CN105086747A - Multi-color epoxy boat topping paint and preparing method thereof - Google Patents

Multi-color epoxy boat topping paint and preparing method thereof Download PDF

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Publication number
CN105086747A
CN105086747A CN201510472168.7A CN201510472168A CN105086747A CN 105086747 A CN105086747 A CN 105086747A CN 201510472168 A CN201510472168 A CN 201510472168A CN 105086747 A CN105086747 A CN 105086747A
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China
Prior art keywords
parts
paint
boat
epoxy
water
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Pending
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CN201510472168.7A
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Chinese (zh)
Inventor
施金龙
王和山
朱建林
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Anhui Qianqian Paints Co Ltd
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Anhui Qianqian Paints Co Ltd
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Priority to CN201510472168.7A priority Critical patent/CN105086747A/en
Publication of CN105086747A publication Critical patent/CN105086747A/en
Pending legal-status Critical Current

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Abstract

The invention provides multi-color epoxy boat topping paint and belongs to the technical field of chemical coating preparation. The paint comprises 50-60 parts of epoxy resin, 1-2 parts of organic soil, 18-23 parts of precipitated barium sulphate, 6-8 parts of dimethylbenzene, 1-2 parts of butanol, 1-2 parts of amino resin, 5-7 parts of chlorinated rubber latex, 2-4 parts of tributyl tin fluoride, 3-5 parts of zinc oxide, 4-6 parts of urea, 2-4 parts of modified asphalt, 2-4 parts of sodium silicate, 5-7 parts of methyl isobutyl ketone, 8-10 parts of pigments, 2-6 parts of anti-settling agents and 60-70 parts of deionized water. The multi-color epoxy boat topping paint has the beneficial effects that the technical process is simple, the ratio of raw materials is reasonable, the coating can prevent attachment and reproduction of marine microorganisms, the paint is not polluted by microorganisms, and a good effect can be achieved by using the multi-color epoxy boat topping paint and common boat topping paint at the same time. The chlorinated rubber boat topping paint has the identification function as the common boat topping paint and meanwhile has an antifouling function. The multi-color epoxy boat topping paint is wide in adaptability, environmentally friendly, free of toxin, efficient, high in market value and convenient to use and popularize.

Description

A kind of polychrome epoxy water-line paint and preparation method thereof
Technical field
The present invention relates to chemistry painting industry preparing technical field, be specifically related to a kind of polychrome epoxy water-line paint and preparation method thereof.
Background technology
Water-line paint is light for boats and ships, the coating at the m-i.e. waterline position of heavy-loaded line, usually general water-line paint and antifouling water-line paint two kinds is divided into, be in often by sea water immersion, wash away and the area, splash zone of alternation of wetting and drying state of solar exposure, this Special Corrosion environmental requirement coating must have good water-fast, weather-proof, humid-dry cycling resistance, there is good physical strength, rub resistance and shock-resistance simultaneously, bituminous epoxy rust-inhibiting paint generally used by priming paint, and finish paint has phenolic alkyd, chlorinated rubber, chlorinated rubber modified acroleic acid and epoxypaint.Generally also require that it has strikingly color, existing decoration also has mark effect, as purplish red and green, but the quality of current this kind of paint on the market does not also pass a test, these demands can not be met, major cause or the problem such as material choice is unreasonable, preparation method's shortcoming.
Summary of the invention:
Technical problem to be solved by this invention is to provide a kind of formula rationally, and production technique is simple, physical strength and protect good polychrome epoxy water-line paint of look performance and preparation method thereof.
Technical problem to be solved by this invention realizes by the following technical solutions:
A kind of polychrome epoxy water-line paint, is characterized in that: be made up of following raw material:
Epoxy resin 50-60 part, organophilic clay 1-2 part, process white 18-23 part, dimethylbenzene 6-8 part, butanols 1-2 part, aminoresin 1-2 part, chlorinated rubber liquid 5-7 part, tributyl tin fluoride 2-4 part, zinc oxide 3-5 part, urea 4-6 part, modifying asphalt 2-4 part, water glass 2-4 part, mibk 5-7 part, pigment 8-10 part, anti-settling agent 2-6 part, deionized water 60-70 part.
The preferred component of each raw material is: epoxy resin 55 parts, organophilic clay 1.5 parts, process white 20 parts, dimethylbenzene 6.6 parts, 1.5 parts, butanols, 1.8 parts, aminoresin, chlorinated rubber liquid 6 parts, tributyl tin fluoride 3 parts, 4 parts, zinc oxide, 5 parts, urea, modifying asphalt 3 parts, water glass 3 parts, mibk 6 parts, pigment 9 parts, anti-settling agent 4 parts, deionized water 65 parts.
Described anti-settling agent is polyethylene wax or hydrogenated castor oil.
Described organophilic clay adopts the silicon-dioxide of equivalent, aluminum oxide, ferric oxide, calcium oxide, manganese oxide, potassium oxide silicon-dioxide and caustic soda to mix.
Described pigment extracts by herbaceous plant, nontoxic.
Another object of the present invention is to provide a kind of method preparing polychrome epoxy water-line paint of the present invention, it is characterized in that comprising the following steps:
(1) Scattered Kettle is selected, above-mentioned epoxy resin, aminoresin and modifying asphalt are added wherein, then adds deionized water and chlorinated rubber liquid, at 20-50 DEG C, be uniformly mixed 20-25 minute, add tributyl tin fluoride, zinc oxide and water glass after stirring, be stirred to normal temperature;
(2) by organophilic clay, process white mixing, join in Scattered Kettle, be uniformly mixed 8-10 minute, add dimethylbenzene and butanols, 500-600 rev/min of dispersed with stirring 6-8 minute;
(3) urea in raw material, mibk, pigment and anti-settling agent are carried out pre-mixing, be then added into 1000-2000 rev/min of dispersed with stirring 20-30 minute in above-mentioned Scattered Kettle, obtain described water-line paint.
The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, coating of the present invention can prevent the attachment of marine microorganism, breeding, from microbial contamination, with general water-line paint and with obtaining good result, chlorinated rubber water-line paint of the present invention has had the general water-line paint of mark action, and also have antifouling effect, suitability is wide simultaneously, environment-protecting asepsis, efficient, marketable value is high, is convenient to promote and use.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
Take epoxy resin 50kg, organophilic clay 1kg, process white 18kg, dimethylbenzene 6kg, butanols 1kg, aminoresin 1kg, chlorinated rubber liquid 5kg, tributyl tin fluoride 2kg, zinc oxide 3kg, urea 4kg, modifying asphalt 2kg, water glass 2kg, mibk 5kg, pigment 8kg, anti-settling agent 2kg, deionized water 60kg.
Described anti-settling agent is polyethylene wax or hydrogenated castor oil.
Described organophilic clay adopts the silicon-dioxide of equivalent, aluminum oxide, ferric oxide, calcium oxide, manganese oxide, potassium oxide silicon-dioxide and caustic soda to mix.
Described pigment extracts by herbaceous plant, nontoxic.
Preparation method is as follows:
(1) Scattered Kettle is selected, above-mentioned epoxy resin, aminoresin and modifying asphalt are added wherein, then adds deionized water and chlorinated rubber liquid, at 20-50 DEG C, be uniformly mixed 20-25 minute, add tributyl tin fluoride, zinc oxide and water glass after stirring, be stirred to normal temperature;
(2) by organophilic clay, process white mixing, join in Scattered Kettle, be uniformly mixed 8-10 minute, add dimethylbenzene and butanols, 500-600 rev/min of dispersed with stirring 6-8 minute;
(3) urea in raw material, mibk, pigment and anti-settling agent are carried out pre-mixing, be then added into 1000-2000 rev/min of dispersed with stirring 20-30 minute in above-mentioned Scattered Kettle, obtain described water-line paint.
Embodiment 2
Take epoxy resin 55g, organophilic clay 1.5g, process white 20g, dimethylbenzene 6.6g, butanols 1.5g, aminoresin 1.8g, chlorinated rubber liquid 6g, tributyl tin fluoride 3g, zinc oxide 4g, urea 5g, modifying asphalt 3g, water glass 3g, mibk 6g, pigment 9g, anti-settling agent 4g, deionized water 65g.
Described anti-settling agent is polyethylene wax or hydrogenated castor oil.
Described organophilic clay adopts the silicon-dioxide of equivalent, aluminum oxide, ferric oxide, calcium oxide, manganese oxide, potassium oxide silicon-dioxide and caustic soda to mix.
Described pigment extracts by herbaceous plant, nontoxic.
Preparation method is as follows:
(1) Scattered Kettle is selected, above-mentioned epoxy resin, aminoresin and modifying asphalt are added wherein, then adds deionized water and chlorinated rubber liquid, at 20-50 DEG C, be uniformly mixed 20-25 minute, add tributyl tin fluoride, zinc oxide and water glass after stirring, be stirred to normal temperature;
(2) by organophilic clay, process white mixing, join in Scattered Kettle, be uniformly mixed 8-10 minute, add dimethylbenzene and butanols, 500-600 rev/min of dispersed with stirring 6-8 minute;
(3) urea in raw material, mibk, pigment and anti-settling agent are carried out pre-mixing, be then added into 1000-2000 rev/min of dispersed with stirring 20-30 minute in above-mentioned Scattered Kettle, obtain described water-line paint.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (6)

1. a polychrome epoxy water-line paint, is characterized in that: be made up of following raw material:
Epoxy resin 50-60 part, organophilic clay 1-2 part, process white 18-23 part, dimethylbenzene 6-8 part, butanols 1-2 part, aminoresin 1-2 part, chlorinated rubber liquid 5-7 part, tributyl tin fluoride 2-4 part, zinc oxide 3-5 part, urea 4-6 part, modifying asphalt 2-4 part, water glass 2-4 part, mibk 5-7 part, pigment 8-10 part, anti-settling agent 2-6 part, deionized water 60-70 part.
2. a kind of polychrome epoxy water-line paint according to claim 1, it is characterized in that, the preferred component of each raw material is: epoxy resin 55 parts, organophilic clay 1.5 parts, process white 20 parts, dimethylbenzene 6.6 parts, 1.5 parts, butanols, 1.8 parts, aminoresin, chlorinated rubber liquid 6 parts, tributyl tin fluoride 3 parts, 4 parts, zinc oxide, 5 parts, urea, modifying asphalt 3 parts, water glass 3 parts, mibk 6 parts, pigment 9 parts, anti-settling agent 4 parts, deionized water 65 parts.
3. a kind of polychrome epoxy water-line paint according to claim 1, is characterized in that: described anti-settling agent is polyethylene wax or hydrogenated castor oil.
4. a kind of polychrome epoxy water-line paint according to claim 1, is characterized in that: described organophilic clay adopts the silicon-dioxide of equivalent, aluminum oxide, ferric oxide, calcium oxide, manganese oxide, potassium oxide silicon-dioxide and caustic soda to mix.
5. a kind of polychrome epoxy water-line paint according to claim 1, is characterized in that: described pigment extracts by herbaceous plant.
6. prepare the method for a kind of polychrome epoxy water-line paint in claim 1 or 2, it is characterized in that, comprise the following steps:
Extracting epoxy resin liquid puts into dispersion tank, logical to grey cloud iron, boron, ethanol, butanols, dimethylbenzene is slowly added in dispersion tank successively and is disperseed, then auxiliary agent, aluminum paste, solvent is added, and stir.
CN201510472168.7A 2015-08-05 2015-08-05 Multi-color epoxy boat topping paint and preparing method thereof Pending CN105086747A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147554A (en) * 2016-07-12 2016-11-23 天长市银狐漆业有限公司 A kind of corrosion-resistant seagoing vessel waterline paint
US11168287B2 (en) 2016-05-26 2021-11-09 Kimberly-Clark Worldwide, Inc. Anti-adherent compositions and methods of inhibiting the adherence of microbes to a surface

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013307A (en) * 2012-11-29 2013-04-03 益阳祥瑞科技有限公司 Antifouling topping paint for boat
CN103342925A (en) * 2013-06-27 2013-10-09 天长市巨龙车船涂料有限公司 Chlorinated rubber topping paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013307A (en) * 2012-11-29 2013-04-03 益阳祥瑞科技有限公司 Antifouling topping paint for boat
CN103342925A (en) * 2013-06-27 2013-10-09 天长市巨龙车船涂料有限公司 Chlorinated rubber topping paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11168287B2 (en) 2016-05-26 2021-11-09 Kimberly-Clark Worldwide, Inc. Anti-adherent compositions and methods of inhibiting the adherence of microbes to a surface
CN106147554A (en) * 2016-07-12 2016-11-23 天长市银狐漆业有限公司 A kind of corrosion-resistant seagoing vessel waterline paint

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Application publication date: 20151125

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