of XLZ type furane resin clay can reach 80～140MPa, and tensile strength can reach 8～12MPa, far above the ultimate compression strength and the tensile strength of YJ type furane resin.
Though XLZ type furane resin all have corrosion resistance nature and physicals preferably, but it is the same with other furfuryl alcohol furfural type furane resin, in construction process (when particularly in airtight container, constructing), resin solidification can produce stronger smell, stimulate eyes and nasal cavity, influence construction speed and construction quality.
The invention technology contents
The objective of the invention is the problem that exists at existing furfuryl alcohol furfural type furane resin, a kind of furane resin that produce low smell, no volatile matter in construction process during resin solidification are provided.
Concrete scheme of the present invention is to add aldehyde capturing agent, acid resistance filler and reactive curing agent to mix in furfuryl alcohol furfural type furane resin.Wherein aldehyde capturing agent mainly adopts trimeric cyanamide, urea, borax, the inferior ethylene urea of ring; Acid resistance filler is quartzy class or graphite type material; Reactive curing agent is Tosyl chloride and thionamic acid mixture (the two mass ratio is 1: 1).Its amount ratio is furane resin 9～66%, aldehyde capturing agent 1～13%, acid resistance filler 0～89%, reactive curing agent 1～17%.
The present invention adds the aldehyde capturing agent modification in furfuryl alcohol furfural type furane resin, prepared clay, mortar, concrete, glass reinforced plastic sizing material etc. remove has performances such as the furane resin resistance to acids and bases is good, physical strength is high, heatproof height, in construction, hang down smell simultaneously, do not have volatile matter, can be widely used in all kinds of antiseptic projects.
Embodiment
The invention provides a kind of in construction, the furane resin of low smell, no volatile matter during resin solidification.Following embodiment describes the present invention in detail, but should not be considered as the restriction of the scope of the invention.
Embodiment one: get furfuryl alcohol furfural type furane resin 23kg, ring inferior ethylene urea 0.8kg, borax 0.5kg, urea 1.1kg, trimeric cyanamide 2.2kg, silica powder 68kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 4.5kg, mixing and stirring, promptly.
Embodiment two: get furfuryl alcohol furfural type furane resin 23kg, trimeric cyanamide 4.5kg, silica powder 68kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 4.5kg, and mixing and stirring, promptly.
Embodiment three: get furfuryl alcohol furfural type furane resin 10kg, urea 2kg, silica powder 25kg, quartz sand 15kg, quartzite 46kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 2kg, and mixing and stirring, promptly.
Embodiment four: get furfuryl alcohol furfural type furane resin 17kg, borax 3kg, silica powder 30kg, quartz sand 37kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 3kg, and mixing and stirring, promptly.
Embodiment five: get furfuryl alcohol furfural type furane resin 50kg, ring inferior ethylene urea 12.5kg, silica powder 25kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 12.5kg, and mixing and stirring, promptly.
Embodiment six: get furfuryl alcohol furfural type furane resin 66kg, ring inferior ethylene urea 2.4kg, borax 1.6kg, urea 3kg, trimeric cyanamide 7kg, toluene sulfonyl chloride and thionamic acid mixture (the two mass ratio is 1: 1) 17kg, and mixing and stirring, promptly.
Claims (5)
1. furane resin that produce low smell, no volatile matter in resin curing process are to add aldehyde capturing agent, acid resistance filler and reactive curing agent in the furfuryl alcohol furfural type furane resin to mix.Wherein aldehyde capturing agent mainly adopts trimeric cyanamide, urea, borax, the inferior ethylene urea of ring; Acid resistance filler is quartzy class or graphite type material; Reactive curing agent is Tosyl chloride and thionamic acid mixture (the two mass ratio is 1: 1).Its amount ratio is furane resin 9～66%, aldehyde capturing agent 1～13%, acid resistance filler 50～89%, reactive curing agent 1～17%.
2. according to the furane resin of the described low smell of claim 1, no volatile matter, it is characterized in that the amount ratio of furane resin clay is: furane resin 20～31%, aldehyde capturing agent 3～5%, acid resistance filler 59～74%, reactive curing agent 3～5%.Purposes: the lining cutting, jointing and the cementation of fissures that are used for bulks such as various acid-proof ceramic tiles, porcelain plate, granite slab.
3. according to the furane resin of the described low smell of claim 1, no volatile matter, it is characterized in that the amount ratio of furan resin concrete is: furane resin 9～12%, aldehyde capturing agent 1～3%, acid resistance filler 82～89%, reactive curing agent 1～3%.Purposes: be used to water smash indoor whole protection against corrosion flooring, trench, catch pit, Equipment Foundations, skirting, anti-along etc.; Make whole acidproof groove jar such as electrolyzer, pickling tank, reactive tank, storage tank etc.
4. according to the furane resin of the described low smell of claim 1, no volatile matter, it is characterized in that the amount ratio of furane resin mortar is: furane resin 15～19%, aldehyde capturing agent 2～4%, acid resistance filler 73～81%, reactive curing agent 2～4%.Purposes: be used for wiping one's face of dado, cornice, Equipment Foundations and the local ground that is not hit.
5. according to the furane resin of the described low smell of claim 1, no volatile matter, it is characterized in that the amount ratio of furane resin glass reinforced plastic sizing material is: furane resin 50～63%, aldehyde capturing agent 9～13%, acid resistance filler 11～32%, reactive curing agent 9～13%.Purposes: be used to serve as a contrast subsides carbon steel or concrete base layer such as groove jar, ground, trench, catch pit, the Corrosion resistant linings of Equipment Foundations, sealing coat; Make whole glass reinforced plastic such as goods such as groove jar, pipeline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910273342XA CN101735550B (en) | 2009-12-23 | 2009-12-23 | Low-smell furan resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910273342XA CN101735550B (en) | 2009-12-23 | 2009-12-23 | Low-smell furan resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101735550A true CN101735550A (en) | 2010-06-16 |
| CN101735550B CN101735550B (en) | 2011-12-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910273342XA Expired - Fee Related CN101735550B (en) | 2009-12-23 | 2009-12-23 | Low-smell furan resin |
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| CN (1) | CN101735550B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504157A (en) * | 2011-10-19 | 2012-06-20 | 珠海市斗门福联造型材料实业有限公司 | Non-dehydrated modified furan resin and production process thereof |
| CN102816407A (en) * | 2012-08-14 | 2012-12-12 | 黄石市汇波防腐技术有限公司 | High temperature-resistant modified furan resin corrosion protection material composition |
| CN102977307A (en) * | 2012-09-29 | 2013-03-20 | 成都市远诚化工有限责任公司 | Aldehyde-free and phenol-free environment protection type furan resin for casting, and preparation method thereof |
| CN103553431A (en) * | 2013-10-24 | 2014-02-05 | 黄石市汇波防腐技术有限公司 | Method for synthesizing toughened anti-corrosion furan resin |
| CN106349640A (en) * | 2016-08-29 | 2017-01-25 | 北海运龙环保材料有限责任公司 | High-strength glass toughened manure pit sizing material |
| CN106832168A (en) * | 2017-01-17 | 2017-06-13 | 石家庄世易糠醛糠醇有限公司 | 3D printing material based on Graphene furane resins and preparation method thereof, purposes |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1128853C (en) * | 1999-05-07 | 2003-11-26 | 黄石市汇波防腐技术有限公司 | Thixotropic furan resin applied in winter construction |
-
2009
- 2009-12-23 CN CN200910273342XA patent/CN101735550B/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504157A (en) * | 2011-10-19 | 2012-06-20 | 珠海市斗门福联造型材料实业有限公司 | Non-dehydrated modified furan resin and production process thereof |
| CN102504157B (en) * | 2011-10-19 | 2013-03-27 | 珠海市斗门福联造型材料实业有限公司 | Non-dehydrated modified furan resin and production process thereof |
| CN102816407A (en) * | 2012-08-14 | 2012-12-12 | 黄石市汇波防腐技术有限公司 | High temperature-resistant modified furan resin corrosion protection material composition |
| CN102816407B (en) * | 2012-08-14 | 2015-12-02 | 黄石汇波材料科技股份有限公司 | Heat resist modification furan resin anticorrosive material composition |
| CN102977307A (en) * | 2012-09-29 | 2013-03-20 | 成都市远诚化工有限责任公司 | Aldehyde-free and phenol-free environment protection type furan resin for casting, and preparation method thereof |
| CN102977307B (en) * | 2012-09-29 | 2014-03-26 | 成都市远诚化工有限责任公司 | Aldehyde-free and phenol-free environment protection type furan resin for casting, and preparation method thereof |
| CN103553431A (en) * | 2013-10-24 | 2014-02-05 | 黄石市汇波防腐技术有限公司 | Method for synthesizing toughened anti-corrosion furan resin |
| CN106349640A (en) * | 2016-08-29 | 2017-01-25 | 北海运龙环保材料有限责任公司 | High-strength glass toughened manure pit sizing material |
| CN106832168A (en) * | 2017-01-17 | 2017-06-13 | 石家庄世易糠醛糠醇有限公司 | 3D printing material based on Graphene furane resins and preparation method thereof, purposes |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101735550B (en) | 2011-12-14 |
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| C14 | Grant of patent or utility model | ||
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Owner name: HUANGSHI HUIBO MATERIALS TECHNOLOGY CO., LTD. Free format text: FORMER NAME: HUIBO ANTI-CORROSION TECHNOLOGY CO., LTD., HUANGSHI CITY |
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| CP01 | Change in the name or title of a patent holder |
Address after: 435003 No. 644, Shen Lu, Huangshi, Hubei Patentee after: HUANGSHI FYBO MATERIAL TECHNOLOGY CO., LTD. Address before: 435003 No. 644, Shen Lu, Huangshi, Hubei Patentee before: Huibo Anti-Corrosion Technology Co., Ltd., Huangshi City |
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Address after: 435003 No. 231 Lake Road, Huangshi, Hubei Patentee after: HUANGSHI FYBO MATERIAL TECHNOLOGY CO., LTD. Address before: 435003 No. 644, Shen Lu, Huangshi, Hubei Patentee before: HUANGSHI FYBO MATERIAL TECHNOLOGY CO., LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111214 Termination date: 20201223 |
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