CN105155308A - Production method of leather achieving crazing sense - Google Patents
Production method of leather achieving crazing sense Download PDFInfo
- Publication number
- CN105155308A CN105155308A CN201510694209.7A CN201510694209A CN105155308A CN 105155308 A CN105155308 A CN 105155308A CN 201510694209 A CN201510694209 A CN 201510694209A CN 105155308 A CN105155308 A CN 105155308A
- Authority
- CN
- China
- Prior art keywords
- leather
- wax
- parts
- crazing
- sense
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010985 leather Substances 0.000 title claims abstract description 49
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000001993 wax Substances 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 6
- 239000000980 acid dye Substances 0.000 claims abstract description 6
- 235000013871 bee wax Nutrition 0.000 claims abstract description 6
- 239000012188 paraffin wax Substances 0.000 claims abstract description 6
- 229920000570 polyether Polymers 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 5
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 8
- 238000007639 printing Methods 0.000 claims description 6
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000012166 beeswax Substances 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims description 5
- 239000011241 protective layer Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 230000011218 segmentation Effects 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 14
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 102000004882 Lipase Human genes 0.000 description 7
- 108090001060 Lipase Proteins 0.000 description 7
- 238000005237 degreasing agent Methods 0.000 description 5
- 239000013527 degreasing agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- 238000004049 embossing Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004144 decalcomania Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010019 resist printing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
Provided is a production method of leather achieving crazing sense. A wax agent is prepared from, by weight, 65 parts of paraffin, 18 parts of beewax, 8 parts of rosin, 3 parts of sodium silicate, 2 parts of polyether modified organic silicon, 2 parts of alkyl modified organic siloxane and 2 parts of polyethylene wax. A dyeing process comprises the steps that the leather is placed in a drum containing 2 wt% of acid dye, the bath ratio is 1:150, the temperature is 55 DEG C, the rotating speed is 6 rpm, rotating is conducted for 5 min, and then rotating is stopped for 5 min; after dyeing is conducted for 60 min, the rotating speed of the drum is increased to 20 rpm to achieve further crazing of the dyed wax agent, and dying is finished after rotating is conducted for 10 min. The dyed leather achieving the crazing sense is obtained after dyeing is conducted.
Description
the application is application number is 2014103166653, and denomination of invention is " a kind of production method of the sense leather that chaps ", and the applying date is the divisional application of the application for a patent for invention of 2014-07-06.
Technical field
The present invention relates to a kind of production method of leather, particularly relate to a kind of production method of the sense leather that chaps.
Background technology
Batik is an ancient long art, and widespread, in manual textile dyeing technology among the people, is in fact the fabric resisting printing technology of folk tradition.Along with the raising of people's living standard, also no longer single color is satisfied with to the requirement of leather wear, has therefore also occurred the batik of leather.
The batik method of so-called leather, utilize wax as resist agent just, it is brushed in fusing on leather, forms dyeing-resisted layer, then through Crack handling, dye again, make dyestuff enter in leather by crackle, there is no the place of crackle owing to being covered by wax, therefore remain and original stay white or ground colour.Battik, the decalcomania obtained on leather by upper dye part and the aberration do not gone up between dye part just.But people, through various trial, expect the characteristic that can reach batik, but fail all the time to obtain meticulous wax line effect.
Beeswax pliability is high, and viscosity is large, and resist printing is effective, rubs without putting forth effort, and dyestuff can not penetrate into leather surface easily and get on, and therefore wax line is not obvious; And paraffin quality conventional in wax-dyeing process is hard, be easy to split, form obvious wax line, but adhesion strength is poor; THE VISCOSITY OF ROSINS is large, and easily cracked, anti-metachromia is good, in prior art, someone adopts above three kinds to carry out the composite blended wax that obtains and carry out batik, but its batik effect is still undesirable, can not obtain rough wax line and meticulous wax line, especially meticulous wax line effect is very undesirable simultaneously.
Along with the raising gradually of people's living standard and consumption idea, the range of application of leather is more and more wider, and people more and more do not meet pattern, the pattern of conventional leather.Generally adopt embossing or cracking resin for synthesizing to obtain cracking patterns leather in prior art, but through the pattern visual weak effect that embossing process obtains, and the complex process equipment that embossing needs, and cracking resin for synthesizing to shrink the cracking patterns fineness obtained poor.
Summary of the invention
For solving the problem, the invention provides a kind of production method of simple be full of cracks sense leather, it can give leather be full of cracks sense by dyeing, and decorative pattern is meticulous.
Chap and feel a production method for leather, it is characterized in that, described method is carried out according to the following step,
(1) select materials, leather pre-treatment;
(2) dewaxing: cerate is melted;
(3) print wax: by fusing wax liquid by serigraphy on leather;
(4) dye: the leather ACID DYES after printing wax liquid is dyeed, utilizes different rotary drum rotating speed to form segmentation crack to the impact of wax line;
(5) dewax: rotary drum falls soft, in carbon tetrachloride, then remove remaining wax;
(6) arrange: extension dries dry, then brushes protective layer.
Preferably, (1) selects crown leather, carries out degreasing, tanning process, then carries out process to leather surface and forms micropore;
(2) dewaxing: cerate is warming up to 80 DEG C with the speed of 0.5 DEG C/min, slowly stirs, is then cooled to 65 DEG C with the speed of 0.5 DEG C/min; The complex wax that described cerate is paraffin, beeswax, rosin, sodium silicate, organic silicon modified by polyether, alkyl-modified organosiloxane, Tissuemat E are formed; More preferably paraffin, beeswax, rosin, sodium silicate, organic silicon modified by polyether, alkyl-modified organosiloxane, Tissuemat E form complex wax with weight ratio 65:18:8:3:2:2:2.
(3) wax is printed: first design required pattern with computer, determine the position of global pattern, select 120 object silk screens, and prepare silk screen as requested, be placed on by the leather of ironing in machine table case, then with silk screen, cerate be printed on leather surface;
(4) dye: leather is placed in the rotary drum that 2wt% ACID DYES is housed, bath raio 1:150, temperature 55 DEG C, 6 revs/min, turn 5min and stop 5min, after dyeing time is 60min, improving rotary drum rotating speed is 20 revs/min, and the cerate of printing is chapped further, terminates dyeing after turning 10min;
(5) dewax: rotary drum falls soft, in carbon tetrachloride, then remove remaining wax;
(6) arrange: extension dries dry, then brushes protective layer.
More preferably, adopt acid lipase enzyme and degreasing agent to carry out ungrease treatment in described step (1), preferably adopt acid lipase enzyme and degreasing agent at room temperature to carry out ungrease treatment further; bath raio 1:1-1.5; first add acid lipase enzyme 1wt%; rotate 1.5 hours, then add degreasing agent 1g/L, rotate 45min; Tanning adopts glucose method configuration Chrome Tanning Liquor to carry out tanning; At leather surface by the solution left standstill process 30min brushing lipase, protease mass ratio is 3:1, form micropore to make the surface of leather.
Described protective layer is formed by polyurethane.
The present invention by increasing sodium silicate, organic silicon modified by polyether, alkyl-modified organosiloxane and Tissuemat E in cerate, optimize wax liquid mobility under molten state, make the cohesiveness of wax liquid and leather surface, both dewaxed after having prevented from dyeing difficulty, avoid again when producing wax line, wax comes off from leather surface, and can not there is bubble in the wax liquid formed, effectively shorten and boil wax temperature, boil the wax time, improve the quality of dewaxing.
In leather pre-treatment, adopt ferment treatment to make leather surface form micropore, improve the coloring effect of leather.And protective polyurethane layer is brushed after dyeing completes, the Color of protection leather is not destroyed.
On the other hand, the present invention by the intermittent rotary of rotary drum, progressively forms meticulous wax line while dyeing, to obtain exquisite be full of cracks sense leather.
The concentration occurred in present specification, specification digest, claims, wt% is the percentage by weight relative to fabric, and all the other are mass concentration, and percentage is weight percentage.
Detailed description of the invention
Illustrate the present invention further below in conjunction with specific embodiment, but protection scope of the present invention is not limited thereto.
embodiment 1:
(1) crown leather is selected, adopt acid lipase enzyme and degreasing agent at room temperature to carry out ungrease treatment; bath raio 1:1; first add acid lipase enzyme 1wt%; rotates 1.5 hours, then add degreasing agent 1g/L, rotate 45min, adopt glucose method configuration Chrome Tanning Liquor to carry out tanning process; be then the solution left standstill process 30min of 3:1 at leather surface by brushing lipase, protease mass ratio, to make the surface formation micropore of leather;
(2) dewaxing: cerate is melted; The process conditions of dewaxing are that cerate is warming up to 80 DEG C with the speed of 0.5 DEG C/min, slowly stir, and are then cooled to 65 DEG C with the speed of 0.5 DEG C/min; Described cerate is paraffin, beeswax, rosin, sodium silicate, organic silicon modified by polyether, alkyl-modified organosiloxane, Tissuemat E form with weight ratio 65:18:8:3:2:2:2;
(3) wax is printed: first design required pattern with computer, determine the position of global pattern, select 120 object silk screens, and prepare silk screen as requested, be placed on by the leather of ironing in machine table case, then with silk screen, cerate be printed on leather surface;
(4) dye: the leather ACID DYES after printing wax liquid is dyeed, forms segmentation crack; Dyeing condition be leather is placed on 2wt% ACID DYES is housed rotary drum in; bath raio 1:150; temperature 55 DEG C; 6 revs/min; turn 5min and stop 5min, after dyeing time is 60min, improving rotary drum rotating speed is 20 revs/min; the cerate of printing is chapped further, terminates dyeing after turning 10min.
(5) dewax: rotary drum falls soft, in carbon tetrachloride, then remove remaining wax;
(6) arrange: extension dries dry, then brushes protective polyurethane layer.
Rotary drum forms meticulous segmentation crack at the low rotational speed, and after raising rotating speed, wax line extends further, therefore can obtain comparatively rough wax line, and two kinds of wax lines compare, and produces visual sense of beauty strongly.
Claims (1)
1. chap and feel a production method for leather, it is characterized in that, described method is carried out according to the following step,
(1) select materials, leather pre-treatment;
(2) dewaxing: cerate is melted;
(3) print wax: by fusing wax liquid by serigraphy on leather;
(4) dye: the leather ACID DYES after printing wax liquid is dyeed, utilizes different rotary drum rotating speed to form segmentation crack to the impact of wax line;
(5) dewax: rotary drum falls soft, in carbon tetrachloride, then remove remaining wax;
(6) arrange: extension dries dry, then brushes protective layer,
It is characterized in that, described complex wax be paraffin, beeswax, rosin, sodium silicate, organic silicon modified by polyether, alkyl-modified organosiloxane, Tissuemat E with weight ratio 65:18:8:3:2:2:2 composition, described protective layer is formed by polyurethane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510694209.7A CN105155308B (en) | 2014-07-06 | 2014-07-06 | The production method of cracking sense leather |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410316665.3A CN104074073B (en) | 2014-07-06 | 2014-07-06 | A kind of production method of the sense leather that chaps |
| CN201510694209.7A CN105155308B (en) | 2014-07-06 | 2014-07-06 | The production method of cracking sense leather |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410316665.3A Division CN104074073B (en) | 2014-07-06 | 2014-07-06 | A kind of production method of the sense leather that chaps |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105155308A true CN105155308A (en) | 2015-12-16 |
| CN105155308B CN105155308B (en) | 2017-11-14 |
Family
ID=51595657
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410316665.3A Expired - Fee Related CN104074073B (en) | 2014-07-06 | 2014-07-06 | A kind of production method of the sense leather that chaps |
| CN201510694209.7A Active CN105155308B (en) | 2014-07-06 | 2014-07-06 | The production method of cracking sense leather |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410316665.3A Expired - Fee Related CN104074073B (en) | 2014-07-06 | 2014-07-06 | A kind of production method of the sense leather that chaps |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104074073B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923374A (en) * | 2019-11-11 | 2020-03-27 | 兴业皮革科技股份有限公司 | Leather crack treatment method, leather comprising crack treatment method and preparation method of leather |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905709B (en) * | 2017-04-13 | 2019-10-08 | 黄平县阿欧桑民间工艺品开发有限责任公司 | Batik resist printing wax and preparation method thereof suitable for felt |
| CN107227635B (en) * | 2017-07-24 | 2019-08-16 | 北京泛博化学股份有限公司 | A kind of colouring method of the coney with segmentation crack effect |
| CN111057804B (en) * | 2020-01-02 | 2022-05-06 | 兴业皮革科技股份有限公司 | Patterned leather manufacturing method, leather and leather product |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58203868A (en) * | 1982-05-12 | 1983-11-28 | 株式会社中村千之助商店 | Method of packing leather for handicraft and batik |
| CN1051949A (en) * | 1990-06-20 | 1991-06-05 | 惠彬 | Wax painting method of leather |
| CN1811053A (en) * | 2006-03-01 | 2006-08-02 | 邢汝玲 | Wax printing method |
| CN101144251A (en) * | 2007-08-31 | 2008-03-19 | 王化斌 | Wax print cloth wax veins producing prescription and technique |
| CN103146852A (en) * | 2012-08-31 | 2013-06-12 | 欧阳海峰 | Leather and leather product, and processing method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02251685A (en) * | 1989-03-23 | 1990-10-09 | Komatsu Seiren Kk | Dyeing of artificial leather |
| CN1038441C (en) * | 1994-04-26 | 1998-05-20 | 刘子龙 | Colour wax printing process |
-
2014
- 2014-07-06 CN CN201410316665.3A patent/CN104074073B/en not_active Expired - Fee Related
- 2014-07-06 CN CN201510694209.7A patent/CN105155308B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58203868A (en) * | 1982-05-12 | 1983-11-28 | 株式会社中村千之助商店 | Method of packing leather for handicraft and batik |
| CN1051949A (en) * | 1990-06-20 | 1991-06-05 | 惠彬 | Wax painting method of leather |
| CN1811053A (en) * | 2006-03-01 | 2006-08-02 | 邢汝玲 | Wax printing method |
| CN101144251A (en) * | 2007-08-31 | 2008-03-19 | 王化斌 | Wax print cloth wax veins producing prescription and technique |
| CN103146852A (en) * | 2012-08-31 | 2013-06-12 | 欧阳海峰 | Leather and leather product, and processing method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘永庆: "古老蜡染再放异彩", 《丝网印刷》 * |
| 刘永庆: "皮革蜡染工艺及其应用", 《网印工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923374A (en) * | 2019-11-11 | 2020-03-27 | 兴业皮革科技股份有限公司 | Leather crack treatment method, leather comprising crack treatment method and preparation method of leather |
| CN110923374B (en) * | 2019-11-11 | 2021-11-02 | 兴业皮革科技股份有限公司 | Leather and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104074073A (en) | 2014-10-01 |
| CN105155308B (en) | 2017-11-14 |
| CN104074073B (en) | 2016-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104074072B (en) | A kind of batik method of leather | |
| CN104074073B (en) | A kind of production method of the sense leather that chaps | |
| CN105200812B (en) | Dyeing process of using dispersal fluorescent dye to dye super-fine polyester elastic fabric | |
| CN104611959B (en) | Method for preparing novel one-bath-multicolor batik silk fabric | |
| CN105970682A (en) | Dyeing agent and process for dyeing real silk by aid of dyeing agent | |
| CN106087470A (en) | A kind of environment-friendly type terylene fabric sand washing dyeing | |
| CN107476081A (en) | A kind of dyeing and finishing technology of polyester fiber cellulose fibre mixed textile product | |
| CN105507029B (en) | A kind of disposable production technology of jeans | |
| CN106544888A (en) | A kind of cashmere dyeing of the natural tea pigment of nanometer | |
| CN107268297B (en) | Wax printing method for cotton cloth and wax printed cotton cloth | |
| CN105421112A (en) | Wax-painting process for vegetable-tanned leather | |
| CN107164898A (en) | A kind of new wax-dyeing process of textile | |
| CN107227615A (en) | A kind of needlework and preparation method thereof | |
| CN107503202A (en) | A kind of random wax line pattern acquisition methods for industrializing printing and dyeing | |
| CN104947464A (en) | Process of super-soft wrinkle finishing and printing with transparent printing paste | |
| CN104264512A (en) | Printing method | |
| CN1307341C (en) | Manufacturing method of cowboy cloth having light coloured lines | |
| CN105773768A (en) | Dyeing and fading technology of bamboo | |
| CN104153216B (en) | A kind of colouring method of eider down | |
| CN104372694B (en) | A kind of arctic fox ginned cotton look processing method | |
| CN102086601B (en) | Woolen sweater printing method | |
| CN103498349A (en) | Technical method of Sichuan embroidery silk | |
| CN110284340A (en) | A kind of seamless swimsuit fabric colouring method of fine-denier full-dull nylon contaminating special dark color | |
| CN109605554A (en) | One kind building water pottery coloured silk and fills out technique | |
| CN106868886A (en) | A kind of acrylic resin non-woven fabrics painting methods |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Fang Jiujun Inventor after: Fang Jiucheng Inventor before: Geng Yunhua |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171010 Address after: Junan 276600 Shandong province Linyi city Junan County Economic Development Zone middle ring road. Applicant after: Shandong Juncheng leather Co Ltd Address before: Plum Street Jing Jia Pingdu City of Qingdao province Shandong 266708 Village Applicant before: Geng Yunhua |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Production method of cracking imitation leather Effective date of registration: 20191025 Granted publication date: 20171114 Pledgee: Shandong Junan Rural Commercial Bank Co., Ltd Pledgor: Shandong Juncheng leather Co Ltd Registration number: Y2019370000074 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |