CN105104407B - A kind of Efficient insecticidal composition - Google Patents
A kind of Efficient insecticidal composition Download PDFInfo
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- CN105104407B CN105104407B CN201510612981.XA CN201510612981A CN105104407B CN 105104407 B CN105104407 B CN 105104407B CN 201510612981 A CN201510612981 A CN 201510612981A CN 105104407 B CN105104407 B CN 105104407B
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- flufenzine
- hexythiazox
- mite
- fenpyroximate
- agent
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Abstract
The invention discloses a kind of Efficient insecticidal composition, comprising active components A and active component B, active components A is selected from flufenzine, and active component B is selected from following any one compound：Fenpyroximate, Hexythiazox, fenazaquin, and the weight ratio of two kinds of active components of A, B is the ︰ 1 of 1 ︰ 60~60.The present composition can prevent and treat various pests, and with obvious synergistic effect, and insecticidal spectrum is expanded, there is greater activity to the panonychus citri on cereal crop, fruit tree, flowers, cotton, tea tree, vegetables, blister mite, pear sucker, oystershell scale, leafhopper, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red spider, rust mite etc.；And pesticide usage amount is reduced, residual quantity of the agricultural chemicals on crop is reduced, environmental pollution is alleviated；, insect good to person poultry safety, Environmental compatibility is not likely to produce the resistance to the action of a drug.
Description
The application is divisional application, and original application is " a kind of high for the patent application of Shaanxi Welch Crop Protection Co., Ltd.
Effect Pesticidal combination ", the application Wei ︰ 2012100617549 of original application, original application day is 2012.03.10.
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of application of Efficient insecticidal composition on preventing and treating crop pest.
Background technology
Flufenzine (diflovidazin), molecular formula：C14H7CLF2N4, flufenzine contact goes out ovum and percutaneous activity, attracts mite
Adult takes food, and also prevents and treats the acarid in pupa stage.The compound effects mechanism is unique, not only has excellent work to ovum and into mite
Property, and female mite is produced unsound ovum, cause destroying the evidence for mite, to natural enemy and Environmental security.
Fenpyroximate (fenpyroximate), chemical name：(E) -4 [1,3- dimethyl-(5- phenoxy group -1H- pyrazolyls)
Methene ammonia oxygen methyl] benzoic acid -1,1 dimethylethyl esters, molecular formula：C24H27N3O4, fenpyroximate is benzene oxygen pyrazoles acaricide.It is high
Mite class can be directly killed during dosage, mite class decortication can be suppressed during low dosage or is laid eggs.With knocking down and suppressing decorticating, without in
Suction is acted on.
Hexythiazox (hexythiazox), molecular formula：C17H21ClN2O2S, Hexythiazox is the new acaricide of thiazolidine ketone,
There is preferable penetrability to plant epidermis layer, but without Uptake and translocation effect.There is strong ovicidal to various plants evil mite, kill
The characteristic of children mite, to invalid into mite, but the ovum that female adult pest to touching liquid is produced has the effect for suppressing hatching.The medicine
Belong to non-temperature sensitive type acaricide, the effect used in high temperature or low temperature is without significant difference, and the longevity of residure is long, be positively retained at 50 days left sides
It is right.
Fenazaquin (fenazaquin), molecular formula：C20H22N2O, chemical formula：4- spy-butyl phenethyl quinazoline -4- bases
Ether, the medicine is quinolines acaricide, by action of contace poison in the mitochondria and genome I of insect cell, occupies ubiquinone
Abutment, to citrus trees, apple tree red spider has preferable prevention effect, and the lasting period is long, to natural enemies security.
However, in the real process of agricultural production, pest control is easiest to generate the problem that the product of pest resistance to insecticide
It is raw.
Different cultivars composition is compounded, and is to prevent and treat the very common method of resistant insect.Heterogeneity is compounded, according to
Practical application effect come judge certain compounding be synergy, plus and or antagonism.In most cases, the compounding of agricultural chemicals
Effect is all additive effect, really have synergistic effect compounding seldom, especially synergistic effect clearly, co-toxicity coefficient it is very high
Compounding just it is less.Studied by inventor, find to be produced after flufenzine and fenpyroximate, Hexythiazox, fenazaquin compounding
Good synergistic effect, and not yet disclosed on the relevant report that flufenzine and fenpyroximate, Hexythiazox, fenazaquin are compounded.
The content of the invention
The problems such as resistance that flufenzine single dose long-term use may be brought occurs, drug effect declines, desinsection proposed by the present invention
Composition contains two kinds of active components of A, B, and appropriate surfactant and carrier.
A kind of Efficient insecticidal composition, comprising effective active components A and active component B, it is characterised in that：Active components A,
B weight ratio is the ︰ 1 of 1 ︰ 60~60, and described active components A is selected from flufenzine, and active component B is selected from fenpyroximate, Hexythiazox, quinoline mite
One of ether is planted.
Described Pesticidal combination, it is characterised in that：The weight ratio of two kinds of active components of A, B is the ︰ 1 of 1 ︰ 40~40.
Described Pesticidal combination, it is characterised in that：Flufenzine is the ︰ 1 of 1 ︰ 10~20 with the weight ratio of fenpyroximate.
Described Pesticidal combination, it is characterised in that：Flufenzine is the ︰ 1 of 1 ︰ 10~20 with the weight ratio of Hexythiazox.
Described Pesticidal combination, it is characterised in that：Flufenzine is the ︰ 1 of 1 ︰ 10~20 with the weight ratio of fenazaquin.
Two kinds of ratios of weight and number of active component of A, B are the ︰ 1 of 1 ︰ 60~60.The weight hundred of active component in usual composition
Content is divided to be the 0.5~90% of gross weight, preferably 5%~85%.According to different preparation types, active component content model
Enclose different.Generally, liquid preparation contains by weight 1~70% active material, preferably 5~50%；Solid system
Agent contains by weight 5~85% active material, preferably 10~80%.
At least contain a kind of surfactant in Pesticidal combination of the invention, active component is in water when being beneficial to administration
Dispersion.Surface-active contents are the 5~30% of total formulation weight, balance of solid or liquid diluent.
Surfactant selected by Pesticidal combination of the invention is known in those skilled in the art：Can be selected from
One or more in dispersant, wetting agent, binding agent or defoamer.Can also contain capable according to different dosage forms, in preparation
Disintegrant, antifreeze well known to field technique personnel etc..
Composition of the invention can by user using it is preceding through dilute or directly use.Its preparation can be by common
It is prepared by processing method well known to art personnel, will after active material mixes with liquid flux or solid carrier, then plus
Enter one or more in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer.
Pesticidal combination of the invention, can on demand be processed into acceptable formulation on any agricultural chemicals, wherein excellent relatively select
Formulation is：Wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-
Suspending agent.
Composition is when being made wettable powder comprising following constituent content：Active components A 1~80%, active component B 1
~80%, dispersant 2~10%, wetting agent 2~10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, filler are mixed, is well mixed in mixed cylinder, through gas
Stream pulverizer remixes uniform after crushing, you can be made wettable powder product of the present invention.
Composition includes following constituent content when being made water dispersible granules：Active components A 1~80%, active component B 1
~80%, dispersant 3~12%, wetting agent 1~8%, disintegrant 1~10%, binding agent 0~8%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are needed through air-flow crushing together
The particle diameter wanted, adds other auxiliary agents such as binding agent, obtains materials of pelletizing.Item is quantitatively sent into fluidized bed granulating dryer
By after granulation and drying, water dispersible granules product of the present invention being obtained.
Composition includes following constituent content when being made suspending agent：Active components A 1~50%, active component B 1~
50%th, dispersant 2~10%, wetting agent 2~10%, defoamer 0.1~2%, thickener 0.05~2%, antifreeze 0~8%,
Deionized water adds to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in above-mentioned formulation material are well mixed by high speed shear,
Active components A, active component B are added, ball milling 2~3 hours in ball mill make diameter of particle all below 5 μm, this is obtained
The described suspending agent product of invention.
Composition includes following constituent content when being made suspension emulsion：Active components A 1~50%, active component B 1~
50%th, emulsifying agent 2~12%, dispersant 2~10%, defoamer 0.1~2%, thickener 0.05~2%, antifreeze 0.1~
8%th, stabilizer 0~3%, water adds to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizer in above-mentioned formulation material are well mixed by high speed shear,
Active components A is added, ball milling 2~3 hours in ball mill make diameter of particle all below 5 μm, active components A is obtained and hangs
Floating agent, during active component B, emulsifying agent and various auxiliary agent high speed agitators directly then emulsified into suspending agent, is obtained this hair
Bright described suspension emulsion product.
Composition is when being made aqueous emulsion comprising following constituent content：Active components A 1~50%, active component B 1~
50%th, solvent 0~30%, emulsifying agent 1~15%, antifreeze 0~10%, thickener 0~2%, defoamer 0.01~2%, go
Ionized water supplies surplus.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifying agent, co-emulsifier are added together, make to be dissolved into uniformly
Oil phase；Water, antifreeze, thickener, defoamer are mixed, into homogeneous water phase.Under high velocity agitation, water is added to oil
Phase, is obtained aqueous emulsion product of the present invention.
Composition is when being made microemulsion comprising following constituent content：Active components A 1~50%, active component B 1~
50%th, solvent 0~30%, emulsifying agent 3~20%, antifreeze 0~10%, defoamer 0.01~2%, stabilizer 0~4%, go
Ionized water supplies surplus.
Active components A and active component B active compounds are dissolved in the homogenizer equipped with solvent and cosolvent；By emulsifying agent,
Stabilizer and antifreeze, water mix and homogenize strongly after being added in the homogenizer equipped with above-mentioned solution, finally obtain
The transparent microemulsion product of the present invention of clear appearance.
Composition is made micro-capsule suspension includes following constituent content：Active components A 0.1%~50%, active ingredient
B 0.1%~50%, macromolecule cyst material 1%~12%, surfactant 2%~10%, organic solvent 1%~15%,
Emulsifying agent 1%~8%, pH adjusting agent 0.1%~5%, deionized water adds to 100%.
Macromolecule cyst material addition PH conditioning agents are heated to uniform temperature, thick liquid is obtained, are then diluted with water,
The prepolymer solution of stabilization is formed, active ingredient B, active components A are dissolved into organic solvent, be then added to prepolymer solution
In, add emulsifying agent, surfactant, and fully shear agitation is dispersed into superfine microgranular, adds PH conditioning agents, and rise
Temperature, catalyzed polycondensation forms the firm microcapsules for being difficult infiltration, and micro-capsule suspension of the present invention is obtained.
When the formulation of composition is microcapsules suspension-suspending agent, the auxiliary agent of addition is surfactant, emulsifying agent, solvent,
PH conditioning agents, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition includes following constituent content when being made microcapsule suspension-suspendinagent agent：Active components A 0.1%~50%, have
Effect composition B 0.1%~50%, macromolecule cyst material 2%~12%, surfactant 3%~15%, organic solvent 1%~
5%th, emulsifying agent 1%~6%, defoamer 0.2%~5%, thickener 0.01%~5%, pH adjusting agent 0.1%~5%, water add
To 100%.
Using interfacial polymerization, will there are active ingredient B, macromolecule cyst material, organic solvent to mix in above-mentioned formula, make
Homogeneous oil phase is dissolved into, oil phase is added in a shear condition containing in emulsifying agent, the aqueous phase solution of pH adjusting agent, two kinds of materials
Material reacts in oil-water interfaces, around the droplet formation high score ascus wall containing chemical substance, is made active ingredient B microcapsules
Suspending agent.Surfactant, defoamer, thickener, antifreeze are well mixed by high speed shear, add active components A former
Medicine, ball milling 2~3 hours in ball mill make diameter of particle all below 5 μm, and active components A suspending agent is obtained, and then will
The active components A suspending agent for being dissolved in water stabilization is added in the aqueous phase solution of active ingredient B micro-capsule suspensions, is made this
The well dispersed microcapsule suspension-suspendinagent agent product of inventive composition.
Described dispersant is selected from alkylnaphthalene sulfonate, double (alkyl) naphthalenesulfonate formaldehyde condensation compounds, naphthalenesulfonateformaldehyde formaldehyde contracting
Compound, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, sulfomethylated lignin
Hydrochlorate, alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, the phonetic formaldehyde condensation products sulfate of alkylphenol-polyethenoxy,
Alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy are phonetic, aliphatic amine polyoxyethylene is phonetic, aliphatic acid
One or more during polyoxyethylene ester, ester polyoxyethylene are phonetic.
Described wetting agent is selected from：Lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent
One or more in F, sldium lauryl sulfate, spaonin powder, tea seed cake, silkworm excrement, spaonin powder.
Described disintegrant is selected from：In sodium acid carbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, aluminium chloride
One or more.
Described thickener is selected from：Hydroxymethyl cellulose, hydroxyethyl cellulose, Magnesiumaluminumsilicate, gelatin, guar gum, Arab
Glue, xanthans, sodium tripolyphosphate, phenolic resin, sodium alginate, white dextrin, methylcellulose, PAA, polyvinyl pyrrole
One or more in alkanone, PVPP, polyethylene glycol, polyvinyl alcohol.
Described emulsifying agent is selected from：Agriculture breast 500# (alkyl benzene calcium sulfonate), OP series phosphate (NPE
Phosphate), 600# phosphates (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl
Ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600# (phenyl phenol polyoxies
Ethylether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36# (phenethyl phenol formaldehyde resin polyoxyethanyls
Ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series
(NPE), By series (castor oil polyoxyethylene ether), agriculture breast 33# (alkylaryl polyoxyethylene polyoxypropylenes
Ether), agriculture breast 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitan monostearate), TWEEN Series
One or more in (sorbitan fatty acid ester APEO), AEO series (AEO).
Described solvent be selected from toluene, dichloromethane, 2,4- toluene di-isocyanate(TDI)s, dimethylbenzene, methyl alcohol, ethanol, acetone,
Ether, cyclohexanone, vegetable oil, dimethylformamide, acetonitrile, polyethylene glycol, pyrrolidones, solvent N-chain alkyl pyrrolidines
One or more in ketone；
Macromolecule cyst material is selected from urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl
Base halogen dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, Arabic gum, sucrose, converted starch, maltose, deformation lactoprotein, sweet
One or more in oil, calcium chloride, carboxymethylcellulose calcium, beta-schardinger dextrin.
Described PH conditioning agents are selected from one or more in NaOH, hydrochloric acid, citric acid, sorbic acid.
Described antifreeze is selected from：In glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol
One or more.
Described defoamer is selected from：Silicone, C8~10Aliphatic alcohols, C10~20Saturated fat acids (such as capric acid) and acid amides,
One or more in silicone oil, silicone compound.
Described preservative is selected from one or more in formaldehyde, sodium salicylate, Sodium Benzoate, dichlorophen；
Described filler is selected from：In kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate
One or more.
Wettable powder the key technical indexes of the invention：
Water dispersible granules the key technical indexes of the invention：
Suspending agent the key technical indexes of the invention：
Suspension emulsion the key technical indexes of the invention：
Aqueous emulsion the key technical indexes of the invention：
Microemulsion the key technical indexes of the invention：
Microcapsule suspending agent the key technical indexes of the invention：
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention：
The advantage of the invention is that：
(1) after flufenzine and Hexythiazox or fenpyroximate are compounded, with notable synergistic and lasting effect；
(2) expand insecticidal spectrum, to the panonychus citri on cereal crop, fruit tree, flowers, cotton, tea tree, vegetables,
Blister mite, pear sucker, oystershell scale, leafhopper, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red spider, rust mite etc. have compared with
High activity；
(3) dosage of agricultural chemicals is reduced, residual quantity of the agricultural chemicals on crop is reduced, environmental pollution is alleviated；
(4), insect good to person poultry safety, Environmental compatibility is not likely to produce the resistance to the action of a drug.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The flufenzine Hexythiazox wettable powder of example 1 30%
Flufenzine 20%, Hexythiazox 10%, polycarboxylate 6%, wetting and penetrating agent F5%, kaolin add to 100%, mixing
Thing carries out air-flow crushing, and 30% flufenzine Hexythiazox wettable powder is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox wettable powder of example 2 45%
Flufenzine 15%, Hexythiazox 30%, alkylaryl APEO 8%, Nekal BX 4%, diatomite are added to
100%, mixture carries out air-flow crushing, and 45% flufenzine Hexythiazox wettable powder is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox wettable powder of example 3 60%
Flufenzine 10%, Hexythiazox 50%, polyoxyethylene carboxylate 7%, lauryl sodium sulfate 5%, lightweight carbonic acid
Calcium adds to 100%, and mixture carries out air-flow crushing, and 60% flufenzine Hexythiazox wettable powder is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox wettable powder of example 4 61%
Flufenzine 1%, Hexythiazox 60%, lignosulfonates 5%, spaonin powder 3%, starch add to 100%, mixture
Air-flow crushing is carried out, 61% flufenzine Hexythiazox wettable powder is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox water dispersible granules of example 5 25%
Flufenzine 10%, Hexythiazox 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%, silkworm excrement 5%, sodium acid carbonate 2.8%,
Diatomite adds to 100%, is mixed to prepare 25% flufenzine Hexythiazox water dispersible granules.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox water dispersible granules of example 6 40%
Flufenzine 10%, Hexythiazox 30%, ester polyoxyethylene phonetic 5%, wetting and penetrating agent F 4%, glucose 2.6%, silicon
Diatomaceous earth adds to 100%, is mixed to prepare 40% flufenzine Hexythiazox water dispersible granules.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox water dispersible granules of example 7 60%
It is flufenzine 20%, Hexythiazox 40%, ester polyoxyethylene phonetic 6%, neopelex 5%, urea 3%, recessed
Convex rod soil adds to 100%, is mixed to prepare 60% flufenzine Hexythiazox water dispersible granules.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox water dispersible granules of example 8 61%
Flufenzine 60%, Hexythiazox 1%, octylphenol polyethylene oxyethylene group ether sulfate 7%, Nekal BX 5%, ammonium sulfate
2.5%th, white carbon adds to 100%, is mixed to prepare 61% flufenzine Hexythiazox water dispersible granules.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine hexythiazox suspension agent of example 9 10%
Flufenzine 5%, Hexythiazox 5%, naphthalene sulfonic acid-formaldehyde condensation product 6%, wetting and penetrating agent F 4%, silicone oil 0.3%, Huang
Virgin rubber 0.17%, ethylene glycol 1.2%, deionized water add to 100%, are mixed to prepare 10% flufenzine hexythiazox suspension agent.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine hexythiazox suspension agent of example 10 20%
Flufenzine 16%, Hexythiazox 4%, double (alkyl) naphthalenesulfonate formaldehyde condensation compounds 8%, sldium lauryl sulfate 5%,
C8~10Aliphatic alcohols 0.4%, methylcellulose 0.15%, triethylene glycol 1.7%, deionized water add to 100%, are mixed to prepare 20%
Flufenzine hexythiazox suspension agent.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine hexythiazox suspension agent of example 11 50%
Flufenzine 20%, Hexythiazox 30%, aryl phenol polyoxyethylene succinate sulfonate 5%, lauryl sodium sulfate
3%th, silicone oil 0.2%, sodium tripolyphosphate 0.12%, polyethylene glycol 1.6%, deionized water add to 100%, are mixed to prepare 50% fluorine
Mite piperazine hexythiazox suspension agent.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox suspension emulsion of example 12 18%
Flufenzine 8%, Hexythiazox 10%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 6%, agriculture breast 1600#5%,
Capric acid 0.43%, Magnesiumaluminumsilicate 0.17%, glycerine 1.2%, deionized water add to 100%, are mixed to prepare 18% flufenzine
Hexythiazox suspension emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox suspension emulsion of example 13 30%
The phonetic formaldehyde condensation products sulfate 8%, Nekal BX of flufenzine 10%, Hexythiazox 20%, alkylphenol-polyethenoxy
4%th, 600# phosphates 7%, silicone compound 0.5%, polyvinylpyrrolidone 0.13%, propane diols 1.4%, deionized water
100% is added to, 30% flufenzine Hexythiazox suspension emulsion is mixed to prepare.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox suspension emulsion of example 14 45%
Flufenzine 40%, Hexythiazox 5%, polycarboxylate 7%, tea seed cake 5%, TWEEN Series 6%, C10~20Saturated fatty acid
Class 0.2%, PAA 0.09%, glycerine 1.2%, deionized water add to 100%, are mixed to prepare 45% flufenzine Hexythiazox
Suspension emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine hexythiazox micro-emulsion of example 15 41%
Flufenzine 40%, Hexythiazox 1%, cyclohexanone 6%, EGME 7%, triethylene glycol 1.5%, oxirane-ring
Ethylene Oxide block copolymer 4%, Nongru-700 #5%, silicone 0.35%, deionized water supplies 100%, and 41% fluorine mite is obtained
Piperazine hexythiazox micro-emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox aqueous emulsion of example 16 22%
Flufenzine 20%, Hexythiazox 2%, N- pyrrolidones 8%, vegetable oil 3%, By series 5%, agriculture breast 500#3%, second
Glycol 1.6%, polyvinyl alcohol 0.14%, C8~10Aliphatic alcohols 0.22%, deionized water supplies 100%, and 22% fluorine mite is obtained
Piperazine Hexythiazox aqueous emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox aqueous emulsion of example 17 25%
Flufenzine 5%, Hexythiazox 20%, toluene 5%, acetone 4%, 600# phosphates 6%, Span series 4%, white dextrin
0.11%th, propane diols 1.7%, silicone compound 0.4%, deionized water supplies 100%, and 25% flufenzine Hexythiazox is obtained
Aqueous emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox aqueous emulsion of example 18 30%
Flufenzine 15%, Hexythiazox 15%, DMF 6%, propyl alcohol 5%, agriculture breast 600#3%, AEO series
6%th, gelatin 0.08%, diethylene glycol (DEG) 1.4%, C10~20Saturated fat acids 0.1%, deionized water supplies 100%, is obtained 30%
Flufenzine Hexythiazox aqueous emulsion.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspending agent of example 19 25%
Flufenzine 10%, Hexythiazox 15%, PIC 2.5%, sodium carboxymethylcellulose 0.7%, propane diols polyoxy
Ethene oxypropylene block polyethers 4%, solvent naphtha 2%, ethyl acetate 2%, ethanol 3%, By series 4%, sorbic acid 0.3%,
Hydrochloric acid 0.2%, NaOH 0.7%, deionized water add to 100% weight portion, 25% flufenzine Hexythiazox micro-capsule is obtained and hangs
Floating agent.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspending agent of example 20 35%
Flufenzine 30%, Hexythiazox 5%, polyvinyl alcohol 1.5%, gelatin 0.5%, glycerine 2.2%, ester polyoxyethylene are phonetic
2%th, styrene-maleic anhydride copolymer sodium salt emulsion 1.5%, agriculture breast 500#3%, agriculture breast 1600#3%, PH conditioning agent hydroxide
Sodium and hydrochloric acid amount to 1.4%, deionized water and add to 100% weight portion, and 35% flufenzine Hexythiazox microcapsule suspending agent is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspending agent of example 21 44%
Flufenzine 4%, Hexythiazox 40%, Arabic gum 6%, spaonin powder 2%, lignosulfonates 5%, acetone
3.2%th, alkylphenol-formaldehyde resin polyoxyethyl ether 4.1%, By series 5%, PH conditioning agents NaOH and citric acid amount to
2%th, deionized water adds to 100% weight portion, and 44% flufenzine Hexythiazox microcapsule suspending agent is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspension-suspendinagent agent of example 22 20%
Flufenzine 10%, Hexythiazox 10%, sodium alginate 1.6%, polyvinyl alcohol 0.3%, glycerine 4%, wetting and penetrating agent
F4.2%, fatty acyl amido are to methoxy benzenesulfonic acid sodium 3.1%, acetone 2.7%, dimethylbenzene 5%, AEO series 4%, epoxy second
Alkane-propylene oxide block copolymer 2%, C8~10Aliphatic alcohols 0.1%, methylcellulose 1%, pH adjusting agent NaOH and lemon
Lemon acid amounts to 2.3%, deionized water and adds to 100% weight portion, and 20% flufenzine Hexythiazox microcapsule suspension-suspendinagent agent is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspension-suspendinagent agent of example 23 30%
Flufenzine 12%, Hexythiazox 18%, urea 2%, formaldehyde 1.2%, di-2-ethylhexylphosphine oxide methyl naphthalene sulfonic acid salt 6%, benzene second
Alkene-maleic anhydride sodium salt emulsion 1.5%, agriculture breast 34#4%, styrene 6%, C8~10Saturated fat acids 0.5%, acetone
1.9%th, cyclohexanone 6%, pH adjusting agent NaOH and citric acid amount to 2.8%, PAA 0.5%, water and add to 100% weight
Amount part, is obtained 30% flufenzine Hexythiazox microcapsule suspension-suspendinagent agent.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine Hexythiazox microcapsule suspension-suspendinagent agent of example 24 40%
Flufenzine 5%, Hexythiazox 35%, polyvinyl alcohol 1.5%, glycerine 2.8%, converted starch 3%, Nekal BX
3.5%th, ester polyoxyethylene phonetic 2.4%, agriculture breast 36#4%th, sodium polymethacrylate 3%, cyclohexanone 2%, ethyl acetate 4%,
C8~10Aliphatic alcohols 0.3%, pH adjusting agent NaOH and sorbic acid amount to 2.8%, PVPP 0.4%,
Deionized water adds to 100% weight portion, and 40% flufenzine Hexythiazox microcapsule suspension-suspendinagent agent is obtained.
Hexythiazox is replaced with into fenpyroximate or fenazaquin forms new embodiment.
The flufenzine fenpyroximate wettable powder of embodiment 25 80%
Flufenzine 20%, fenpyroximate 60%, polycarboxylate 6%, wetting and penetrating agent F 5%, diatomite add to 100%, mix
Compound carries out air-flow crushing, and 80% flufenzine fenpyroximate wettable powder is obtained.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The flufenzine fenpyroximate water dispersible granule of embodiment 26 75%
Flufenzine 25%, fenpyroximate 50%, sldium lauryl sulfate 4%, ester polyoxyethylene phonetic 7%, aluminium chloride 2%, hard charcoal
It is black to add to 100%, it is mixed to prepare 75% flufenzine fenpyroximate water dispersible granule.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The flufenzine Enpyfoximate dispersant of embodiment 27 40%
The phonetic formaldehyde condensation products sulfate 7% of flufenzine 8%, fenpyroximate 32%, alkylphenol-polyethenoxy, spaonin powder 3%,
C8~10Aliphatic alcohols 0.1%, PAA 0.06%, deionized water add to 100%, are mixed to prepare 40% flufenzine fenpyroximate
Suspending agent.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The flufenzine fenpyroximate suspension emulsion of embodiment 28 30%
Flufenzine 20%, fenpyroximate 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, silkworm excrement 4%, alkyl benzene calcium sulfonate
6%th, N- pyrrolidones 5%, C8~10Aliphatic alcohols 0.3%, phenolic resin 0.08%, propane diols 1.8%, deionized water are added to
100%, it is mixed to prepare 30% flufenzine fenpyroximate suspension emulsion.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The flufenzine fenpyroximate microemulsion of embodiment 29 30%
Flufenzine 10%, fenpyroximate 20%, 3-methyl cyclohexanol ketenes 6%, sodium tripolyphosphate 0.2%, alkylaryl polyoxy
Ethene polyethenoxy ether 7%, silicone oil 0.4%, deionized water supply 100%, and 30% flufenzine fenpyroximate microemulsion is obtained.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The flufenzine fenpyroximate aqueous emulsion of embodiment 30 30%
Flufenzine 6%, fenpyroximate 24%, acetone 5%, butyl ether 5%, phenyl phenol polyoxyethyl ether 6%, polyvinylpyrrolidine
Ketone 0.18%, silicone 0.2%, deionized water adds to 100%, is mixed to prepare 30% flufenzine fenpyroximate aqueous emulsion.
Effective active composition fenpyroximate is changed to Hexythiazox, fenazaquin and forms new embodiment.
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
Calmly, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are compounded by a certain percentage, CTC ＜ 80 are antagonism, 80≤CTC≤120
It is summation action, CTC ＞ 120 are synergistic effect, on this basis, then carry out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment, is respectively placed in beaker
It is standby.Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the liquid for having configured
Taken out after immersion 5s, dried naturally, be put into insect box, then connected for examination larva, raised under the conditions of 25 DEG C, often process 3
Secondary repetition, often repeats test worm number used for 50, while setting blank, dead borer population is checked in 72h, calculates the death rate and correction
The death rate, tries to achieve virulence regression equation and calculates LC50Value.If the control death rate is more than 10%, it is considered as invalid experiment.Calculate public
Formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with minimum
Square law draws virulence regression equation, and thus calculates the value of every kind of medicament.Common poison system is calculated according to the abundant equations of Sun Yun
Number CTC.Computing formula is following, and (with flufenzine as standard agent, its toxicity index is for 100)：
TI × the P of theoretical toxicity index (the TTI)=flufenzine of MFlufenzineTI × the P of+effective active composition BEffective active compositionB
In formula：M is the mixture of different ratio
PEffective active compositionB is effective active composition B ratios shared in the composition
PFlufenzineIt is flufenzine ratio shared in the composition
A is selected from flufenzine；
B is selected from following any one compound：One of fenpyroximate, Hexythiazox, fenazaquin are planted.
Application Example two：
For examination insect：Panonychus citri.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective cause of flufenzine, fenpyroximate active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result one
The toxicity test of the flufenzine of table 1 and fenpyroximate different ratio to panonychus citri
As shown in Table 1, flufenzine prevents and treats the proportioning of panonychus citri in 60 ︰ 1 to 1 with fenpyroximate compounding：When 60, poison is altogether
Number is all higher than 120, illustrates both 60：Mixture shows synergistic effect in the range of 1 to 1 ︰ 60, especially when flufenzine and azoles
The proportioning of mite ester is 1：1 to 1：When 10, synergistic effect becomes apparent protruding, wherein when flufenzine and fenpyroximate weight ratio are 2 ︰ 1
When co-toxicity coefficient it is maximum, synergistic effect is the most obvious, is found through testing people, and flufenzine is compounded 60 with fenpyroximate：During 1 to 1 ︰ 60
To preventing and treating panonychus citri, blister mite, pear sucker, oystershell scale, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red spider,
The insects such as rust mite also have preferable synergistic effect, particularly when the proportioning of the two is 10:1、9:1、8:1、7:1、6:1、5:1、
4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:
15、1:16、1:17、1:18、1:19、1:Co-toxicity coefficient is all higher than 140 when 20, and synergistic effect is obvious.
Application Example three：
For examination insect：European red mite.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective cause of flufenzine, Hexythiazox active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result two
The toxicity test of the flufenzine of table 2 and Hexythiazox different ratio to European red mite
As shown in Table 2, flufenzine prevents and treats the proportioning of European red mite in 60 ︰ 1 to 1 with Hexythiazox compounding：When 60, poison is altogether
Number is all higher than 120, illustrates both 60：Mixture shows synergistic effect in the range of 1 to 1 ︰ 60, especially when flufenzine and thiophene
The proportioning of mite ketone is 10：1 to 1：When 10, synergistic effect becomes apparent protruding, wherein when flufenzine and Hexythiazox weight ratio are 2 ︰ 1
When co-toxicity coefficient it is maximum, synergistic effect is the most obvious, is found through testing people, and flufenzine is compounded 60 with Hexythiazox：During 1 to 1 ︰ 60
To preventing and treating blister mite, pear sucker, oystershell scale, leafhopper, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red spider, rust mite etc.
Evil mite also has preferable synergistic effect, particularly when the proportioning of the two is 20:1、19:1、18:1、17:1、16:1、15:1、
14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、
1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:17、1:18、1:19、1:It is malicious altogether when 20
Coefficient is all higher than 140, and synergistic effect is obvious.
Application Example four：
For examination insect：Cotton tetranychid.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective cause of flufenzine, fenazaquin active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result three
The toxicity test of the flufenzine of table 3 and fenazaquin different ratio to cotton tetranychid
As shown in Table 3, flufenzine prevents and treats the proportioning of cotton tetranychid in 60 ︰ 1 to 1 with fenazaquin compounding：When 60, co-toxicity coefficient
120 are all higher than, illustrate both 60：Mixture shows synergistic effect in the range of 1 to 1 ︰ 60, especially when flufenzine and quinoline mite
The proportioning of ether is 10：1 to 1：When 10, synergistic effect becomes apparent protruding, wherein when flufenzine and fenazaquin weight ratio are 2 ︰ 1
Co-toxicity coefficient is maximum, and synergistic effect is the most obvious, is found through testing people, and flufenzine is compounded 60 with fenazaquin：During 1 to 1 ︰ 60 pair
The evils such as preventing and treating blister mite, pear sucker, oystershell scale, leafhopper, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red spider, rust mite
Mite also has preferable synergistic effect, particularly when the proportioning of the two is 20:1、19:1、18:1、17:1、16:1、15:1、14:
1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:
6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:17、1:18、1:19、1:Poison is altogether when 20
Number is all higher than 140, and synergistic effect is obvious.
The flufenzine of Application Example five and Hexythiazox and its compounding preventing and treating panonychus citri test of pesticide effectiveness
This EE is ground in Sichuan Province Chengdu Pujiang County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, offer, the flufenzine suspending agent (autogamy) of comparison medicament 15%, 5% Hexythiazox missible oil (purchased in market).
Panonychus citri insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 7 days after dispenser, is investigated within 25 days, 50 days
Insect pest index simultaneously calculates preventive effect.Experimental result is as follows：
The flufenzine of table 4, Hexythiazox and its compounding preventing and treating panonychus citri test of pesticide effectiveness
As can be seen from Table 4, panonychus citri can be effectively prevented and treated after flufenzine and Hexythiazox compounding, prevention effect is superior to
The preventive effect of single dose.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example six and Hexythiazox and its compounding preventing and treating cotton red spider test of pesticide effectiveness
This EE is ground in Shaanxi Province Weinan City Dali County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, offer, the flufenzine suspending agent (autogamy) of comparison medicament 15%, 5% Hexythiazox missible oil (purchased in market).
Cotton red spider insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 7 days after dispenser, is investigated within 25 days, 50 days
Insect pest index simultaneously calculates preventive effect.Experimental result is as follows：
The flufenzine of table 5, Hexythiazox and its compounding preventing and treating cotton red spider test of pesticide effectiveness
As can be seen from Table 5, cotton red spider can be effectively prevented and treated after flufenzine and Hexythiazox compounding, prevention effect is superior to
The preventive effect of single dose.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example seven and Hexythiazox and its compounding preventing and treating apple Tetranychus urticae test of pesticide effectiveness
This EE is ground in Shaanxi Province Weinan City Pucheng County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, offer, the flufenzine suspending agent (autogamy) of comparison medicament 15%, 5% Hexythiazox missible oil (purchased in market).
Apple Tetranychus urticae insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 7 days after dispenser, is adjusted within 25 days, 50 days
Look into insect pest index and calculate preventive effect.Experimental result is as follows：
The flufenzine of table 6, Hexythiazox and its compounding preventing and treating apple Tetranychus urticae test of pesticide effectiveness
As can be seen from Table 6, apple Tetranychus urticae can be effectively prevented and treated after flufenzine and Hexythiazox compounding, prevention effect is excellent
In the preventive effect of single dose.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example eight and Hexythiazox and its compounding preventing and treating tetranychus vinenensis zacher test of pesticide effectiveness
This EE is ground in Shandong Weifang City Linqu County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, offer, the flufenzine suspending agent (autogamy) of comparison medicament 15%, 5% Hexythiazox missible oil (purchased in market).
Tetranychus vinenensis zacher insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 7 days after dispenser, is investigated within 25 days, 50 days
Insect pest index simultaneously calculates preventive effect.Experimental result is as follows：
The flufenzine of table 7, Hexythiazox and its compounding preventing and treating tetranychus vinenensis zacher test of pesticide effectiveness
As can be seen from Table 7, tetranychus vinenensis zacher can be effectively prevented and treated after flufenzine and Hexythiazox compounding, prevention effect is superior to
The preventive effect of single dose.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example nine and fenpyroximate and its compounding preventing and treating citrus red mite test of pesticide effectiveness
This EE is ground in Sichuan Province Chengdu Pujiang County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, offer, the flufenzine suspending agent (autogamy) of comparison medicament 15%, 5% hexythiazox suspension agent (purchased in market).
Citrus red mite insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 7 days after dispenser, is investigated within 25 days, 50 days
Insect pest index simultaneously calculates preventive effect.Experimental result is as follows：
The flufenzine of table 8, Hexythiazox and its compounding preventing and treating citrus red mite test of pesticide effectiveness
As can be seen from Table 8, citrus red mite can be effectively prevented and treated after flufenzine and fenpyroximate compounding, prevention effect is superior to
The preventive effect of single dose.Target crop is had no adverse effects in experiment scope of medication.
After different crop tests is directed to throughout the country, it is found that flufenzine is multiple with fenpyroximate, Hexythiazox, fenazaquin
To panonychus citri, blister mite, pear sucker, oystershell scale, leafhopper, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, tetranychid, red after matching somebody with somebody
Spider, rust mite have good synergy, 30 after medicine after preventive effect be more than 95%, preventive effect be better than single dose, experiment scope of medication in
Target crop is had no adverse effects.
Claims (9)
1. a kind of Efficient insecticidal composition, comprising effective active components A and active component B, it is characterised in that：Active components A, B
Weight ratio is the ︰ 1 of 1 ︰ 60~60, and described active components A is flufenzine, and active component B is selected from one of Hexythiazox, fenazaquin
Kind.
2. Pesticidal combination according to claim 1, it is characterised in that：The weight ratio of two kinds of active components of A, B is 1 ︰ 40
~40 ︰ 1.
3. Pesticidal combination according to claim 2, it is characterised in that：The weight ratio of flufenzine and Hexythiazox for 1 ︰ 10~
20 ︰ 1.
4. Pesticidal combination according to claim 2, it is characterised in that：The weight ratio of flufenzine and fenazaquin for 1 ︰ 10~
20 ︰ 1.
5. Pesticidal combination according to claim 1, it is characterised in that：The weight percentage of active component in composition
It is the 0.5%~90% of gross weight.
6. the Pesticidal combination according to any one of Claims 1 to 5, it is characterised in that：Composition is made wettable powder
Agent, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
7. Pesticidal combination according to claim 6 is used to prevent and treat cereal crop, fruit tree, flowers, cotton, tea tree, vegetable
The purposes of the insect on dish.
8. purposes according to claim 7, it is characterised in that：Described insect be blister mite, pear sucker, oystershell scale,
Leafhopper, yellow tea mite, red spider, rust mite.
9. purposes according to claim 7, it is characterised in that：Described insect is tetranychid.
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|---|---|---|---|---|
| CN1105025A (en) * | 1993-07-21 | 1995-07-12 | 奇诺英药物化学工厂有限公司 | Novel acaricidally active tetrazine derivatives |
| WO2000078739A1 (en) * | 1999-06-21 | 2000-12-28 | Syngenta Participations Ag | Pesticidally active tetrazine derivatives |
| CN101653126A (en) * | 2009-08-12 | 2010-02-24 | 东莞市瑞德丰生物科技有限公司 | Mite-killing composition containing fenazaquin |
| CN101731228A (en) * | 2010-01-20 | 2010-06-16 | 东莞市瑞德丰生物科技有限公司 | Fenazaquin-containing acaricidal composition |
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| CN100559947C (en) * | 2006-01-24 | 2009-11-18 | 浙江富来森中竹科技股份有限公司 | A kind of miticide that contains biomass gasification tar |
| CN101530090B (en) * | 2008-03-14 | 2012-10-03 | 北京绿色农华植保科技有限责任公司 | Suspending agent of fenproximate and clofentezine composite pesticide |
| EP2269455A1 (en) * | 2009-06-24 | 2011-01-05 | Bayer CropScience AG | Combinations of biological control agents and insecticides |
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|---|---|---|---|---|
| CN1105025A (en) * | 1993-07-21 | 1995-07-12 | 奇诺英药物化学工厂有限公司 | Novel acaricidally active tetrazine derivatives |
| WO2000078739A1 (en) * | 1999-06-21 | 2000-12-28 | Syngenta Participations Ag | Pesticidally active tetrazine derivatives |
| CN101653126A (en) * | 2009-08-12 | 2010-02-24 | 东莞市瑞德丰生物科技有限公司 | Mite-killing composition containing fenazaquin |
| CN101731228A (en) * | 2010-01-20 | 2010-06-16 | 东莞市瑞德丰生物科技有限公司 | Fenazaquin-containing acaricidal composition |
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| 氟螨嗪的合成;吕冬华 等;《现代农药》;20050228;第4卷(第1期);第10-11页 * |
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| CN103300040A (en) | 2013-09-18 |
| CN103300040B (en) | 2015-11-25 |
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