CN105199527A - Stain-resistant acrylic ester waterproof coating - Google Patents
Stain-resistant acrylic ester waterproof coating Download PDFInfo
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- CN105199527A CN105199527A CN201510725572.0A CN201510725572A CN105199527A CN 105199527 A CN105199527 A CN 105199527A CN 201510725572 A CN201510725572 A CN 201510725572A CN 105199527 A CN105199527 A CN 105199527A
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Abstract
The invention discloses a stain-resistant acrylic ester waterproof coating. The waterproof coating is prepared from raw materials in parts by weight as follows: 30-50 parts of parts of an acrylic ester modified compound emulsion, 1-3 parts of a fluorocarbon surfactant, 4-8 parts of nano-modified materials, 20-30 parts of pigment filler, 0.1-0.3 parts of a humidity controlling agent, 0.3-0.5 parts of a dispersing agent, 0.1-0.5 parts of a defoaming agent, 1-2 parts of a coalescing agent, 0.2-0.6 parts of a thickening agent, 0.1-0.3 parts of an antioxidant, 0.1-0.5 parts of glass fiber, 0.1-0.3 parts of a preservative sterilizing agent, 0.2-0.4 parts of emulsified paraffin and 20-40 parts of water. The waterproof coating adopts a reasonable formula, has good stain resistance, high hardness and excellent overall performance and can be applied to waterproofing work of a roof, a basement, a toilet and the like.
Description
Technical field
The present invention relates to a kind of stain resistant acrylate waterproof paint, belong to concrete construction water-proof material technical field.
Background technology
Concrete is one of material that in modern architecture, consumption is maximum, purposes is the widest.This is because it not only has abundant raw material, cheap, the simple feature of production technique, but also it is high to have ultimate compression strength, good endurance, the advantage of strength grade wide ranges.Little by little, concrete is posted by people with very high great expectations.But in fact, volume shrinkage strain can be there is in concrete hydrating process of setting, also inside concrete tensile stress can be caused to be greater than tensile strength simultaneously, occur cracking and infiltration phenomenon, have a strong impact on concrete weather resistance, the stability of reinforcing bar and the security of building.Therefore, solution cracking and seepage problem are that people study one of concrete important directions.
Waterproof is the key solving concrete cracking and seepage problem, and water is a kind of polar material, and surface tension is about 72mN/m, diffustivity is very strong, can many kinds of substance be soaked, not only can be flowed by larger interstitial channels under gravity, and can be spread to all directions by pore.In order to anti-sealing is to the infiltration at some position of buildings, people are generally-material waterproofings of taking measures from material of construction.Material waterproofing mainly utilizes architectural waterproof material (as waterproof roll, waterproof paint) to block the path of water, to reach the object of waterproof or to increase the ability of anti-leakage.Waterproof roll is mainly used for construction wall, roofing etc., plays the flexible building material product of a kind of rollable one-tenth web-like resisting extraneous rainwater, underground water seepage, but there is such problem: coiled material poor toughness, seam crossing imprecision, easy seepage.Waterproof paint mainly refers to that brushing is on building surface, forms thin film, building surface and water are completely cut off, thus plays the effect of waterproof, sealing through the volatilization of solvent or moisture or the chemical reaction of two kinds of components.The waterproofing membrane that waterproof paint is formed after solidification has certain extensibility, elastoplasticity, splitting resistance, impermeability and weathering resistance, can play waterproof, prevent blending provide protection.Conventional waterproof paint has: polyurethane water-proof paint, epoxy resin waterproof coating and acrylate waterproof paint.Wherein, acrylate waterproof paint is base-material with acrylate polymer emulsion, and add other additives and obtained single-component water-emulsifying type waterproof coatings.It has excellent weathering resistance, thermotolerance and ultraviolet resistance, and within the scope of-30 DEG C to 80 DEG C, performance is substantially unchanged, and can adapt to the craze and transfiguration of basal plane certain amplitude.But acrylate waterproof paint also exists the limitation existing for simple a kind of macromolecule emulsion, as: film compactness is poor, bad to the shielding of water vapour and oxygen, tensile strength is lower, unit elongation is less, and work-ing life is shorter, limits its application to a certain extent.In order to solve the problem, people have carried out a lot of research, if Chinese patent application publication No. is the acrylate waterproof paint that CN103436159A discloses a kind of name and is called " Composite high-polymer waterproof paint and preparation method thereof ", it is made up of following weight part: acrylate modified composite emulsion 35 ~ 48 parts, waterproofing agent of organosilicon 1 ~ 5 part, nano powder 1 ~ 5 part, color stuffing 15 ~ 35 parts, fungicidal preservative 0.2 ~ 0.5 part, antiaging agent 0.1 ~ 0.5 part, dispersion agent 0.2 ~ 1 part, wetting agent 0.1 ~ 0.15 part, film coalescence aid 1 ~ 1.5 part, flow agent 0.1 ~ 0.3 part, defoamer 0.2 ~ 0.4 part, thickening material 0.4 ~ 1.5 part, PH stablizer 0.1 ~ 0.5 part, 15 ~ 30 parts, water, described acrylate modified composite emulsion is acrylic ester elastic water-proof emulsion, the special high-elastic water-proof emulsion of cement, polyurethane-modified polyacrylate water-proof emulsion are composited.Although this acrylate waterproof paint overcomes the limitation existing for simple a kind of macromolecule emulsion, the over-all propertieies such as the cementability of film, elasticity, water tolerance are made to be able to comprehensive raising, there is after dried coating film good hydrophobic nature, but its contamination resistance is bad, and hardness is low, thus limit its range of application in Concrete Anti Hydraulic Projects.Therefore, want the range of application widening acrylate waterproof paint, need to develop other materials and modification is carried out to acrylate waterproof paint thus obtains the good waterproof paint of over-all properties.
Summary of the invention
Bad for acrylate waterproof paint contamination resistance in above-mentioned prior art, and the technical problem that hardness is low, technical problem to be solved by this invention is that to propose a kind of contamination resistance good, and hardness is high, and the acrylate waterproof paint that over-all properties is good.
The present invention for the taked technical scheme that solves the problem is:
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylate modified composite emulsion 30 ~ 50 parts, fluorocarbon surfactant 1 ~ 3 part, nano modified material 4 ~ 8 parts, color stuffing 20 ~ 30 parts, humextant 0.1 ~ 0.3 part, dispersion agent 0.3 ~ 0.5 part, defoamer 0.1 ~ 0.5 part, film coalescence aid 1 ~ 2 part, thickening material 0.2 ~ 0.6 part, antioxidant 0.1 ~ 0.3 part, 0.1 ~ 0.5 part, glass fibre, anticorrosion and bactericidal agent 0.1 ~ 0.3 part, emulsified olefin 0.2 ~ 0.4 part, 20 ~ 40 parts, water.
Described acrylate modified composite emulsion is 4 ~ 8 parts of acrylic ester emulsions, 4 ~ 8 parts of styrene monomer modified acrylate emulsions, 5 ~ 8 parts of polyurethane-modified polyacrylate emulsions, 5 ~ 8 parts of epoxy resin modification acrylic ester emulsions, 6 ~ 9 parts of organosilicon-modified acrylate emulsions, 6 ~ 9 parts of emulsion modified acrylic ester emulsions of inorganic silicon are composited.
Described acrylate is methyl methacrylate; Described epoxy resin is bisphenol A epoxide resin; Described organosilicon is polysiloxane; Described inorganic silicon emulsion is silicon-dioxide emulsion.
Described nano modified material is 2 ~ 4 parts of nano titanium oxides, the mixture of 2 ~ 4 parts of carbon nanotubes.
Described color stuffing is 10 ~ 16 parts of talcum powder, 8 ~ 10 parts of calcium carbonate, the mixture of 2 ~ 4 parts of montmorillonites.
Described humextant is sepiolite/sodium polyacrylate mixture; Described dispersion agent is sodium polymethacrylate; Described defoamer is dimethyl silicone oil; Described film coalescence aid is cellulose acetate-butyrate; Described thickening material is Natvosol; Described antioxidant is xitix, and described anticorrosion and bactericidal agent is BIT.
Preferably, its weight is as follows:
Acrylic ester emulsion 6 parts, styrene monomer modified acrylate emulsion 6 parts, polyurethane-modified polyacrylate emulsion 7 parts, epoxy resin modification acrylic ester emulsion 7 parts, organosilicon-modified acrylate emulsion 8 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 8 parts, fluorocarbon surfactant 2 parts, nano titanium oxide 3 parts, carbon nanotube 3 parts, talcum powder 13 parts, 9 parts, calcium carbonate, montmorillonite 3 parts, sepiolite/sodium polyacrylate mixture 0.2 part, sodium polymethacrylate 0.4 part, dimethyl silicone oil 0.3 part, cellulose acetate-butyrate 1.5 parts, Natvosol 0.4 part, 0.2 part, xitix, 0.3 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.2 part, emulsified olefin 0.3 part, 30 parts, water.
In the present invention, styrene monomer modified acrylate emulsion has the features such as hardness is high, resistance is accomplished fluently, fastness is good, and the hardness of coating film and anti-shot ability are improved significantly; Polyurethane-modified polyacrylate emulsion has the features such as good snappiness, lower temperature resistance, water tolerance, ageing resistance, package stability, and the over-all properties of film is improved significantly; Epoxy resin has the good shielding to water vapour and oxygen, and sticking power is good, shrinking percentage is low, and therefore modified emulsion had both had good film-forming property, strong adhesion, improved again weather-proof ability; Organosilicon has heat-resisting, anti-oxidant, the performance such as stain resistant, radiation hardness, and therefore modified emulsion had both had good film-forming properties, turn improved the sticking power of film, ageing resistance, anti-stain characteristic, water tolerance, physical strength etc.; It is low that the emulsion modified acrylic ester emulsion of inorganic silicon had both had film-forming temperature, and the resistance to blocking of film is good, and the sticking power for base material is good, improves again heat-resisting, scoring resistance, the contamination resistance of film and ventilative and water vapour permeability; Methyl methacrylate has excellent weather resistance, and the weather resistance of coating is improved significantly.
Have the performances such as satisfactory stability, weathering resistance, erosion resistance, oxidation-resistance due to fluorine cpd, therefore fluorocarbon surfactant can modified acrylate emulsion, makes it have good weather resistance, chemical stability, water resistance.In addition, fluorocarbon surfactant is not only a kind of superpower hydrophobizing agent, and film coated surface can be made to have ultra-low surface energy, and dust not easily sticks, and strengthens the anti-contamination capability of coating; Itself or a kind of flow agent of coating, can accelerate levelling speed and the wetting speed of coating, impel coating in drying and forming-film process, form smooth, smooth, a uniform film.
It is large that nano titanium oxide has specific surface area, and magnetic is strong, and heat conductance is good, and with the feature of UV-light generation light-catalyzed reaction.These features can improve the weathering resistance of coating, also can reduce film coated surface energy simultaneously, give film super-hydrophobicity, make it have superpower anti-contamination capability.In addition, by its light-catalyzed reaction, the performance preventing bacterial adhesion, clear the pollution off can also be made it have.
Carbon nanotube has high Young's modulus, hardness and toughness, special electroconductibility and thermal conductivity.Adding of its, the electroconductibility of coating, hardness, snappiness and impact resistance can be improved well.
Talcum powder is a kind of color stuffing, and its main component is the Magnesium Silicate q-agent of sheet structure, can reduce the crack sensitivity of coating, improves overall performance and the weathering resistance of film, also can improve the associativity with substrate.In addition, talcum powder can also improve the viscosity of coating and make it have thixotropy, reduces the Subsidence trend of color stuffing, thus reduces the consumption of thickening material.Calcium carbonate not only can reduce the cost of coating, improves the performance such as hardness, opacity, can also be hydrolyzed generation calcium hydroxide, increases the sticking power of coating.Polynite is layered silicate crystal, and it is as filler, can improve its shock resistance, antifatigue and gas barrier property etc., thus plays the effect strengthening coating physicals, can also improve materiel machining performance simultaneously.
Sepiolite/sodium polyacrylate mixture is a kind of humidity adjusting material with better adjusting air humidity automatically.When it is coated onto water-proof surface, the film with protection, decoration, humidity conditioning function can be formed, thus make coating have the function of good adjustment humidity.
Sodium polymethacrylate has good dissemination, can enhance productivity, the stability of the storage of coating and improve covering, the gloss of film; Dimethyl silicone oil, can suppress the bubble in coating, and then improves the barrier propterty of coating film; Cellulose acetate-butyrate, has excellent moisture-resistant, and ultraviolet resistance, cold-resistant, pliable and tough, transparent, the performance such as film forming, levelling, can increase the over-all properties of coating effectively; Natvosol, can improve the sticking power of coating, prevent Paint Falling; Xitix, can improve the oxidation-resistance of coating; Glass fibre, can strengthen toughness and the shock-resistance of coating; BIT, can sterilization and anticorrosion, improves the weather resistance of coating; Emulsified olefin, can stop entering of oxygen, improves the stability of film forming.
In use, only need direct spraying or brushing on the surface needing waterproof thing, overcoating brush of laying equal stress on is to certain thickness for stain resistant acrylate waterproof paint of the present invention, and maintenance 3 days or more.
The invention has the beneficial effects as follows:
The present invention is a kind of stain resistant acrylate waterproof paint be made up of acrylate modified composite emulsion, fluorocarbon surfactant, nano modified material, color stuffing and various auxiliary agent.Compared with prior art, the present invention has following several advantage:
First, present invention employs styrene monomer, urethane, epoxy resin, organosilicon and inorganic silicon emulsion and modification compound is carried out to acrylate, overcome the low and technical problem that contamination resistance is bad of the hardness of acrylate in prior art, also improve physicals and the chemical property of coating simultaneously, thus obtain the coating of high comprehensive performance.
Secondly, fluorocarbon surfactant can not only modified acrylate emulsion, make it have good weather resistance, chemical stability, water resistance, and film coated surface can also be made to have ultra-low surface energy, dust not easily sticks, strengthen the anti-contamination capability of coating, even can also accelerate levelling speed and the wetting speed of coating, impel coating in drying and forming-film process, form smooth, smooth, a uniform film.
Then, adding of nano titanium oxide and carbon nanotube, make the various performances of coating more excellent.As, nano titanium oxide can improve weathering resistance, the reduction film coated surface energy of coating, makes it have superpower anti-contamination capability.In addition, by its light-catalyzed reaction, the performance preventing bacterial adhesion, clear the pollution off can also be made it have.Carbon nanotube then can improve the electroconductibility of coating, hardness, snappiness and impact resistance well.
Finally, adding of various auxiliary agent, make the function of coating more comprehensively, range of application is wider.As, sepiolite/sodium polyacrylate mixture, can make coating have the function regulating humidity; BIT, can make coating have sterilization and rot-resistant function; Emulsified olefin, can make coating have the function stoping oxygen to enter, improve the stability of film forming.
Waterproof paint disclosed in this invention have formula rationally, construction is simple, contamination resistance is good, hardness is high, and the feature that over-all properties is good, can be applicable to the waterproof of roofing, vault and toilet etc.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
In use, only need direct spraying or brushing on the surface needing waterproof thing, overcoating brush of laying equal stress on is to 2mm thickness for stain resistant acrylate waterproof paint of the present invention, and maintenance 3 days.
Embodiment 1
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylic ester emulsion 6 parts, styrene monomer modified acrylate emulsion 6 parts, polyurethane-modified polyacrylate emulsion 7 parts, epoxy resin modification acrylic ester emulsion 7 parts, organosilicon-modified acrylate emulsion 8 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 8 parts, fluorocarbon surfactant 2 parts, nano titanium oxide 3 parts, carbon nanotube 3 parts, talcum powder 13 parts, 9 parts, calcium carbonate, montmorillonite 3 parts, sepiolite/sodium polyacrylate mixture 0.2 part, sodium polymethacrylate 0.4 part, dimethyl silicone oil 0.3 part, cellulose acetate-butyrate 1.5 parts, Natvosol 0.4 part, 0.2 part, xitix, 0.3 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.2 part, emulsified olefin 0.3 part, 30 parts, water.
Embodiment 2
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylic ester emulsion 4 parts, styrene monomer modified acrylate emulsion 4 parts, polyurethane-modified polyacrylate emulsion 5 parts, epoxy resin modification acrylic ester emulsion 5 parts, organosilicon-modified acrylate emulsion 6 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 6 parts, fluorocarbon surfactant 1 part, nano titanium oxide 2 parts, carbon nanotube 2 parts, talcum powder 10 parts, 8 parts, calcium carbonate, montmorillonite 2 part, sepiolite/sodium polyacrylate mixture 0.1 part, sodium polymethacrylate 0.3 part, dimethyl silicone oil 0.1 part, cellulose acetate-butyrate 1 part, Natvosol 0.2 part, 0.1 part, xitix, 0.1 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.1 part, emulsified olefin 0.2 part, 20 parts, water.
Embodiment 3
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylic ester emulsion 8 parts, styrene monomer modified acrylate emulsion 8 parts, polyurethane-modified polyacrylate emulsion 8 parts, epoxy resin modification acrylic ester emulsion 8 parts, organosilicon-modified acrylate emulsion 9 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 9 parts, fluorocarbon surfactant 3 parts, nano titanium oxide 4 parts, carbon nanotube 4 parts, talcum powder 16 parts, 10 parts, calcium carbonate, montmorillonite 4 parts, sepiolite/sodium polyacrylate mixture 0.3 part, sodium polymethacrylate 0.5 part, dimethyl silicone oil 0.5 part, cellulose acetate-butyrate 2 parts, Natvosol 0.6 part, 0.3 part, xitix, 0.5 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.3 part, emulsified olefin 0.4 part, 40 parts, water.
Embodiment 4
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylic ester emulsion 5 parts, styrene monomer modified acrylate emulsion 5 parts, polyurethane-modified polyacrylate emulsion 6 parts, epoxy resin modification acrylic ester emulsion 6 parts, organosilicon-modified acrylate emulsion 7 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 7 parts, fluorocarbon surfactant 2 parts, nano titanium oxide 3 parts, carbon nanotube 3 parts, talcum powder 12 parts, 9 parts, calcium carbonate, montmorillonite 3 parts, sepiolite/sodium polyacrylate mixture 0.2 part, sodium polymethacrylate 0.4 part, dimethyl silicone oil 0.2 part, cellulose acetate-butyrate 1.2 parts, Natvosol 0.3 part, 0.2 part, xitix, 0.2 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.2 part, emulsified olefin 0.3 part, 25 parts, water.
Embodiment 5
A kind of stain resistant acrylate waterproof paint, be made up of each component of following weight: acrylic ester emulsion 7 parts, styrene monomer modified acrylate emulsion 7 parts, polyurethane-modified polyacrylate emulsion 7 parts, epoxy resin modification acrylic ester emulsion 7 parts, organosilicon-modified acrylate emulsion 8 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 8 parts, fluorocarbon surfactant 3 parts, nano titanium oxide 4 parts, carbon nanotube 4 parts, talcum powder 14 parts, 10 parts, calcium carbonate, montmorillonite 4 parts, sepiolite/sodium polyacrylate mixture 0.3 part, sodium polymethacrylate 0.5 part, dimethyl silicone oil 0.4 part, cellulose acetate-butyrate 1.8 parts, Natvosol 0.5 part, 0.3 part, xitix, 0.4 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.3 part, emulsified olefin 0.4 part, 35 parts, water.
The performance test results of the stain resistant acrylate waterproof paint that table 1 is made for embodiment 1 ~ 5.
Table 1
Certainly, just the preferred embodiments of the disclosure is described in detail above, not limits practical range of the present invention with this, and all equivalence changes done according to principle of the present invention, structure and structure, all should be covered by protection scope of the present invention.
Claims (5)
1. a stain resistant acrylate waterproof paint, it is characterized in that: it is made up of each component of following weight: acrylate modified composite emulsion 30 ~ 50 parts, fluorocarbon surfactant 1 ~ 3 part, nano modified material 4 ~ 8 parts, color stuffing 20 ~ 30 parts, humextant 0.1 ~ 0.3 part, dispersion agent 0.3 ~ 0.5 part, defoamer 0.1 ~ 0.5 part, film coalescence aid 1 ~ 2 part, thickening material 0.2 ~ 0.6 part, antioxidant 0.1 ~ 0.3 part, 0.1 ~ 0.5 part, glass fibre, anticorrosion and bactericidal agent 0.1 ~ 0.3 part, emulsified olefin 0.2 ~ 0.4 part, 20 ~ 40 parts, water.
2. stain resistant acrylate waterproof paint according to claim 1, it is characterized in that: described acrylate modified composite emulsion is 4 ~ 8 parts of acrylic ester emulsions, 4 ~ 8 parts of styrene monomer modified acrylate emulsions, 5 ~ 8 parts of polyurethane-modified polyacrylate emulsions, 5 ~ 8 parts of epoxy resin modification acrylic ester emulsions, 6 ~ 9 parts of organosilicon-modified acrylate emulsions, 6 ~ 9 parts of emulsion modified acrylic ester emulsions of inorganic silicon are composited.
3. stain resistant acrylate waterproof paint according to claim 1, is characterized in that: described nano modified material is 2 ~ 4 parts of nano titanium oxides, the mixture of 2 ~ 4 parts of carbon nanotubes.
4. stain resistant acrylate waterproof paint according to claim 1, is characterized in that: described color stuffing is 10 ~ 16 parts of talcum powder, 8 ~ 10 parts of calcium carbonate, the mixture of 2 ~ 4 parts of montmorillonites.
5. stain resistant acrylate waterproof paint according to claim 1, it is characterized in that: acrylic ester emulsion 6 parts, styrene monomer modified acrylate emulsion 6 parts, polyurethane-modified polyacrylate emulsion 7 parts, epoxy resin modification acrylic ester emulsion 7 parts, organosilicon-modified acrylate emulsion 8 parts, the emulsion modified acrylic ester emulsion of inorganic silicon 8 parts, fluorocarbon surfactant 2 parts, nano titanium oxide 3 parts, carbon nanotube 3 parts, talcum powder 13 parts, 9 parts, calcium carbonate, montmorillonite 3 parts, sepiolite/sodium polyacrylate mixture 0.2 part, sodium polymethacrylate 0.4 part, dimethyl silicone oil 0.3 part, cellulose acetate-butyrate 1.5 parts, Natvosol 0.4 part, 0.2 part, xitix, 0.3 part, glass fibre, 1, 2-benzisothiazole-3-ketone 0.2 part, emulsified olefin 0.3 part, 30 parts, water.
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| CN201510725572.0A CN105199527A (en) | 2015-10-30 | 2015-10-30 | Stain-resistant acrylic ester waterproof coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106499068A (en) * | 2016-12-06 | 2017-03-15 | 平顶山环宇星防水科技有限公司 | Acrylate polymer composite waterproof system and its construction method |
| CN106634502A (en) * | 2016-10-11 | 2017-05-10 | 安徽卡塔门窗有限公司 | Easy-to-clean aluminum alloy windows and doors and preparation method thereof |
| CN108977051A (en) * | 2018-06-29 | 2018-12-11 | 安徽天锦云漆业有限公司 | A kind of water-fast stain-resistant exterior wall coating |
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| CN103666155A (en) * | 2013-12-11 | 2014-03-26 | 青岛益群漆业集团有限公司 | Nano modified high-stain-resistance elastic paint |
| CN104927536A (en) * | 2015-06-23 | 2015-09-23 | 陈良伢 | Anti-pollution self-cleaning coating and preparation method thereof |
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| US20120004357A1 (en) * | 2009-03-13 | 2012-01-05 | Seawax Marine Coatings | Aqueous formulation for an antifouling coating system for submerged substrates, method for treating same, and use thereof |
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| CN106634502A (en) * | 2016-10-11 | 2017-05-10 | 安徽卡塔门窗有限公司 | Easy-to-clean aluminum alloy windows and doors and preparation method thereof |
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Application publication date: 20151230 |