CN103436159B - Composite high-polymer waterproof paint and preparation method thereof - Google Patents
Composite high-polymer waterproof paint and preparation method thereof Download PDFInfo
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Abstract
The invention provides a kind of Composite high-polymer waterproof paint and preparation method, described Composite high-polymer waterproof paint, comprise the component of following weight part: acrylate modified composite emulsion 35 ~ 48 parts, waterproofing agent of organosilicon 1 ~ 5 part, nano powder 1 ~ 5 part, color stuffing 15 ~ 35 parts, fungicidal preservative 0.2 ~ 0.5 part, antiaging agent 0.1 ~ 0.5 part, dispersion agent 0.2 ~ 1 part, wetting agent 0.1 ~ 0.15 part, film coalescence aid 1 ~ 1.5 part, flow agent 0.1 ~ 0.3 part, defoamer 0.2 ~ 0.4 part, thickening material 0.4 ~ 1.5 part, PH stablizer 0.1 ~ 0.5 part, 15 ~ 30 parts, water, described acrylate modified composite emulsion is acrylic ester elastic water-proof emulsion, the special high-elastic water-proof emulsion of cement, polyurethane-modified polyacrylate water-proof emulsion are composited.Instant invention overcomes the limitation existing for simple a kind of macromolecule emulsion, make the over-all propertieies such as the cementability of film, elasticity, water tolerance be able to comprehensive raising, there is after dried coating film good hydrophobic nature.
Description
Technical field
The invention belongs to chemical field field, especially a kind of Composite high-polymer waterproof paint and preparation method thereof.
Background technology
Current waterproof paint is mostly solvent-borne type, wherein containing a large amount of organic volatiles, can cause serious pollution to environment, and solvent-borne type water-proof material is just in the surface waterproofing of basic unit, and existence is combined shortcoming loosely with silicate material basic unit; Environment amenable water-emulsifying type waterproof coatings will be the developing direction of waterproof paint, but due to the aspect such as technology, construction, product performance are relatively poor: tensile strength is lower, and unit elongation is less, and weathering resistance is poor, and work-ing life is shorter.Therefore, how improving the performance such as work-ing life of flexible, the excellent anti-uv-ray of the enhanced water resistance of waterproof paint, high tensile, high tension set, very low temperature, significant prolongation waterproofing work, will be the important indicator that product innovation is pursued.Publication number is that CN1670096A application for a patent for invention discloses one " monocomponent high elastic aqueous polyurethane/acrylate building water-proof paint ", its proportioning (parts by weight) is: polyurethane/acrylic ester composite emulsion 30 ~ 90 parts, filling material 5 ~ 45 parts, dispersion agent 0.2 ~ 1.1 part, film coalescence aid 0.6 ~ 1.5 part, flow agent 0.05 ~ 0.35 part, defoamer 0.08 ~ 0.32 part, 0.6 ~ 12 part, softening agent, thickening material 0.01 ~ 1.0 part, pH stablizer 0.01 ~ 5.0 part, ultraviolet absorbers 0.5 ~ 1.0 part, 1 ~ 15 part, water.Preparation method's step is: by above-mentioned formula by dispersion agent, film coalescence aid, defoamer, softening agent, pH stablizer, ultraviolet absorbers stirs in water, adds filling material high speed dispersion, then slowly polyaminoester emulsion is poured into stirring, add flow agent again, defoamer, thickening material, continue stirring at low speed, obtain monocomponent high elastic aqueous polyurethane building water-proof paint.The monocomponent high elastic aqueous polyurethane building water-proof paint of this invention has the advantages such as high tensile, high tension set, very low temperature flexibility.Notification number is that the patent of invention of CN1441015C discloses " a kind of nano modification polymer-based carbon roofing waterproof paint and manufacture method thereof ", described waterproof paint, comprise the polymer emulsion as base-material, as the calcium carbonate of filler, talcum powder or mica powder, it is characterized in that adding the inorganic nano-particle as properties-correcting agent and the sodium-based montmorillonite as properties-correcting agent, the weight percent in coating shared by each raw material: polymer emulsion 38.9 ~ 65; Inorganic nano-particle 0.1 ~ 5; Sodium-based montmorillonite 1 ~ 6; Filler 30 ~ 60.Its manufacture method: add inorganic nano particle modified dose in base-material and disperse under ul-trasonic irradiation, then add sodium-based montmorillonite high-speed stirring and carry out intercalation synthesis, finally adds filler again through stirring, grinding, filter and obtain.This invention adopts inorganic nano-particle and the modification of sodium-based montmorillonite intercalation synthesis to combine, and makes this coating both have excellent mechanical property and water resistance, has again excellent anti-uv-ray, can work-ing life of significant prolongation roof waterproof engineering.
Summary of the invention
Emulsion is most important integral part in water-emulsifying type waterproof coatings, in order to solve the problems of the technologies described above, the invention provides a kind of Composite high-polymer waterproof paint and preparation method thereof, described Composite high-polymer waterproof paint adopts several emulsion to be compounded to form acrylate modified composite emulsion and closes, overcome the limitation existing for simple a kind of emulsion, make the over-all properties of waterproof paint more excellent; Simultaneously the adding of nano powder, the performance of described waterproof paint in ageing-resistant, antiseep, washability etc. can be improved further.
The present invention realizes above-mentioned technical purpose by following technique means.
A kind of Composite high-polymer waterproof paint, it is characterized in that, comprise following component: acrylate modified composite emulsion 35 ~ 48 weight part, waterproofing agent of organosilicon 1 ~ 5 weight part, nano powder 1 ~ 5 weight part, color stuffing 15 ~ 35 weight part, fungicidal preservative 0.2 ~ 0.5 weight part, antiaging agent 0.1 ~ 0.5 weight part, dispersion agent 0.2 ~ 1 weight part, wetting agent 0.1 ~ 0.15 weight part, film coalescence aid 1 ~ 1.5 weight part, flow agent 0.1 ~ 0.3 weight part, defoamer 0.2 ~ 0.4 weight part, thickening material 0.4 ~ 1.5 weight part, PH stablizer 0.1 ~ 0.5 weight part, water 15 ~ 30 weight part,
Described acrylate modified composite emulsion is 10 ~ 15 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 ~ 15 parts by weight of cement, 15 ~ 18 parts by weight of polyurethane modification acrylate water-proof emulsions are composited.
Preferably, described Composite high-polymer waterproof paint comprises following component: acrylic ester elastic water-proof emulsion 12 weight part, special high-elastic water-proof emulsion 10 weight part of cement, polyurethane-modified polyacrylate water-proof emulsion 18 weight part, waterproofing agent of organosilicon 3 weight part, nano powder 1.0 weight part, color stuffing 32 weight part, fungicidal preservative 0.2 weight part, antiaging agent 0.1 weight part, dispersion agent 0.4 weight part, wetting agent 0.1 weight part, defoamer 0.3 weight part, film coalescence aid 1 weight part, flow agent 0.2 weight part, thickening material 1 weight part, PH stablizer 0.2 weight part, water 22 weight part.
Preferably, described nano powder is nano silicon or ceramic.
Preferably, described color stuffing is one or more in titanium dioxide, talcum powder, wollastonite powder, coarse whiting, silica powder, mica powder, kaolin, sodium bentonite.
The preparation method of Composite high-polymer waterproof paint of the present invention, comprises the following steps:
(1) in dispersion machine, add the water of 15 ~ 30 weight parts, 0.2 ~ 0.5 weight part fungicidal preservative, 0.2 ~ 1 parts per weight dispersing agent, 0.1 ~ 0.2 weight part defoamer, 0.1 ~ 0.15 weight part wetting agent, 0.1 ~ 0.5 weight part PH stablizer are added to the water respectively, stir 10 minutes; Add 1 ~ 5 weight part nano powder and 15-35 weight part color stuffing, disperse 40 minutes;
(2) in dispersion machine, add 0.1 ~ 0.2 weight part defoamer, 1 ~ 1.5 weight part film coalescence aid again, respectively 10 ~ 15 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 ~ 15 parts by weight of cement, 15 ~ 18 parts by weight of polyurethane modification acrylate water-proof emulsions, 1 ~ 5 weight part waterproofing agent of organosilicon are slowly poured in dispersion machine again, stir 15 minutes, add 0.1 ~ 0.5 weight part antiaging agent, 0.1 ~ 0.3 weight part flow agent, 0.4 ~ 1.5 parts by weight of thickening agent again, continue stirring 25 minutes, namely make Composite high-polymer waterproof paint.
Preferably, in the preparation method of described Composite high-polymer waterproof paint, the water added in step (1) in dispersion machine is 22 weight parts, fungicidal preservative 0.2 weight part, dispersion agent 0.4 weight part, defoamer 0.2 weight part, wetting agent 0.1 weight part, PH stablizer 0.2 weight part, nano powder 1 weight part, color stuffing 32 weight part; In step (2), add defoamer 0.1 weight part in dispersion machine, film coalescence aid 1 weight part, acrylic ester elastic water-proof emulsion 12 weight part, special high-elastic water-proof emulsion 10 weight part of cement, polyurethane-modified polyacrylate water-proof emulsion 18 weight part, waterproofing agent of organosilicon 3 weight part, antiaging agent 0.1 weight part, flow agent 0.2 weight part, thickening material 1 weight part.
The acrylate modified composite emulsion that Composite high-polymer waterproof paint provided by the invention is composited with acrylic ester elastic water-proof emulsion, the special high-elastic water-proof emulsion of cement, polyurethane-modified polyacrylate water-proof emulsion is for base-material, and the multiple auxiliary agent of admixture, waterproofing agent of organosilicon, nano powder, antiaging agent and mineral filler are formulated.Wherein, acrylate modified composite emulsion overcomes the limitation existing for simple a kind of macromolecule emulsion, makes the over-all propertieies such as the cementability of film, elasticity, water tolerance be able to comprehensive raising, has good hydrophobic nature after dried coating film.
Because Composite high-polymer waterproof paint of the present invention is water-borne coatings, directly can construct on the basal plane of moist or dry various material.After application, can ooze in basic unit inner, close basic unit's internal capillary and kapillary; Waterproofing agent of organosilicon can also form water-repellent layer in silicate material; The coating formed has the performance of microdilatancy, can increase degree of compactness, strengthens water proof anti-seepage function further; Can form at coatingsurface the elastic water-proof film that tough and tensile, cohesive force is strong, have hydrophobic nature, the special shape of coated substrates can be adapted to.Rigid flexible system in table, forms complete water-proof system, reaches the effect of long-term water proof anti-seepage.
Composite high-polymer waterproof paint of the present invention, film is tough and tensile, and cohesive force is strong, and good-extensibility is water-fast hydrophobic; General waterproof product is better than in high-low temperature resistant, resistance to deterioration; Owing to being single component, directly brush, easy construction; Nonpoisonous and tasteless, environmental protection.Be applicable to the waterproof of all kinds of buildings such as new old roof, vault, toilet, windowsill, antiseepage, protection against the tide.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to this.
A kind of Composite high-polymer waterproof paint provided by the invention, the acrylate modified composite emulsion be composited with acrylic ester elastic water-proof emulsion, the special high-elastic water-proof emulsion of cement, polyurethane-modified polyacrylate water-proof emulsion is for base-material, admixture fungicidal preservative, antiaging agent, dispersion agent, wetting agent, film coalescence aid, flow agent, defoamer, thickening material, waterproofing agent of organosilicon, nano powder, antiaging agent and color stuffing, PH stablizer are formulated, are a kind of water-borne coatings.Acrylate modified composite emulsion is selected to overcome limitation existing for simple a kind of macromolecule emulsion, the over-all propertieies such as the cementability of film, elasticity, water tolerance are made to be able to comprehensive raising, after application, can ooze in basic unit inner, close basic unit's internal capillary and kapillary; Waterproofing agent of organosilicon can also form water-repellent layer in silicate material; The coating formed has the performance of microdilatancy, can increase degree of compactness, strengthens water proof anti-seepage function further; Can form at coatingsurface the elastic water-proof film that tough and tensile, cohesive force is strong, have hydrophobic nature, the special shape of coated substrates can be adapted to.Rigid flexible system in table, forms complete water-proof system, reaches the effect of long-term water proof anti-seepage, has good hydrophobic nature after dried coating film; Directly can construct on the basal plane of moist or dry various material.
The preparation method of described Composite high-polymer waterproof paint, comprises the following steps:
(1) in dispersion machine, add the water of 15 ~ 30 weight parts, 0.2 ~ 0.5 weight part fungicidal preservative, 0.2 ~ 1 parts per weight dispersing agent, 0.1 ~ 0.2 weight part defoamer, 0.1 ~ 0.15 weight part wetting agent, 0.1 ~ 0.5 weight part PH stablizer are added to the water respectively, stir 10 minutes; Add 1 ~ 5 weight part nano powder and 15-35 weight part color stuffing, disperse 40 minutes;
(2) in dispersion machine, add 0.1 ~ 0.2 weight part defoamer, 1 ~ 1.5 weight part film coalescence aid again, respectively 10 ~ 15 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 ~ 15 parts by weight of cement, 15 ~ 18 parts by weight of polyurethane modification acrylate water-proof emulsions, 1 ~ 5 weight part waterproofing agent of organosilicon are slowly poured in dispersion machine again, stir 15 minutes, add 0.1 ~ 0.5 weight part antiaging agent, 0.1 ~ 0.3 weight part flow agent, 0.4 ~ 1.5 parts by weight of thickening agent again, continue stirring 25 minutes, namely make Composite high-polymer waterproof paint.
The Composite high-polymer waterproof paint obtained comprises following component: acrylate modified composite emulsion 35 ~ 48 weight part, waterproofing agent of organosilicon 1 ~ 5 weight part, nano powder 1 ~ 5 weight part, color stuffing 15 ~ 35 weight part, fungicidal preservative 0.2 ~ 0.5 weight part, antiaging agent 0.1 ~ 0.5 weight part, dispersion agent 0.2 ~ 1 weight part, wetting agent 0.1 ~ 0.15 weight part, film coalescence aid 1 ~ 1.5 weight part, flow agent 0.1 ~ 0.3 weight part, defoamer 0.2 ~ 0.4 weight part, thickening material 0.4 ~ 1.5 weight part, PH stablizer 0.1 ~ 0.5 weight part, water 15 ~ 30 weight part, described acrylate modified composite emulsion is 10 ~ 15 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 ~ 15 parts by weight of cement, 15 ~ 18 parts by weight of polyurethane modification acrylate water-proof emulsions are composited.
In the present invention, the waterproofing agent of organosilicon used can select methylsiloxane or sodium methyl silicate; Described nano powder is nano silicon or ceramic; Described color stuffing is one or more in titanium dioxide, talcum powder, wollastonite powder, coarse whiting, silica powder, mica powder, kaolin, sodium bentonite; Described fungicidal preservative is the one in promise moral C15 fungicidal preservative, ROHM AND HAAS LXE fungicidal preservative, the good bright K-03 fungicidal preservative in Shanghai; Described antiaging agent is Shanghai section king Nano uvioresistant agent or the clear UV light absorber of Weihai cloud; Described dispersion agent is extra large river chemical industry SN-5040 dispersion agent, described wetting agent is long weathering work CF-01 dispersion agent, one in the good bright PE-100 dispersion agent in Shanghai; Described defoamer is the peaceful NopcoNXZ defoamer of Hong Kong section; Described film coalescence aid is the one in propylene glycol or Texanol ester alcohol (2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate); Described flow agent is the one in SN-612, water-borne coatings flow agent LD-108A; Described thickening material is one or more in Natvosol, thickening material TT-935, thickening material ASE-65; Described PH stablizer is AMP-95(2-amino-2-methyl-1-propyl alcohol).
Embodiment 1:
The preparation method of Composite high-polymer waterproof paint, comprises the following steps:
(1) in dispersion machine, add the water of 22 weight parts, 0.2 weight part fungicidal preservative, 0.4 parts per weight dispersing agent, 0.2 weight part defoamer, 0.1 weight part wetting agent, 0.2 weight part PH stablizer are added to the water respectively, stir 10 minutes; Add 1 weight part nano powder and 32 weight part color stuffings, disperse 40 minutes.
(2) in dispersion machine, 0.1 weight part defoamer is added again, 1 weight part film coalescence aid, again respectively by 12 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 parts by weight of cement, 18 parts by weight of polyurethane modification acrylate water-proof emulsions, 3 weight part waterproofing agent of organosilicon are slowly poured in dispersion machine, stir 15 minutes, add 0.1 weight part antiaging agent again, 0.2 weight part flow agent, 1 parts by weight of thickening agent, continue stirring 25 minutes, namely the Composite high-polymer waterproof paint comprising following component is made: acrylic ester elastic water-proof emulsion 12 weight part, special high-elastic water-proof emulsion 10 weight part of cement, polyurethane-modified polyacrylate water-proof emulsion 18 weight part, waterproofing agent of organosilicon 3 weight part, nano powder 1 weight part, color stuffing 32 weight part, fungicidal preservative 0.2 weight part, antiaging agent 0.1 weight part, dispersion agent 0.4 weight part, wetting agent 0.1 weight part, defoamer 0.3 weight part, film coalescence aid 1 weight part, flow agent 0.2 weight part, thickening material 1 weight part, PH stablizer 0.2 weight part, water 22 weight part.
The Composite high-polymer waterproof paint obtained, be creamy white liquid state at normal temperatures, and after stirring, nothing is lumpd, in uniform state.Through performance test, its physical and mechanical property is all higher than JC/T864-2008 standard, and main physico-mechanical performance is in table 1:
Table 1
Composite high-polymer waterproof paint provided by the present invention should be noted when applying:
1, base treatment: basic unit should smooth, solid, clean, without open fire, without floating ash and greasy dirt, have crack and pipe root to stay the groove established to basic unit, should first pointing sealing material.Should clear up before construction, clean totally.
2, thin portion's additional waterproof process: before big area construction of waterproof layer, the Nodes such as negative and positive angle, pipeline root are first brushed 1 ~ 2 time coating and done additional waterproofing layer, and thickness is not less than 1mm.When adopting increasing paving one deck carcass strongthener, carcass should be clipped in the middle of film.
3, film waterproof material: should divide all over coating composition, preferably brush 2 ~ 3 times, often all over just can Tu Houyi time after drying, and different directions carries out, and second time brushing direction is vertical with first pass brushing direction.During as overlayed carcass strongthener, carcass material should be open and flat, no wrinkle and soaking into, and under carcass, film should be not less than 1.0mm, should be not less than 0.5mm above.
4, surface layer coating: adopt and add a small amount of water-reducible paint rolling applying one time, to improve surfacing, bright and clean effect.
5, protecting insulating layer: film waterproof material complete and qualified by inspection after, protecting insulating layer construction should be carried out by design requirements.
The reference consumption of the film of above-mentioned every mm thick is that weight of coated paint is about 2.5kg/m
2.
During the construction of this product, temperature need higher than 5 DEG C, and rainy weather or basic unit have during open fire and should not construct.
Top layer decoration construction can be carried out after waterproof coating answers complete drying.
Film complete drying is about 2 ~ 3 days, and wet environment answers proper extension, can carry out water-storing test after complete drying.
Coating can thin up, and amount of water should not exceed 10% of coating content.
The present invention is not limited to above-mentioned embodiment, and when not deviating from flesh and blood of the present invention, any apparent improvement that those skilled in the art can make, replacement or modification all belong to protection scope of the present invention.
Claims (3)
1. Composite high-polymer waterproof paint, it is characterized in that, comprise following component: acrylic ester elastic water-proof emulsion 12 weight part, special high-elastic water-proof emulsion 10 weight part of cement, polyurethane-modified polyacrylate water-proof emulsion 18 weight part, waterproofing agent of organosilicon 3 weight part, nano powder 1.0 weight part, color stuffing 32 weight part, fungicidal preservative 0.2 weight part, antiaging agent 0.1 weight part, dispersion agent 0.4 weight part, wetting agent 0.1 weight part, defoamer 0.3 weight part, film coalescence aid 1 weight part, flow agent 0.2 weight part, thickening material 1 weight part, pH stablizer 0.2 weight part, water 22 weight part, described nano powder is nano silicon or ceramic, described thickening material is Natvosol.
2. Composite high-polymer waterproof paint according to claim 1, is characterized in that, described color stuffing is one or more in titanium dioxide, talcum powder, wollastonite powder, coarse whiting, silica powder, mica powder, kaolin, sodium bentonite.
3. the preparation method of Composite high-polymer waterproof paint according to claim 1, is characterized in that, comprises the following steps:
(1) in dispersion machine, add the water of 22 weight parts, 0.2 weight part fungicidal preservative, 0.4 parts per weight dispersing agent, 0.2 weight part defoamer, 0.1 weight part wetting agent, 0.2 weight part pH stablizer are added to the water respectively, stir 10 minutes; Add 1 weight part nano powder and 32 weight part color stuffings, disperse 40 minutes;
(2) in dispersion machine, add 0.1 weight part defoamer, 1 weight part film coalescence aid again, respectively 12 parts by weight of acrylic acid ester elastomer water-proof emulsions, the special high-elastic water-proof emulsion of 10 parts by weight of cement, 18 parts by weight of polyurethane modification acrylate water-proof emulsions, 3 weight part waterproofing agent of organosilicon are slowly poured in dispersion machine again, stir 15 minutes, add 0.1 weight part antiaging agent, 0.2 weight part flow agent, 1 parts by weight of thickening agent again, continue stirring 25 minutes, namely make Composite high-polymer waterproof paint.
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| CN102433052A (en) * | 2011-09-10 | 2012-05-02 | 中国十七冶集团有限公司 | Aqueous polyurethane modified silicon-acrylate multifunctional waterproof heat-insulation elastic paint and preparation method thereof |
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