CN105176442B - A kind of environment-protective adhesive - Google Patents
A kind of environment-protective adhesive Download PDFInfo
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- CN105176442B CN105176442B CN201510592415.7A CN201510592415A CN105176442B CN 105176442 B CN105176442 B CN 105176442B CN 201510592415 A CN201510592415 A CN 201510592415A CN 105176442 B CN105176442 B CN 105176442B
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- protective adhesive
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Abstract
The present invention relates to a kind of adhesive, more particularly to a kind of environment-protective adhesive.The environment-protective adhesive includes the raw material of following parts by weight：20 40 parts of polyisoprene, 15 30 parts of polyvinyl alcohol, 15 30 parts of polyacrylamide, 10 22 parts of butanol, 12 25 parts of methyl hydroxyethylcellulose, 8 12 parts of boric acid, 2,5 12 parts of 6 three-level butyl, 4 methylphenol, 8 14 parts of sodium monofluorophosphate, 10 15 parts of organic siliconresin, modified 59 parts of bay alcohol radical sodium sulphate, 59 parts of puffing glutinous rice powder, 35 parts of urea, 15 30 parts of deionized water.The present invention has excellent caking property and good application property without formaldehyde, nonpoisonous and tasteless, simple production process, product, and adhesive force is strong, intensity is high, do not ftracture, water proofing property, alkali resistance are good, easy construction, easily blade coating, easily polishing.
Description
（One）Technical field
The present invention relates to a kind of adhesive, more particularly to a kind of environment-protective adhesive.
（Two）Background technology
It is in the majority with the not environmentally glue containing free formaldehyde more than decorations industry glue, although this kind of glue price is low,
Adhesive property is good；But formaldehyde is a kind of colourless intense irritation gas, it is defined as carcinogenic by the World Health Organization and causes
Abnormal material, and it has been included in glue banned substance.Undoubtedly, formaldehyde is to the toxic effect of the mankind, particularly if made in glue
With formaldehyde, then this kind of glue is indoors by after use, and Form aldehyde release is especially slow, environment indoors even up to after the several years
In can be tested with the presence of free formaldehyde, the injury for giving people to cause is irreversible, and the clear and definite mankind are many now
All to there is formaldehyde in disease relevant with interior.Therefore, develop a kind of without formaldehyde, safety and environmental protection indoor decorating glue
It is very urgent.
（Three）The content of the invention
There is provided a kind of environment-protective adhesive in order to make up the deficiencies in the prior art by the present invention.
The present invention is achieved through the following technical solutions：
A kind of environment-protective adhesive, includes the raw material of following parts by weight：20-40 parts of polyisoprene, polyvinyl alcohol 15-30
Part, 15-30 parts of polyacrylamide, 10-22 parts of butanol, 12-25 parts of methyl hydroxyethylcellulose, 8-12 parts of boric acid, 2,6- three-levels
5-12 parts of butyl -4- methylphenols, 8-14 parts of sodium monofluorophosphate, 10-15 parts of organic siliconresin, modified bay alcohol radical sodium sulphate 5-
9 parts, 5-9 parts of puffing glutinous rice powder, 3-5 parts of urea, 15-30 parts of deionized water.
Further, the raw material of following parts by weight is included：36 parts of polyisoprene, 21 parts of polyvinyl alcohol, polyacrylamide
18 parts, 16 parts of butanol, 21 parts of methyl hydroxyethylcellulose, 10 parts of boric acid, 2,6- 10 parts of three-level butyl -4- methylphenols, single fluorine
11 parts of sodium phosphate, 13 parts of organic siliconresin, modified 8 parts of bay alcohol radical sodium sulphate, 8 parts of puffing glutinous rice powder, 4 parts of urea, deionization
22 parts of water.
The polyisoprene degree of polymerization is 50-200.
By in deionized water plus 1 liter of four-hole boiling flask, 80 DEG C are heated to, mixer is started, polyethylene is then added slowly
Alcohol is simultaneously warming up to 90 DEG C -95 DEG C, is completely dissolved polyvinyl alcohol.Allow poly-vinyl alcohol solution to be cooled to 75-85 DEG C, continuing
Under stirring, butanol and boric acid are added in thread mode, stirs 30 minutes, adds polyacrylamide, methyl hydroxyethyl cellulose
Element, urea, organic siliconresin are stirred with 80 turns of ∕ component velocities, are warming up to 90-95 DEG C, time control was at 60 minutes；Reduce temperature
To 60-75 DEG C, add 2,6- three-level butyl -4- methylphenols, sodium monofluorophosphate, modified bay alcohol radical sodium sulphate and be stirred,
Stir after 15-20min, polyisoprene, puffing glutinous rice powder are added 80-85 DEG C is heated in four-hole boiling flask, stir 10-
15min, is then cooled to 45-50 DEG C of discharging, you can.
The beneficial effects of the invention are as follows：The present invention has excellent without formaldehyde, nonpoisonous and tasteless, simple production process, product
Caking property and good application property, adhesive force is strong, intensity is high, do not ftracture, water proofing property, alkali resistance are good, easy construction, easily scrape
Apply, easily polish.
（Four）Embodiment
Embodiment 1：
A kind of environment-protective adhesive, includes the raw material of following parts by weight：Polyisoprene 20g, polyvinyl alcohol 15g, poly- third
Acrylamide 15g, butanol 10g, methyl hydroxyethylcellulose 12g, boric acid 8g, 2,6- three-level butyl -4- methylphenols 5g, single fluorine phosphorus
Sour sodium 8g, organic siliconresin 10g, modified bay alcohol radical sodium sulphate 5g, puffing glutinous rice powder 5g, urea 3 g, deionized water 15g.
Said ratio raw material is produced by the following method：By in deionized water plus 1 liter of four-hole boiling flask, 80 DEG C are heated to,
Mixer is started, polyvinyl alcohol is then added slowly and 90 DEG C -95 DEG C are warming up to, polyvinyl alcohol is completely dissolved.Allow poly- second
Enolate solution is cooled to 75-85 DEG C, under continued mixing, and butanol and boric acid are added in thread mode, stirs 30 minutes, then adds
Enter polyacrylamide, methyl hydroxyethylcellulose, urea, organic siliconresin to stir with 80 turns of ∕ component velocities, be warming up to 90-95 DEG C,
Time control was at 60 minutes；Temperature is reduced to 60-75 DEG C, add 2,6- three-level butyl -4- methylphenols, sodium monofluorophosphate,
Modified bay alcohol radical sodium sulphate is stirred, after stirring 15-20min, and polyisoprene, puffing glutinous rice powder are added into four-hole boiling flask
80-85 DEG C is inside heated to, 10-15min is stirred, is then cooled to 45-50 DEG C of discharging, you can
Embodiment 2：
A kind of environment-protective adhesive, includes the raw material of following parts by weight：Polyisoprene 40g, polyvinyl alcohol 30g, poly- third
Acrylamide 30g, butanol 22g, methyl hydroxyethylcellulose 25g, boric acid 12g, 2,6- three-level butyl -4- methylphenols 12g, single fluorine
Sodium phosphate 14g, organic siliconresin 15g, modified bay alcohol radical sodium sulphate 9g, puffing glutinous rice powder 9g, urea 5g, deionized water 30g.
Operating procedure is same as Example 1.
Embodiment 3：
A kind of environment-protective adhesive, includes the raw material of following parts by weight：Polyisoprene 36g, polyvinyl alcohol 21g, poly- third
Acrylamide 18g, butanol 16g, methyl hydroxyethylcellulose 21g, boric acid 10g, 2,6- three-level butyl -4- methylphenols 10g, single fluorine
Sodium phosphate 11g, organic siliconresin 13g, modified bay alcohol radical sodium sulphate 8g, puffing glutinous rice powder 8g, urea 4g, deionized water 22g.
Operating procedure is same as Example 1.
Claims (2)
1. a kind of environment-protective adhesive, it is characterised in that：Include the raw material of following parts by weight：20-40 parts of polyisoprene, poly- second
15-30 parts of enol, 15-30 parts of polyacrylamide, 10-22 parts of butanol, 12-25 parts of methyl hydroxyethylcellulose, 8-12 parts of boric acid,
2,6- 5-12 parts of three-level butyl -4- methylphenols, 8-14 parts of sodium monofluorophosphate, 10-15 parts of organic siliconresin, modified bay alcohol radical
5-9 parts of sodium sulphate, 5-9 parts of puffing glutinous rice powder, 3-5 parts of urea, 15-30 parts of deionized water；The polyisoprene degree of polymerization
For 50-200.
2. environment-protective adhesive according to claim 1, it is characterised in that：Include the raw material of following parts by weight：Poly- isoamyl
36 parts of diene, 21 parts of polyvinyl alcohol, 18 parts of polyacrylamide, 16 parts of butanol, 21 parts of methyl hydroxyethylcellulose, 10 parts of boric acid,
2,6- 10 parts of three-level butyl -4- methylphenols, 11 parts of sodium monofluorophosphate, 13 parts of organic siliconresin, modified bay alcohol radical sodium sulphate 8
Part, 8 parts of puffing glutinous rice powder, 4 parts of urea, 22 parts of deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510592415.7A CN105176442B (en) | 2015-09-17 | 2015-09-17 | A kind of environment-protective adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510592415.7A CN105176442B (en) | 2015-09-17 | 2015-09-17 | A kind of environment-protective adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105176442A CN105176442A (en) | 2015-12-23 |
| CN105176442B true CN105176442B (en) | 2017-10-31 |
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ID=54898893
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510592415.7A Active CN105176442B (en) | 2015-09-17 | 2015-09-17 | A kind of environment-protective adhesive |
Country Status (1)
| Country | Link |
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Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1720887B1 (en) * | 2004-02-23 | 2008-04-02 | Dow Gloval Technologies Inc. | Aqueous-based adhesive for bonding low surface energy substrates |
| CN104263284A (en) * | 2014-09-16 | 2015-01-07 | 石麓瑶 | Glass cement |
| CN104388010A (en) * | 2014-10-31 | 2015-03-04 | 青岛昌安达药业有限公司 | High-efficiency, low-toxicity and environment-friendly adhesive |
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2015
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| CN105176442A (en) | 2015-12-23 |
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Effective date of registration: 20190827 Address after: 065800 Taoguanying Village, Zuogezhuang Town, Wen'an County, Langfang City, Hebei Province Patentee after: Langfang strives Wood Industry Co., Ltd. Address before: 274000 Shandong city of Heze province of East Road, Maoyebaihuo West No. 39-2 Patentee before: HEZE HAINUO INTELLECTUAL PROPERTY SERVICES CO., LTD. |
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