CN105086936B - A kind of artificial quartz stone plate polishing abrasive material and preparation method thereof - Google Patents

A kind of artificial quartz stone plate polishing abrasive material and preparation method thereof Download PDF

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Publication number
CN105086936B
CN105086936B CN201510410985.XA CN201510410985A CN105086936B CN 105086936 B CN105086936 B CN 105086936B CN 201510410985 A CN201510410985 A CN 201510410985A CN 105086936 B CN105086936 B CN 105086936B
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abrasive material
stone plate
artificial quartz
quartz stone
plate polishing
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CN105086936A (en
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郭栋
徐仲宝
杨东生
吴勇杰
朱学文
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Global Classical New Material Co Ltd In Dongguan
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Global Classical New Material Co Ltd In Dongguan
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Abstract

The invention discloses a kind of artificial quartz stone plate polishing abrasive material and preparation method thereof.Artificial quartz stone plate polishing abrasive material of the present invention is that raw material is prepared from 1% Graphene modified epoxy, sic powder, white fused alumina micro mist, short carbon fiber, high-carbon chromium iron, graphited oil, curing agent and wetting dispersing agent.Artificial quartz stone plate polishing of the present invention has wearability very high with abrasive material, compared with existing quartz abrasive material, coefficient of friction reduction by 50%, grinding efficiency improves 50%, with area rate of depreciation reduction by 40%, glossiness after polishing improves 3 ~ 8 °, the problems such as solving that existing quartz abrasive material grinding efficiency is low, be easily lost, with good application value.

Description

A kind of artificial quartz stone plate polishing abrasive material and preparation method thereof
Technical field
The present invention relates to be ground, polishing tool technical field, and in particular to a kind of artificial quartz stone plate polishing abrasive material And preparation method thereof.
Technical background
In the Home Industry that China develops rapidly, artificial quartz in lump as a kind of novel high polymer composite, except conduct It is increasingly extensive in whole sector application outside the auxiliary products of cabinet industry.The sheet material of quartz is widely used in cabinet table surface, defends Table top, Dining table top, hospital's table top and laboratory table top etc. between life.Current quartz, the especially conduct of artificial quartz in lump product A kind of high-end table top, ground decoration facestock increasingly liked by vast construction material consumer deeply, in recent years the market share Increased with 20%, domestic quartz annual turnover is more than 10,000,000 square metres within 2014.
Quartz is by the colorant of more than 90% natural quartz and 10% or so, adhesive and other regulation bonding, solidifications Deng additive composition.It is by negative-pressure vacuum, dither shaping, heating cure maintenance, the production method of compression molding The hair plates of formation, hair plates need to carry out fixed thick polishing, polishing could by it decorative cover perfect expressions out, but due to Its hardness is especially high(Quartz material Mohs' hardness 7), compact structure(2.35-2.5 grams/cc of density), make it in hair plates Requirement in fixed thickness bruting process to abrasive material is higher, and most durable stone material abrasive material on the market is for natural flowers hilllock of polishing at present Rock beam material, but such abrasive material is used for polishing quartz, because quartzite slate is more difficult to mill, causes that grinding efficiency is low, abrasive material is damaged Consumption speed is high, or even the problems such as the complete rear glossiness of sanding and polishing can be caused not high.
The content of the invention
It is an object of the invention to overcome existing building stones polished material to exist be not suitable for polishing artificial quartz stone plate and Caused grinding efficiency is low, quick abrasion, close after polishing pool degree it is not high the problems such as, there is provided a kind of grinding efficiency is high, abrasion is slow, polish The preferable artificial quartz stone plate polishing abrasive material of glossiness afterwards.
Another object of the present invention is the preparation method for providing above-mentioned artificial quartz stone plate polishing abrasive material.
Above-mentioned purpose of the present invention is achieved by the following technical programs:
A kind of artificial quartz stone plate polishing abrasive material, with 1wt% Graphenes modified epoxy, sic powder, Bai Gang Beautiful micro mist, short carbon fiber, high-carbon chromium iron, graphited oil, curing agent and wetting dispersing agent are raw material, are 12 according to mass ratio ~35:20~60:5~30:2~10:3~15:0.2~2:0.1~0.5:0.1 ~ 0.5 is prepared from.
In the preparing raw material of artificial quartz stone plate polishing abrasive material of the present invention, the sic powder, white fused alumina Micro mist, short carbon fiber, high-carbon chromium iron, graphited oil, curing agent and wetting dispersing agent are technical grade;The 1wt% graphite Alkene modified epoxy is glycidyl ester epoxy resin, the glycidol amine asphalt mixtures modified by epoxy resin of 1wt% Graphene toughening modifyings One or more in fat, cycloaliphatic epoxy resin;The particle diameter of the sic powder is 80 ~ 325 mesh;The white fused alumina micro mist Particle diameter be 100 ~ 200 mesh;The length of the short carbon fiber is 2mm;The particle diameter of the high-carbon chromium iron is 40 ~ 150 mesh.
The preparation method of artificial quartz stone plate polishing abrasive material of the present invention comprises the following steps:
(1)1wt% Graphenes modified epoxy, wetting dispersing agent and curing agent are proportionally poured into liquid stirrers Middle stirring, stir speed (S.S.) is 100 ~ 1000rpm, and mixing time is 3 ~ 20min, standby;
(2)Sic powder, white fused alumina micro mist, short carbon fiber, high-carbon chromium iron and graphited oil are proportionally fallen Enter material agitator to be stirred, stir speed (S.S.) is 100 ~ 500rpm, after 5 ~ 30min of stirring, pours into step(1)Products therefrom, It is again stirring for, stir speed (S.S.) is 100 ~ 800rpm, mixing time is 5 ~ 20min;
(3)By step(2)Gained compound add double-roll type material-twisting machine in, two roller spacing of adjustment be 5 ~ 10mm, left roller 50 ~ 100rpm, right 100 ~ 200rpm of roller, compound is carried out to rub scattered dispersion;
(4)By step(3)Resulting material is poured into abrasive material mould, under vacuum after 3 ~ 10min of vibration compacting, 100 ~ 200 DEG C of 1 ~ 5h of curing conservation, cooling and demolding obtains artificial quartz stone plate polishing abrasive material.
Compared with prior art, the present invention has the advantages that:
(1)The epoxy resin that the present invention is modified from Graphene as adhesive, using the sic powder of special ratios, White fused alumina micro mist, high-carbon chromium iron, short carbon fiber etc. using graphited oil as auxiliary agent dispensing formulations, then add as filler Enter auxiliary curing agent, the wearability of gained abrasive material is greatly improved, contrast the similar abrasive material of in the market, artificial quartz in lump of the present invention The coefficient of friction reduction by 50% of sheet material polishing abrasive material, grinding efficiency improves 50%, and polishing is beaten with area rate of depreciation reduction by 40% Glossiness improves 3 ~ 8 ° after mill.
Specific embodiment
With reference to embodiment, the present invention is further elaborated.But embodiment does not do any type of to the present invention Limit.
Embodiment 1
First by 42 kilograms of sic powders, 25 kilograms of white fused alumina micro mists, 5 kilograms of short carbon fibers, 10 kilograms of high-carbon chromium irons Planetary material agitator is successively poured into 0.8 kilogram of graphited oil, mixer is opened, stir speed (S.S.) is 400 rpms, Dispersed with stirring 10 minutes, period is by 16.7 kilograms of 1% Graphene modified epoxy, 0.2 kilogram of wetting dispersing agent and 0.3 Kilogram epoxy curing agent is stirred 5 minutes with liquid stirrers using 800 rpms, is stirred, the tree that will be mixed Lipoprotein mixture is added in planetary material agitator, and stir speed (S.S.) is 500 rpms, is mixed 10 minutes at room temperature, and In entering abrasive material mould under Material disintegrator particle afterwards, will material cloth be abound with it is flat after, being sent under vacuum suppressing room, vacuum carries out vibration compacting 5 minutes, 150 DEG C of curing conservations 3 hours, cooling and demolding is that can be used.
The quartz abrasive material of gained, contrast market Hengchang's stone material abrasive material conventional at present, the friction co-efficient value of abrasive material test block Reduce 57.1%;In production polishing contrast, grinding efficiency improves 52.0%, and abrasive material damages rate reduction 42%, and glossiness is averagely carried It is high 4 °.
Embodiment 2
First by 37 kilograms of sic powders, 27 kilograms of white fused alumina micro mists, 6 kilograms of short carbon fibers, 8 kilograms of high-carbon chromium irons and 0.5 kilogram of graphited oil successively pours into planetary material agitator, opens mixer, and stir speed (S.S.) is 300 rpms, is stirred Dispersion 8 minutes is mixed, period is by 20.8 kilograms of 1% Graphene modified epoxy, 0.3 kilogram of wetting dispersing agent and 0.4 kilogram Epoxy curing agent is stirred 10 minutes with liquid stirrers using 600 rpms, is stirred, and the resin that will be mixed is mixed Compound is added in planetary material agitator, and stir speed (S.S.) is 500 rpms, is mixed 15 minutes at room temperature, then broken In entering abrasive material mould under material machine particle, will material cloth be abound with it is flat after, being sent under vacuum suppressing room, vacuum carries out 8 points of vibration compacting Clock, 180 DEG C of curing conservations 2 hours, cooling and demolding is that can be used.
The quartz abrasive material of gained, contrast market Hengchang's stone material abrasive material conventional at present, the friction co-efficient value of abrasive material test block Reduce 52.7%;In production polishing contrast, grinding efficiency improves 48.8%, and abrasive material damages rate reduction 45%, and glossiness is averagely carried It is high 3 °.
Embodiment 3
First by 50 kilograms of sic powders, 10 kilograms of white fused alumina micro mists, 8 kilograms of short carbon fibers, 12 kilograms of high-carbon chromium irons Planetary material agitator is successively poured into 1.2 kilograms of graphited oils, mixer is opened, stir speed (S.S.) is 400 rpms, Dispersed with stirring 10 minutes, period is by 18.1 kilograms of 1% Graphene modified epoxy, 0.3 kilogram of wetting dispersing agent and 0.4 Kilogram epoxy curing agent is stirred 8 minutes with liquid stirrers using 600 rpms, is stirred, the tree that will be mixed Lipoprotein mixture is added in planetary material agitator, and stir speed (S.S.) is 400 rpms, is mixed 12 minutes at room temperature, and In entering abrasive material mould under Material disintegrator particle afterwards, will material cloth be abound with it is flat after, being sent under vacuum suppressing room, vacuum carries out vibration compacting 7 minutes, 120 DEG C of curing conservations 4 hours, cooling and demolding is that can be used.
The quartz abrasive material of gained, contrast market Hengchang's stone material abrasive material conventional at present, the friction co-efficient value of abrasive material test block Reduce 52.1%;In production polishing contrast, grinding efficiency improves 49.0%, and abrasive material damages rate reduction 45%, and glossiness is averagely carried It is high 3 °.

Claims (1)

1. a kind of artificial quartz stone plate polishing abrasive material, it is characterised in that with 1wt% Graphenes modified epoxy, carborundum Powder, white fused alumina micro mist, short carbon fiber, high-carbon chromium iron, graphited oil, curing agent and wetting dispersing agent are raw material, according to Mass ratio is 12 ~ 35:20~60:5~30:2~10:3~15:0.2~2:0.1~0.5:0.1 ~ 0.5 is prepared from;
Glycidyl ester epoxy resin, shrink of the 1wt% Graphenes modified epoxy for 1wt% Graphene toughening modifyings One or more in glycerine amine epoxy resin, cycloaliphatic epoxy resin;The particle diameter of the sic powder is 80 ~ 325 mesh; The particle diameter of the white fused alumina micro mist is 100 ~ 200 mesh;The length of the short carbon fiber is 2mm;The particle diameter of the high-carbon chromium iron It is 40 ~ 150 mesh;
The preparation method of the artificial quartz stone plate polishing abrasive material, comprises the following steps:
(1)1wt% Graphenes modified epoxy, wetting dispersing agent and curing agent are proportionally poured into liquid stirrers and stirred Mix, stir speed (S.S.) is 100 ~ 1000rpm, and mixing time is 3 ~ 20min, standby;
(2)Sic powder, white fused alumina micro mist, short carbon fiber, high-carbon chromium iron and graphited oil are proportionally poured into thing Material mixer is stirred, and stir speed (S.S.) is 100 ~ 500rpm, after 5 ~ 30min of stirring, pours into step(1)Products therefrom, again Stirring, stir speed (S.S.) is 100 ~ 800rpm, and mixing time is 5 ~ 20min;
(3)By step(2)Gained compound add double-roll type material-twisting machine in, two roller spacing of adjustment be 5 ~ 10mm, left roller 50 ~ 100rpm, right 100 ~ 200rpm of roller, compound is carried out to rub scattered dispersion;
(4)By step(3)Resulting material is poured into abrasive material mould, under vacuum after 3 ~ 10min of vibration compacting, 100 ~ 200 DEG C 1 ~ 5h of curing conservation, cooling and demolding obtains artificial quartz stone plate polishing abrasive material.
CN201510410985.XA 2015-07-14 2015-07-14 A kind of artificial quartz stone plate polishing abrasive material and preparation method thereof Active CN105086936B (en)

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CN108503362B (en) * 2018-05-25 2020-10-13 黑龙江省广盛达新材料科技有限公司 Preparation method of nano graphite-based grinding material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102363287A (en) * 2011-10-20 2012-02-29 宁波大华砂轮有限公司 Resin grinding wheel and manufacturing method thereof
CN103612216A (en) * 2013-12-04 2014-03-05 江苏锋芒复合材料科技集团有限公司 Manufacturing method for environment-friendly coated abrasive tool product
CN103921220A (en) * 2014-05-08 2014-07-16 武汉法山磨料磨具有限公司 Method for preparing resin grinding wheel containing epoxy resin

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070293130A1 (en) * 2006-02-01 2007-12-20 Sierra Madre Marketing Group Wearable Abrasive Surfaces for Dry Applications

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102363287A (en) * 2011-10-20 2012-02-29 宁波大华砂轮有限公司 Resin grinding wheel and manufacturing method thereof
CN103612216A (en) * 2013-12-04 2014-03-05 江苏锋芒复合材料科技集团有限公司 Manufacturing method for environment-friendly coated abrasive tool product
CN103921220A (en) * 2014-05-08 2014-07-16 武汉法山磨料磨具有限公司 Method for preparing resin grinding wheel containing epoxy resin

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